Irminger Basin Research Articles

Freshwater runoff on the east Greenland shelf

The Greenland Ice Sheet releases fresh water from ice melt, tundra snow melt, and solid ice at an increasing rate during recent decades resulting in an increasing amount of freshwater runoff into the ocean. As a result, freshwater runoff is changing the continental shelf circulation by increasing the amount of fresher water on the shelf that may then enter the deep ocean. Observational studies show that dense water does traverse the east Greenland shelf near the ocean bottom but it is unclear to what extent the transport of near surface fresh water, as a result of runoff, reaches deeper water and enters the Irminger Basin. Using 4 km resolution nested numerical model simulations with and without freshwater runoff, we show freshwater runoff increases salinity variability with increased baroclinicity. While higher salinity variability and baroclinicity suggest a greater potential for water mass exchange across the East Greenland Current, most freshwater runoff along east Greenland remains on the shelf. From freshwater runoff alone, salinity and salt mass decreases by 0.22% on the continental shelf compared to a 0.01% in the rest of the Nordic Seas. There is a 0.05% reduction in salt mass on the Greenland shelf region that makes up 8% of the simulation domain, suggesting little water exits the shelf along the east coast of Greenland. The largest reduction in salt mass occurs around Iceland, where substantial freshwater runoff exists. A calculation of baroclinic conversion rate suggests likely pathways for runoff to exit the continental shelf and enter deep water in the Denmark Strait and over the Greenland/Scottland ridge east of Iceland. Most of the fresh water, however, released along the east coast of Greenland continues towards Cape Farewell, outside our modeling domain, and into the Labrador Sea.

Variability of Iceland Scotland Overflow Water Across the Reykjanes Ridge: 2‐Years of Moored Observations in the Bight Fracture Zone

AbstractThis study presents the first continuous observations of Iceland Scotland Overflow Water (ISOW) passing through the Bight Fracture Zone (BFZ), the northernmost deep bathymetric channel across the Reykjanes Ridge between the Iceland and Irminger Basins in the subpolar North Atlantic. Data from two 2‐year moorings, measuring temperature, salinity, and current velocity from 2015 to 2017, along with a set of deep ISOW‐embedded RAFOS floats, are used to investigate ISOW transport and water property variability through the BFZ, as well as advective pathways between the Iceland and Irminger Basins. The mooring‐derived record‐mean ISOW transport through the BFZ was −0.59 ± 0.27 × 1e6 m3/s (westward) and varied seasonally with weaker transport in winter and stronger transport in summer. Flow direction of ISOW through the BFZ was consistently westward except in winter, when week‐long flow reversals were frequently observed. The previously reported subpolar North Atlantic freshening event of the 2010s is evident in the BFZ mooring records beginning about January 2017. About one‐quarter of floats deployed in ISOW at 1800‐m depth upstream in the Iceland Basin show a direct advective pathway into the BFZ that appears to be primarily determined by bathymetry. Another quarter of the floats crossed over the ridge to the Irminger Sea through other gaps prior to reaching the Charlie‐Gibbs Fracture Zone.

Seasonal Variability of Near-Inertial/Semidiurnal Fluctuations and Turbulence in the Subarctic North Atlantic

Abstract Six profiling floats measured water-mass properties (T, S), horizontal velocities (u, υ), and microstructure thermal-variance dissipation rates χT in the upper ∼1 km of the Iceland and Irminger Basins in the eastern subpolar North Atlantic from June 2019 to April 2021. The floats drifted into slope boundary currents to travel counterclockwise around the basins. Pairs of velocity profiles half an inertial period apart were collected every 7–14 days. These half-inertial-period pairs are separated into subinertial eddy (sum) and inertial/semidiurnal (difference) motions. Eddy flow speeds are ∼O(0.1) m s−1 in the upper 400 m, diminishing to ∼O(0.01) m s−1 by ∼800-m depth. In late summer through early spring, near-inertial motions are energized in the surface layer and permanent pycnocline to at least 800-m depth almost simultaneously (within the 14-day temporal resolution), suggesting rapid transformation of large-horizontal-scale surface-layer inertial oscillations into near-inertial internal waves with high vertical group velocities through interactions with eddy vorticity gradients (effective β). During the same period, internal-wave vertical shear variance was 2–5 times canonical midlatitude magnitudes and dominantly clockwise-with-depth (downward energy propagation). In late spring and early summer, shear levels are comparable to canonical midlatitude values and dominantly counterclockwise-with-depth (upward energy propagation), particularly over major topographic ridges. Turbulent diapycnal diffusivities K ∼ O(10−4) m2 s−1 are an order of magnitude larger than canonical midlatitude values. Depth-averaged (10–1000 m) diffusivities exhibit factor-of-3 month-by-month variability with minima in early August.

Seasonal overturning variability in the eastern North Atlantic subpolar gyre: a Lagrangian perspective

Abstract. Both observations and ocean reanalyses show a pronounced seasonality in the strength of the Atlantic meridional overturning circulation (MOC) within the eastern North Atlantic subpolar gyre (eSPG). However, attributing this overturning seasonality to seasonal dense water formation remains challenging owing to the wide distribution of recirculation timescales within the Iceland and Irminger basins. Here, we investigate the nature of seasonal overturning variability using Lagrangian water parcel trajectories initialised across the Overturning in the Subpolar North Atlantic Program (OSNAP) East section within an eddy-permitting ocean sea ice hindcast. By adopting a Lagrangian perspective, we show that the seasonal minimum of the Eulerian overturning at OSNAP East in autumn results from a combination of enhanced stratification and increased southward transport within the upper East Greenland Current. This convergence of southward transport within the MOC upper limb is explained by decreasing water parcel recirculation times in the upper Irminger Sea, consistent with a gyre-scale response to seasonal wind forcing. To account for the diversity of recirculation times within the eSPG, we also quantify the Lagrangian overturning (LMOC) as the total dense water formation along water parcel trajectories. The majority of water parcels, sourced from the central and southern branches of the North Atlantic Current, fail to return to OSNAP East prior to experiencing wintertime diapycnal transformation into the lower limb, and thus they determine the mean strength of the LMOC within the eSPG (8.9 ± 2.2 Sv). The strong seasonality of the LMOC is explained by a small collection of upper-limb water parcels, circulating rapidly (≤ 8.5 months) in the upper Irminger and central Iceland basins, whose along-stream transformation is determined by their month of arrival at OSNAP East.

The distribution of 227Ac along the GA01 section in the North Atlantic

Actinium-227 is a powerful tool to study vertical mixing in the ocean, and was more recently proposed as a tracer of hydrothermal plumes. However, because 227Ac activities are especially low in the ocean, relatively few studies have been conducted to date, and none has been done on the large scale, as is reported in the present study. Here, we report a section of dissolved 227Ac in the North Atlantic Ocean between Portugal-Greenland-Canada based on nine full-depth profiles obtained in the framework of the international GEOTRACES program (GA01 section - GEOVIDE cruise, May–July 2014). The simultaneous determination of 231Pa, the parent nuclide of 227Ac, along the section allowed us to report a section of excess 227Ac activities (227Acex).Actinium-227 activities were especially low along the section (<0.4 dpm m−3) compared to other ocean basins. In most cases, 227Ac activities reached secular equilibrium with 231Pa in the water column 500 m above the seafloor. Secular equilibrium is considered reached after ∼five half-lives of the daughter. Secular equilibrium therefore suggests no external input over the last ∼100 years. The highest 227Ac activities were often found close to the seafloor, indicating that 227Ac diffuses out of the sediments. However, two different patterns question the traditional one-dimensional vertical mixing model typically applied to 227Ac released by deep-sea sediments: first, significant 227Acex were found in the upper 500 m of the water column at several stations located near the Iberian margin. In the upper 500 m, the high 227Acex activities could indicate lateral advection of waters that interacted with the margins. Second, mid-water peaks of 227Acex were occasionally observed along the transect. At station 44 in the Irminger Basin, a peak of 227Acex activity at 2500 m that was co-located with high dissolved Fe concentrations could be interpreted as the signature of a hydrothermal plume. Near the seafloor, we often observed bottom nepheloid layers and we cannot exclude that these layers impact the 227Ac distributions.

The Annual Salinity Cycle of the Denmark Strait Overflow

AbstractThe Denmark Strait Overflow (DSO) is an important source of dense water input to the deep limb of the Atlantic Meridional Overturning Circulation (AMOC). It is fed by separate currents from the north that advect dense water masses formed in the Nordic Seas and Arctic Ocean which then converge at Denmark Strait. Here we identify an annual salinity cycle of the DSO, characterized by freshening in winter and spring. The freshening is linked to freshening of the Shelfbreak East Greenland Current in the Blosseville Basin north of the Denmark Strait. We demonstrate that the East Greenland Current advects fresh pycnocline water above the recirculating Atlantic Water, which forms a low salinity lid for the overflow in Denmark Strait and in the Irminger Basin. This concept is supported by intensified freshening of the DSO in lighter density classes on the Greenland side of the overflow. The salinity of the DSO in the Irminger Basin is significantly correlated with northerly/northeasterly winds in the Blosseville Basin at a lag of 3–4 months, consistent with estimated transit times. This suggests that wind driven variability of DSO source water exerts an important influence on the salinity variability of the downstream DSO, and hence the composition of the deep limb of the AMOC.

Recent deep-sea ostracods of the sub-polar North Atlantic Ocean

Presented here is an illustrated checklist of benthic marine Ostracoda (Crustacea) recorded from Recent surface sediments of the sub-polar North Atlantic Ocean (SPNA). It presents 142 species (and species groups) belonging to 62 genera from 41 sampling sites collected from the water depths of 144–2749 m.We provide census data with scanning electron microscope images of representative specimens of most species, as well as geographical and bathymetrical distribution maps of selected species and genera. Samples from the Nordic seas (i.e., Greenland Sea, Norwegian Sea), as well as North Atlantic proper waters (i.e., Irminger Sea, Iceland Sea) are included. The bathymetry covers shelf to continental rise surface sediments from the Irminger Basin, the Iceland Basin, the Iceland Plateau, the Denmark Strait, the Faeroe-Shetland Channel, the Iceland-Faeroe Ridge, the Reykjanes Ridge, and the Faeroe Plateau. The data presented here is an important taxonomic and biogeographical baseline of the SPNA benthic ostracod fauna.

Mesoplankton across the North Atlantic: Composition and environmental drivers at 59.5th latitude

North Atlantic zooplankton communities vary in terms of abundance, biomass and species composition depending on various environmental factors. In this study we analyzed the influence of hydrological factors (water temperature, salinity and density) on mesoplankton and retrieve boundaries between mesoplankton assemblages across the Subpolar North Atlantic. The material was collected in July 2013 with the use of Juday plankton net vertical hauls (0–300 m layer) at 55 stations arranged along a longitudinal transect along 59.5° N during the 41-th expedition of R/V “Akademik Ioffe”. Both total abundance and biomass were higher in the eastern part of the transect and greatly decreased in the western part except the Greenland shelf and slope where the values were high. Four mesoplankton assemblages were retrieved by cluster analysis: two of them (above the Rockall Plateau and the Island Basin) were associated with warm Atlantic waters, the other two assemblages (in the Irminger Basin and above the Greenland slope and shelf) inhabited cold Arctic waters. The major biogeographic boundary was linked to the Subarctic Front above the Reykjanes Ridge. The best correlations of zooplankton characteristics with the surface chlorophyll a amount were obtained when averaging the surface chlorophyll data over May and 3 latitudinal and longitudinal degrees around each station. This can be connected to the main spring phytoplankton bloom, occurring during May in this area. The exception was the western-most part of the transect above the Greenland shelf and slope that harbored separate mesoplankton assemblages with high abundance and biomass, dominated by early mesoplankton stages (e.g. young copepodites and nauplii). These assemblages were likely supported by summer subsurface phytoplankton bloom caused by a water discharge from the melting Greenland Ice Shield.

Moored Observations of the Iceland‐Scotland Overflow Plume Along the Eastern Flank of the Reykjanes Ridge

AbstractSince 2014, an array of current meters deployed in the Iceland Basin as part of the Overturning in the Subpolar North Atlantic Program has provided new measurements of the southward flow of Iceland‐Scotland Overflow Water (ISOW) along the eastern flank of the Reykjanes Ridge. The location of the array, near 58–59°N, captures the ISOW plume at the farthest downstream location in the Iceland Basin before significant amounts of ISOW can flow into the Irminger Basin through deep fractures in the Reykjanes Ridge. The net transport of the ISOW plume at this location—approximately 5.3 Sv based on the first 4 years of observations—is significantly larger than previous values obtained farther north in the Iceland Basin, suggesting that either previous measurements did not fully capture the plume transport or that additional entrainment into the ISOW plume occurs as it approaches the southern tip of the Reykjanes Ridge. A detailed water mass analysis of the plume from continuous temperature/salinity observations shows that about 50% of the plume transport (2.6 Sv) is derived from dense waters flowing over the Nordic Sea sills into the Iceland Basin, while the remainder is made up of nearly equal parts of entrained Atlantic thermocline water and modified Labrador Sea Water. The overall results from this study suggest that the ISOW plume approximately doubles its transport through entrainment, similar to that of the Denmark Strait overflow plume in the Irminger Sea that forms the other major overflow source of North Atlantic Deep Water.

Seasonal and Interannual Variability of the Meridional Overturning Circulation in the Subpolar North Atlantic Diagnosed From a High Resolution Reanalysis Data Set

AbstractSubpolar North Atlantic is a vital region to modulate the variation of Atlantic Meridional Overturning Circulation (MOC). Recently, trans‐basin mooring arrays were deployed to monitor the meridional volume and heat transport in this region. Motivated by these new observations, this study investigates the structure and variability of MOC using a high resolution data assimilative reanalysis product. Our results indicate that the reanalysis product successfully captures the vertical structure and variability for the basinwide integrated stream function. In accord with observations, the meridional volume transport across the section from Greenland to Scotland (i.e., the East Section) is much stronger than that in the Labrador Sea (i.e., the West Section). While the boundary currents in the Labrador Sea display dramatic seasonal variations, their seasonal cycles are largely compensated, leading to very weak seasonality in the MOC. On the other hand, the MOC across the East section has an apparent seasonal cycle with the density changes in the Irminger Basin playing a dominant role. On the interannual time scale, MOC variations across both the West and East sections have comparable amplitudes. In addition, we further split the MOC fluctuations into components induced by barotropic and baroclinic processes. The decomposed fields point out that the isopycnal layer thickness at the west of Greenland is the primary factor to modulate the MOC interannual variability across the West section. MOC interannual variability across the East section is mostly determined by barotropic velocity changes near the pathway of the North Atlantic Current.

Particulate iron and other trace elements in near-surface waters of the high latitude North Atlantic following the 2010 Eyjafjallajökull eruption

In situ pumps were used to collect size-fractionated particles (>53 μm and 1–53 μm) from the upper ocean of the high latitude North Atlantic during spring and summer 2010, and samples were subsequently analysed for Al, P, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Cd, Ba and Pb. Two research cruises during May 2010 coincided with an eruption of the Eyjafjallajökull volcano in southern Iceland, which resulted in widespread dispersal of ash over the region. Ash deposition caused a noticeable perturbation of particulate trace element concentrations and content within marine particles in the Iceland Basin, relative to the Irminger Basin, most evident for lithogenic elements (Al, Ti, Fe), but also noticeable in elemental ratios for the other elements. The initial volcanic ash influence had largely disappeared by the third research cruise in July/August 2010, although there was evidence for a recent wind erosion event having transported remobilized volcanic ash from southern Iceland to the northern Iceland Basin in early July, further perturbing local trace element biogeochemistry. During summer 2010, concentrations of all measured elements except Ba were typically lower 10 m beneath the surface mixed layer relative to those within it, driven primarily by a rapid decrease in the concentrations of large (>53 μm) biogenic particles. Depth-dependent trends were more variable over the next hundred metres for all elements except the biogenic elements P and Cd, for which concentrations decreased further. The continued loss of biogenic material with depth due to remineralization (reflected by particulate P concentrations) led to an increase in content per mass of material for all other elements measured. The observed differences in upper ocean particulate P and Fe distributions highlight the mechanism driving seasonal Fe limitation in the high latitude North Atlantic: rapid loss of P by remineralization regenerates dissolved phosphate close to the base of the mixed layer, while most particulate Fe persists deeper in the water column, removing the potential for resupply of dissolved Fe to surface waters.

Trace Element Biogeochemistry in the High‐Latitude North Atlantic Ocean: Seasonal Variations and Volcanic Inputs

AbstractWe present dissolved and total dissolvable trace elements for spring and summer cruises in 2010 in the high‐latitude North Atlantic. Surface and full depth data are provided for Al, Cd, Co, Cu, Mn, Ni, Pb, and Zn in the Iceland and Irminger Basins, and consequences of biological uptake and inputs by the spring Eyjafjallajökull volcanic eruption are assessed. Ash from Eyjafjallajökull resulted in pronounced increases in Al, Mn, and Zn in surface waters in close proximity to Iceland during the eruption, while 3 months later during the summer cruise levels had returned to more typical values for the region. The apparent seasonal removal ratios of surface trace elements were consistent with biological export. Assessment of supply of trace elements to the surface mixed layer for the region, excluding volcanic inputs, indicated that deep winter mixing was the dominant source, with diffusive mixing being a minor source (between 13.5% [dissolved Cd, DCd] and −2.43% [DZn] of deep winter flux), and atmospheric inputs being an important source only for DAl and DZn (DAl up to 42% and DZn up to 4.2% of deep winter + diffusive fluxes) and typically less than 1% for the other elements. Elemental supply ratios to the surface mixed layer through convection were comparable to apparent removal ratios we calculated between spring and summer. Given that deep mixing dominated nutrient and trace element supply to surface waters, predicted increases in water column stratification in this region may reduce supply, with potential consequences for primary production and the biological carbon pump.

Representation of the Denmark Strait overflow in a &amp;lt;i&amp;gt;z&amp;lt;/i&amp;gt;-coordinate eddying configuration of the NEMO (v3.6) ocean model: resolution and parameter impacts

Abstract. We investigate in this paper the sensitivity of the representation of the Denmark Strait overflow produced by a regional z-coordinate configuration of NEMO (version 3.6) to the horizontal and vertical grid resolutions and to various numerical and physical parameters. Three different horizontal resolutions, 1∕12, 1∕36, and 1/60∘, are respectively used with 46, 75, 150, and 300 vertical levels. In the given numerical set-up, the increase in the vertical resolution did not bring improvement at eddy-permitting resolution (1/12∘). We find a greater dilution of the overflow as the number of vertical level increases, and the worst solution is the one with 300 vertical levels. It is found that when the local slope of the grid is weaker than the slope of the topography the result is a more diluted vein. Such a grid enhances the dilution of the plume in the ambient fluid and produces its thickening. Although the greater number of levels allows for a better resolution of the ageostrophic Ekman flow in the bottom layer, the final result also depends on how the local grid slope matches the topographic slope. We also find that for a fixed number of levels, the representation of the overflow is improved when horizontal resolution is increased to 1∕36 and 1/60∘, with the most drastic improvements being obtained with 150 levels. With such a number of vertical levels, the enhanced vertical mixing associated with the step-like representation of the topography remains limited to a thin bottom layer representing a minor portion of the overflow. Two major additional players contribute to the sinking of the overflow: the breaking of the overflow into boluses of dense water which contribute to spreading the overflow waters along the Greenland shelf and within the Irminger Basin, and the resolved vertical shear that results from the resolution of the bottom Ekman boundary layer dynamics. This improves the accuracy of the calculation of the entrainment by the turbulent kinetic energy mixing scheme (as it depends on the local shear) and improves the properties of the overflow waters such that they more favourably compare with observations. At 300 vertical levels the dilution is again increased for all horizontal resolutions. The impact on the overflow representation of many other numerical parameters was tested (momentum advection scheme, lateral friction, bottom boundary layer parameterization, closure parameterization, etc.), but none had a significant impact on the overflow representation.

Redrawing the Iceland\u2212Scotland Overflow Water pathways in the North Atlantic

Iceland-Scotland Overflow Water (ISOW) is a primary deep water mass exported from the Norwegian Sea into the North Atlantic as part of the global Meridional Overturning Circulation. ISOW has historically been depicted as flowing counter-clockwise in a deep boundary current around the subpolar North Atlantic, but this single-boundary-following pathway is being challenged by new Lagrangian observations and model simulations. We show here that ISOW leaves the boundary and spreads into the interior towards the central Labrador and Irminger basins after flowing through the Charlie-Gibbs Fracture Zone. We also describe a newly observed southward pathway of ISOW along the western flank of the Mid-Atlantic Ridge. The partitioning of these pathways is shown to be influenced by deep-reaching eddies and meanders of the North Atlantic Current. Our results, in tandem with previous studies, call for a revision in the historical depiction of ISOW pathways throughout the North Atlantic.

Heme b distributions through the Atlantic Ocean: evidence for \u201canemic\u201d phytoplankton populations

Heme b is an iron-containing cofactor in hemoproteins that participates in the fundamental processes of photosynthesis and respiration in phytoplankton. Heme b concentrations typically decline in waters with low iron concentrations but due to lack of field data, the distribution of heme b in particulate material in the ocean is poorly constrained. Here we report particulate heme b distributions across the Atlantic Ocean (59.9°N to 34.6°S). Heme b concentrations in surface waters ranged from 0.10 to 33.7 pmol L−1 (median = 1.47 pmol L−1, n = 974) and were highest in regions with a high biomass. The ratio of heme b to particulate organic carbon (POC) exhibited a mean value of 0.44 μmol heme b mol−1 POC. We identified the ratio of 0.10 µmol heme b mol−1 POC as the cut-off between heme b replete and heme b deficient (anemic) phytoplankton. By this definition, we observed anemic phytoplankton populations in the Subtropical South Atlantic and Irminger Basin. Comparison of observed and modelled heme b suggested that heme b could account for between 0.17–9.1% of biogenic iron. Our large scale observations of heme b relative to organic matter provide further evidence of the impact of changes in iron supply on phytoplankton iron status across the Atlantic Ocean.

Regulation of the Phytoplankton Heme b Iron Pool During the North Atlantic Spring Bloom.

Heme b is an iron-containing co-factor in hemoproteins. Heme b concentrations are low (<1 pmol L-1) in iron limited phytoplankton in cultures and in the field. Here, we determined heme b in marine particulate material (>0.7 μm) from the North Atlantic Ocean (GEOVIDE cruise – GEOTRACES section GA01), which spanned several biogeochemical regimes. We examined the relationship between heme b abundance and the microbial community composition, and its utility for mapping iron limited phytoplankton. Heme b concentrations ranged from 0.16 to 5.1 pmol L-1 (median = 2.0 pmol L-1, n = 62) in the surface mixed layer (SML) along the cruise track, driven mainly by variability in biomass. However, in the Irminger Basin, the lowest heme b levels (SML: median = 0.53 pmol L-1, n = 12) were observed, whilst the biomass was highest (particulate organic carbon, median = 14.2 μmol L-1, n = 25; chlorophyll a: median = 2.0 nmol L-1, n = 23) pointing to regulatory mechanisms of the heme b pool for growth conservation. Dissolved iron (DFe) was not depleted (SML: median = 0.38 nmol L-1, n = 11) in the Irminger Basin, but large diatoms (Rhizosolenia sp.) dominated. Hence, heme b depletion and regulation is likely to occur during bloom progression when phytoplankton class-dependent absolute iron requirements exceed the available ambient concentration of DFe. Furthermore, high heme b concentrations found in the Iceland Basin and Labrador Sea (median = 3.4 pmol L-1, n = 20), despite having similar DFe concentrations to the Irminger Basin, were attributed to an earlier growth phase of the extant phytoplankton populations. Thus, heme b provides a snapshot of the cellular activity in situ and could both be used as indicator of iron limitation and contribute to understanding phytoplankton adaptation mechanisms to changing iron supplies.

Dating the Anthropocene in deep-sea sediments: How much carbon is buried in the Irminger Basin?

Evaluation of biogeochemical processes in Anthropocene deep-sea sediments require accurate dating techniques. Here we show the results of an approach using high resolution low level background gamma spectrometry with two simultaneous hyper-pure germanium (HPGe) detectors. The quantitative role of the deepest zones (>3000 m depth) of the Irminger Basin (Subpolar North Atlantic Ocean) as a carbon sink during the Anthropocene is evaluated combining a chronology based in the natural radionuclide 210Pb with sedimentological analysis and elemental composition. The average sedimentation rate of the central Irminger is 1.28 ± 0.18 mm·yr−1, with a mean weighted flux to the sediment for inorganic and organic carbon of 46 ± 15 g·Cinorg·m−2·yr−1 and 8 ± 1 g·Corg·m−2·yr−1. The biogenic fraction of the mass flux is increased since the XXth century. The contribution of the deepest zones of the Irminger Basin to the Anthropocene carbon sequestration in the North Atlantic Ocean is considerable at basin-scale.

High variability of particulate organic carbon export along the North Atlantic GEOTRACES section GA01 as deduced from &amp;lt;sup&amp;gt;234&amp;lt;/sup&amp;gt;Th fluxes

Abstract. In this study we report particulate organic carbon (POC) export fluxes for different biogeochemical basins in the North Atlantic as part of the GEOTRACES GA01 expedition (GEOVIDE, May–June 2014). Surface POC export fluxes were deduced by combining export fluxes of total Thorium-234 (234Th) with the ratio of POC to 234Th of sinking particles at the depth of export. Particles were collected in two size classes (&gt;53 and 1–53 µm) using in situ pumps and the large size fraction was considered representative of sinking material. Surface POC export fluxes revealed latitudinal variations between provinces, ranging from 1.4 mmol m−2 d−1 in the Irminger basin, where the bloom was close to its maximum, to 12 mmol m−2 d−1 near the Iberian Margin, where the bloom had already declined. In addition to the state of progress of the bloom, variations of the POC export fluxes were also related to the phytoplankton size and community structure. In line with previous studies, the presence of coccolithophorids and diatoms appeared to enhance the POC export flux, while the dominance of picophytoplankton cells, such as cyanobacteria, resulted in lower fluxes. The ratio of POC export to primary production (PP) strongly varied regionally and was generally low (≤14 %), except at two stations located near the Iberian Margin (35 %) and within the Labrador basin (38 %), which were characterized by unusual low in situ PP. We thus conclude that during the GEOVIDE cruise, the North Atlantic was not as efficient in exporting carbon from the surface, as reported earlier by others. Finally, we also estimated the POC export at 100 m below the surface export depth to investigate the POC transfer efficiencies. This parameter was also highly variable amongst regions, with the highest transfer efficiency at sites where coccolithophorids dominated.

Fe(II) oxidation kinetics in the North Atlantic along the 59.5° N during 2016

The Fe(II) oxidation rate was studied in different water masses present in the subarctic North Atlantic ocean along the 59.5° N transatlantic section. Temperature, pH, salinity and total organic carbon (TOC) in natural conditions, fixed temperature conditions and both fixed temperature and pH conditions, were considered in order to understand the combined effects of the variables that control the Fe(II) oxidation kinetics in the ocean. The study shows that in natural conditions, temperature was the master variable which controlled 75% of the pseudo-first order kinetics rate (k′). This value rose to 90% when pHF (free scale) and salinity were also considered. At a fixed temperature, 72% of k′ was controlled by pH and at both fixed temperature and pH, salinity controled 62% of the Fe(II) oxidation rate. Sources and characteristics of TOC are important factors influencing the oxidation of Fe(II). The organic matter had both positive and negative effects on Fe(II) oxidation. In surface and coastal waters, TOC accelerated k′, decreasing the Fe(II) half-life time (t1/2). In Subpolar Mode Water, Labrador Sea Water (for the Irminger Basin) and Denmark Straight Overflow Water, TOC slowed down k′, increasing Fe(II) t1/2. This shifting behaviour where TOC affects Fe(II) oxidation depending on its marine or terrestrial origin, depth and remineralization stage proves that TOC cannot be used as a variable in an equation describing k′. The temperature dependence study indicated that the energy requirement for Fe(II) oxidation in surface waters was 32% lower than the required for bottom waters at both pH 7.7 and 8.0. This variability confirmed the importance of the organic matter composition of the selected samples. The Fe(II) oxidation rate constants in the region can be obtained from an empirical equation considering the natural conditions of temperature, pHF and salinity for the area, producing an error of estimation of 0.0072 min−1. This equation should be incorporated in global Fe models.

A tip of the iceberg\u2014Pseudotanaidae (Tanaidacea) diversity in the North Atlantic

During two IceAGE expeditions, a large collection of Tanaidacea was gathered from the shelf down to the slope (213−2750 m) in six areas off Iceland—the Irminger Basin, the Iceland Basin, the Norwegian Sea, the Denmark Strait, the Iceland-Faroe Ridge, and the Norwegian Channel. In this collection, members of the family Pseudotanaidae were most numerous component. We examined 40 samples collected with different gears (e.g., EBS, VVG. GKG), in which 323 pseudotanaid individuals were counted and covered a total depth from 213.9 to 2746.4 m. Morphological identification of the material has revealed the presence of five species: Akanthinotanais cf. longipes, Mystriocentrus biho sp. n. Pseudotanais misericorde sp. n., P. svavarssoni sp. n., and P. sigrunis sp. n. The description of the four new species has been presented in the paper and a rank of the subgenus Akanthinotanais is elevated to a genus rank. A large group of morphologically almost identical specimens, similar with P. svavarssoni sp. n. from a wide depth range and from various areas off Iceland was discriminated to species by applying morphometric methods; one distinct species (P. svavarssoni sp. n.) and complex of presumably cryptic species the species was discovered. Based on current data and literature records, similarity among fauna of Pseudotanaidae was assessed with applying Bray–Curtis formula. As results, potential zoogeographic regions in the North Atlantic have been distinguished.