Isotropic Pressure Research Articles

Investigation on hyperbolic Ricci soliton in a perfect fluid spacetime

The aim of this paper is to inspect the geometrical aspects of a perfect fluid spacetime conveying hyperbolic Ricci soliton with torse-forming vector field [Formula: see text]. Next, we have investigated some physical perceptions of perfect fluid spacetime such as dark fluid spacetime, stiff matter fluid spacetime, dust fluid spacetime and radiation fluid spacetime with hyperbolic Ricci soliton in terms of isotropic pressure, the cosmological constant, energy density and gravitational constant. We have also provided two examples of hyperbolic Ricci soliton and hyperbolic Ricci–Bourguignon soliton. Later, we explore the relativistic magneto-fluid spacetime obeying hyperbolic Ricci soliton along with different vector fields.

Semiconductor-metal transition in TlPbF3 under isotropic pressure and its impact on optical, elastic and mechanical properties: a DFT computation with HSE06

This research aims to comprehensively evaluate the structure, elasticity, mechanics, anisotropy, electrical properties, and optical attributes of TlPbF3 at pressures from 0 to 60 GPa. A cubic structure of the material remains same without any phase changes, but there is a reduction in the lattice parameters. The material is determined to be mechanically secure by doing calculations on a variety of mechanical and elastic characteristics, including bulk, shear, and Young’s modulus, stiff, and not particularly flexible. It also shows a significant resistance to shear force. The material’s ability to withstand high pressures, its metallic bond nature, and ductility have been shown by the Kleinman’s parameter, Poisson’s ratio, Cauchy pressure, and Pugh ratio. Anisotropy can be confirmed by activating specific anisotropy factors. When we consider the electronic band structure, we observe a transition from a broad gap in the band (3.719 eV) comparable with a small band distance (0.65 eV), and converts to a metal (0 eV). To explore this, we have estimated the total, partial and elemental partial density of states. Additionally, we have computed the real and imaginary functions of dielectric, absorption factor, refractive index, extinction coefficient, loss function, reflectivity and real/imaginary conductivity to assess the material’s applicability. As pressure is applied, the static values of ε1(ω) and n(ω) increase. This material is also well-suited for optoelectronic devices due to its high conductivity, reflectivity, absorption, and refractive index.

Casimir wormholes with GUP correction in the Loop Quantum Cosmology

In this paper, we obtain novel traversable, static, and spherically symmetric wormhole solutions, derived from the effective energy density and isotropic pressure resulting from the Casimir effect, corrected by the Generalized Uncertainty Principle (GUP) within the framework of Loop Quantum Cosmology (LQC). The goal is to explore the interplay between competing quantum gravity effects and quantum vacuum phenomena in the emergence of non-trivial spacetime structures. We examine features such as traversability, embedding diagrams, energy conditions, curvature, and stability of the obtained solutions. Additionally, we analyze the junction conditions required to integrate the wormhole spacetime with an external Schwarzschild spacetime and calculate the amount of exotic matter needed to maintain the wormhole. Finally, we evaluate the conditions under which this latter remains visible or is hidden by the event horizon associated with the Schwarzschild spacetime.

Smart composite based on fly ash cenospheres and transformer oil with switchable electrical conductivity

Fly ash cenospheres serve as an inexpensive filler for various composites. Coating their surface with metal significantly alters the properties of the resulting composites. In this study, aluminosilicate cenospheres receive a copper coating using a plasma method with magnetron sputtering. Based on these copper-coated cenospheres, composites are created, and their dielectric properties are investigated in a parallel plate capacitor cell under isotropic pressures ranging from 1 to 75 atm. Composites based on pure fly ash cenospheres exhibit pressure-invariant properties, including the dielectric constant and loss factor. However, for composites based on copper-coated fly ash cenospheres, an abrupt increase in electrical conductivity is observed as the pressure increases. Interestingly, significant changes in electrodynamics characteristics are not detected under the influence of anisotropic stress. The methodology tested in this work can be utilized for creating smart materials based on cenospheres.

Late Jurassic High-Pressure Metamorphism of Variscan I-Type Granitoids in the Northern Part of the Pelagonian Unit (Republic of North Macedonia)

Abstract The high P/T metamorphic Pelagonian Unit in the Republic of North Macedonia comprises (1) a Variscan basement consisting of gneisses, schists and minor meta-mafic rocks, which are all intruded by I-type granitoids and rare related dikes; (2) a metamorphosed sedimentary sequence of Permian to Lower Triassic age, and (3) a sequence of calcite and dolomite marbles resulting from Late Triassic to Middle Jurassic carbonate sediments. All these rocks underwent a common high-P/T metamorphism of Late Jurassic age. This paper deals with the metamorphism of the Variscan I-type granitoids which contained the igneous mineral assemblage plagioclase I + alkali feldspar I + quartz I + biotite I + titanite I + allanite I + zircon I + apatite I ± magnetite I. During Late Jurassic high-P/T metamorphism, these undeformed granitoids were thoroughly metamorphosed under isotropic pressure conditions as documented by undeformed granitic textures that are overgrown by metamorphic minerals such as garnet II, epidote II, and phengite II. Various, eventually metasomatic mineral reactions took place in different textural positions: (1) Former igneous plagioclase grains became completely transformed to Na-rich plagioclase IIa (An09–14) containing numerous small grains of epidote IIa and phengite IIa. Either this transformation was an allochemical one and was accompanied by the syn-metamorphic introduction of an aqueous fluid phase containing Fe, Mg and K or, alternatively, the more Ca-rich parts of plagioclase I became considerably sericitized before high-P/T metamorphism, and the resulting mixture of more Na-rich relic plagioclase with its sericite-rich domains became later metamorphosed under high-P/T conditions. In the first case, an aqueous phase is needed during metamorphism, while in the second case high-P/T metamorphism might have proceeded under H2O-undersaturated conditions; (2) igneous alkali feldspar I was changed to albite-poor orthoclase II or microcline II; (3) igneous Ti-rich biotite I reacted with plagioclase to metamorphic garnet II + Ti-poorer biotite II + titanite II + phengite II + quartz II ± epidote II ± rutile II, which is rimmed by Ttn II. At textural positions, where igneous plagioclase I was not available, igneous biotite I was transformed to Ti-poorer biotite II + titanite II ± ilmenite-hematite II; (4) during uplift, high-P/T metamorphic rutile II became marginally overgrown by titanite II ± ilmenite II; (5) igneous allanite I grains stayed unaltered, but when located near to former plagiocase I, they became partially rimmed by metamorphic epidote II. Equilibrium phase diagram calculations showed that the observed metamorphic paragenesis (plagioclase II + K-rich feldspar II + biotite II + garnet II + epidote II + phengite II + garnet II + quartz II + rutile II + titanite II) is only stable under H2O-unsaturated conditions. The I-type granitoids and their metamorphic country rocks were metamorphosed under high-P/T conditions of 1.3 to 1.5 GPa and 560 to 590 °C.

The role of dimensions in gravitating relativistic shear-free fluids

We study the dynamics of relativistic shear-free gravitating fluids in higher dimensions for both neutral and charged matter. We reduce the Einstein–Maxwell equations to a single second order nonlinear partial differential equation which contains two arbitrary functions. This generalizes the condition of pressure isotropy to higher dimensions; the new condition is functionally different from four dimensions. Our result in higher dimensions reduces to known results in four dimensions. The presence of higher dimensions affects the dynamics of relativistic fluids in general relativity. The dynamical behaviour of the gravitating fluid in higher dimensions is qualitatively different to the four dimensional case. Higher dimensions affect astrophysical and cosmological processes in gravitating shear-free fluids.

Bond Lengths and Dipole Moments of Diatomic Molecules under Isotropic Pressure with the XP-PCM and GOSTSHYP Models.

While high-pressure chemistry has a well-established history, methods to simulate pressure at the single-molecule level have been somewhat lacking. The current work aims at comparing two static models (XP-PCM and GOSTSHYP) to apply isotropic pressure to single molecules, focusing on the equilibrium bond length and electric dipole moment of diatomic molecules. Numerical challenges arising in the potential energy surface using the XP-PCM method were examined, and a pragmatic approach was followed to mitigate these. The definition of the cavity was scrutinized, and two approaches to retrieve the isotropic character that could potentially be lost when using the standard methodology were suggested. Subsequently, equilibrium bond lengths under pressure were evaluated, showing reasonable agreement between GOSTSHYP and XP-PCM, but some discrepancies persist. A Taylor series analysis introduced elsewhere was then applied to rationalize the observed trends in terms of the bond surface. Finally, the dipole moment was shown to be highly sensitive to the cavity definition, and qualitative agreement necessitates the use of our adapted procedure.

Study of structural, electronic, optical and mechanical properties of PbZrO3 under stress: a DFT approach

The structural, electronic, optical and mechanical characteristics of PbZrO3 (PZO) at external pressure ranging from 0–550 GPa have been analysed via density functional theory via generalised gradient approximation (GGA) and Perdew–Burke–Ernzerhof (PBE) exchange-correlation functional by applying external pressure up to 0–550 GPa. Band gap of electronic structure gradually decreased (2.434–0.181 eV) as pressure increased, and structure remains cubic at all pressures (0–550 GPa). The ultra-soft pseudopotential technique was applied to analyse the structure of band and its effects at the optical features of PZO in cubic phase. Several mechanical and elastic parameters have been calculated and the results indicate that the material is stiff, inflexible and resistant to shear stress. To confirm that a substance is anisotropic, various anisotropy factors are calculated. Optical properties such as absorption, loss function (L), refractive index (n), reflectivity (R) and the extinction coefficient (k) was computed to determine the impact of external isotropic pressure. PZO is extensively used in optoelectronic devices, it is now possible to employ it in a wide range of electromechanical systems, including infrared detectors, optoelectrical modulators circuits, storage device for memories and capacitors for use in microwave devices with high frequencies.

Nb-based copper sulvanites for potential green energy harvesting under induced isotropic pressure

This work explores the mechanical, electronic, dynamical stability, optical, and thermoelectric properties of Nb-based copper sulvanite compounds Cu3NbX4 (X=S, Se, Te) at 0, 5, 10, 15, and 20 GPa isotropic pressure within the framework of density functional theory (DFT). Calculated results are found in good agreement with experimental data, specifically in the values of their lattice parameters and optical band gaps. Cu3NbX4 exhibits promising optical properties for photovoltaic applications with enhanced properties under pressure. Exploration on transport properties also shows moderate thermoelectric figure of merit with slight improvement under pressure.

New Numerical Technique for the Inbuilt Modified Cam Clay Constitutive Model in FLAC3D

Fast Lagrangian Analysis of Continua (FLAC) is a powerful numerical platform for simulating the deformation and stability of geotechnical structures. Presently, it is documented that the embedded Modified Cam Clay constitutive model in the FLAC platform is deficient in solving geotechnical problems. This paper outlines the new calibration approach by determining the isotropic preconsolidation pressure multiplier based on the relationship between the total stress in the geotechnical problem and the reference pressure. The multiplier was used to establish the nominated maximum isotopic preconsolidation pressure and maximum referential consolidation ratio at the bottom of the soil layer. Subsequently, the maximum isotopic preconsolidation pressure was used to determine the bulk maximum. In addition, the developed approach was used to investigate the lateral displacement of the large grid wall foundation by deep mixing under the adjacent surcharge loading. The feasibility was validated using the centrifuge results. The coefficient of determination between lateral displacement from numerical and centrifuge modelling R2 was 0.95. The proposed numerical technique and calibration approach demonstrated that the embedded Modified Cam Clay model can be used to solve practical geotechnical problems.

On pseudo-𝒦-symmetric semi-Riemannian manifolds and relativistic applications

In this paper, we present a novel curvature tensor called the [Formula: see text]-curvature tensor, which is formed by combining the Weyl tensor and the [Formula: see text]-curvature tensor. It is proved that a semi-Riemannian manifold with traceless [Formula: see text]-curvature tensor is Einstein, while a [Formula: see text]-curvature flat semi-Riemannian manifold exhibits constant sectional curvature. We show that a space-time with traceless [Formula: see text]-curvature tensor or [Formula: see text]-curvature flat represents dark energy era. A semi-Riemannian manifold with divergence-free [Formula: see text]-curvature tensor is Weyl harmonic. In a space-time where the [Formula: see text]-curvature tensor is of divergence-free, both the isotropic pressure and energy density are constants. Under certain conditions, it is shown that a pseudo-[Formula: see text]-symmetric semi-Riemannian manifold reduces to a pseudo-Riemannian manifold. It is demonstrated that pseudo-[Formula: see text]-symmetric space-times can be regarded as generalized Robertson–Walker (GRW) space-times. Finally, a concrete example of pseudo-[Formula: see text]-symmetric semi-Riemannian manifolds is presented.

Multicaloric Cryocooling Using Heavy Rare-Earth Free La(Fe,Si)13-Based Compounds.

The transition toward a carbon-neutral society based on renewable energies goes hand in hand with the availability of energy-efficient technologies. Magnetocaloric cooling is a very promising refrigeration technology to fulfill this role regarding cryogenic gas liquefaction. However, the current reliance on highly resource critical, heavy rare-earth-based compounds as magnetocaloric material makes global usage unsustainable. Here, we aim to mitigate this limitation through the utilization of a multicaloric cooling concept, which uses the external stimuli of isotropic pressure and magnetic field to tailor and induce magnetostructural phase transitions associated with large caloric effects. In this study, La0.7Ce0.3Fe11.6Si1.4 is used as a nontoxic, low-cost, low-criticality multiferroic material to explore the potential, challenges, and peculiarities of multicaloric cryocooling, achieving maximum isothermal entropy changes up to -28 J (kg K)-1 in the temperature range from 190 K down to 30 K. Thus, the multicaloric cooling approach offers an additional degree of freedom to tailor the phase transition properties and may lead to energy-efficient and environmentally friendly gas liquefaction based on designed-for-purpose, noncritical multiferroic materials.

Moment of inertia and compactness of quark stars within the context of f(R, T, L m ) gravity

Within the metric formalism of f(R, T, L m ) gravity theories, we investigate the hydrostatic equilibrium structure of compact stars taking into account both isotropic and anisotropic pressure. For this purpose, we focus on the f(R, T, L m ) = R + α TL m model, where α is a free parameter. We derive the modified TOV equations and the relativistic moment of inertia in the slowly rotating approximation. Using an equation of state (EoS) for color-superconducting quark stars, we examine the effects of the α TL m term on the different macroscopic properties of these stars. Our results reveal that the decrease of the parameter α leads to a noticeable increase in the maximum-mass values. For negative α with sufficiently small ∣α∣, we obtain a qualitative behavior similar to the general relativistic (GR) context, namely, it is possible to obtain a critical stellar configuration such that the mass reaches its maximum. However, for sufficiently large values of ∣α∣ keeping negative α, the critical point cannot be found on the mass-radius diagram. We also find that the inclusion of anisotropic pressure can provide masses and radii quite consistent with the current observational measurements, which opens an outstanding window onto the physics of anisotropic quark stars. By comparing the I − C relations of isotropic quark stars in modified gravity, we show that such a correlation remains almost unchanged as the parameter α varies from GR counterpart. On the other hand, given a fixed α, the I − C relation is insensitive to variations of the anisotropy parameter β to O(4%) .

Anisotropic stellar evolution and exotic matter

In this paper, we discuss the stability of isotropic pressure conditions for a spherically symmetric dissipative fluid distribution in the framework of f(G,T) gravity. We consider the fluid to be composed of seen and exotic matter particles. The Gauss Bonnet terms represent exotic matter particles. For the physical significance of the pressure isotropy conditions, we transform the system into the hydrostatic equilibrium approximation. We observe the presence of shear, dissipative fluxes, energy density inhomogeneities, and prominently, the exotic matter tends to abandon isotropy leading to pressure anisotropy. It is found that exotic matter and dissipation are major factors that induce matter anisotropy in the evolving stellar system. In order to discuss the physical significance of the stellar model in f(G,T) gravity, the behaviour of stellar structure is explored according to the observational data of a compact star 4U1820 − 30. It is found that f(G,T) terms indicating the exotic material in the stellar model plays a vital role in governing the dynamics of the evolution. To strengthen the results, we also incorporate some arguments by choosing an axially symmetric case.

Structural phase transition of G-type antiferromagnetic SrMnO3 under pressure

Perovskite SrMnO3 is a versatile material with applications in transistors, supercapacitors, and spintronic devices. This study employs the DFT+U calculations to investigate the electronic and magnetic properties of two polymorphs: 4H-SrMnO3 and 3C-SrMnO3 under isotropic pressure conditions up to 60 GPa. A novel approach based on density functional perturbation theory (DFPT) is employed to precisely determine the on-site Hubbard U value, yielding a computed value of 4.552 eV, consistent with experimental reports. Below P = 14 GPa, the G-AFM phase of 4H-SrMnO3 is the most favored stable, and transitioning to the G-AFM phase of 3C-SrMnO3 beyond 14 GPa. Notably, we observed significant changes in the band gaps, exhibiting an increasing trend under isotropic pressure, while the magnetic moments of the Mn sites exhibit a decreasing trend from ≈2.8 μ B to ≈2.3 μ B for P = 0 GPa and 60 GPa, respectively. The projected density of states (PDOS) reveals the p-d hybridization contributions between the 3d-Mn and 2p-O covalent bonds, along with d-d Mott Hubbard interactions within the localized 3d orbitals of neighboring Mn-Mn atoms. Furthermore, a decrease in the Mn1-O-Mn2 distance prompts enhanced charge transfer which was facilitated by ligand holes, leading to a noticeable decrease in the magnetic moment of the Mn site in the G-AFM phase of SrMnO3.

Pressure and thermal effects on Rayleigh fiber-optic strain measurment for soil-structure interaction

Optical strain sensing in civil engineering has been adopted for both field applications and advanced laboratory testing of structural health monitoring. Rayleigh backscatter devices (ROFDR) are presented for use with geotechnical centrifuge research since they offer distributed sensing capabilities, and through this study have been shown to have negligible interference from pressure effects, and can be made with low-cost disposable sensors. A comparison between a single channel and multi-channel fiber optic rotary joint (FORJ) is presented in the context of transmitting optical strain data across a rotating interface. The orthogonal pressure effects (eg. From soil) of a free-floating fiber under isotropic pressure was less than 0.32 με / kPa and that the pressure effect on a fiber bonded to a metal surface was below the detection limit of the instrument, 1 με, for an applied pressure of 60 kPa. The ROFDR system showed highly repeatable measurement of a constant temperature reading through the use of a water bath experiment. The system is stable to +/- 10 microstrain within 2-sigma for a >12 hr constant temperature test. An example case of a pipeline buried in a slope experiencing a landslide is presented where the optical strain sensing is used to capture strain pairs along the crownline and pipe invert to capture bending moment of the pipeline. Geotechnical centrifuge modelling in a 1 metre drum was carried out using a multi-channel FORJ coupled with an ROFDR system.

Optical and Electrical Properties of SiO2 under Uniaxial, Biaxial, and Isotropic Pressure: a First Principles Study

Optical and Electrical Properties of SiO2 under Uniaxial, Biaxial, and Isotropic Pressure: a First Principles Study

Ultrasensitive Piezochromic Molecular Crystals: Mechanical Pressure‐Induced Controlled Regulation of TADF and RTP

AbstractConsidering that regulation of thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP) is necessary for a fluorophore to survive and properly show its characteristic features, it is successfully shown herein that a carefully designed novel pyrene derivative can exhibit remarkable aggregation‐induced emission (AIE) overcoming the characteristic fast excitonic decay of pyrene compounds. Moreover, it is established that J‐aggregation in the red‐emitting molecular crystals of the compound reduces the singlet‐triplet energy gap (∆EST), allowing TADF with a very high photoluminescence quantum yield (PLQY) of 72%. Whereas, anisotropic grinding of the same crystals generates well‐defined microcrystals that show RTP as the nature of aggregation changes. Impressively, under isotropic hydrostatic pressure, the crystals show near‐infra‐red (NIR) emission with a very high piezochromic luminescence sensitivity of 46.2 nm GPa−1. The results have established that formation of stable H‐aggregates in the microcrystals is responsible for the ultra‐long RTP. A highly sophisticated full‐spectrum Mueller‐matrix analysis is used for the first time in such systems to demonstrate the details of the effect of perturbation (pressure) on molecular conformation.

Energy-Based Assessment of Liquefaction Behavior of a Non-Plastic Silt Based on Cyclic Triaxial Tests

Earthquakes cause cyclic shear deformations in soil and build-up of excessive pore water pressure as a result of undrained loading, accompanied with rearrangement of soil particles and degradation in stiffness of the soil due to decrease in effective stresses. During loading, the onset of soil liquefaction is defined as a stress state in which the excess pore water pressure is equalized to the total stress. From this point of view, assessment of the pore water pressure development pattern under cyclic loading has been one of the most salient research topics in geotechnical and earthquake engineering. In this study, results of a series of cyclic triaxial tests on non-plastic silt specimens consolidated under 100 kPa effective isotropic consolidation pressure were used to question the modelling ability of pore pressure development models previously proposed for sands. Tests were performed on specimens of 6 different initial relative densities (Dr) ranging between 30-80% and 10 different cyclic stress ratios (CSR). The key parameters of pore water pressure development and shear deformation in the energy-based model used are relative density, cyclic stress ratio and number of cycles. The results revealed that, these energy-based models have a strong potential in evaluation of pore water pressure development pattern of non-plastic silts. Test results also show that the increase in relative density and decrease in CSR causes a ladderlike behavior among pore water pressure and cyclic shear strain, which is relevantly rendered by energy-based models.

Plasma wave propagation conditions analysis using the warm multi-fluid model

Although an accurate description of wave propagation and absorption in plasmas requires complicated full-wave solutions or kinetic simulations, local dispersion analysis can still be helpful to capture the main physics of wave properties. Plasma wave propagation conditions or accessibility informs whether a wave can propagate to a region, which usually depends on the wave frequency, wave vector, the local plasma density, and magnetic field. We demonstrate a warm multi-fluid eigenvalue model and a matrix approach to rapidly calculate plasma wave accessibility diagrams, where thermal effects are also included via an isotropic pressure term. All cold plasma waves, from high-frequency electron cyclotron waves, intermediate-frequency lower hybrid waves, to low-frequency ion cyclotron waves, are presented. By comparing with the kinetic model, it is interesting to find that the warm multi-fluid model, though incapable of reproducing the Bernstein modes, can provide a quick way to determine whether thermal effects are important.