The graphite anode electrode in commercial lithium ion batteries has several disadvantages such as its electrical disconnection, structural deformation, and initial loss of capacity [1 3]. Especially, TiO2 is regarded as a promising active lithium intercalation material with low production cost and high capacity, low-voltage (below ca. 2.0 V vs. Li/Li) for lithium intercalation. More recently, much attention has been paid to fabricate TiO2-based hybrid nanostructures as anode materials with enhanced lithium storage performance. One of the strategy is to introduce a bu ering matrix that can prevent the breaking down of TiO2-based hybrid nanostructures during cycling. Since the landmark paper by Iijima [4], carbon nanotubes (CNTs) have attracted considerable research interest due to their unique combination of mechanical, electrical and thermal properties. Forms of CNTs in the macroscopic level, such as forests, yarns and lms have been reported providing a practical venue to utilize and manipulate the remarkable properties of CNTs for broad applications [5, 6]. Paper-like CNT lms, also called buckypapers, are self-supporting networks of entangled CNT assemblies arranged in a random fashion and held together by van der Waals interactions at the tube tube junctions. In this study, CNTs-TiO2 nanocomposite structures are studied, which integrates both electronic conductivity and bu ering matrix design strategies. The CNTs-TiO2 nanostructured electrodes have been prepared and applied as anode materials for lithium-ion batteries, which exhibit higher lithium storage capacities and better cycling performance compared to single CNTs and TiO2 electrodes.