MITICA (Megavolt ITER Injector & Concept Advancement), the full scale prototype of ITER Heating Neutral Beam, is under realization at the Neutral Beam Test Facility (Padova, Italy). It is designed to deliver 16.5 MW to ITER plasma, obtained by accelerating negative Deuterium ions up to 1 MeV for a total ion current of 40 A and then neutralized.MITICA Acceleration Power Supply is composed of several non-standard equipment, beyond industrial standard for insulation voltage level (-1 MVdc) and dimensions.Voltage withstand tests (up to 1.265 MVdc) have been performed in five subsequent steps (from 2018 to 2019), according to the installation progress, after connecting equipment belonging to different procurements.During integrated commissioning, started in 2021, two breakdowns occurred in a position of the HV plant not still identified, so they could be occurred either in air or in SF6. To identify the locations of possible weak insulation points, the existing diagnostics for partial discharge detection (the precursor of breakdowns) as a first step have been improved on air-insulated parts by consisting in a set of instrumentation, like capacitive probes and off-the-shelf instruments for AC application (acoustic and electromagnetic sensors).The paper deals with the instruments qualification to assess their suitability for DC usage and then with the investigation performed in MITICA, in particular:1) sensitivity assessment campaign, with artificially produced corona effect to identify the minimum threshold of each diagnostics2) voltage application to MITICA plant, moving the instrumentation around equipment and increasing progressively the voltage looking for corona phenomena to identify possible weak insulation points.