Photoexcitation of chlorine {ital DX} centers induces a transition of the Cl atoms to the shallow-donor state and persistent photoconductivity at low temperature in Cd{sub 0.8 }Zn{sub 0.2}Te:Cl. The relaxation of the substitutional Cl atoms to the {ital DX} state at 140K is coincident with a decrease of the positron line-shape parameter and an increase of annihilation with high-momentum core electrons. The results indicate positron trapping and annihilation at {ital DX} centers and at chlorine {ital A} centers. The data support the bond breaking model of the {ital DX} centers and the outward relaxation of the Cl and Cd(Zn) atoms along the [111] direction. The thermal barrier for the shallow-deep transition was found to be 0.44eV. {copyright} {ital 1997} {ital The American Physical Society}
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