Irrigation Water Quality Research Articles

Spatial distribution of physicochemical parameters and drinking and irrigation water quality indices in the Jhelum River, Pakistan.

Sustainable management of river systems is a serious concern, requiring vigilant monitoring of water contamination levels that could potentially threaten the ecological community. This study focused on the evaluation of water quality in the Jhelum River (JR), Azad Jammu and Kashmir, and northern Punjab, Pakistan. To achieve this, 60 water samples were collected from various points within the JR Basin (JRB) and subjected to a comprehensive analysis of their physicochemical parameters. The study findings indicated that the concentrations of physicochemical parameters in the JRB water remained within safety thresholds for both drinking and irrigation water, as established by the World Health Organization and Pakistan Environmental Protection Agency. These physicochemical parameters refer to various chemical and physical characteristics of the water that can have implications for both human health (drinking water) and agricultural practices (irrigation water). The spatial variations throughout the river course distinguished between the upstream, midstream, and downstream sections. Specifically, the downstream section exhibited significantly higher values for physicochemical parameters and a broader range, highlighting a substantial decline in its quality. Significant disparities in mean values and ranges were evident, particularly in the case of nitrates and total dissolved solids, when the downstream section was compared with its upstream and midstream counterparts. These variations indicated a deteriorating downstream water quality profile, which is likely attributable to a combination of geological and anthropogenic influences. Despite the observed deterioration in the downstream water quality, this study underscores that the JRB within the upper Indus Basin remains safe and suitable for domestic and agricultural purposes. The JRB was evaluated for various irrigation water quality indices. The principal component analysis conducted in this study revealed distinct covariance patterns among water quality variables, with the first five components explaining approximately 79% of the total variance. Recommending the continued utilization of the JRB for irrigation, we advocate for the preservation and enhancement of water quality in the downstream regions.

Seed germination and seedling growth performance of berseem clover (Trifolium alexandrinum L.) populations under different irrigation water sources

Irrigation water quality is closely associated with seed germination, however, information on the effect of water quality on berseem seed germination and seedling establishment is deficient. The present study evaluated the effects of using different irrigation water quality (indicative of local field practices); including distilled water (as control), canal water, tube well water and a mixture of canal and tube well water in a 50:50 ratio on three populations of berseem clover viz. cv. Agaitti Berseem-2002 (AB-2002) and two local landraces exchanged between farmers (LBF1) or available from local markets (LBM1). Seed germination percentage (GP) ranged from 89.5% to 99.5%, while the emergence energy four days after sowing (EE4DAS) ranged from 42.7% to 77.6%. The use of tube well water alone or in combination with canal water produced the highest GP (98.5%), EE4DAS (77.6%), germination rate (GR; 3.5 %/day), emergence index (EI; 13.8), shoot length (40.7mm), root length (20.9mm), root to shoot ratio (0.48), seedling vigour index (5835), shoot fresh and dry weights (135.7mg and 6.5mg) and root fresh and dry weights (58.8mg and 1.6mg), respectively. Moreover, all the pair-combination treatments between the water source and measured variables of using tube well water showed a strong positive correlation with increasing seedling growth parameters. The results further demonstrated that the seed genotypes significantly affected (P < 0.05) the studied parameters, with the AB-2002 population overall performed better in most seed germination and emergence parameters. However, the LBF1 seed population was found to be more robust in seedling growth and development traits.

GROUNDWATER QUALITY ASSESSMENT FOR RESIDENTIAL AND IRRIGATION PURPOSES: A CASE STUDY OF FUTUK AND ITS ENVIRONS, NORTHERN BENUE TROUGH, NORTHEAST NIGERIA

This research assesses the suitability of groundwater quality in the region for residential and agricultural use. To evaluate the water quality for domestic purposes, 15 samples of groundwater were taken and tested for various physicochemical parameters including pH, electrical conductivity (EC), total dissolved solids (TDS), calcium (Ca), magnesium (Mg), sodium (Na), potassium (K), sulfate (SO4), chloride (Cl), bicarbonate (HCO3), carbonate (CO3), and nitrate (NO3). The quality of irrigation water was evaluated using several parameters: permeability index (PI), sodium absorption ratio (SAR), total hardness (TH), residual sodium carbonate (RSC), and water quality index (WQI). Piper diagrams, Gibbs diagrams, and the chloro-alkaline index were used to determine groundwater facie classification and ion exchange mechanisms. When compared to the WHO 2011 standard, the physiochemical parameters are within the appropriate limits, with the exception of EC and NO3, which revealed excessive values in some samples. All of the measured parameters are suitable for irrigation activities. According to the Kelly index, there is just one sample that is inappropriate for irrigation. The predominant groundwater type in the area is calcium chloride, with sodium chloride constituting the second most common groundwater facies. The hydrochemical mechanism that regulates the local groundwater chemistry is reverse ion exchange. This indicates a positive index, resulting from the exchange of sodium (Na) and potassium (K) in the groundwater with calcium (Ca) and magnesium (Mg) in the aquifer components.

Investigation of the impact of municipal solid waste disposal site leachate on surface water resources in Hosanna Town, Ethiopia.

Surface water resources are the most precious, yet they are also the most vulnerable to pollution. Consequently, maintaining the sustainability of water supplies is critical for livestock support to achieve SDG goals. Landfill leachate poses a significant threat to water resources in developing countries. This study aims to determine how the Hosanna town landfill site affects the Jewie River by analysing the quality of the Alela and Ajew streams and the landfill leachate in both wet and dry seasons. Furthermore, assess the suitability of the water quality for agricultural purposes. The leachate pollution index (LPI), Canadian Council Member of the Environment Water Quality Index (CCMEWQI), and irrigation water quality indices (IWQI) were computed for both seasons using two composite leachate samples and five flow-pace composite river samples. In the wet season, the leachate pollution indices for L1 and L2 ranged from 20.87 to 22.47, respectively. During the dry season, the leachate pollutant index of L1 and L2 was found to be 24.42 and 27.98. Only the Ajew River stream was affected during the dry season because the landfill site is only 46m away. Both the Ajew and Alela River streams are infested during the rainy season. Irrigation index concentrations revealed that the river water is suitable for cultivation. The early stages of landfill waste maturation are evident from the LPI results. Relocating the dump site is necessary to safeguard water resources because leachate has entered the river streams.

Hydrogeochemical signatures of spring water in geologically diverse terrains: a case study of Southern Western Ghats, India.

Out of 5 million Indian spring water systems, a few were characterised for hydrochemistry and freshwater potential. The present study focuses on analysing the hydrochemistry, discharge, and drinking/irrigation water quality of both cold and thermal spring clusters namely Southern Kerala Springs (SKS) and Dakshina Kannada Springs (DKS) of Southern Western Ghats, India. Currently, eleven springs from SKS and ten from DKS including one thermal spring (TS) with temperature ranges from 34 to 37°C were considered. The study revealed that cold springs (CS) of SKS are Na-Cl type, while the thermal and cold-water springs in DKS are Na-HCO3 and mixing water type, respectively. Two distinct mechanisms predominantly define the hydro-chemical composition of the springs-SKS are influenced by precipitation, whereas DKS is likely by chemical weathering processes. While comparing the major ions and saturation indices of thermal springs (TS), it is evident that silicate minerals predominantly affect the chemical composition of water. CaCO3- is oversaturated in TS water and tends to precipitate as a scale layer. PCA showed that both geogenic and anthropogenic factors influence water chemistry. WQI categorized the CS in both the clusters are in the "Excellent" rank as compared to TS. Irrigation water quality signifies that the cold springs are only suitable for irrigation. Moreover, it is evident from the discharge that both SKS and DKS were rainfed in nature. Discharge monitoring designated that the CS could augment drinking water supplies in the nearby regions indicating the necessity of conservation and sustainable use considering future freshwater scarcity.

Sustaining Irrigation Supplies through Immobilization of Groundwater Arsenic In Situ.

Geogenic arsenic (As) in groundwater is widespread, affecting drinking water and irrigation supplies globally, with food security and safety concerns on the rise. Here, we present push-pull tests that demonstrate field-scale As immobilization through the injection of small amounts of ferrous iron (Fe) and nitrate, two readily available agricultural fertilizers. Such injections into an aquifer with As-rich (200 ± 52 μg/L) reducing groundwater led to the formation of a regenerable As reactive filter in situ, producing 15 m3 of groundwater meeting the irrigation water quality standard of 50 μg/L. Concurrently, sediment magnetic properties were markedly enhanced around the well screen, pointing to neo-formed magnetite-like minerals. A reactive transport modeling approach was used to quantitatively evaluate the experimental observations and assess potential strategies for larger-scale implementation. The modeling results demonstrate that As removal was primarily achieved by adsorption onto neo-formed minerals and that an increased adsorption site density coincides with the finer-grained textures of the target aquifer. Up-scaled model simulations with 80-fold more Fe-nitrate reactants suggest that enough As-safe water can be produced to irrigate 1000 m2 of arid land for one season of water-intense rice cultivation at a low cost without causing undue contamination in surface soils that threatens agricultural sustainability.

Appraising water resources for irrigation and spatial analysis based on fuzzy logic model in the tribal-prone areas of Bangladesh.

The lack of quality water resources for irrigation is one of the main threats for sustainable farming. This pioneering study focused on finding the best area for farming by looking at irrigation water quality and analyzing its location using a fuzzy logic model on a Geographic Information System platform. In the tribal-prone areas of Khagrachhari Sadar Upazila, Bangladesh, 28 surface water and 39 groundwater samples were taken from shallow tube wells, rivers, canals, ponds, lakes, and waterfalls. The samples were then analyzed for irrigation water quality parameters like electrical conductivity (EC), total dissolved solids (TDS), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium bicarbonate (RSBC), magnesium hazard ratio (MHR), Kelley's ratio (KR), and permeability index (PI). Fuzzy Irrigation Water Quality Index (FIWQI) was employed to determine the irrigation suitability of water resources. Spatial maps for parameters like EC, KR, MH, Na%, PI, SAR, and RSBC were developed using fuzzy membership values for groundwater and surface water. The FIWQI results indicate that 100% of the groundwater and 75% of the surface water samples range in the categories of excellent to good for irrigation uses. A new irrigation suitability map constructed by overlaying all parameters showed that surface water (75%) and some groundwater (100%) in the northern and southwestern portions are fit for agriculture. The western and central parts are unfit for irrigation due to higher bicarbonate and magnesium contents. The Piper and Gibbs diagram also indicated that the water in the study area is magnesium-bicarbonate type and the primary mechanism of water chemistry is controlled by the weathering of rocks, respectively. This research pinpoints the irrigation spatial pattern for regional water resource practices, identifies novel suitable areas, and improves sustainable agricultural uses in tribal-prone areas.

Assessment of Soil and Water Salinity Status of Bitata Small Scale Irrigation Scheme of Guji Zone Oromia, Ethiopia

The Soil salinity, sodicity and water logging are becoming an emerging challenge for the irrigation development. So, assessments of irrigation schemes are very important to see the problems they have. The assessment of soil and water salinity status of Bitata small scale irrigation scheme of Guji Zone, Oromia region was done to identify, analyze and map salinity level using Geographic information System, the chemical properties of the soil was done at laboratory for samples analysis. After, spatial analyst and interpolation by Inverse distance Weight and Re-class the soil analyzed. Then the area of influence of the points was determined for the selected parameters and the results of investigation shows the majority of sample results are non-saline non sodic, even if, the samples were less, the sodicity problems occur at the study area on surface soil by considering three parameters at once and non-saline and non-sodic for profile soil. And when considering individual parameters of surface soil the results shows slightly saline depends on Electrical conductivity of saturation extracts, considering the exchangeable sodium percentage slightly to extremely sodic results was observed. And the results of irrigation water quality shows Very high Saline and Low Sodicity. The finding of the study recommends intervention of sodicity for surface soil and salinity and sodicity for water source used for irrigation is very important to control the expansions of it to the whole area of the scheme and to minimize the risk of salinity and sodicity problems of the water source used for irrigation. Management techniques that improve soil fertility such as crop rotations, manuring, fallow periods, proper management of crop residues, vermicomposting and leguminous cover crops and water-saving irrigation technologies suitable to the land of the area are the best options. And similar work is necessary to get additional information of the study areas because of the results of surface and profile soil and water source used for irrigation were far apart from each other.

Enhancement in Tomato Yield and Quality Using Biochar Amendments in Greenhouse under Salinity and Drought Stress.

Enhancing saline water productivity in arid regions is essential for sustainable agriculture. Adding biochar can improve the quantity and quality of tomato yield under higher levels of salinity and lower levels of irrigation. The experiment aimed to evaluate the effects of biochar on enhancing tomato fruit quality and yield under salinity and drought stress. The experiment combines two treatments for irrigation water quality (0.9 and 2.3 dS m-1), four irrigation levels (40, 60, 80, and 100%) of crop evapotranspiration (ETc), and the addition of 5% of biochar to treated soil (BC5%) and untreated soil (BC0%). The results showed that the decrease in the water quality and irrigation levels negatively impacted the yield and properties of tomato fruit, while 5% of biochar application positively improved the yield. Adding biochar decreased the tomato yield by 29.33% and 42.51% under lower-saline-irrigation water than the control, negatively affecting the fruit's physical parameters and mineral content. In contrast, adding biochar and irrigating with saline water at 60% of ETc improved the firmness and quality characteristics of the fruit by 56.60%, 67.19, 99.75, and 73.57% for vitamin C (VC), total titratable acidity (TA), total soluble solids (TSS), and total sugars (TS), respectively, compared to the control, and also reduced the sodium content of the fruits under all irrigation levels compared to untreated plants by biochar. Generally, biochar with saline water under deficit irrigation with 80 and 60% of ETc could be an excellent strategy to enhance the qualitative characteristics of tomato fruits and save approximately 20-40% of the applied water.

Groundwater quality appraisal and zone mapping for agriculture utilities in Wadi Fatima, Saudi Arabia using water quality indices, boron and trace metals.

Groundwater quality in Wadi Fatimah is evaluated and demarcated for agriculture utilities using comprehensive approaches namely, international standards, agricultural water quality (AWQ) indices, irrigation water quality index (IWQI), and trace metals. Groundwater samples were collected (n = 59) and analysed for EC, pH, major and minor ions and trace metals. According to FAO recommendations, 42% of samples (EC > 3000 µS/cm) are inappropriate for agricultural uses. AWQ indices including salinity hazard, Kelly's ratio and Na% show that 50%, 19% and 37% of samples, respectively, are unsuitable for agricultural uses. USSL classification reveals that groundwater is preferable only for high-permeability soils and salt-tolerant crops. IWQI suggests that 88% of samples are moderately usable for agriculture. The interrelationship between water salinity and crop yield justified that 73%, 59%, 51% and 25% of samples are desirable to yield 90% in date palm trees, sorghum, rice and citrus fruits, respectively. Groundwater is appropriate for date palm trees except in downstream regions. Boron concentration suggests that 52%, 81% and 92% of samples are suitable for sensitive, semi-tolerant and tolerant crops, respectively. Groundwater in the central part (suitable for sensitive crops), central and upstream regions (semi-tolerant crops) and all regions except downstream (tolerant crops) are suitable for cultivation. Trace metals contents illustrate that 36%, 34%, 22%, 8%, 5% and 100% of samples are inappropriate for agriculture due to high concentrations of Cr, Cu, Ni, V, Mn and Mo, respectively in the groundwater. Further, AWQ indices, IWQI, USSL classifications and trace metals ensure that groundwater in the downstream, and a few pockets in the upstream are unfit for agricultural uses. This study recommends that groundwater in this basin is more suitable for tolerant crops (ie. date palm, sorghum) followed by semi-tolerant and sensitive crops.

The Impact of Salinity in the Irrigation of a Wild Underutilized Leafy Vegetable, Sonchus oleraceus L.

Introducing non- or under-utilized crops to cultivation generates benefits such as biodiversity enrichment, supporting mitigation actions towards climate change-induced effects. The salinization of soil and water supplies is progressively disrupting natural habitats and food production, especially in regions such as the Mediterranean. Sonchus oleraceus L. is a Mediterranean wild leafy green with nutritional and medicinal properties. This study's purpose was to determine whether salinity affects the growth, quality, and nutrient composition of Sonchus oleraceus L. In an unheated plastic greenhouse, seedlings were transplanted in pots filled with perlite and irrigated with a nutrient solution with no NaCl added (the control, C) or with the addition of 40, 60, 80, and 100 mM of NaCl (treatments S4, S6, S8, and S10, respectively). The leaf and root growth, leaf quality, and the nutrient composition of leaves and roots were determined. Regarding the results, growth was mainly affected at high salinity levels (S8 and S10), with no observed effects of salinity on the determined quality parameters. The nutrient composition was variably affected by salinity in leaves but not in roots (except in the case of Na and the K/Na ratio). Sonchus oleraceus L. showed a general relative tolerance in moderate salinity levels (40 and 60 mM of NaCl), suggesting potential commercial exploitation of the species in areas where the quality of irrigation water is low. However, the health effects of consuming this species grown under salinity stress need to be studied in future research.

English

The issue of water scarcity in Pakistan is a significant challenge which is due to exacerbated population growth as well as increase in freshwater demand. The application of wastewater for irrigation, especially in semi-urban regions, can indeed be a practical solution due to its ready availability and affordability. While wastewater can serve as a valuable resource in water-scarce regions, its use must be carefully managed to minimize potential risks to plant health, soil fertility, and human well-being. A study was conducted aiming to assess the seasonal changes in physicochemical properties of irrigated wastewater and their influence on morphological, physiological and biochemical responses of sugarcane (Saccharum officinarum L.). Sugarcane plants were grown for consecutive two years in peri-urban agricultural areas near the water channels. Sugarcane plants were grown in two different fields and irrigation of the crop was done with wastewater and freshwater, respectively. Water (wastewater and freshwater) and plant samples were collected four times in a year in different seasons (winter, spring, summer, fall) for two consecutive years (2016-2017). All the collected data had been subjected to multivariate analysis of variance (MANOVA) for assessing the impact of seasonal variation on plant responses under the influence of irrigated wastewater. The findings from the study highlighted the complex relationship between wastewater irrigation and the physiological responses of sugarcane plants. The observed increase in antioxidant activities of wastewater irrigated plants compared to freshwater irrigated plants suggested that sugarcane may undergo biochemical adjustments to cope with the stress induced by the contaminants present in the wastewater. Moreover, the significant differences in plant mineral contents across different seasons were observed which indicated the dynamic nature of nutrient availability in the irrigation water and its impact on plant growth and development. We concluded that wastewater irrigation can affect the potential output of the agriculture sector by altering plant physiology which underscores the importance of considering the quality of irrigation water in agricultural practices. For future prospectives, the study can be extended to other crops to develop comprehensive strategies for sustainable agriculture.

Transfer of heavy metals from soil to vegetables: A comparative assessment of different irrigation water sources

This study aimed to assess the transfer factor (TF) of heavy metals (HMs) from soil to commonly consumed vegetables irrigated with different water sources. The field study covered 36 m2 of agricultural land in Kermanshah province, Iran, divided into nine equal-sized plots. Coriander, basil, and radish were the three types of vegetables cultivated and subjected to irrigation over two months, utilizing three different water sources: treated wastewater effluent (TWE), river water (RW), and well water + nitrogen fertilizer (WWF). After the irrigation and harvesting stages, soil samples from the cultivation area and harvested vegetables were collected. These samples underwent analysis using the ICP-OES method to assess HM levels and subsequent calculation of the TF of HMs from soil to plants. The results revealed that the TF levels indicated plants' relatively weak response (TF < 1) to the absorption of HMs. For non-toxic elements (Mn, Fe, Zn, Cu, Ni), TF values were generally higher than those for toxic elements (Cd, As, Pb) across all three vegetable types and irrigation treatments. The study's findings suggest that the TF of HMs in the studied vegetables varied based on the irrigation source and vegetable type. Various factors, including the type of irrigation source and vegetable, influenced the TF of HMs, each having different impacts on the transfer rate of each HM. The study highlights the importance of monitoring irrigation water and soil quality to prevent the accumulation of HMs in cultivated vegetables, thereby mitigating potential risks to human health.

The Effect of Senegal River Irrigation Water Quality on Soil Salinization: A Study of the Main Canal of the M’Pourie Plain in Mauritania

In this study, the Senegal River, being the main source of water, plays a crucial role in the area’s agricultural development. Irrigation on the M’Pourie plain using water from the Senegal River is carried out without any prior sanitation control. An evaluation of the quality of irrigation water and its impact on soil salinization in different agricultural plots soil salinity is crucial for the effective utilization of traditional irrigation water over extended periods. Comprehensive physico-chemical analyses were conducted across nine locations on the M’Pourie plain in Rosso during the dynamic seasons of 2021-2023. Nevertheless, a relatively small number of studies have employed soil salinity indexing methods to examine the consequences of river irrigation on soil salinity. The analysis and interpretation of the results obtained were based both on classic methods (average and correlations) and more advanced techniques such as principal component analysis (PCA) and the Piper diagram which allow characterization and a spatial typology of water. Analysis of the Piper diagram highlights the distinction between two groups of water, weakly and moderately mineralized, ranging from 52.22 μS.cm-1 in the dry season to 72.22 μS.cm-1 in the rainy season, presenting a sodium-potassium bicarbonate facies The variability of irrigation water supplies, proves to be important in the functioning of an agro-systems. Two modes of operation have become individualized: the dry phase mode, characterized by very strong mineralization of the water linked to a significant load of dissolved elements, and the wet phase mode, whose water quality is poorly mineralized but shows the impact that its irrigation water can represent in the loading of organic and mineral pollution and the need for strict control of these waters upstream before their agricultural use. The results of this study show the absence of risks of soil salinization in relation to the chemical nature of irrigation water and the impact of agriculture on the M’Pourie plain.

Assessment of Surface Water Quality Drain Using Various Physicochemical Parameters of Lasara Dhanola Drain, Punjab

Abstract: In this study, observations were carried out in the surface waters of Lasara Dhanola drain of Punjab within to determine water quality. The basic physicochemical variables were used to determine water quality. Taking into account the World Health Organization's drinking water standards and the water quality index (WQI) were used in determining the water quality. In addition, irrigation water quality was examined. Some of the water quality parameters exceed the recommended limit values in all at all sites. According to these values, the Lasara Dhanola drain water belongs to the 'very poor' class in terms of irrigation water quality. According to results of factor analysis, pH, temperature, electrical conductivity, suspended solid matter, biological oxygen demand, total hardness, total alkalinity, calcium, nitrate, chlorides, fluorides and dissolved oxygen are the main variables responsible for the processes in the ecosystem

Investigating the effects of surface water recharge on groundwater quality using hydrochemistry and ANFIS model: A case study Minia Governorate, Egypt

Monitoring and assessing groundwater quality and quantity lays the basis for sustainable management. Therefore, this research aims to investigate various factors that affect groundwater quality, emphasizing its distance to the primary source of recharge, the Nile River. To this end, two separate study areas have been considered, including the West and West-West of Minia, Egypt, located around 30 and 80 km from the Nile River. The chosen areas rely on the same aquifer as groundwater source (Eocene aquifer). Groundwater quality has been assessed in the two studied regions to investigate the difference in quality parameters due to the river's distance. The power of machine learning to associate different variables and generate beneficial relationships has been utilized to mitigate the cost consumed in chemical analysis and alleviate the calculation complexity. Two adaptive neuro-fuzzy inference system (ANFIS) models were developed to predict the water quality index (WQI) and the irrigation water quality index (IWQI) using EC and the distance to the river. The findings of the assessment of groundwater quality revealed that the groundwater in the west of Minia exhibits suitability for agricultural utilization and partially meets the criteria for potable drinking water. Conversely, the findings strongly recommend the implementation of treatment processes for groundwater sourced from the West-West of Minia before its usage for various purposes. These outcomes underscore the significant influence of surface water recharge on the overall quality of groundwater. Also, the results revealed the uncertainty of using sodium adsorption ratio (SAR), Sodium Percentage (Na%), and Permeability Index (PI) techniques in assessing groundwater for irrigation and recommended using IWQI. The developed ANFIS models depicted perfect accuracy during the training and validation stages, reporting a coefficient of correlation (R) equal to 0.97 and 0.99 in the case of WQI and 0.96 and 0.98 in the case of IWQI. The research findings could incentivize decision-makers to monitor, manage, and sustain groundwater.

Evaluation of treated wastewater quality from Cap-falcon plant for agriculture irrigation

Wastewater reuse is a useful tool for minimizing the amount of wastewater discharged into the environment. However, it is associated with threats to the environment and public health; consequently, effluent quality assessment is essential prior to reuse. The aim of this study is to assess the physicochemical and microbiological quality of treated wastewater from Cap Falcon wastewater treatment plant for reuse in irrigation. The suitability of treated wastewater from Cap Falcon plant for irrigation was assessed based on its composition and Algerian irrigation water quality standards. The average biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) values decrease from 316 mg/L to 21 mg/L with a mean removal efficiency of 93.0% and from 659 to 40 mg/L with removal efficiency of 93.7% respectively. For total suspended solids (TSS), the concentration at the inlet of the treatment plant is very high but reduces greatly after biological treatment with a removal efficiency over 94.5%. The physico-chemical analyses of treated wastewater samples from the storage reservoir indicated that pH varied from 6.81 to 8.20 with an average value of 7.43, which is slightly alkaline in nature. Electrical conductivity is one of the criteria used to evaluate the suitability of water for agricultural use; the average value was found less than 1500 μS/cm, indicating that the treated wastewater is considered as suitable for irrigation use. On the other hand, microbiological analyses indicate that faecal coliforms are high compared with Algerian water quality reuse standards. Furthermore, the overall quality of tertiary treated wastewater was analyzed by calculating the water quality index. The calculated index for the physicochemical and microbiological parameters was 96, which corresponds to a water quality type “very poor” signifying that this effluent can only be used for restricted irrigation practices.

Groundwater suitability assessment for irrigation and drinking purposes by integrating spatial analysis, machine learning, water quality index, and health risk model.

An in-depth understanding of nitrate-contaminated surface water and groundwater quality and associated risks is important for groundwater management. Hydrochemical characteristics and driving forces of groundwater quality and non-carcinogenic risks of nitrate were revealed by the integrated approaches of self-organizing map analysis, spatial visualization by geography information system, entropy and irrigation water quality indices, and human health risk model. Groundwater samples were categorized into two clusters by SOM analysis. Cluster I including three samples were Ca-SO4 type and cluster II of remaining 136 samples were Ca-HCO3 type. Hydrochemical compositions of two cluster samples were dominated by water-rock interaction: (1) calcite and gypsum dissolution for cluster I samples and (2) calcite dissolution, silicate weathering, and positive cation exchange for cluster II samples. Nitrate contamination occurred in both cluster I and II samples, primarily induced by agricultural nitrogen fertilizer. The EWQI results showed that 90.97% in total groundwater samples were suitable for drinking purpose, while the IWQI results demonstrated that 65.03% in total groundwater samples were appropriate for irrigation purpose. The HHR model and Monte Carlo simulation indicated that the non-carcinogenic nitrated risk was highest in children. Exposure frequency was the most sensitive factor (86.33% in total) influencing the total non-carcinogenic risk, indicated by sensitivity analysis. Compared with the two clusters of groundwater, surface water has a shorter circulation cycle and lower ion concentrations resulting in better water quality. This study can provide scientific basis for groundwater quality evaluation in other parts of the world.

Hydrogeochemical Evaluation of Groundwater Quality and Its Applicability for Various Purposes in the Drought-Prone Konso Zone, Rift Valley, Southern Ethiopia

The present study area, the Konso Zone, is in Rift Valley, Southern Ethiopia, and highly depends on rivers and groundwater for economic and social development. Water availability in this area faces multiple challenges, including scarcity, quality concerns, and seasonal variations. In the Rift Valley region, including the present study area, groundwater quality is particularly problematic due to high fluoride levels. Moreover, the high concentrations of total dissolved solids in Konso Zone groundwater pose challenges for industrial, agricultural, and drinking purposes. GIS-based spatial analysis techniques, hydrogeochemical analyses, and water quality indices were used in the current study. The evaluation of water quality involved the utilization of both groundwater quality and irrigation water quality indices. In the study area, the cations and anions exhibited a general trend with Na+ &gt; Mg2+ &gt; Ca2+ &gt; K+ &gt; Fe2+ and HCO3− &gt; Cl−, SO42− &gt; NO3− &gt; F−. Multiple water types were identified within the research area, including Na-HCO3, Ca-Na-HCO3, NaCl, and Ca-Mg/Cl, with Na-HCO3 being the most prevalent. The formation of the NaHCO3 water type is primarily attributed to ion exchange processes, with siliciclastic aquifers being linked to cation exchange in sodium bicarbonate groundwater. Total Dissolved Solids and SO42− contaminants significantly impact the water quality, resulting in deterioration. Gibbs’s figure indicates that 50% of the water samples were found where rocks were weathered, demonstrating the importance of water-rock interactions in groundwater composition. Water samples containing more fluoride than the WHO’s limit of 1.50 mg/L were deemed unsuitable for consumption. Regarding irrigation suitability, most water samples from the Konso area were acceptable, except for the sodium percentage in 66.6% of the samples, which was unsuitable for irrigation. There are 26.67% of samples that are of questionable quality, 66.67% that are deemed inappropriate, and 26.67% that are deemed unacceptable. These findings underscore the pressing need for comprehensive strategies and interventions to address water quality issues in the Konso Zone, emphasizing the critical importance of monitoring and managing groundwater resources to ensure sustainable and safe water access for various regional uses.

Water Quality from Natural Sources for Sustainable Agricultural Development Strategies: Galapagos, Ecuador

Water is an essential element for agricultural sustainability. In volcanic islands, freshwater sources are limited, challenging the local farming water supply. Rainfall dependence in the Galapagos Islands limits continuous agriculture, and despite using natural water sources, their irrigation quality is little known. This study aimed to carry out a control–diagnosis of irrigation water quality of the natural sources of the four agrarian islands of the Galapagos, considering water quality parameters for the proposal of sustainability strategies in the water and agricultural context. The workflow included (i) freshwater supply situation diagnosis, (ii) physicochemical parameters measurement and hydrochemical characterisation, and (iii) irrigation analysis and sustainability strategies configuration. Results indicated that of the 34 sources analysed, 55.88% are suitable for irrigation and are located in San Cristobal and Santa Cruz. The remaining 44.12% showed problems with parameters such as faecal coliforms, salinity, metals, carbonates, BOD5, and COD above the national permitted limits. Six strategies for water and agricultural sustainability are proposed, including periodic water monitoring, academy–government–community projects, community water board creation, water sowing and harvesting systems, effective management of effluent, and agricultural strengthening. The study guides comprehensive hydric management initiatives to benefit agrarian development and food security, aligning with SDGs 2 and 6.