IUPAC-NIST Solubility Data Series Research Articles

IUPAC-NIST Solubility Data Series. 88. Esters with Water—Revised and Updated. Part 3. C7 to C9 Esters

The mutual solubilities and related liquid-liquid equilibria of 60 binary systems of C7 to C9 esters with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2007 are compiled. For 26 systems, sufficient data are available to allow critical evaluation. All data are expressed as mass fraction and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of esters was used.

Editorial: IUPAC-NIST Solubility Data Series

First Page

The IUPAC-NIST Solubility Data Series: A guide to preparation and use of compilations and evaluations (IUPAC Technical Report)

The IUPAC-NIST Solubility Data Series (SDS) is an ongoing project that provides comprehensive reviews of published data for solubilities of gases, liquids, and solids in liquids or solids. Data are compiled in a uniform format, evaluated, and, where data from independent sources agree sufficiently, recommended values are proposed. This paper is a guide to the SDS and is intended for the benefit of both those who use the SDS as a source of critically evaluated solubility data and who prepare compilations and evaluations for future volumes. A major portion of this paper presents terminology and nomenclature currently recommended by IUPAC and other international bodies and relates these to obsolete forms that appear in the older solubility literature. In addition, this paper presents a detailed guide to the criteria and procedures used in data compilation, evaluation, and presentation and considers special features of solubility in gas + liquid, liquid + liquid, and solid + liquid systems. In the past, much of this information was included in introductory sections of individual volumes of the SDS. However, to eliminate repetitive publication, this information has been collected, updated, and expanded for separate publication here.

IUPAC-NIST Solubility Data Series. 88. Esters with Water—Revised and Updated. Part 2. C5 and C6 Esters

The mutual solubilities and related liquid-liquid equilibria of 33 binary systems of C5 and C6 esters with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2007 are compiled. For 19 systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of esters was used.

The IUPAC-NIST Solubility Data Series: A Guide to Preparation and Use of Compilations and Evaluations (IUPAC Technical Report)

The IUPAC-NIST Solubility Data Series: A Guide to Preparation and Use of Compilations and Evaluations (IUPAC Technical Report)

IUPAC-NIST Solubility Data Series. 88. Esters with Water—Revised and Updated. Part 1. C2 to C4 Esters

The mutual solubilities and related liquid-liquid equilibria of 19 binary systems of C2 to C4 esters with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2007 are compiled. For ten systems, sufficient data are available to allow critical evaluation. All data are expressed as mass fraction and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of esters was used.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 6. C7–C12 Ketones with Water

The mutual solubilities and related liquid-liquid equilibria of 25 binary systems of C7–C12 ketones with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to July 2007 are compiled. For 12 systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of ketones was used. This completes a six-part series of papers which compile and evaluate mutual solubility data of ethers and ketones with water.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 5. C6 Ketones with Water

The mutual solubilities and related liquid-liquid equilibria of eight binary systems of C6 ketones with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the middle of 2007 are compiled. For five systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of ketones was used.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 4. C4 and C5 Ketones with Water

The mutual solubilities and related liquid-liquid equilibria of six binary systems of C4 and C5 ketones with water are exhaustively and critically reviewed. Acetone, the only C3 ketone, is soluble with water in all proportions; C6 and higher ketones will be treated in subsequent parts of this volume. Reports of experimental determination of solubility that appeared in the primary literature prior to the middle of 2007 are compiled. For all six systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of ketones was used.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 3. C7–C14 Ethers with Water

The mutual solubilities and related liquid-liquid equilibria of nine binary systems of C7–C14 ethers with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2006 are compiled. For three systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of ethers was used.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 2. C6 Ethers with Water

The mutual solubilities and related liquid-liquid equilibria of C6 ethers with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in binary systems that appeared in the primary literature prior to the end of 2006 are compiled. For four of the seven systems treated, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of ethers was used.

IUPAC-NIST Solubility Data Series. 86. Ethers and Ketones with Water. Part 1. C2–C5 Ethers with Water

The mutual solubilities and related liquid-liquid equilibria of C2–C5 ethers with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in ten chemically distinct binary systems that appeared in the primary literature prior to the end of 2006 are compiled. For three systems, sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a recently developed method based on the evaluation of all experimental data for a given series of ethers was used.

IUPAC-NIST Solubility Data Series. 85. Transition and 12–14 Main Group Metals, Lanthanide, Actinide, and Ammonium Halates

This paper is the fourth and final volume in the halate solubility series. The solubility data for halates of transition metals, lanthanides, actinides, ammonium, and metallic elements of the main groups 12–14 are reviewed. Where appropriate, binary, ternary, and multicomponent systems are critically evaluated. Most of the solubility results were obtained in water or aqueous solutions of electrolytes. The solubility in organic solvents and aqueous-organic solvent mixtures is also collected in this volume. All these data were critically examined for their reliability. The best values were selected on the basis of critical evaluations and presented in tabular form. Fitting equations and graphical plots are also provided. When numerical data were not reported in an original publication, they were read out from figures and digitized by the compilers. The quantities, units, and symbols used in this volume are in accord with IUPAC recommendations. We always reported the original data and, if necessary, transferred them into the IUPAC recommended units and symbols. The literature on the solubility data was researched through 2002. The halates of these metals play a role in industrial processes. For example, some halates are essential as catalysts, heat stabilizers, and blanching reagents for manufacturing polymer products such as textiles and resins. Some iodates are used in pyrotechnic compounds for weather modification and colored smoke generation. The nonlinear halate crystals are important in construction of optical devices.

IUPAC-NIST Solubility Data Series. 82. Alcohols with Water–Revised and Updated: Part 5. C8–C17 Alcohols with Water

The mutual solubilities and related liquid–liquid equilibria of C8–C17 alcohols with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 21 chemically distinct binary systems that appeared in the primary literature prior to the end of 2004 are compiled. For 12 systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of the all experimental data for a given homologous series of saturated alcohols was used.

IUPAC-NIST Solubility Data Series. 82. Alcohols with Water—Revised and Updated: Part 4. C7 Alcohols with Water

The mutual solubility and related liquid-liquid equilibria of C7 alcohols with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 20 chemically distinct binary systems that appeared in the primary literature prior to end of 2004 are compiled. For 14 systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of the all experimental data for a given homologous series of saturated alcohols was used.

IUPAC-NIST Solubility Data Series. 82. Alcohols with Water—Revised and Updated: Part 3. C6 Alcohols with Water

The solubility and related liquid–liquid equilibria in systems C6 alcohols+water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 13 chemically distinct binary systems that appeared in the primary literature prior to end of 2004 are compiled. 12 systems are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of the all experimental data for a given homologous series of saturated alcohols was used.

IUPAC-NIST Solubility Data Series. 82. Alcohols with Water—Revised and Updated: Part 1. C4 Alcohols with Water

The mutual solubility and related liquid–liquid equilibria of C4 alcohols with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in three chemically distinct binary systems that appeared in the primary literature prior to end of 2004 are compiled. For all the systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of all experimental data for a given homologous series of saturated alcohols was used.

IUPAC-NIST Solubility Data Series. 82: Alcohols with Water—Revised and Updated: Part 2. C5 Alcohols with Water

The mutual solubility and related liquid–liquid equilibria of C5 alcohols with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in ten chemically distinct binary systems for which data appeared in the primary literature prior to the end of 2004 are compiled. For eight systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the simultaneous evaluation of the all experimental data, which includes liquid–liquid equilibrium correlation and prediction.

IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater—Revised and Updated Part 12. C5–C26 Hydrocarbons with Seawater

The mutual solubility of C5–C26 hydrocarbons with seawater is exhaustively and critically reviewed. Reports of experimental determination of solubility in 46 chemically distinct binary systems that appeared in the primary literature prior to end of 2002 are compiled. For 15 of these systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units.

IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater—Revised and Updated. Part 11. C13–C36 Hydrocarbons with Water

The mutual solubilities and related liquid–liquid equilibria of C13–C36 hydrocarbons with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 56 chemically distinct binary systems that appeared in the primary literature prior to end of 2002 are compiled. For 17 systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of all the experimental data for a given homologous series of aliphatic and aromatic hydrocarbons was used.