Isotopic Resetting Research Articles

Absolute dating of the L-chondrite parent body breakup with high-precision U–Pb zircon geochronology from Ordovician limestone

The breakup of the L-chondrite parent body (LCPB) in the mid-Ordovician is the largest documented asteroid breakup event during the past 3 Gyr. It affected Earth by a dramatic increase in the flux of L-chondritic material and left prominent traces in both meteorite and sedimentary records. A precise constraint on the timing of the LCPB breakup is important when evaluating the terrestrial biotic and climatic effects of the event, as well as for global stratigraphic correlations. Direct dating using heavily shocked L chondrites is hampered by both incomplete initial K-Ar degassing and isotopic resetting by later impact events. In order to better constrain the absolute age of this event we carried out high-precision U–Pb dating of zircons from three limestone beds recording discrete volcanic ash fallouts within mid-Ordovician strata in southern Sweden. These strata are rich in fossilized L-chondritic meteorites (1-20 cm large) that arrived on Earth shortly after the breakup event. Zircons from the ash-bearing layers provide stratigraphically consistent depositional ages that range from 464.22 ± 0.37 Ma to 465.01 ± 0.26 Ma. Combined with recently published 3He profiles that pinpoint the arrival on Earth of the first dust from the breakup, and sedimentation rates constrained by cosmogenic 21Ne in the fossil meteorites, the LCPB breakup is estimated to have occurred at 465.76 ± 0.30 Ma. This provides the presently most precise absolute dating of the LCPB breakup, enabling a robust global stratigraphic correlation of bounding strata. Based on our new U–Pb data for the ash-bearing beds, the absolute ages for the boundaries of biozones and Dapingian–Floian stages overlap within error with those given by the 2012 Geological Timescale and require no modification.

Impact-triggered nanoscale Pb clustering and Pb loss domains in Archean zircon

Zircon microcrystals are found in many planetary crustal rocks and nanoscale research on grains from well-characterized impact environments on Earth provide a baseline for reconstructing extreme shock and thermal histories elsewhere. However, using zircon to date large impact events can be challenging given that shock-related isotopic re-setting of U–Pb ratios, when measured at micrometre scale, is often incomplete and difficult to interpret as the underlying Pb migration mechanisms are unclear. To better understand shocked zircon U–Pb systematics, we performed atom probe tomography and electron microscopy with the previous SIMS analyses of two shock metamorphosed Mesoarchean zircon grains from deep (≥ 15 km) beneath the centre of the 2.020 Ga giant Vredefort impact structure. We find evidence of two types of impact-related nanoscale Pb mobility. In one grain, clustering has produced ~ 10 nm diameter bodies of radiogenic Pb, unsupported by U and co-located with Al, with an average 207Pb/206Pb ratio of ~ 0.50 (n = 4); the value extant in the grain at the time of impact. Conversely, nearby nanodomains exhibit randomly distributed radiogenic Pb, U and Al and yield 206Pb/238U dates consistent with 100% loss of pre-impact radiogenic Pb atoms during shock metamorphic processes. Notably, domains with multiple Pb clusters occur within micrometres of domains that experienced 100% Pb loss, precluding a uniform radial pattern of thermally-driven Pb diffusion at the grain scale. These cases of broadly coeval clustering and outward Pb mobility during geologically instantaneous shock metamorphism point to unusually rapid, multi-path diffusion processes within sub-micrometre volumes which, when averaged, yield normally discordant U–Pb dates. The isolation of spatially variable styles of Pb retention and loss at nanoscale amidst classical grain-scale shock microstructures shows promise for recognizing and resolving bombardment histories in planetary crusts using zircon.

Alteration of magmatic monazite in granitoids from the Ryoke belt (SW Japan): Processes and consequences

AbstractThe alteration of magmatic monazite and its consequences for monazite geochronology are explored in granitoids from the western part of the Ryoke belt (Iwakuni-Yanai area, SW Japan). Biotite-granite samples were collected in two plutons emplaced slightly before the main tectono-metamorphic event: the first one, a massive granite (Shimokuhara) adjoins schistose rocks affected by greenschist facies metamorphism; and the second, a gneissose granite (Namera) adjoins migmatitic gneiss that experienced upper-amphibolite facies conditions. Despite contrasting textures, the granite samples have similar mineral modes and compositions. Monazite in the massive granite is dominated by primary domains with limited secondary recrystallization along cracks and veinlets. It is variably replaced by allanite+apatite±xenotime±Th-U-rich phases. The outermost rims of primary domains yield a weighted average 206Pb/238U date of 102 ± 2 Ma while the Th-U phases show Th-U-Pb dates of 58 ± 5 and 15 to 14 ± 2–3 Ma. Monazite in the gneissose granite preserves sector- or oscillatory-zoned primary domains cross-cut by secondary domains enriched in Ca, Y, U, P, and containing numerous inclusions. The secondary domains preserve concordant 206Pb/238U dates spreading from 102 ± 3 to 91 ± 2 Ma while primary domain analyses are commonly discordant and range from 116 to 101 Ma.Monazite alteration textures in the two granites chiefly reflect differences in their post-magmatic histories. In the massive granite, monazite replacement occurred via a nearly stoichiometrically balanced reaction reflecting interaction with an aqueous fluid enriched in Ca+Al+Si±F during hydrothermal alteration of the granitic assemblage, likely below 500 °C. In the gneissose granite, a small amount of anatectic melt, probably derived from the neighboring metasedimentary rocks, was responsible for pseudomorphic recrystallization of monazite by dissolution-reprecipitation above 600 °C. Regardless of whether monazite underwent replacement or recrystallization, primary monazite domains preserve the age of magmatic crystallization for both plutons (102 ± 2 and 106 ± 5 Ma). Conversely, the age of monazite alteration is not easily resolved. Monazite replacement in the massive granite might be constrained using the Th-U-rich alteration products; with due caution and despite probable radiogenic Pb loss, the oldest date of 58 ± 5 Ma could be ascribed to chloritization during final exhumation of the granite. The spread in apparently concordant 206Pb/238U dates for secondary domains in the gneissose granite is attributed to incomplete isotopic resetting during dissolution-reprecipitation, and the youngest date of 91 ± 2 Ma is considered as the age of monazite recrystallization during a suprasolidus metamorphic event. These results reveal a diachronous, ca. 10 Ma-long high-temperature (HT) history and an overall duration of about 15 Ma for the metamorphic evolution of the western part of the Ryoke belt.

Petrogenesis of the Gifford Creek Carbonatite Complex, Western Australia

The 1370 Ma Gifford Creek Carbonatite Complex (GCCC) comprises a diverse suite of alkaline dyke and sill complexes that cover an area of ~ 250 km2 in the Gascoyne Province, Western Australia. Most carbonatite types are interpreted to be related products of fractional crystallisation, with calcite carbonatites representing cumulate rocks and dolomite carbonatites representing crystallised products of the derivative liquids. Genetic relationships between these carbonatites and other alkaline igneous units are less clear. The ankerite–siderite carbonatites and magnetite-biotite dykes are likely of related magmatic origin as both have distinctly high LREE and low HFSE contents. The ankerite–siderite carbonatites have mantle-like δ13C isotope values of − 6.1 to − 7.1‰ and similar geochemistry to other known magmatic ferrocarbonatites. Silica-rich alkaline veins found near the centre of the complex have trace element signatures that are antithetic to the magnetite–biotite dykes, so these veins are interpreted to represent products of alkali- and F-rich magmatic-hydrothermal fluids exsolved from the magnetite–biotite dykes during their emplacement. Carbon, O, Sr, and Nd isotope data are consistent with an enriched mantle source for the origin of the GCCC, with mantle enrichment likely caused by plate convergence processes associated with the c. 2.0 Ga Glenburgh Orogeny. There is no evidence to link mantle plume activity with formation of the GCCC; rather, alkaline magmatism is interpreted to result from low degree melting of the metasomatised mantle during reactivation of the crustal suture zone at 1370 Ma. The carbonatitic magmas utilised the Lyons River Fault to traverse the crust to be emplaced as the GCCC. Post magmatic alteration has variably modified the O and Sr isotope compositions of carbonates from these rocks. We therefore appeal for careful evaluation of isotopic data from ancient carbonatites, as isotopic resetting may be more common than currently recognised.

Paleoproterozoic juvenile magmatism within the northeastern sector of the São Francisco paleocontinent: Insights from the shoshonitic high Ba–Sr Montezuma granitoids

New, integrated petrographic, mineral chemistry, whole rock geochemical, zircon and titanite U–Pb geochronology, and zircon Hf isotopic data from the Montezuma granitoids, as well as new geochemical results for its host rocks represented by the Corrego Tingui Complex, provides new insights into the late- to post-collisional evolution of the northeastern São Francisco paleocontinent. U–Pb zircon dates from the Montezuma granitoids spread along the Concordia between ca. 2.2 ​Ga to 1.8 ​Ga and comprise distinct groups. Group I have crystallization ages between ca. 2.15 ​Ga and 2.05 ​Ga and are interpreted as inherited grains. Group II zircon dates vary from 2.04 ​Ga to 1.9 ​Ga and corresponds to the crystallization of the Montezuma granitoids, which were constrained at ca. 2.03 ​Ga by the titanite U–Pb age. Inverse age zoning is common within the ca. 1.8 ​Ga Group III zircon ages, being related to fluid isotopic re-setting during the Espinhaco rifiting event. Zircon εHf(t) analysis show dominantly positive values for both Group I (−4 to +9) and II (−3 to +8) zircons and TDM2 model ages of 2.7–2.1 ​Ga and 2.5–1.95 ​Ga, respectively. Geochemically, the Montezuma granitoids are weakly peraluminous to metaluminous magnesian granitoids, enriched in LILES and LREE, with high to moderate Mg# and depleted in some of the HFSE. Their lithochemical signature, added to the juvenile signature of both inherited and crystallized zircons, allowed its classification as a shoshonitic high Ba–Sr granitoid related to a late- to post-collisional lithosphere delamination followed by asthenospheric upwelling. In this scenario, the partial melting of the lithospheric mantle interacted with the roots of an accreted juvenile intra-oceanic arc, being these hybrid magma interpreted as the source of the Montezuma granitoids. The Córrego Tinguí Complex host rocks are akin to a syn- to late-collisional volcanic arc granitoids originated from the partial melting of ancient crustal rocks. The results presented in this study have revealed the occurrence of juvenile rocks, probably related to an island arc environment, that are exotic in relation to the Paleo- to Neoarchean crust from the São Francisco paleocontinent’s core.

Multiphase U-Pb geochronology of sintered breccias from the Steen River impact structure, Canada: Mixed target considerations for a Jurassic-Cretaceous boundary event

In situ U-Pb geochronology has been conducted using laser ablation inductively coupled mass spectrometry (LA-ICP-MS) on shocked and thermally metamorphosed apatite, titanite, and zircon grains from the Steen River impact structure, Canada. The dated relict mineral phases occur within impact melt-bearing breccias that underwent post-deposition sintering at 450 °C > T < 800 °C. Apatite yields a refined lower intercept age of 141 ± 4 Ma, which we interpret as the best estimate age for the Steen River impact event. Titanite was only partially reset; yielding a lower intercept age of 113 ± 41 Ma. Zircon yields a lower intercept impact age of 120 ± 14 Ma, which is considered a minimum best-estimate impact age. The most reset zircon analyses that control this lower intercept are complicated by combinations of common-Pb incorporation and recent Pb loss associated with granularized and radiation-damaged (metamict) domains. All three phases preserve Paleoproterozoic crystalline basement ages, with a single concordant 206Pb/238U age of 1914 ± 39 Ma from apatite, an upper intercept age of 1882 ± 11 Ma from zircon, and an upper intercept age of 1842 ± 9 Ma from titanite. For apatite, the degree of isotopic resetting is largely thermally controlled, with the extent of reset closely associated with textural setting (degree of grain armouring, melt proximity and sample temperature) and, to a lesser extent, by shock/thermally generated microstructures (i.e., planar fractures, micro-vesicles, and recrystallized domains). While titanite records an impact age that falls within error of apatite and zircon, the majority of grains experienced only partial isotopic resetting, which we attribute to incomplete Pb loss associated with rapid cooling and post-depositional sintering of the breccia matrix below the titanite closure temperature (∼800 °C). In zircon, ancient (impact) Pb loss was facilitated along defect-related, fast-diffusion pathways within pre-impact metamict domains, shock defects, and via recrystallization. These same domains were also subject to recent (post-impact) Pb loss and common Pb contamination, significantly compromising the reliability of zircon ages. The distribution of U-Pb ratios in apatite and titanite is unlike those obtained in crystalline targets, a feature we interpret to be characteristic of impact structures developed in mixed (sedimentary – crystalline) targets, such as Steen River. In this case, disaggregated melt systems create thermal regimes distinct from those derived from predominantly igneous/metamorphic targets. With an age of 141 ± 4 Ma, Steen River joins the Dellen (Sweden), Gosses Bluff (Australia), Mjølnir (Barents Sea), and Morokweng (South Africa) impact structures in being formed at, or close to, the Jurassic-Cretaceous boundary.

The impact of the Pan-African-aged tectonothermal event on high-grade rocks at Mount Brown, East Antarctica

AbstractThis study presents monazite and rutile U–Pb and hornblende and biotite40Ar/39Ar geochronological data for high-grade rocks of the eastern Grenville-aged Rayner orogen at Mount Brown in order to analyse the extent and degree of Pan-African-aged reworking. Monazite from paragneiss yields U–Pb ages of 910 Ma for larger granular grains and 670–630 Ma for smaller globular beads around garnet porphyroblasts or hosted by symplectites. Rutile from leucogneiss yields U–Pb ages of 520–515 Ma. Hornblende and biotite from different rock types yield40Ar/39Ar plateau ages of 744 and 520–505 Ma, respectively. Combining these results with published zircon U–Pb age data suggests that granulite facies metamorphism occurred at 910 Ma, with a local low-temperature fluid flow event at 670–630 Ma and thermal reworking at 520–505 Ma. The older age of 744 Ma may reflect cooling or partial resetting of the hornblende40Ar/39Ar system, indicating that Pan-African-aged reworking did not exceed temperatures much higher than the hornblende Ar closure temperature. These data also suggest that the complete isotopic resetting of some minerals may occur without the growth of new mineral phases, providing an example of the style of reworking that is likely to occur in polymetamorphic terranes.

In situ multiphase U–Pb geochronology and shock analysis of apatite, titanite and zircon from the Lac La Moinerie impact structure, Canada

In situ U–Pb geochronology has been performed via laser ablation inductively coupled mass spectrometry on shocked apatite, titanite and zircon from the ~ 8-km-diameter Lac La Moinerie impact structure, Canada. The three analyzed phases are inherited from target rocks that were transformed to impact melt-bearing breccias and clast-laden impact melts. Apatite yields an array of U–Pb ratios populating a region between a younger regression with a refined age of 453 ± 5 Ma, and an older regression with a lower intercept age of 1708 ± 10 Ma. Titanite defines a younger regression with an age of 444 ± 15 Ma, and an older array with a lower intercept at 1844 ± 24 Ma. Zircon yields an upper intercept age of 1810 ± 13 Ma and a lower intercept age of 433 ± 21 Ma, within error of apatite and titanite. The oldest ages from all three phases define Paleoproterozoic igneous–metamorphic events in granitoid target rocks of the De Pas Suite. Isotopic resetting in apatite and titanite, with relatively high Pb-diffusion rates, was controlled by a combination of proximity to impact-generated superheated melt and the formation of fast diffusion pathways facilitated by shock effects and dynamic recrystallization. Zircon resetting was controlled by shock effects and metamictization, which resulted in significant Pb loss. We outline an approach for discriminating ‘true’ impact ages from metamict zircons with high common Pb that have experienced post-impact Pb loss. Lower intercept ages of all phases constrain the age of formation for the Lac La Moinerie impact structure, with apatite yielding the most precise age of 453 ± 5 Ma. With an age of 453 Ma, Lac La Moinerie joins a growing cluster of more than 12 terrestrial impact structures formed in the Middle-to-Late Ordovician, with potential connection to the L-chondrite parent body breakup event and a period of enhanced bombardment on Earth.

Carbonatites as recorders of mantle-derived magmatism and subsequent tectonic events: An example of the Gifford Creek Carbonatite Complex, Western Australia

The Gifford Creek Carbonatite Complex (GCCC), Western Australia contains a diverse suite of alkaline igneous rocks, including magnesiocarbonatites, ferrocarbonatites, phoscorites, fenites, magmatic-hydrothermal peralkaline dykes, and ironstones. This study employs U-Pb, Sm-Nd, and Lu-Hf radiogenic isotope techniques on monazite – (Ce), fluorapatite, and zircon to determine the origin, age, and history of the GCCC.Zircon crystals found in glimmerite alteration selvages adjacent to ferrocarbonatites exhibit pyramidal crystal morphologies, εHf values of −1.8 to −4.3, high Th/U, and variable Zr/Hf, all of which are indicative of carbonatitic zircon sourced from an enriched mantle component. Uranium-Pb dating of these zircons returned a definitive magmatic age of ~1370 Ma for the GCCC. Monazite hosted in the ferrocarbonatites, phoscorites, and fenite alteration assemblages yielded variable U-Pb ages ranging from ca. 1250 Ma to 815 Ma. Neodymium isotope isochrons determined from coexisting monazite and apatite gave ages between ca. 1310 Ma to ca. 1190 Ma, but all with similar initial 143Nd/144Nd values of 0.51078–0.51087.The 1370 Ma age of the GCCC does not correspond to any known mantle plume activity, but does broadly correlate with the separation of the North China Craton from the West Australian Craton as part of the greater breakup of Nuna. The monazite and apatite εNd data illustrate that the multiple younger U-Pb monazite and Nd isotope isochron ages are not recording multiple magmatic intrusions into the complex, but rather represent partial recrystallisation/resetting of REE-bearing minerals during the protracted tectonic history of the Western Australia Craton from ~1300 Ma to 815 Ma and its involvement in the breakup of Nuna and assembly and disassembly of Rodinia.The age variability in the U-Pb and the Sm-Nd isotope systems in monazite and apatite reveal that tectonically-induced hydrothermalism can contribute to the isotopic resetting of phosphate minerals. This age resetting, if properly identified, can be used as a thorough geochronological record of tectonism affecting alkaline igneous complexes after initial magmatic emplacement.

Prograde metamorphic zircon formation in gabbroic rocks: The tale of microtextures

AbstractU–Pb zircon dates of metagabbroic rocks, such as eclogite, mafic granulite, and garnet amphibolite, are used to constrain the timing of tectonometamorphic evolution in orogens worldwide. For such interpretation, however, it is imperative to define at which stage of the P–T evolution that zircon crystallization took place: the prograde, peak, or retrograde stage. In order to accurately interpret metamorphic zircon ages, it is necessary to assess how the zircon crystallized or recrystallized, as zircon can dissolve or grow under different metamorphic conditions. Zircon is robust to retrograde isotopic resetting under most crustal conditions, but equilibrium Zr mass balance models have suggested that zircon is largely produced during retrograde metamorphism. This study takes a textural approach and identifies and reviews zircon‐forming textures and reactions in gabbro and metagabbro at different metamorphic grades, ranging from subgreenschist to upper amphibolite‐ and eclogite‐facies, and at different stages of metamorphic recrystallization. The textural relationships demonstrate that, in metagabbro, metamorphic zircon grows during the early stage of metamorphic recrystallization, independent of pressure and temperature. The mode of zircon formation is remarkably similar throughout different stages of metamorphic recrystallization, and the most significant source of Zr is igneous baddeleyite. Hence, in contrast to the equilibrium mass balance model, most zircon in metagabbro forms by prograde metamorphic reactions that consume igneous phases, and not by late retrograde reactions, and the onset of zircon forming reactions is governed primarily by the introduction of a hydrous fluid, commonly accompanied by ductile deformation.

Quantitative reconstruction of seasonality from stable isotopes in teeth

Seasonal variation in rainfall and temperature are major determinants of ecosystem structure and productivity and influence physical processes such as erosion rates and glaciation. By extension, seasonality can drive evolutionary change, and is hypothesized to have influenced early human subsistence and technological development. Rainfall patterns are reflected by oxygen isotope ratios (δ18O values) in mammalian tooth enamel, which records environmental chemistry as reflected by blood chemistry during mineralization. Fossilized herbivore molars are commonly used to study paleoseasonality, since temporal variation in precipitation δ18O results in spatial variation in tooth mineral δ18O. However, this approach has been hampered by incomplete knowledge of isotope incorporation during tooth mineralization. Here we test a new synchrotron-based mineralization model and demonstrate its potential to quantitatively reconstruct original seasonal input histories under a Bayesian computational framework. To accomplish this, we first integrate the mineralization model with blood water oxygen isotope turnover to produce high-resolution spatial δ18O predictions. We test these predictions using fine-scaled tooth enamel phosphate δ18O measurements (n = 109 locations sampled in a 2D grid format) in a sheep (Ovis aries) subjected to a controlled water switch (switch δ18O magnitude of 12‰). Tooth mineralization, blood oxygen turnover and isotopic measurements demonstrate that enamel secretion and maturation waves advance at nonlinear rates with distinct geometries. Final enamel isotopic composition may be influenced by isotopic shifts during enamel maturation from amorphous precursors. We combine these observations to produce a Bayesian inverse model for reconstructing water δ18O inputs from tooth isotopic measurements. The system accurately reproduces the controlled switch of the experimental animal and reveals transient documented meteorological events that were unplanned during the experiment. A simulation approach shows that given appropriate priors and search methodologies, this system also reconstructs precipitation histories at different latitudes with striking fidelity. We show that in some contexts even simple sampling approaches (i.e. 1D transects) can yield accurate reconstructions of seasonality. Finally, we refine our mineralization model further by exploring the possible extent of isotopic resetting during mineral phase transitions. This work demonstrates that tooth isotopic measurements can be employed to reconstruct past seasonal isotopic variation in rainfall quantitatively, allowing exploration of the relationships among climate, earth history and evolution.

U-Pb geochronology of monazite in Precambrian tuffs reveals depositional and metamorphic histories

Uranium-lead geochronology of zircon in felsic tuffs plays a key role in the development of chronostratigraphic frameworks for sedimentary successions. This is particularly true for Precambrian basins, where biostratigraphy is of limited use for age determination or stratigraphic correlation. Although zircon is widely used to date tuffs, it can yield null results due to the presence of xenocrystic populations or isotopic resetting. Other potential U-Pb chronometers, such as monazite, which also crystallize from felsic magmas, are largely unreported from felsic tuff layers. Consequently, there has been a lack of studies to evaluate the potential of monazite for U-Pb isotope geochronology of tuffs. We present results of in situ U-Pb ion microprobe dating of monazite that co-exists with zircon in felsic tuffs from two Precambrian basins: the Earaheedy Basin (Frere Formation) in Western Australia and the Bushveld Basin (Lephala Formation) in southern Africa. We show that 207Pb/206Pb ages from monazite in felsic tuffs from the Frere Formation (1891 ± 9 Ma) and the Lephala Formation (2307 ± 9 Ma) are identical to zircon ages from the respective tuffs. Also, monazite in the Bushveld tuff preserves additional information, including a chronological fingerprint of the volcanic source (2.4–2.5 Ga xenocrysts) and the timing of low-grade metamorphism (2.16 Ga overgrowths). The ca. 2.16 Ga low-grade metamorphism identified in the Bushveld Basin is reminiscent of that widely recorded in the Pilbara Craton, Western Australian, lending support to arguments for a connection between the Kaapvaal and Pilbara cratons. Igneous and low-grade metamorphic monazites are readily distinguished based on texture and chemistry. Our study demonstrates that monazite can be used to accurately date felsic tuffs, offering a powerful tool for constraining depositional and metamorphic histories of Precambrian sedimentary basins.

New constraints on genesis of the polymetallic veins at Port Radium, Great Bear Lake, Northwest Canadian Shield

The historic Eldorado U-Co-Ni-Cu-Ag veins at Port Radium are hosted by one of the arrays of northeast-trending quartz-filled brittle fault zones in the 1875–1855 Ma Great Bear magmatic zone. The veins formed in a lensoid segment of the fault, which underwent repeated reactivation that created subsidiary fractures, tensional openings, and breccia zones that were favorable for precipitation of multiple stages of ore minerals. The timing of ore precipitation is constrained by two swarms of diabase intrusions. The older ca. 1740 Ma Cleaver dikes predate the polymetallic mineralization and deposition of Mesoproterozoic strata of Hornby Bay Group. The ca. 1590 Ma Western Channel sheets postdate the main ore stages in the veins and intrude the lower strata of the Hornby Bay Group.While diabase intrusions constrain ore precipitation to 1740–1590 Ma, in situ U-Pb analyses of fine-grained uraninite record isotopic resetting at 1453 ± 18 Ma. The δ18O compositions of all uraninite stages range from −35.0 to −27.4 per mil, and reflect an overprint by late meteoric fluids. Chondrite-normalized rare earth element data for uraninite produce bell-shaped patterns centered on Sm-Dy, with slight negative Eu anomalies. The age constraints imposed by the dikes, δ18O values and REE signatures of the early U and Co-Ni sulfarsenide stages indicate that the U and base metal mineralization at Port Radium is akin to the basement-hosted, polymetallic unconformity-related U deposits in the coeval Athabasca and Thelon basins. The 1453 Ma isotopic resetting builds to the growing body of evidence for a major event in Laurentia at 1.4 Ga while the youngest Ag-Bi stage at Port Radium was likely related to intrusion of the Western Channel diabase.

Geobody architecture, genesis and petrophysical characteristics of the Budakalász travertines, Buda Hills (Hungary)

Subsurface Pre-salt Lower Cretaceous reservoir systems encountered offshore Brazil and Angola that consist of porous continental carbonates are difficult to access because of the limited core material that is under concession. Therefore, it is important to study comparable continental carbonate analogues, such as travertines and lacustrine carbonates, that potentially possess similar porosity and permeability characteristics. The Budakalasz Pleistocene travertines (Buda Hills, Hungary) have been studied from a sedimentological, geochemical and reservoir properties point of view in order to understand their formation, petrophysical properties and 3D reservoir architecture. The three-dimensional geobody architecture of the Budakalasz travertines illustrates the potential complexity of kilometre scale continental carbonate systems. Heterogeneous low angle sloping travertine lobes consisting of terrace slope, smooth slope and reed facies, are covered by a lime mudstone dominated, gastropod- and charophyte-rich marsh-pool facies. The observed facies represent a change from a subaerial travertine to a palustrine to lacustrine system, reflecting the ceasing of the system due to tectonic uplift. The dominant paleo-flow direction of the sloping lobes was towards the Danube depression, with several subordinate flow systems identified. The SrCO isotope geochemical signatures reflect travertine precipitation at ambient to superambient temperatures from meteoric derived fluids with a mixed CO2 origin of the marine carbonate substrate rocks, a potential atmospheric and a soil-derived component. Although the uniform signatures of the stable oxygen and carbon isotopes, in addition to petrographic observations suggest partial diagenetic isotopic resetting, the primary isotope trends seem to have been preserved. A reservoir-oriented facies evaluation in the three-dimensional geobody frame of the Budakalasz carbonates based on porosity and permeability core plug analyses reveals their heterogeneous nature. Terrace, smooth slope and marsh-pool facies have considerable porosities of 5–15%, while the porosity of the reed facies may reach up to 27%. Permeability of all facies is strongly anisotropic, mainly controlled by a better connectivity along layer-parallel primary pores. The reconstruction of the 3D geobody architecture of the Budakalasz lobe complex coupled to its geochemical and petrophysical properties provides a unique dataset that contributes in understanding fossil travertine systems.

Tracing the fluid source of heavy REE mineralisation in carbonatites using a novel method of oxygen-isotope analysis in apatite: The example of Songwe Hill, Malawi

Stable (C and O) isotope data from carbonates are one of the most important methods used to infer genetic processes in carbonatites. However despite their ubiquitous use in geological studies, it is suspected that carbonates are susceptible to dissolution-reprecipitation and isotopic resetting, especially in shallow intrusions, and may not be the best records of either igneous or hydrothermal processes. Apatite, however, should be much less susceptible to these resetting problems but has not been used for O isotope analysis. In this contribution, a novel bulk-carbonatite method for the analysis of O isotopes in the apatite PO4 site demonstrates a more robust record of stable isotope values. Analyses of apatite from five carbonatites with magmatic textures establishes a preliminary Primary Igneous Apatite (PIA) field of δ18O=+2.5 to +6.0‰ (VSMOW), comparable to Primary Igneous Carbonatite (PIC) compositions from carbonates.Carbonate and apatite stable isotope data are compared in 10 carbonatite samples from Songwe Hill, Malawi. Apatite is heavy rare earth element (HREE) enriched at Songwe and, therefore, oxygen isotope analyses of this mineral are ideal for understanding HREE-related mineralisation in carbonatites. Carbonate C and O isotope ratios show a general trend, from early to late in the evolution, towards higher δ18O values (+7.8 to +26.7‰, VSMOW), with a slight increase in δ13C (−4.6 to −0.1‰, VPDB). Oxygen isotope ratios from apatite show a contrary trend, decreasing from a PIA field towards more negative values (+2.5 to −0.7‰, VSMOW). The contrasting results are interpreted as the product of the different minerals recording fluid interaction at different temperatures and compositions. Modelling indicates the possibility of both a CO2 rich fluid and mixing between meteoric and deuteric waters. A model is proposed where brecciation leads to depressurisation and rapid apatite precipitation. Subsequently, a convection cell develops from a carbonatite, interacting with surrounding meteoric water. REE are likely to be transported in this convection cell and precipitate owing to decreasing salinity and/or temperature.

“Satellite monazites” in polymetamorphic basement rocks of the Alps: Their origin and petrological significance

Allanite-fluorapatite reaction coronas around monazite are abundant in metamorphic rocks. We report here special cases where a new generation of “satellite” monazite grains formed within these coronas. Using examples from different P-T regions in the eastern Alps, we examine the origin and the petrological significance of this complex mineralogical association by means of the electron microprobe utilizing Th-U-Pb monazite dating and high-resolution BSE imaging. Satellite monazite grains form when a monazite-bearing rock is metamorphosed in the allanite stability field (partial breakdown of first generation monazite to fluorapatite plus allanite), and is then heated to temperatures that permit a back reaction of fluorapatite plus allanite to secondary satellite monazite grains surrounding the remaining original first generation monazite. Depending on the whole-rock geochemistry satellite monazites can form under upper greenschist- as well as amphibolite-facies conditions. In each of the three examples focused on here, the inherited core monazite was resistant to recrystallization and isotopic resetting, even though in one of the samples the metamorphic temperatures reached 720 °C. This shows that in greenschist- and amphibolite-facies polymetamorphic rocks, individual grains of inherited and newly formed monazite can and often will occur side by side. The original, inherited monazite will preferentially be preserved in low-Ca, high-Al lithologies, where its breakdown to allanite plus fluorapatite is suppressed. Conversely, a medium- or high-Ca, monazite-bearing rock will become particularly fertile for secondary monazite regrowth after passing through a phase of strong retrogression in the allanite stability field. Based on this knowledge, specific sampling strategies for monazite dating campaigns in polymetamorphic basement can be developed.

Rapid extensional unroofing of a granite–migmatite dome with relics of high-pressure rocks, the Podolsko complex, Bohemian Massif

AbstractThe Podolsko complex, Bohemian Massif, is a high-grade dome that is exposed along the suprastructure–infrastructure boundary of the Variscan orogen and records snapshots of its protracted evolution. The dome is cored by leucocratic migmatites and anatectic granites that enclose relics of high- to ultrahigh-pressure rocks and is mantled by biotite migmatites and paragneisses whose degree of anatexis decreases outwards. Our new U–Pb zircon ages indicate that the leucocratic migmatites were derived from Early Ordovician (c. 480 Ma) felsic igneous crust; the same age is inferred for melting the proto-source of the metapelitic migmatites. The relics of high- to ultrahigh-pressure rocks suggest that at least some portions of the complex witnessed an early Variscan subduction to mantle depths, followed by high-temperature anatexis and syntectonic growth of the Podolsko dome in the middle crust at c. 340–339 Ma. Subsequently, the dome exhumation was accommodated by crustal-scale extensional detachments. Similar c. 340 Ma ages have also been reported from other segments of the Variscan belt, yet the significance of this tectonothermal event remains uncertain. Here we conclude that the 340 Ma age post-dates the high-pressure metamorphism; the high temperatures required to cause the observed isotopic resetting and new growth of zircon were probably caused by heat input from the underlying mantle and, finally, the extensional unroofing of the complex requires a minimum throw of about 8–10 km. We use this as an argument for significant early Carboniferous palaeotopography in the interior of the Variscan orogen.

The Nolans Bore rare-earth element-phosphorus-uranium mineral system: geology, origin and post-depositional modifications

Nolans Bore is a rare-earth element (REE)-U-P fluorapatite vein deposit hosted mostly by the ~1805 Ma Boothby Orthogneiss in the Aileron Province, Northern Territory, Australia. The fluorapatite veins are complex, with two stages: (1) massive to granular fluorapatite with inclusions of REE silicates, phosphates and (fluoro)carbonates, and (2) calcite-allanite with accessory REE-bearing phosphate and (fluoro)carbonate minerals that vein and brecciate the earlier stage. The veins are locally accompanied by narrow skarn-like (garnet-diopside-amphibole) wall rock alteration zones. SHRIMP Th-Pb analyses of allanite yielded an age of 1525 ± 18 Ma, interpreted as the minimum age of mineralisation. The maximum age is provided by a ~1550 Ma SHRIMP U-Pb age for a pegmatite that predates the fluorapatite veins. Other isotopic systems yielded ages from ~1443 to ~345 Ma, implying significant post-depositional isotopic disturbance. Calculation of initial eNd and 87Sr/86Sr at 1525 Ma and stable isotope data are consistent with an enriched mantle or lower crust source, although post-depositional disturbance is likely. Processes leading to formation of Nolans Bore began with north-dipping subduction along the south margin of the Aileron Province at 1820–1750 Ma, producing a metasomatised, volatile-rich, lithospheric mantle wedge. About 200 million years later, near the end of the Chewings Orogeny, this reservoir and/or the lower crust sourced alkaline low-degree partial melts which passed into the mid- and upper-crust. Fluids derived from these melts, which may have included phosphatic melts, eventually deposited the Nolans Bore fluorapatite veins due to fluid-rock interaction, cooling, depressurisation and/or fluid mixing. Owing to its size and high concentration of Th (2500 ppm), in situ radiogenic heating caused significant recrystallisation and isotopic resetting. The system finally cooled below 300 °C at ~370 Ma, possibly in response to unroofing during the Alice Springs Orogeny. Surface exposure and weathering of fluorapatite produced acidic fluids and intense, near-surface kaolinitised zones that include high-grade, supergene-enriched cheralite-rich ores.

Zirconolite, zircon and monazite-(Ce) U-Th-Pb age constraints on the emplacement, deformation and alteration history of the Cummins Range Carbonatite Complex, Halls Creek Orogen, Kimberley region, Western Australia

In situ SHRIMP U-Pb dating of zirconolite in clinopyroxenite from the Cummins Range Carbonatite Complex, situated in the southern Halls Creek Orogen, Kimberley region, Western Australia, has provided a reliable 207Pb/206Pb age of emplacement of 1009 ± 16 Ma. Variably metamict and recrystallised zircons from co-magmatic carbonatites, including a megacryst ~1.5 cm long, gave a range of ages from ~1043–998 Ma, reflecting partial isotopic resetting during post-emplacement deformation and alteration. Monazite-(Ce) in a strongly foliated dolomite carbonatite produced U-Th-Pb dates ranging from ~900–590 Ma. Although the monazite-(Ce) data cannot give any definitive ages, they clearly reflect a long history of hydrothermal alteration/recrystallisation, over at least 300 million years. This is consistent with the apparent resetting of the Rb-Sr and K-Ar isotopic systems by a post-emplacement thermal event at ~900 Ma during the intracratonic Yampi Orogeny. The emplacement of the Cummins Range Carbonatite Complex probably resulted from the reactivation of a deep crustal structure within the Halls Creek Orogen during the amalgamation of Proterozoic Australia with Rodinia over the period ~1000–950 Ma. This may have allowed an alkaline carbonated silicate magma that was parental to the Cummins Range carbonatites, and generated by redox and/or decompression partial melting of the asthenospheric mantle, to ascend from the base of the continental lithosphere along the lithospheric discontinuity constituted by the southern edge of the Halls Creek Orogen. There is no evidence of a link between the emplacement of the Cummins Range Carbonatite Complex and mafic large igneous province magmatism indicative of mantle plume activity. Rather, patterns of Proterozoic alkaline magmatism in the Kimberley Craton may have been controlled by changing plate motions during the Nuna–Rodinia supercontinent cycles (~1200–800 Ma).

Zircon reconnaissance dating of Proterozoic gneisses along the Kunene River of northwestern Namibia

The northern margin of the Epupa Metamorphic Complex (EMC) along the Kunene River in NW Namibia is one of the geologically least known terranes in Africa because of its remoteness and difficult accessibility. We report field relationships and reconnaissance zircon ages for granitoid gneisses from a 120km foot-traverse along the Kunene River between the Ruacana Falls in the east and Marienfluss in the west. Most rocks are late Palaeoproterozoic in age and correlate well with similar rocks of the EMC farther south in Kaokoland (1757–1835Ma, one sample 1861Ma) and with granitoid rocks in the Kamanjab Inlier, some 400km SE of the Kunene River (1801–1836Ma). All these rocks constitute a large magmatic province on the southwestern margin of the Congo Craton, whose protoliths are possibly related to arc magmatism during the Africa-wide so-called Eburnian event (ca. 2000±200Ma). However, there are also Mesoproterozoic granitoids, 1520–1530Ma in age, whose tectonic significance remains uncertain but which seem to document a thermal event also seen in high-grade metamorphism and isotopic resetting in this part of SW Africa.