Ion Streams Research Articles

Effective removal of Calcium and Magnesium Ions from boiler feed Water using Polyacrylonitrile supported titanium tungstovanadate composite ion exchange nanofiber

<p><em><strong>​​​​​​</strong></em><span style="font-family:"Times New Roman","serif";font-size:12.0pt;line-height:150%;">The challenge posed by the presence of calcium ions (Ca<sup>2+</sup>) in process streams is attributed to its adverse effects on the heat transfer efficiency of process equipment. In this study, a novel electrospun nanofibrous composite was synthesized by combining polyacrylonitrile (PAN) with well-dispersed Titanium tungestovanadate (TWV) cation exchanger. Homogeneous precipitation technique was employed to synthesize nano-titanium (IV) tungstovanadate (TWV) cation exchanger. Various synthesis parameters, including reactant volume ratio, amount of precipitating agent and reaction temperature, were optimized to achieve the highest ion exchange capacity (IEC). The prepared ion exchange material exhibited an ion exchange capacity (IEC) of 2.39 meq.g<sup>-1</sup> for Na<sup>+</sup> ions. The incorporation of the prepared nanoparticles into nanofibers conferred the sorption capabilities of the composite. The nanofibers' morphologies and structures were analyzed using Fourier transform infrared (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Batch sorption experiments were carried out to investigate the sorption properties. Controlled experiments were conducted to investigate the impact of various factors, including solution pH, temperature, dosage, contact time, and the initial concentration of the hard water. The results indicated that the optimum adsorption conditions that gave the highest percentage of removal 99%, 98% for Ca<sup>2+</sup> and Mg<sup>2+</sup>  ions respectively were 50 mg of adsorbent dosage, 500 ppm of Ca<sup>2+</sup> and Mg<sup>2+</sup>  solution =7, and a contact time of 30 min at room temperature .The  kinetic data were fitted to pseudo second order model. Furthermore, the thermodynamic study suggested that the adsorption on PAN/TWV NF was endothermic and spontaneous.</span></p>

Nonlinear Structures of Dispersive Electrostatic Solitary Waves in a Multi‐Ion Partially Ionized Plasma

ABSTRACTThe nonlinear structure and dynamics of dispersive solitons and breather waves described by Korteweg‐de Vries and nonlinear Schrödinger equations are studied. The theoretical and numerical study of the generalized hydrodynamic equations, accounting for wave dissipation and particle production‐loss mechanism, are considered. The reductive expansion method has been used in the context of the instability problem of multi‐fluid dynamics, applied to the study of electrostatic solitons and ion‐acoustic waves. A nonlocal model of interacting solitary‐breather waves has been presented. Applications of the theory, concerning the ion streaming instability in the framework of plasma physics, are presented.

Heterojunction of natural clay minerals and carbon nanotubes as robust moisture electric generator

Among various sustainable energy harvesting devices, moisture electric generators (MEG) possess distinct advantages like portability, minimum human intervention, absence of moving parts, unnecessity of fuels, and potential for off-grid power generation. However, maturing this emerging technology requires the exploration of a diverse range of materials and device configurations. Here, we report the fabrication of heterojunction-based robust MEGs by using reconstructed layers of natural vermiculite clay (VM) and HNO3-treated oxidized multi-walled carbon nanotubes (o-CNT). The heterojunction of negatively charged VM and o-CNT membranes (o-CNT-VM) prepared through a facile water-assisted fusion process yielded voltages of ∼ 790 mV for more than 2000 s (at 75 % RH). Assembling multiple o-CNT-VM devices in series connection output potentials up to 98 V were achieved. The mechanistic studies revealed the junction potential between VM and o-CNT to be the major contributor to the observed potential, with minor contributions arising from evaporation-driven streaming of ions through the 2D nanofluidic channels. The o-CNT-VM devices can function in extreme conditions such as temperatures ranging from 0 to 80 °C. The practical applicability of the o-CNT-VM-based MEG devices is demonstrated by lighting LED, and powering calculators by assembling o-CNT-VM devices in simultaneous series and parallel connection.

(Invited) Understanding Potential Losses and pH Distribution in Electrochemical Nitrate Reduction Reaction to Ammonia

Electrochemical nitrate reduction reaction (NO3 -RR) to ammonia is a promising route to eliminate one of the major pollutants in surface and groundwater. When powered by renewable electricity, electrolysis provides a sustainable method to generate ammonia from nitrate ions, facilitating the transition from a linear to a circular economy. Optimizing the physical and chemical properties of electrolysis cells is crucial to make this process economically viable for widespread implementation. Here, we explore how the choice of current density, conductivity, pH, inter-electrode distance, membrane, catalyst, and buffer solution affect nitrate removal performance and efficiency. We develop a modeling framework to investigate the cell characteristics and fluid dynamics during electrochemical NO3-RR using both laminar and bubbly flows. To obtain more precise results, we employed the bubbly flow model (i.e., Multi-phase Fluid) to take into account how gas production near the electrode surface affects liquid velocity, pH distribution, and, ultimately, potential losses. We exploit mass transfer theory to include the current density effect on migration and diffusion. In the absence of a buffer solution, the Nernstian loss became a significant portion of the polarization loss, which increased with current density. We identified the positive effect of the membrane on energy efficiency to be more significant at smaller inter-electrode distances. This study provides insights into the origin of potential losses and pH distribution, enabling electrochemical cell optimization for renewable fuel synthesis. Next, we will discuss our recent work on designing single atom alloys (SAAs) for selective conversion of low concentration nitrate ions in natural wastewater streams from Dairy farm into ammonia. We benchmarked the catalyst's selectivity, activity, and stability following standard protocols established in the field of nitrogen fixation, including control experiments by using an electrolyte that does not contain nitrate ions and performing experiments under the same operating conditions using nitrogen isotopes (i.e., 14NO3 -, 15NO3 -).

Enhanced laser absorption and ion acceleration by boron nitride nanotube targets and high-energy PW laser pulses

Enhancing laser energy absorption with energy transfer to fast electrons is crucial for efficient laser-driven ion acceleration. In this work, we present an experimental demonstration of volumetric laser absorption using boron nitride nanotube (BNNT) targets with an average density of 15 of the solid density. We use a PW laser system operating at a pulse duration of 1.2 ps and an energy of 1.3 kJ, reaching intensities of 2 × 1019 Wcm−2 on target with moderate nanosecond contrast (109), to generate energetic ion streams from a 250 µm thick BNNT target. To characterize laser-accelerated ions, Thomson parabola spectrometers, CR-39 nuclear track detectors, and an electron spectrometer are employed. The results are compared to those achieved using flat targets made of polystyrene (PS) of the same thickness. The comparison reveals a 1.5-fold increase in proton maximum energy and a 2.5-fold increase in the maximum energy of heavy ions (C and N) when comparing the BNNT to PS. Moreover, the high-energy ion flux recorded at CR-39 is orders of magnitude higher for the BNNT after cutting off low-energy ions with Al filters. The enhanced ion acceleration is the result of a 2.3-fold increase in the electron temperature for BNNT, as measured by the electron spectrometer. These experimental findings are further validated through two-dimensional particle-in-cell simulations, which confirm the increase in electron temperature due to enhanced laser absorption ascribable to the low density and nanostructure of the BNNT target compared to the flat foil. Published by the American Physical Society 2024

Influence of a transverse magnetic field on wakefield oscillations around a charged dust grain in complex plasma

In the presence of ion streaming, the potential around dust particles immersed in plasma becomes anisotropic. In this scenario, the repulsive Debye–Hückel potential is superimposed with an attractive wake potential. This work presents an analytical study of the complex behavior of such a wake potential in the presence of a magnetic field (oriented transversely to the ion flow) and ion-neutral collisions using linear response formalism, both in subsonic and supersonic regimes. The amplitude and periodicity of this potential are found to be controlled by the interplay among ion streaming velocity, ion cyclotron frequency, and ion-neutral collision frequency. Due to the tunable nature of this potential, it is possible to control the crystal formation, phase transitions, and transport properties of dusty plasma by adjusting the external magnetic field. The study also reveals that the wake potential almost disappears in a collision-dominant regime.

The Limited Effect of Reduced Typhoon Frequency on Stream Hydrochemistry in a Subtropical Forest Watershed

AbstractTropical cyclones are often accompanied by large amount of precipitation potentially impacting stream hydrochemistry. Global warming is altering typhoon disturbance regime. Little is known about how cyclone changes, especially cyclone‐frequency reduction may affect stream hydrochemistry. In this study, we compared water and nutrient input via precipitation and output via streamflow between a frequent‐typhoon period (2013–2017), with 1.2 typhoon yr−1, and a no‐typhoon period (2018–2022) at a long‐term monitoring site, the Fushan Experimental Forest of Taiwan. Precipitation and streamflow quantities were not different between the two periods because typhoons increased the fluctuation but not the mean of monthly precipitation in the major typhoon months (July–September). Inputs of Mg2+, NO3−, and SO42− via precipitation were greater in the frequent‐typhoon period than the no‐typhoon period while inputs of other ions were not different between the two periods. Only the output of Mg2+ was different between the two periods, greater in the frequent‐typhoon period. Output/input ratio of NO3− was greater in the no‐typhoon period than the frequent‐typhoon period despite the greater input in the frequent‐typhoon period, while no differences were found for others. Increases in mineralization rates due to warming is suggested to be the cause of the greater NO3− output/input ratio during the no‐typhoon period. Relationships between stream discharge and ion export were similar between the two periods both with and without removing typhoon events. The limited variation in hydrochemistry between periods of contrasting cyclone activities suggests high resilience of the undisturbed subtropical forests to changes in cyclone frequency at the decadal scale.

Enhancing particle string detection in electrorheological plasmas using asymmetrical kernel convolutional networks

Under different plasma conditions and electric fields in a complex plasma the plasma particles organize themselves in a string-like or chain-like manner. A phase transition from string-like to an isotropic particle distribution is observed at different electrical conditions. The streaming of charged ions around plasma particles with the surrounding electric field gives the plasma its electrorheological properties. The visibility of individual particles in a complex plasma opens up the opportunity to examine properties and phase transitions of such electrorheological fluids in detail. Because of the limited one-dimensional symmetry, determining the configuration of a particle and recognizing strings in particle distributions is not always straightforward. Several approaches have already been used to analyse particle clouds while either considering each particle locally or considering the particle cloud as a whole without providing information about single particle configurations. This paper presents a new machine learning approach that takes advantage of particle distributions over the entire particle cloud and detects all string-like particles at once, using a convolutional neural network in form of an encoder-decoder network with asymmetric kernel convolutions. This not only enhances the result quality but also accelerates the evaluation process, possibly enabling real-time analyses on electrorheological phase transitions, while achieving an accuracy of over 95% on manually labelled data.

Electron acceleration influenced by sinh-Gaussian laser pulses in a prepared ion channel

The acceleration of electron in a produced ion channel is studied theoretically using a sinh-Gaussian (shG) laser pulse with radial polarization. Compared to Gaussian laser pulses, shG laser pulses propagate differently, presenting as a bright ring encircling a dark hollow core that inhibits early focusing and promotes self-defocusing. They can therefore be used to accelerate electrons to extremely high energies. The electron energy gain is influenced by the laser pulse decentred parameter linked to the shG function, however, the ion stream’s electric field prevents the transverse oscillations from pushing electrons out of the interaction zone. With a decentred parameter of ∼2.15 and a laser pulse intensity value of ∼1020 Wcm −2 incident on density of ∼ 1022 m −3, where the incident pulse phase is ψ 0 = 0, the combined effect of ion channelling and radially polarized (RP) shG laser pulses leads to a significant enhancement of electron energy gain within the ion density channel to the GeV level.

Reliability Assessment of Indium Micro Bumps for 2.5D/3D Electronic Packaging through Cryo-Argon Milling Technique

Indium bumps are widely used in electronic packaging for interconnecting microelectronic devices due to their low melting point of 156.6°C, excellent bonding capabilities at room temperature, high thermal conductivity, ductility at extremely low temperatures, and ability to compensate for the mismatched coefficient of thermal expansion (CTE) between different materials. However, cross-sectioning indium bumps can be challenging due to the softness and low melting point of indium. The cutting tools and techniques used must be optimized for the specific sample being analyzed, and specialized preparation techniques such as cryogenic freezing or chemical etching may be required, which can be expensive and time-consuming. Cryo-Focused Ion Beam (FIB) is also a technically demanding process that requires careful optimization of milling parameters, multiple iterations of milling and imaging, specialized equipment, and expertise, which can make it too expensive. It should be noted that the maximum achievable cross-sectional area with cryo-FIB is limited, typically in the range of hundreds of micrometers. Cryo-Argon milling is an effective technique for obtaining high-quality cross-sections of indium bumps arrays and other materials prone to deformation or melting during traditional cross-sectioning. This process involves freezing the sample using liquid nitrogen and bombarding it with a stream of Argon gas ions, which reduces the deformation and melting of the indium. This paper presents challenges related to sample preparation and mechanical polishing for Ar milling technique, and we provide key solutions to these challenges to obtain millimeter-wide and damage-free cross-sections of arrays of indium micro bumps.

Green technology for carbon dioxide utilization: Vermiculite based hydrotalcite for methane dry reforming

In this paper, the abundant metal ions in the vermiculite-modified waste stream were utilized to prepare vermiculite-based hydrotalcite precursors, and hydrotalcite-like bimetallic catalysts were synthesized by the co-precipitation method and used in the methane dry reforming reaction. The experimental results showed that the Ni-Co/VMT-LDO catalyst showed good activity with 84% CH4 conversion and 87% CO2 conversion at 750 °C and 18000 mL/(g·h). The catalyst was characterized by XRD, SEM, BET, H2-TPR, TEM and TG. TEM tests before and after the reaction showed that the addition of Co decreased the average particle size of Ni. Meanwhile, thermogravimetric tests of the spent catalysts revealed that the weight loss of the bimetallic catalysts was significantly smaller than that of the monometallic catalysts, in which the Ni-Co/VMT-LDO showed better anti-carbon accumulation performance than the other two catalysts. This study not only solves the environmental problems caused by vermiculite modification, but also enhances the economic utilization of vermiculite. Vermiculite-based hydrotalcite-loaded bimetallic catalysts have been shown to be effective catalysts for dry reforming of methane.

Nanoscale electrohydrodynamic ion transport: Influences of channel geometry and polarization-induced surface charges.

Electrohydrodynamic ion transport has been studied in nanotubes, nanoslits, and nanopores to mimic the advanced functionalities of biological ion channels. However, probing how the intricate interplay between the electrical and mechanical interactions affects ion conduction in asymmetric nanoconduits presents further obstacles. Here, ion transport across a conical nanopore embedded in a polarizable membrane under an electric field and pressure is analyzed by numerically solving a continuum model based on the Poisson, Nernst-Planck, and Navier-Stokes equations. We report an anomalous ionic current depletion, of up to 75%, and an unexpected rise in current rectification when pressure is exerted along the external electric field. Membrane polarization is revealed as the prerequisite to obtain this previously undetected electrohydrodynamic coupling. The electric field induces large surface charges at the pore tip due to its conical shape, creating nonuniform electrical double layers (EDL) with a massive accumulation of electrolyte ions near the orifice. Once applied, the pressure distorts the quasiequilibrium distribution of the EDL ions to influence the nanopore conductivity. Our fundamental approach to inspect the effect of pressure on the channel EDL (and thus ionic conductance) in contrast to its effect on the current arising from the hydrodynamic streaming of ions further explains the pressure-sensitive ion transport in different nanochannels and physical regimes manifested in past experiments, including the hitherto inexplicit mechanism behind the mechanically activated ion transport in carbon nanotubes. This enhances our broad understanding of nanoscale electrohydrodynamic ion transport, yielding a platform to build nanofluidic devices and ionic circuits with more robust and tunable responses to electrical and mechanical stimuli.

Cost-effective layered double hydroxides/conductive polymer nanocomposites for electrochemical detection of wastewater pollutants

There is an urgent need to develop multifunctional cost-effective nanomaterials and nanocomposites that can be used in numerous applications while showing high efficiency and cheaper implementation compared to conventional techniques and/or materials. In this work, zinc/iron layered double hydroxide (LDH) and polyaniline (PANI) were synthesized as a model LDH/conductive polymer nanocomposite, which is a promising family of cheap multifunctional materials. This electrochemical properties of this nanocomposite was investigated for detection of heavy metal (HM) ions in water streams, using lead as a model HM. In the present work, zinc/iron LDH and PANI was assigned as carbon paste electrode modifier. The composite was fully characterized using various characterization techniques including X-ray diffraction (XRD), scanning electron microscope (SEM), and Fourier transform InfraRed (FTIR). The electrochemical redox reactions of lead (II) ions at the modified electrode interface were investigated using cyclic voltammetry (CV), differential pulse voltammetry (DPV), Accordingly, a linear relation of Pb2+ ions was achieved in the concentration range 1–80 µM with limit of detection (LOD) was 167.8 nM and limit of quantification (LOQ) was 559.4 nM. Furthermore, the cost of using such material for lead removal using a typical adsorption study was compared to using conventional inductively coupled plasma (ICP) or atomic absorption spectrometry (AAS) equipment for tracking HM removal during the adsorption process. Cost analysis revealed that the final overall cost of the modified carbon paste electrode is estimated as 1.25 USD. This cost represents less than 0.1% of the total cost required to conduct the same adsorption study using a typical ICP or AAS equipment. This composite can pave the road towards portable measurements for onsite detection of wastewater pollutants using cheap disposable-electrodes as compared to massive expensive off site equipment such as ICP and AAS.

A novel annular slit-type emitter developed for multi-jet electrospray propulsion

Electrospray thrusters employ ionization in the liquid phase to produce and propel streams of molecular ions or highly charged droplets at significant velocities. In this study, we developed a novel annular slit-type emitter for electrospray and investigated its operational modes under varying applied potentials in both open atmosphere and vacuum conditions. To assess the performance of the annular slit-type emitter in comparison to the conventional capillary-type emitter, benchtop electrospray experiments were conducted using water and glycerin as working fluids for both emitter types. The study examined the formation of the Taylor cone, cone-to-jet transition, stable jet, whipping jet, and multi-jet, along with their dependence on fluid viscosity and electric potential for both emitter designs. Clear distinctions in hydrodynamic mode, drop-to-cone mode, and cone-to-jet transition mode were observed between the two emitters. As the electric potential increased, the capillary-type emitter exhibited a whipping and pulsating water jet, while glycerin displayed a steady tilted jet. In contrast, the annular slit-type emitter demonstrated a pulsating water jet followed by a distinctive dripping mode at higher electric potentials, while glycerin formed multiple steady jets around the annular slit. Notably, the annular slit-type emitter, when subjected to an 18.5 kV potential, produced seven electrospray jets for glycerin, a phenomenon attributed to the novel design of the emitter and the viscosity of glycerin enabling the generation of multiple cone-jets at a specific electrostatic potential around the slit peripheral meniscus. Vacuum chamber tests of the annular-type emitter using liquid indium as an ion source at 1 × 10−5 Torr revealed an ion-current density of 0.3 mA/mm, resulting in a thrust of 290 μN.

Advances in asymmetric moist-electric generators with innovative heterogeneous structures

Harvesting energy from the ubiquitous moisture induced streaming potential or ion concentration gradients is a promising green technology. Lately, the emergence of high-performance asymmetric moist-electric generators (AMEGs) with inhomogeneous distribution...

Fluid simulation for detachment process in magnetic nozzle of magnetoplasma rocket engine

Magnetoplasma rocket engine has a broad application prospect in the deep space exploration, manned space flight and other space missions. The ion energy is converted into the directed velocity in the magnetic nozzle of the engine. The investigation into the detachment process of the plasma with the magnetic field is of great significance for improving the engine propulsion efficiency. However, there are roughly five kinds of physical mechanisms which can all contribute to the detachment process and make the detachment in the magnetic nozzle quite complicated. Furthermore, the ion temperature is much higher than the electron temperature in the magnetic nozzle of the magnetoplasma rocket engine due to the heating effect of the ion cyclotron resonance stage. As a result, previous numerical model which were based on the assumption of cold ions are unapplicable for the simulation of the engine. In this work, a fluid simulation model is developed which is used for simulating the magnetic nozzle in the magnetoplasma rocket engine. The model includes the electron and the ion of single charge. For the characteristics of the magnetoplasma rocket engine, the ion energy equation is added into the governing equations. In order to analyze the effect of the inertial detachment, the static electric field due to the charge separation is also included. The simulations are performed under the conditions of different inlet ion temperatures and background magnetic fields. The results show that the ion axial velocity gradually increases in the magnetic nozzle and the ion stream lines detach from the magnetic field lines gradually. The loss of adiabaticity is the dominant mechanism in the detachment process. The ion axial velocity increases with the inlet ion temperature rising, and the ion streamlines detach earlier from the magnetic field lines. The resistive diffusion is unaffected by the inlet ion temperature while the detachment interfaces of other three mechanisms all move toward the upstream. With the increase of the background magnetic field, ion axial velocity decreases and the angle included between the streamline and the axis becomes smaller. The loss of adiabaticity is still the dominant physical mechanism when the magnetic field is changed.

Divergent effect of landscape patterns on stream water chemistry and seasonal variations across mountainous watersheds in a Northwest Pacific island

The impacts of landscape pattern on water quality of streams are intricate and influenced by spatiotemporal scales. Untangling the interactions between landscapes and water, and identifying the pivotal indicators that drive spatial and temporal changes in nutrient dynamics, are essential steps towards facilitating sustainable water resource management. This study explored the relationship between landscape patterns and annual and seasonal (wet and dry seasons) exports of major cations (Na+, K+, Ca2+, and Mg2+) and anions (Cl-, SO42-, NO3-N, and PO4-P) in 43 watersheds across subtropical mountainous regions of Taiwan during the 2015–2016 period. Multiple stepwise regression models were constructed to elucidate the crucial landscape variables influencing variations in stream ion exports across different time scales, and spatial extent, ranging from watershed to various riparian buffer widths (100, 200, 500, 1000, 1500, and 2000 m). The findings indicated that the buffer width of 200 m emerged as the optimal scale for illustrating the connections between landscape patterns and water chemistry, outperforming larger scales. Nevertheless, there were minor deviations in the optimal scale for Na+ and Cl- (ranging from 100 to 500 m). Landscape-level configuration metrics (PD [patch density], CONTAG [Contagion], and IJI [Interspersion and Juxtaposition]) played a significant role in explaining the majority of data variations in cations. This suggest that overall landscape fragmentation tends to enhance cations exports, regardless of land cover types. On the contrary, class-level configuration metrics (EDBUD [edge density of buildup], PDBAR [patch density of bareland], and IJIAGR [Interspersion and Juxtaposition of agriculture]) played a primary role in interpreting data variations of anions. This indicated that the configurations of specific land cover types, such as buildup, agriculture and bareland, are the primary factors influencing anion exports. Furthermore, the regression models exhibited robust performance during both wet and dry seasons, implying their consistent efficacy in estimating ion exports. This synthesis illustrated the benefits of utilizing this cost-effective approach to assess landscape-water connections in challenging mountainous regions, assisting water resources management.

Plasma flow and instabilities in the magnetic mirror with ion recycling and neutral back-flow

Magnetic mirror configurations are observed in natural settings and have various applications in laboratory plasmas, such as a magnetic expander of the open mirror fusion devices. The axial plasma flow in open mirror systems is significantly influenced by atomic processes involving neutrals, such as ionization and charge-exchange collisions. A quasi-two-dimensional computational model was developed to study these effects on accelerated plasma flow in magnetic mirror configurations. This model includes an emitting wall, a quasineutral flow/acceleration region with a magnetic expander, and a recycling/absorbing wall. Implemented in a hybrid quasineutral code, the model incorporates drift-kinetic ions, fluid electrons, and fully kinetic neutral atoms with collision processes simulated using the direct simulation Monte Carlo approach. Ion recycling on the wall is accounted for using empirical methods. The model demonstrates that slow atoms with short mean free paths create a dense plasma layer near the wall, modifying the plasma potential which can lead to large-scale perturbations due to ion–ion streaming instabilities.

Gas Discharge Source of Synchronous Flows of UV Radiation and Silver Sulphide Microstructures

The results of the study of the characteristics of a pulsed source of time-synchronous UV radiation streams of silver atoms and ions and micro-nanostructures of silver sulfide are given. An overvoltage nanosecond discharge was ignited in nitrogen between electrodes made of silver sulfide (Ag2S) at a distance between electrodes of 2 mm. Silver sulfide vapors were introduced into the gas-vapor mixture "Nitrogen - Ag2S" due to the ectonic mechanism. The voltage and current pulses, the pulsed power of the discharge, the energy contribution to the plasma for one pulse at pulse repetition frequencies of 40-1000 Hz were studied. The spectral characteristics of the discharge and the spatial characteristics of the microstructures deposited from the discharge plasma on a quartz substrate installed near the electrode system were studied.
 The discharge can be used as a source of bactericidal radiation and a source of microstructures based on silver sulfide, as well as a plasma chemical reactor for the synthesis of thin microstructured films of silver sulfide.

Jovian Periodicities (~10 h, ~40, 20, 15 min) at ACE, Upstream from the Earth’s Bow Shock, on 25–27 November 2003

It is known that Jovian radio and high energy electron emissions are observed near Earth. The question we address in this study is whether the quasi-periodic ~10 h and ~40/15–20 min (QP-10 h, QP-40/15–20 min) energetic particle and magnetic field periodicities observed by Ulysses during its distant encounter with Jupiter in 2003 were also detectable as far as the Earth’s orbit. Surprisingly, we found that at the end of the extreme 2003 Halloween events, during times of a highly disturbed Jovian magnetosphere, as inferred from strong bKOM radio emissions observed by Ulysses, and a magnetic connection of Earth with the Jovian magnetosphere, as suggested by simulation results of the interplanetary magnetic field (IMF), the ACE satellite observed, between at least 25–27 November 2013 at the Lagrangian Point L1 (LPL1), all the characteristic Jovian periodicities. In particular, by using high-time resolution data (1/5 min), we found, for the first time, quasi-permanent electron, and magnetic field QP-10/5 h, QP-40 min and QP-15/20 data variations at LPL1 for at least three days. These observations reasonably suggest that low energy (~50–~300 keV) Jovian electrons reached the Earth’s environment; the observations examined extend the lowest energy limit of the Jovian electron spectrum from 200 keV to ~50 keV. In addition, the ACE satellite observed an impressive series of QP-10/5 h energetic (≤0.05 MeV) ion bursts (EIBs) with strong cross-field intensity gradients at the onset/decay phase of the events and energy-dependent field aligned anisotropy suggesting ion streaming in the anti-sunward direction during their main phase. A comparison of simultaneously obtained measurements by ACE at the LPL1 and by Geotail upstream from the bow shock and in the magnetosphere suggests that the QP-10/5 h EIBs are inconsistent with the concept of a terrestrial origin. On the contrary, the observations indicate that the series of QP-10/5 h EIBs on 25–27 November 2003 was a spatial effect caused by the ~10/5 h quasi-periodic approach of a large-scale sheet to the Earth’s environment. The source of the ion population forming the QP-10/5 h sharp EIBs seems most probably Jovian ions accumulated in the interplanetary space, although a solar ion contribution is possible. Based on the above results, it is reasonable to suggest that the observed QP-10 h, QP-40 min and QP-15/20 periodicities are due to Jovian influence. Further research is needed to study the cause of the QP-10/5 h EIBs. This study presents new data which extend our view on the influence of the QP-10 h/QP-40/QP-15/20 min Jovian emissions from the outer to the inner heliosphere at 1 AU.