Electroreduction Of Ions Research Articles

Theoretical and electrochemical investigation of free convection mass transfer at vertical cylinders

The influence of the transverse curvature on free convection heat or mass transfer at vertical cylinders is investigated. Mass transfer coefficient have been determined from limiting current density measurements, using the electroreduction of ferricyanide ions as the model reaction. The evaluation of the dimensionless free convection mass transfer variables for this system leads to reliable results. The data in the laminar region show good agreement with theoretical predictions, based on a Pohlhausen approximation for infinite Schmidt or Prandtl number, and with heat transfer measurements in water. Theory and experiments are increasingly accurate with stronger curvature. The limiting behaviour for very thick and infinitely thin cylinders is discussed. For turbulent flow at thin cylinders, the electrochemical measurements are in close agreement with heat transfer data in air. The combined data lead to the correlation Sh R =0.6 Ra sol:1 10 R . whereas thick cylinders with Ra R > 800 behave like a flat plate. Emperical and theoretical evidence points to a critical value of Gr x / Sc, corresponding to Re x ≈10 3, as a criterion for the transition from laminar to turbulent flow, with a slightly destabilizing influence of the curvature.

Hydrodynamic Voltammetry with the Convection Electrode. III. The Measurements of the Kinetic Parameters of the Electrode Reaction. Part I

Abstract We have proposed the determination of the kinetic parameters of the electrode reaction by means of convective voltammetry. At the pushed-out mercury-drop convection electrode (PM-DCE), the ratio of the current on a totally-irreversible wave to the limiting current was derived as follows: (Remark: Graphics omitted.) This equation was applied to the determination of the kinetic parameters for the electro-reduction of cupric ions in a 0.1 m perchloric acid solution containing 0.05% Triton X-100. It was found that the values of αn and k° the kinetic parameters are 0.59 and 4.2×10−9 cm/sec respectively.