Isotropic Angular Distribution Research Articles

Neutron emission from a source moving in a gravitational field

This work is devoted to the problem of neutron field formation near elliptical orbits of space objects equipped with nuclear power plants. The high-energy part of the fission spectrum is not affected by the gravitational field. Radiation safety is ensured by the triad fair for a point source: activity-distance-time. The connection between space object orbit parameters and neutron flux density occurs for the thermal (near-thermal) part of the spectrum. The possibility of formation of a stable neutron trace in the volume of a «torus» around the orbit of a space object is considered. The paper presents theoretical and numerical evidence of the validity of the hypothesis put forward. The introduction considers the separation effect of Galileo's relativity principle in the case of rectilinear uniform motion of a point isotropic neutron source on a plane. The occurrence of angular asymmetry of the neutron distribution in a stationary coordinate system when their relative velocity is close to the transport velocity of the source is illustrated. Under these conditions, a significant velocity dispersion of initially monochromatic neutrons is also recorded. This expected fundamental kinematic effect determines the characteristic distribution of neutrons in the gravitational field when the source moves along the Kepler orbit. The solution of the problem is carried out in the velocity space. It is argued that if the distribution of neutrons in the velocity space is such that their velocities are collinear to the orbital velocity of the source, this indicates the existence of a neutron flux near the orbit. The problem is analysed on the example of one revolution of a hypothetical space station by simulation modelling. For this purpose, thermal neutron packets with isotropic angular distribution were generated at eight points of an elliptical orbit. The neutron and source velocity fluxes at the selected points of the orbit were compared in a coordinate system related to the earth. The obtained data made it possible to calculate the densities of neutron velocity fluxes to the front and rear hemispheres relative to the source orbital motion as a function of the polar angle, while the value of the determinant of the correlation matrix – an indicator of collinearity of neutron velocity vectors in the flux - was fixed. The results of the studies confirm the hypothesis put forward about the possibility of formation of a «trace» in the orbit of a thermal neutron source, which determines the need to take it into account as a significant component of radiation risk.

Imaging Rovibrational Excitation of Scattered YO Molecules in Inelastic Collisions with Kr and Ne.

Energy transfer between atoms and molecules is fundamental to many physical and chemical processes, and understanding the mechanisms and outcomes of energy transfer is crucial for various applications in physics and chemistry. Here, the rovibrational excitation of YO(X 2Σ+) molecules with the collision of Kr and Ne has been studied in the laser-ablation crossed beam and time-sliced ion velocity map imaging setup in combination with the resonance enhanced multiphoton ionization scheme. Significant changes in the angular distribution for different rovibrational excitations of YO molecules are observed with the collision of Kr. The sharp forward distribution for low rovibrational excitation of YO(v' = 0, 1) molecules suggest that the weak attractive potential between Kr and YO is dominant at large impact parameters. Comparatively, the strong sideway distribution for highly rovibrationally excited YO(v' = 1, 2, 3, and 5) is due to rainbow scattering from the stronger attractive potential of Kr···YO at relatively small impact parameters. The more isotropic angular distribution in the highly rovibrationally excited YO(v' = 11) indicates the formation of a short-lived complex. A change in the angular distribution of scattered YO with different rovibrational excitations was also observed in the collisions of Ne. For YO as a heteronuclear diatomic molecule, collisions of the Y- and the O-end of YO with rare gases would affect the contribution of inelastic processes at different impact parameters.

Ultraviolet photochemistry of the 2-buten-2-yl radical.

The ultraviolet (UV) photodissociation dynamics of the 2-buten-2-yl (C4H7) radical were studied using the high-n Rydberg atom time-of-flight (HRTOF) technique in the photolysis region of 226-246 nm. 2-Buten-2-yl radicals were generated by 193 nm photodissociation of the precursor 2-chloro-2-butene. The H-atom photofragment yield (PFY) spectrum of 2-buten-2-yl is broad, peaking at 234 nm. Quantum chemistry calculations show that the UV absorption is due to the 3py and 3px Rydberg states (parallel to the plane of CC double bond). The translational energy distributions of the H-atom loss product channel, P(ET)'s, of 2-buten-2-yl show a bimodal distribution indicating two dissociation pathways. The major pathway peaks at ET ∼ 7 kcal mol-1 with a nearly constant fraction of average ET in the total excess energy, 〈fT〉, at ∼0.11-0.12. This main pathway has an isotropic product angular distribution with β ∼ 0, consistent with the unimolecular dissociation of a hot 2-buten-2-yl radical following internal conversion from the electronically excited state, resulting in the formation of 2-butyne + H (∼84%) and 1,2-butadiene + H (∼16%). Additionally, there is a minor non-statistical pathway with an isotropic angular distribution. The minor pathway peaks at ET ∼ 35 kcal mol-1 in the P(ET) distributions and exhibits a large 〈fT〉 of ∼0.40-0.46. This fast pathway suggests a direct dissociation of the methyl H-atom on a repulsive excited state surface or on the repulsive part of the ground state surface, forming 1,2-butadiene + H. The fast/slow pathway branching ratio is in the range of 0.03-0.08.

Photodissociation dynamics of the ethyl radical via the Ã2A'(3s) state: H-atom product channels and ethylene product vibrational state distribution.

The photodissociation dynamics of jet-cooled ethyl radical (C2H5) via the Ã2A'(3s) states are studied in the wavelength region of 230-260nm using the high-n Rydberg H-atom time-of-flight (TOF) technique. The H + C2H4 product channels are reexamined using the H-atom TOF spectra and photofragment translational spectroscopy. A prompt H + C2H4(X̃1Ag) product channel is characterized by a repulsive translational energy release, anisotropic product angular distribution, and partially resolved vibrational state distribution of the C2H4(X̃1Ag) product. This fast dissociation is initiated from the 3s Rydberg state and proceeds via a H-bridged configuration directly to the H + C2H4(X̃1Ag) products. A statistical-like H + C2H4(X̃1Ag) product channel via unimolecular dissociation of the hot electronic ground-state ethyl (X̃2A') after internal conversion from the 3s Rydberg state is also examined, showing a modest translational energy release and isotropic angular distribution. An adiabatic H + excited triplet C2H4(ã3B1u) product channel (a minor channel) is identified by energy-dependent product angular distribution, showing a small translational energy release, anisotropic angular distribution, and significant internal excitation in the C2H4(ã3B1u) product. The dissociation times of the different product channels are evaluated using energy-dependent product angular distribution and pump-probe delay measurements. The prompt H + C2H4(X̃1Ag) product channel has a dissociation time scale of <10ps, and the upper bound of the dissociation time scale of the statistical-like H + C2H4(X̃1Ag) product channel is <5ns.

Prediction of Betavoltaic Battery Parameters

The approaches for predicting output parameters of betavoltaic batteries are reviewed. The need to develop a strategy for predicting these parameters with sufficient accuracy for the optimization of betavoltaic cell design without using the simple trial and error approach is discussed. The strengths and weaknesses of previously proposed approaches for the prediction are considered. Possible reasons for the difference between the calculated and measured parameters are analyzed. The depth dependencies of beta particles deposited energy for Si, SiC, GaN, and Ga2O3 and 20% purity 63Ni and titanium tritide as radioisotope sources are simulated using the Monte Carlo algorithm taking into account the full beta energy spectrum, the isotropic angular distribution of emitted electrons and the self-absorption inside the radioisotope source for homogeneously distributed emitting points. The maximum short circuit current densities for the same semiconductors and radioisotope sources are calculated. The methodology allowing the prediction of betavoltaic cell output parameters with accuracy no worse than 30% is described. The results of experimental and theoretical investigations of the temperature dependence of betavoltaic cell output parameters are briefly discussed. The radiation damage by electrons with the subthreshold energy and the need to develop models for its prediction is considered.

Modeling of aluminum erosion by neutral particles in dedicated EAST experiments using the 3D-GAPS code

To evaluate the erosion effects of charge exchange (CX) neutrals on first wall materials, aluminum (Al) coated samples installed in a cylindrical sleeve were exposed to EAST plasmas with the Material and Plasma Evaluation System (MAPES). The 3D-GAPS code was firstly used to simulate the dedicated experiments with the neutral energy spectrums measured by the Low Energy Neutral Particle Analyzer located at the MAPES. The modeled Al erosion rates with isotropic angular distributions for incident D neutrals are consistent with the measured erosion thicknesses of Al layer by Rutherford backscattering spectrometry before and after the plasma exposure. The effects of neutral reflection coefficients and the heights of cylindrical sleeve on material erosion are also studied. The measured material erosion rate by CX neutrals in EAST verified by the modeling can help to us understand the effects of neutrals on first wall erosion, which is an important erosion process in future fusion reactors.

Photodissociation dynamics of tetrahydrofuran at 193 nm.

Tetrahydrofuran (THF), a cyclic ether with the chemical formula C4H8O, can be considered the simplest analog of the deoxyribose backbone component of deoxyribonucleic acid (DNA). As such, it provides a useful model for probing the photochemistry of such biomolecular motifs. We present a velocity-map imaging study into the ultraviolet dissociation of THF at a wavelength of 193 nm. Excitation to the S1 state occurs via a 3s ← n transition involving a lone-pair electron on the oxygen atom, and has been shown by other authors to result in rapid ring opening via cleavage of one of the C-O bonds to form a ring-opened C4H8O diradical, followed by C-C bond cleavage over a longer timescale to form either OCH2 + C3H6 products (Channel 1a), HOCH2 + C2H5 products (Channel 1b), or OCH2CH2 + C2H4 products (Channel 2). The C2H4O products formed via Channel 2 are unstable on the timescale of our experiment and dissociate further to form CH3 and CHO. We also observe a number of minor products resulting from H or H2 loss from the primary photofragments. The speed distributions observed for all photofragments are broad, indicating excitation of a range of rotational and vibrational states of the products. The angular distributions of the photofragments show an interesting speed dependence: the slowest products have almost isotropic angular distributions, but the magnitude of the recoil anisotropy increases monotonically with photofragment speed. The fastest products exhibit highly anisotropic angular distributions, with the recoil anisotropy parameter β approaching its limiting value of -1 (-0.75 for Channel 1 and -0.5 for Channel 2). This behaviour is attributed to the range of timescales over which the diradical intermediate dissociates into the observed photofragments. Rapid dissociation leads to fast photofragments which retain the correlation between the transition dipole moment for the S1 ← S0 excitation (which lies perpendicular to the ring) and the photofragment velocities (which lie predominantly in the plane of the ring). Slow dissociation results in a high degree of energy redistribution into internal modes, slower photofragments, and loss of correlation between the photofragment velocities and the transition dipole. The higher barrier associated with dissociation via Channel 2 suggests somewhat longer lifetimes for the diradical intermediate and is consistent with a corresponding reduction in the maximum observed value for β.

Ultraviolet photodissociation of 2-methylallyl radical

Ultraviolet photodissociation dynamics of 2-methylallyl radical from the 3p Rydberg state were investigated in the wavelength region of 226–244 nm using the high-n Rydberg atom time-of-flight (HRTOF) technique. The 2-methylallyl radicals were generated by 193 nm photolysis of 3-chloro-2-methyl-1-propene precursors. The photofragment yield spectrum of H-atom products increases in intensity with decreasing wavelengths in 226–244 nm. The TOF spectra of H-atom products show a bimodal structure. The predominant product channel (with ∼98% branching ratio) has a kinetic energy release peaking at ∼7 kcal/mol, with an average ratio of ET in the total available energy, (fT), of ∼0.18 in 226–244 nm and an isotropic product angular distribution. At the low ET, isotropic component is from statistical unimolecular decomposition of highly vibrationally excited hot 2-methylallyl to the methylenecyclopropane+H products, following internal conversion from the excited electronic state. The minor product channel (with ∼2% branching ratio) has a large kinetic energy peaking at ∼50 kcal/mol, with (fT)≈0.63 and an anisotropic angular distribution (β≈−0.2). At the high ET, anisotropic component is non-statistical and is postulated to be from direct loss of H atom via the 3p Rydberg state or repulsive part of the ground state to the 1,3-butadiene+H products.

Voltage waveform tailoring for high aspect ratio plasma etching of SiO2 using Ar/CF4/O2 mixtures: Consequences of ion and electron distributions on etch profiles

The quality of high aspect ratio (HAR) features etched into dielectrics for microelectronics fabrication using halogen containing low temperature plasmas strongly depends on the energy and angular distribution of the incident ions (IEAD) onto the wafer, as well as potentially that of the electrons (EEAD). Positive ions, accelerated to high energies by the sheath electric field, have narrow angular spreads and can penetrate deeply into HAR features. Electrons typically arrive at the wafer with nearly thermal energy and isotropic angular distributions and so do not directly penetrate deeply into features. These differences can lead to positive charging of the insides of the features that can slow etching rates and produce geometric defects such as twisting. In this work, we computationally investigated the plasma etching of HAR features into SiO2 using tailored voltage waveforms in a geometrically asymmetric capacitively coupled plasma sustained in an Ar/CF4/O2 mixture at 40 mTorr. The tailored waveform consisted of a sinusoidal wave and its higher harmonics with a fundamental frequency of 1 MHz. We found that some degree of control of the IEADs and EEADs is possible by adjusting the phase of higher harmonics φ through the resulting generation of electrical asymmetry and electric field reversal. However, the IEADs and EEADs cannot easily be separately controlled. The control of IEADs and EEADs is inherently linked. The highest quality feature was obtained with a phase angle φ = 0° as this value generated the largest (most negative) DC self-bias and largest electric field reversal for accelerating electrons into the feature. That said, the consequences of voltage waveform tailoring (VWT) on etched features are dominated by the change in the IEADs. Although VWT does produce EEADs with higher energy and narrower angular spread, the effect of these electrons on the feature compared to thermal electrons is not large. This smaller impact of VWT produced EEADs is attributed to thermal electrons being accelerated into the feature by electric fields produced by the positive in-feature charging.

Photoinduced charge transfer in the Zn-methanol cation studied with selected-ion photofragment imaging.

The Zn+(methanol) ion molecule complex produced by laser vaporization is studied with photofragment imaging at 280 and 266nm. Photodissociation produces the methanol cation CH3OH+ via excitation of a charge-transfer excited state. Surprisingly, excitation of bound excited states produces the same fragment via a curve crossing prior to separation of products. Significant kinetic energy release is detected at both wavelengths with isotropic angular distributions. Similar experiments are conducted on the perdeuterated methanol complex. The Zn+ cation is a minor product channel that also exhibits significant kinetic energy release. An energetic cycle using the ionization energies of zinc and methanol together with the kinetic energy release produces an upper limit on the Zn+-methanol bond energy of 33.7 ± 4.2 kcal/mol (1.46 ± 0.18eV).

The influence of phonon boundary scattering on the thermal conductivity of a two-dimensional noninteractive phonon system of nanosized structures

One of the problems that arise when studying the thermal conductivity of low-dimensional phonon systems at low temperatures is the appearance of differences in expressions for the thermal conductivity as a function of sample size, as well as the appearance of unusual dependences of heat fluxes on temperature gradients. For example, in the generally accepted Casimir – Zaiman model, it is assumed that a linear temperature gradient is created on the lateral surface by external sources. Moreover, the Casimir model requires two conditions at the border. This is a diffuse reflection in which the phonon is reflected with an isotropic angular distribution function. The second condition is the presence of redistribution of phonons by energy, so that the distribution of reflected phonons corresponds to the radiation of an absolutely black body - that is, the reflection of phonons must be inelastic. And if the first condition can be achieved, for example, by boundaries with a certain degree of roughness, the second condition can be achieved only in the presence of thermal contact between the side edges of the sample and the thermal medium at a certain temperature distribution. In the case of thermally insulated sample boundaries (for example, when the sample is in vacuum) or at least with imperfect thermal contact, the fulfillment of the second condition is practically impossible.In this paper, we consider the problem of thermal conductivity of two-dimensional nanostructures - nanobands - in the temperature range, when the interaction between phonons can be neglected. In this ballistic mode, heat fluxes can be limited only by the interaction of phonons with the sample boundaries. A number of types of interaction of phonons with the boundaries of two-dimensional samples are considered: absorption at the boundary, finite number of reflections, absorption inside the sample on defects, impurities, etc. Explicit expressions of thermal conductivity in these cases are derived. Interpolation relations are obtained, which generalize the existing expressions of thermal conductivity in the case of mirror reflection and reflection with losses.

Photodissociation dynamics of methyl vinyl ketone oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis.

The electronic spectrum of methyl vinyl ketone oxide (MVK-oxide), a four-carbon Criegee intermediate derived from isoprene ozonolysis, is examined on its second π* ← π transition, involving primarily the vinyl group, at UV wavelengths (λ) below 300nm. A broad and unstructured spectrum is obtained by a UV-induced ground state depletion method with photoionization detection on the parent mass (m/z 86). Electronic excitation of MVK-oxide results in dissociation to O (1D) products that are characterized using velocity map imaging. Electronic excitation of MVK-oxide on the first π* ← π transition associated primarily with the carbonyl oxide group at λ > 300nm results in a prompt dissociation and yields broad total kinetic energy release (TKER) and anisotropic angular distributions for the O (1D) + methyl vinyl ketone products. By contrast, electronic excitation at λ ≤ 300nm results in bimodal TKER and angular distributions, indicating two distinct dissociation pathways to O (1D) products. One pathway is analogous to that at λ > 300nm, while the second pathway results in very low TKER and isotropic angular distributions indicative of internal conversion to the ground electronic state and statistical unimolecular dissociation.

Photodissociation study of spatially oriented (R)-3-bromocamphor by the hexapole state selector

A photodissociation experiment of (R)-3-bromocamphor was carried out by the hexapole orientation technique by (2 + 1) REMPI detection at about 234 nm. The atomic bromine products in excited state (Br 2P1/2) and in ground state (Br 2P3/2) were observed by the velocity map imaging. The anisotropy parameters of Br (2P1/2) and Br (2P3/2) were obtained as 0.75 ± 0.04 and 0.48 ± 0.03, respectively. In addition, we also successfully controlled (R)-3-bromocamphor, the bulky and asymmetric bio-molecule’s, spatial orientation using the electrostatic hexapole. The orientational distribution was derived and its orientation efficiency was estimated as |<cos θ>|=0.35. We carried out a slice imaging experiment with the spatially oriented parent molecules to study the photodissociation dynamics of (R)-3-bromocamphor. The angular analysis of the obtained slice images suggests fast axial recoiling of the bromine atomic fragments and comparable contributions from the multiple upper states involved in A-band excitation, which results in the relatively isotropic angular distributions.

Space radiation electrostatic shielding scaling laws: Beam-like and isotropic angular distributions

Passive radiation shielding alone cannot provide adequate protection for astronauts on long-term, deep-space missions. High atomic number and energy (HZE) ions, and/or their secondaries, can penetrate any realistic mass shielding for long-term deep-space missions and cause damage to cells via direct energy deposition and/or through the production of secondary particles and fragmented nuclei. Active shielding, or the use of electromagnetic fields to deflect or stop incoming ions before reaching the spacecraft, has gained substantial attention over the last decade as a way to augment passive shielding. Recently, a mathematical relationship between a dimensionless scaling parameter characterizing the active shield and the incoming ion and a protected area formed on a downstream detector due to the deflection of HZE ions by the applied field was validated in Earth-based laboratory conditions. In the present work, the mathematical formulation is extended to relate electrostatic shielding efficacy with the ability to deflect positively charged ions with parameters relevant to space applications. Additionally, a modified scaling parameter is formulated to characterize the shielding efficacy of a “family” of electrostatic active shielding configurations for reducing flux density for a space-relevant isotropic source of energetic protons. The results of this study demonstrate a strong correlation among dimensionless scaling parameters and shielding efficacy metrics for space radiation-relevant HZE ions in beam and isotropic angular distributions. Furthermore, it establishes a framework for optimizing design of three-dimensional electrostatic shielding configurations to improve space radiation protection for astronauts on exploration-class missions.

Stochastic light concentration from 3D to 2D reveals ultraweak chemi- and bioluminescence

For countless applications in science and technology, light must be concentrated, and concentration is classically achieved with reflective and refractive elements. However, there is so far no efficient way, with a 2D detector, to detect photons produced inside an extended volume with a broad or isotropic angular distribution. Here, with theory and experiment, we propose to stochastically transform and concentrate a volume into a smaller surface, using a high-albedo Ulbricht cavity and a small exit orifice through cavity walls. A 3D gas of photons produced inside the cavity is transformed with a 50% number efficiency into a 2D Lambertian emitting orifice with maximal radiance and a much smaller size. With high-albedo quartz-powder cavity walls (rho =99.94%), the orifice area is 1/(1-rho )approx 1600 times smaller than the walls’ area. When coupled to a detectivity-optimized photon-counter (mathcal{D}=0.015,{text{photon}}^{-1},{text{s}}^{1/2}text{ cm}) the detection limit is 110;{text{photon}};{text{s}}^{ - 1} ;{text{L}}^{ - 1}. Thanks to this unprecedented sensitivity, we could detect the luminescence produced by the non-catalytic disproportionation of hydrogen peroxide in pure water, which has not been observed so far. We could also detect the ultraweak bioluminescence produced by yeast cells at the onset of their growth. Our work opens new perspectives for studying ultraweak luminescence, and the concept of stochastic 3D/2D conjugation should help design novel light detection methods for large samples or diluted emitters.

Anisotropy in fission fragment and prompt neutron angular distributions

Several physics mechanisms can lead to the deviation from an isotropic angular distribution for both fission fragments and the neutrons that are emitted during the fission event. Two of these effects have recently been implemented into CGMF, the Monte Carlo fission event generator developed at Los Alamos National Laboratory: angular distribution sampling for fission fragments and pre-equilibrium neutrons (those emitted before the compound nucleus forms). Using these new developments, we show that the anisotropy of the neutrons reflects the anisotropy of the fission fragments, in particular as the outgoing energy of neutrons increases. Correlations between the fission fragment and neutron anisotropies could be used to extract the fission fragment anisotropy from the neutron angular distributions.

Probing the Potential Energy Surfaces of BrCN- by Dissociative Electron Attachment.

State coupling certainly determines the topologic features of the molecular potential energy surface (PES) and potentially diversifies chemical reaction pathways. Here we report the new PESs of BrCN- in the low-lying electronic states that are distinctly different from the previous predictions in the short Br-CN bond region but validated by the high-resolution ion velocity imaging measurements of low-energy dissociative electron attachment (DEA) to BrCN. Besides the vibrating CN- ions produced in the fast Br-CN bond stretching motions, we confirm that the ro-vibrating CN- ions with a nearly isotropic angular distribution are produced by receiving a torque in the combinational motion of Br-CN bond bending and stretching. The latter process is closely related to the potential well of BrCN- at the first excited state A2Π3/2 that arises from the Π-Σ state couplings. Our findings not only suggest that the PESs of other anionic cyanogen halides are in dire need of reexamination but also show that ion velocity imaging of the DEA process is a powerful experimental method for evaluating the theoretical PESs of molecular anions.

The magnetoelectric effect due to a semispherical capacitor surrounded by a spherical topologically insulating shell

We calculate the magnetic field produced by a capacitor formed by two semispherical perfectly conducting plates of radius a, subjected to a potential difference and surrounded by a spherical shell of a topologically insulating material having internal radius r1 and external radius r2. Fixing r2 = 1 μm and considering the case where the shell touches the metallic plates, i. e. when r1 = a, we find that the maximum magnetic field occurs at the external surface of the shell when r1≲ 0.75 μm. For these cases we examine the effect in the two remaining variables: the thickness of the shell and axial angular dependence of the magnetic field. For r1 = 0.5 μm we find a highly isotropic angular distribution with an average field of magnitude G. The angular anisotropy increases with r1, yielding for r1 = 0.62 μm and for r1 = 0.75 μm. These magnitudes fall within the sensitivities of magnetometers based upon nitrogen-vacancy centers in diamond, as well as of devices using scanning SQUID magnetometry. In the latter case we obtain fluxes in the range of (6 − 10) × 10−10 G cm2 for a pickup loop of radius 10 μm centered at the axial symmetry axis and located parallel to the equatorial plane at distances ranging from 2 to 6 μm from the center of the capacitor.

The First Terrestrial Electron Beam Observed by the Atmosphere‐Space Interactions Monitor

AbstractWe report the first Terrestrial Electron Beam detected by the Atmosphere‐Space Interactions Monitor. It happened on 16 September 2018. The Atmosphere‐Space Interactions Monitor Modular X and Gamma ray Sensor recorded a 2 ms long event, with a softer spectrum than typically recorded for Terrestrial Gamma ray Flashes (TGFs). The lightning discharge associated to this event was found in the World Wide Lightning Location Network data, close to the northern footpoint of the magnetic field line that intercepts the International Space Station location. Imaging from a GOES‐R geostationary satellite shows that the source TGF was produced close to an overshooting top of a thunderstorm. Monte‐Carlo simulations were performed to reproduce the observed light curve and energy spectrum. The event can be explained by the secondary electrons and positrons produced by the TGF (i.e., the Terrestrial Electron Beam), even if about 3.5% to 10% of the detected counts may be due to direct TGF photons. A source TGF with a Gaussian angular distribution with standard deviation between 20.6° and 29.8° was found to reproduce the measurement. Assuming an isotropic angular distribution within a cone, compatible half angles are between 30.6° and 41.9°, in agreement with previous studies. The number of required photons for the source TGF could be estimated for various assumption of the source (altitude of production and angular distribution) and is estimated between 1017.2 and 1018.9 photons, that is, compatible with the current consensus.

Ultraviolet photodissociation dynamics of DNCO + hν → D + NCO: Two competitive pathways

Photodissociation dynamics of DNCO + hν → D + NCO at photolysis wavelengths between 200 and 235 nm have been studied using the D-atom Rydberg tagging time-of-flight technique. Product translational energy distributions and angular distributions have been determined. Nearly statistical distribution of the product translational energy with nearly isotropic angular distribution was observed at 210–235 nm, which may come from the predissociation pathway of internal conversion from S1 to S0 state followed by decomposition on S0 surface. At shorter photolysis wavelengths, in addition to the statistical distribution, another feature with anisotropic angular distribution appears at high translational energy region, which can be attributed to direct dissociation on S1 surface. Compared with HNCO, the direct dissociation pathway for DNCO photodissociation opens at higher excitation energy. According to our assignment of the NCO internal energy distribution, dominantly bending and a little stretching excited NCO was produced via both dissociation pathways.