The presented paper deals with the investigation of test samples in air with nonuniform potential distribution along the insulating boundary surface. The applied D.C. test voltage, the stressing time and the polarity have been varied as well as the relative air humidity (20% – 80%) for different insulator materials (epoxy resin, PMMA, PVC, kraftboard). The surface charge distribution was recorded by means of a computer controlled measuring system using an electrostatic probe. Increasing the voltage and stressing time as well as the surface resistivity of the insulator material increases the measured charge density, as expected. In contrast, especially two phenomena are observed as being considerable: 1. 1. An increase in humidity causes a partly enormous rise of the charge density. In case of a relatively high humidity, the measured charge distribution is always reproducible. In dry conditions the charge density is lower and the charge distribution is indeterminate. 2. 2. Charges may accumulate on the surface in the case of nearly uniform electrode configurations, i.e. without measurable partial discharges. Above a humidity of 30% the polarity of the charges always corresponds to the polarity of the D.C. voltage. Based on the assumption that the charge accumulation is attributed to ionization processes in air a model conception is derived. In spite of a larger attachment coefficient the influence of the humidity is traced back to a rise in the frequency of ionization events in air.
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