Ionic Conductivity Research Articles

Controlled Interfacial Tailoring of Hierarchical Silicon Synergizes Charge Transport Enabling Stable and Fast Lithium Storage

AbstractSilicon is a promising anode material candidate but encounters volume change and capacity decay issues. Although diverse demonstrations in structural and interfacial engineering, the performance toward industrial applications remains to be improved. Herein, a controlled interfacial tailoring strategy is proposed for micro‐nano hierarchically structured silicon. The resultant granules, consisting of randomly interconnected silicon debris modified by an electrically conductive carbon layer and a superionic sulfide conductor specifically in a controlled form (nanoparticles, coats, and matrices), attain distinctly different cyclic performances. As the carbon coating generally provides electron transfer paths for silicon, the introduced fast ion conductor exhibits a strong correlation with its configuration in facilitating ion transportation as well as improving the materials utilization and cyclic stability. Impressively, the granules encapsulated with a fast ion conductor layer show remarkably improved cycling performance and rate capability, attributable to a decent synergy of transmitting both electrons and lithium ions throughout the granule.

Sodium-Selective Channelrhodopsins

Channelrhodopsins (ChRs) are light-gated ion channels originally discovered in algae and are commonly used in neuroscience for controlling the electrical activity of neurons with high precision. Initially-discovered ChRs were non-selective cation channels, allowing the flow of multiple ions, such as Na+, K+, H+, and Ca2+, leading to membrane depolarization and triggering action potentials in neurons. As the field of optogenetics has evolved, ChRs with more specific ion selectivity were discovered or engineered, offering more precise optogenetic manipulation. This review highlights the natural occurrence and engineered variants of sodium-selective channelrhodopsins (NaChRs), emphasizing their importance in optogenetic applications. These tools offer enhanced specificity in Na+ ion conduction, reducing unwanted effects from other ions, and generating strong depolarizing currents. Some of the NaChRs showed nearly no desensitization upon light illumination. These characteristics make them particularly useful for experiments requiring robust depolarization or direct Na+ ion manipulation. The review further discusses the molecular structure of these channels, recent advances in their development, and potential applications, including a proposed drug delivery system using NaChR-expressing red blood cells that could be triggered to release therapeutic agents upon light activation. This review concludes with a forward-looking perspective on expanding the use of NaChRs in both basic research and clinical settings.

Energy storaging multifunctional carbon fiber composites based on Nano‐SiO2 reinforced epoxy matrix structural electrolytes

AbstractMultifunctional carbon fiber composite materials capable of storing energy and carrying structural loads have advantages for aerospace structures. In this paper, a structural supercapacitor that consists of an epoxy‐based solid polymer electrolytes (E‐SPEs) and carbon fiber was proposed. To develop an E‐SPEs with better mechanical properties and ionic conductivity, Nano‐SiO2 was introduced into the solid polymer electrolytes. Nano‐SiO2 reinforced E‐SPEs (Nano‐SiO2/E‐SPEs) show improved mechanical properties (Young's modulus [E] = 0.85 GPa) and ionic conductivity (4.99 × 10−4 S cm−1), compared to E‐SPEs without Nano‐SiO2. Structural supercapacitors were further prepared by combining E‐SPEs with carbon fibers. The structural supercapacitor prepared with Nano‐SiO2/E‐SPEs exhibits the higher power and energy density (261.93 W kg−1 and 2.11 Wh kg−1) compared to the structural supercapacitor prepared with E‐SPEs without Nano‐SiO2 (51 W kg−1 and 0.34 Wh kg−1), indicating improved mechanical and energy storage properties for structural supercapacitors after incorporation of Nano‐SiO2. This strategy has great potential in enhancing performance of structural energy storage composite materials for application in next‐generation aerospace vehicles.

Nanomaterials in Solid-State Batteries: Enhancing Safety and Performance

Solid-state batteries (SSBs), utilizing solid electrolytes instead of liquid ones, represent a promising advancement in energy storage technology due to their higher energy density and enhanced safety. Despite their potential, SSBs face significant challenges such as high interfacial resistance, low ionic conductivity, and high production costs. Recent advancements in nanomaterial technology have offered innovative solutions to these issues. Nanomaterials with high specific surface areas and controllable morphologies optimize interfacial contact, reduce resistance, and enhance ionic conductivity through efficient ion transport channels. Additionally, surface modifications and doping improve the chemical and thermal stability of SSB components, extending battery life and preventing adverse reactions. Although initial preparation costs are high, advancements in production technology and large-scale manufacturing are expected to lower these costs, facilitating commercialization. Future research should focus on new nanostructure designs, nanocomposites, and interfacial engineering to further enhance battery performance and safety. Understanding the influence of nanomaterials on safety performance and improving thermal and mechanical shock resistance are crucial for the reliable implementation of solid-state batteries in practical applications.

Bismuth and Fluorine Dual‐Doping of Lithium Argyrodite toward High‐Performance All‐Solid‐State Lithium Metal Batteries

The chlorine‐rich lithium argyrodite is considered a promising superionic conductor electrolyte, but its practical application is limited due to poor air stability and instability toward lithium metal. In this work, BiF3 is proposed as a multi‐functional dopant for electrolyte modification, and the effects on the ionic conductivity, air stability, critical current density, and electrolyte/Li metal interfacial stability are studied. The results show that the doped electrolyte Li5.54P0.98Bi0.02S4.5Cl1.44F0.06 (LPBiSClF0.06) still maintains a relatively high ionic conductivity of 5.37 mS cm−1. Additionally, the formation of BiS45− unit and LiBiS2 phase provides high air/moisture resistibility. Meanwhile, the critical current density of the Li/LPBiSClF0.06/Li cell is increased two‐fold (2.1 mA cm−2). The in‐situ formation of LiF and Li‐Bi alloy at the lithium metal/electrolyte interface plays a key role in achieving high performance. As a result, the assembled LCO@LNO/LPBiSClF0.06/Li battery retains 78.4% of its capacity after 100 cycles at 0.2C.

Nanostructured Solid Electrolytes for Enhanced Safety and Performance of Battery Materials

Solid-state batteries (SSB) have garnered significant attention by reason of their potential advantages over traditional liquid electrolyte batteries, including higher energy density, enhanced safety, and reduced volume. However, the development and implementation of solid electrolytes confront several challenges, such as lower ionic conductivity, dendrite formation, and interface stability issues. This review explores the current advancements in solid electrolytes (SLs), with a focus on nanostructured materials, including solid polymer electrolytes (SPEs), solid inorganic electrolytes (SIEs), and composite solid electrolytes (CSEs). The review highlights the benefits of nanostructuring in improving mechanical intensity, ionic conductivity and thermostability. Key methods for synthesizing nanostructured solid electrolytes (NSLs), such as the sol-gel method and 3D printing, are discussed. Additionally, the review addresses critical challenges, including the high cost of materials and manufacturing processes, and proposes future research directions to overcome these barriers. The purpose is to comprehensively understand the current status and future potential of NSL in promoting SSB technology.

Nanotechnology in Lithium-Sulfur Batteries: Addressing the Challenges in Battery Cycle Life and Safety

Lithium-sulfur (Li-S) batteries, with their high energy density and affordable material prices, are a viable alternative to ordinary lithium-ion batteries, especially for electric cars. Their actual application is limited by challenges such as substantial volume expansion, low electrical conductivity, and the polysulfide shuttle effect, despite their advantages. This research investigates how incorporating nanomaterials into Li-S battery cathodes, anodes, and electrolytes might improve battery performance and analyzes the potential of nanotechnology to address these problems. The application of metal oxides, graphene oxide, and carbon nanofibers to improve the stability and conductivity of sulfur cathodes is covered. Additionally, it examines anode protection strategies using nanocoating and protective layers to inhibit dendrite growth and improve safety. The incorporation of nanoparticles in electrolytes to improve ionic conductivity and reduce side reactions is also analyzed. Despite the progress, challenges such as the polysulfide shuttle effect and volume changes remain. The paper concludes with recommendations for future research to develop commercially viable Li-S batteries with higher capacity, longer lifespan, and improved safety.

High‐Entropy Electrolyte Driven by Multi‐Solvation Structures for Long‐Lifespan Aqueous Zinc Metal Pouch Cells

Aqueous zinc metal batteries (AZMBs) are promising for grid‐scale energy storage due to their low cost and high safety. However, poor stability and an unfavorable freezing point hinder their actual application. Herein, a ternary salts‐based high‐entropy electrolyte (HEE) composed of Zn0.2Na0.4Li0.4(ClO4)1.2·7H2O is proposed to address the above issues. The addition of perchlorate salts with different cations reduces the size of ion clusters, significantly increases the solvation structure species, and promotes the anion‐rich Zn2+ solvation structures, resulting in an enlarged electrochemical stability window, favorable viscosity and ionic conductivity, and low freezing point. Furthermore, characterization and calculations confirm that multiple types of solvation structures effectively increase the electrolyte entropy. As a consequence, the Zn/Zn symmetric cells in HEE can sustainably cycle for at least 1000 hours and 1500 hours under room and subzero temperatures, respectively. The Na0.33V2O5/Zn and polyaniline/Zn full cells can even last for 30000 and 20000 cycles without capacity decay at −20 °C, respectively. The pouch cells employing HEE deliver promising capacity and stability, even at high mass loading of active materials. This strategy of introducing multiple salts with different cations to construct a high‐entropy environment provides a facile approach for high‐performance and long‐lifespan AZMBs across a wide temperature range.

Anion‐Anchored Polymer‐in‐Salt Solid Electrolyte for High‐Performance Zinc Batteries

AbstractSolid polymer electrolytes hold promise for addressing key challenges in rechargeable zinc batteries (ZBs) utilizing aqueous electrolytes. However, achieving simultaneous high ionic conductivity, excellent mechanical strength, and a high cation transference number while effectively suppressing Zn dendrites remains challenging. Herein, we design a novel polymer‐in‐salt solid electrolyte (PISSE) composed of polyacrylonitrile (PAN), zinc chloride (ZnCl2), and niobium pentoxide with oxygen vacancies (Nb2O5‐x) with high ionic conductivity. PAN polymer matrix provides the electrolyte good mechanical properties and solubility of Zn salt. The high concentration of ZnCl2 effectively decouples the Zn2+ from polymer chain segments and provides more ionic conduction amorphous region. Moreover, incorporating Nb2O5‐x filler accelerates Zn2+ desolvation by anchoring (ZnxCly)2x–y clusters and enhances the system's mechanical properties, achieving a superior Zn2+ transference number (~0.93) and interfacial stability. Consequently, the optimized PISSE demonstrates exceptional stability during prolonged cycling periods, wide temperature range operation (−40 °C to 60 °C), remarkable flexibility, and compatibility with diverse electrode materials. This study provides valuable insights into the design of solid‐state electrolytes based on ZBs and elucidates their multifunctional prospects.

High-Entropy Electrolyte Driven by Multi-Solvation Structures for Long-Lifespan Aqueous Zinc Metal Pouch Cells.

Aqueous zinc metal batteries (AZMBs) are promising for grid-scale energy storage due to their low cost and high safety. However, poor stability and an unfavorable freezing point hinder their actual application. Herein, a ternary salts-based high-entropy electrolyte (HEE) composed of Zn0.2Na0.4Li0.4(ClO4)1.2·7H2O is proposed to address the above issues. The addition of perchlorate salts with different cations reduces the size of ion clusters, significantly increases the solvation structure species, and promotes the anion-rich Zn2+ solvation structures, resulting in an enlarged electrochemical stability window, favorable viscosity and ionic conductivity, and low freezing point. Furthermore, characterization and calculations confirm that multiple types of solvation structures effectively increase the electrolyte entropy. As a consequence, the Zn/Zn symmetric cells in HEE can sustainably cycle for at least 1000 hours and 1500 hours under room and subzero temperatures, respectively. The Na0.33V2O5/Zn and polyaniline/Zn full cells can even last for 30000 and 20000 cycles without capacity decay at -20 °C, respectively. The pouch cells employing HEE deliver promising capacity and stability, even at high mass loading of active materials. This strategy of introducing multiple salts with different cations to construct a high-entropy environment provides a facile approach for high-performance and long-lifespan AZMBs across a wide temperature range.

Comprehensive and Robust Anti-Jamming Dual-Electrode Pair Sensor.

Capacitive flexible sensors often encounter instability caused by temperature fluctuations, electromagnetic interference, stray capacitance effects, and signal noise induced by ubiquitous vibrations. The challenge lies in achieving comprehensive anti-jamming abilities while preserving a simplistic structure and manufacturing process. To tackle this dilemma, a straightforward and effective design is utilized to achieve comprehensive and robust anti-jamming properties in capacitive sensors. Electrospinning thermoplastic polyurethane (TPU) fiber mats soak with ionic liquid (IL) to create a co-continuous structure (TPU@IL) with high ionic conductivity and dielectric constant, which acts as the sensing units. The sensing mechanism of the TPU@IL with multiple electrode pairs encapsulated by polyethylene terephthalate (PET) is systematically elucidated. The optimal dual-electrode pair design for capacitive and resistive sensors, which have different sensitivities to temperature and stress, simultaneous realizes temperature-stress dual-mode sensing. Remarkably, the sensitivity curve of the TPU@IL/PET capacitive sensor exhibits an intriguing rarely reported S-shape with an adjustable step stress point. No liquid leakage even during extensive stress-strain cycling (>4000 cycles). Despite a slight compromise in sensitivity and response time, the TPU@IL/PET sensor demonstrates exceptional electromechanical stability, reliability, and powerful anti-jamming abilities against various interferences. A simple yet innovative sensor design enhances the performance and applicability of capacitive sensors in challenging environments.

Polyoxovanadates as Effective Coating Materials for Layered Ni‐rich Oxide Cathodes in Liquid‐ and Solid‐State Batteries

Advanced coatings for improving the electro‐chemo‐mechanical stability of high‐capacity, layered Ni‐rich oxide cathode materials play an important role in modern battery technology. Vanadium‐based protective coatings are particularly promising owing to their ability to provide high ionic conductivity and their intrinsic robustness. In addition, diminishing or eliminating residual lithium through surface coating shows great promise in mitigating capacity losses and addressing associated challenges. Herein, we report on a strategic exploration of a facile coating approach for Ni‐rich LiNixCoyMn1−x−yO2 (NCM851005, 85% Ni content) utilizing polyoxovanadate. Specifically, TBA3H3[V10O28] was applied due to its solubility in non‐aqueous media, avoiding H2O‐induced side reactions and achieving a more uniform surface coverage. The cycling performance of NCM851005 before and after modification was tested in conventional Li‐ion cells, as well as in all‐solid‐state batteries with a lithium thiophosphate superionic electrolyte. Our findings highlight the potential of polyoxovanadate‐derived protective coatings for improving the cyclability of Ni‐rich cathodes.

Selective ion transport through hydrated micropores in polymer membranes.

Ion-conducting polymer membranes are essential in manyseparation processes and electrochemical devices, including electrodialysis1, redox flow batteries2, fuel cells3 and electrolysers4,5. Controlling ion transport and selectivity in these membranes largely hinges on the manipulation of pore size. Although membrane pore structures can be designed in the dry state6, they are redefined upon hydration owing to swelling in electrolyte solutions. Strategies to control pore hydration and a deeper understanding of pore structure evolution are vital for accurate pore size tuning. Here we report polymer membranes containing pendant groups of varying hydrophobicity, strategically positioned near charged groups to regulate theirhydration capacity and pore swelling. Modulation of thehydrated micropore size (less thantwo nanometres) enables direct control over water and ion transport across broad length scales, as quantified by spectroscopic and computational methods. Ion selectivity improves in hydration-restrained pores created by more hydrophobic pendant groups. These highly interconnected ion transport channels, with tuned pore gate sizes, show higher ionic conductivity and orders-of-magnitude lower permeation rates of redox-active species compared with conventional membranes, enabling stable cycling of energy-dense aqueous organic redox flow batteries. This pore size tailoringapproach provides a promising avenue to membranes with precisely controlled ionic and molecular transportfunctions.

Experimental and Theoretical Investigation of Anisotropic Proton Conduction in Two-Dimensional Metal-Organic Frameworks.

Two-dimensional (2D) materials are known for their potential to exhibit anisotropic transport properties due to their layered structures. However, the anisotropic ion conduction of 2D metal-organic frameworks (MOFs) has been rarely explored. In this study, we investigated the anisotropic proton conduction along the in-plane and stacking directions of two analogs of undulating 2D MOFs: [Mn(salen)]2[Pt(CN)4]·H2O (MnPt) and [Mn(salen)]2[PtI2(CN)4]·H2O (MnPtI). This investigation was conducted using both experimental methods, involving single crystals, and theoretical calculations. Compared to the relatively isotropic proton conduction of MnPt at 85 °C and 95% relative humidity (RH), with a stacking direction conductivity (σstacking) of 1.8 × 10-5 S/cm, which is approximately 2.9 times the in-plane conductivity (σin-plane), MnPtI exhibited highly anisotropic proton conduction. The σstacking of MnPtI under the same conditions (85 °C, 95% RH) was 1.5 × 10-4 S/cm, which is 83 times higher than its σin-plane. Additionally, the activation energy for proton conduction in MnPtI ranged from 0.65 to 0.73 eV, which is higher than the 0.48 eV observed for MnPt. Theoretical calculations confirmed that slight differences in local structures, including node distortions between MnPt and MnPtI, significantly influenced the activation energies for water migration. This was attributed to the formation of hydrogen bonds between layers and water molecules.

A Li-Rich Fluorinated Lithium Zirconium Chloride Solid Electrolyte for 4.8 V-Class All-Solid-State Batteries.

Chloride solid-state electrolytes (SEs) represent an important advance for applications in all-solid-state batteries (ASSBs). Among various chloride SEs, lithium zirconium chloride (Li2ZrCl6) is an attractive candidate considering the high natural abundance of Zr. However, Li2ZrCl6 meets the challenge in practical ASSBs because of its limited ionic conductivity and instability when paired with high-voltage cathodes. This is a major drawback, which can result in a high internal resistance, a low capacity utilization of cathode, and poor cycle stability, especially at high voltage. Existing methods cannot achieve simultaneous enhancement on both ionic conductivity and high-voltage stability due to a trade-off between lithium-ion migration and structural stability. Here a two-pronged strategy based on partial fluorination and incorporation of lithium ions in excess of stoichiometric ratios is introduced that enables high-voltage stability while increasing ionic conductivity concurrently. The Li-rich fluorinated halide SE (Li2.3ZrCl6.1F0.2) exhibits a significant advancement in performance, with an ionic conductivity that is double that of the pristine Li2ZrCl6 and much better high-voltage stability. By leveraging Li2.3ZrCl6.1F0.2 with the LiCoO2 cathode and the Li-In anode, the all-solid-state cell exhibits a remarkable initial specific capacity (198.0 mAh g-1 at 0.1 C) and a high capacity retention (78.5% after 150 cycles) within 3.0-4.8V.

Research Progress on Solid-State Electrolytes in Solid-State Lithium Batteries: Classification, Ionic Conductive Mechanism, Interfacial Challenges

Solid-state lithium batteries exhibit high-energy density and exceptional safety performance, thereby enabling an extended driving range for electric vehicles in the future. Solid-state electrolytes (SSEs) are the key materials in solid-state batteries that guarantee the safety performance of the battery. This review assesses the research progress on solid-state electrolytes, including polymers, inorganic compounds (oxides, sulfides, halides), and organic–inorganic composites, the challenges related to solid-state batteries in terms of their interfaces, and the status of industrialization research on solid-state electrolytes. For each kind of solid-state electrolytes, details on the preparation, properties, composition, ionic conductivity, ionic migration mechanism, and structure–activity relationship, are collected. For the challenges faced by solid-state batteries, the high interfacial resistance, the side reactions between solid-state electrolytes and electrodes, and interface instability, are mainly discussed. The current industrialization research status of various solid electrolytes is analyzed in regard to relevant enterprises from different countries. Finally, the potential development directions and prospects of high-energy density solid-state batteries are discussed. This review provides a comprehensive reference for SSE researchers and paves the way for innovative advancements in regard to solid-state lithium batteries.

2D Graphene‐Like Carbon Coated Solid Electrolyte for Reducing Inhomogeneous Reactions of All‐Solid‐State Batteries

AbstractRecent studies have identified an imbalance between the electronic and ionic conductivities as the drivers of inhomogeneous reactions in composite cathodes, which cause the rapid degradation of all‐solid‐state battery (ASSB). To mitigate localized overcharge and utilize isolated active materials, the study proposes the coating of an argyrodite‐type Li6PS5Cl solid electrolyte (SE) with graphene‐like carbon (GLC@LPSCl), a 2D conductive material, to offer a continuous three‐dimensionally connected electron pathway within the composite cathode to facilitate ion mobility and promote homogeneous reactions. Despite reducing the content of the conducting agent, it is observed that the GLC@LPSCl cell exhibits high initial Coulombic efficiency and discharge capacity, reducing the inhomogeneous reactivity after 200 cycles compared with when ordinary conductive agents are deployed. Additionally, the presence of GLC@LPSCI surface suppresses the interfacial reaction between SE–cathode material, thus imparting the cell with excellent capacity retention (≈90%) after 200 cycles. Furthermore, the cell performance improves even after a fourfold increase in the cathode loading amount, demonstrating the criticality of a well‐developed continuous electron pathway to cell performance and highlighting the key role of ensuring a balance between the electron and ion conductivities in the development of high‐energy‐density and high‐power ASSBs.

Robust, High-Temperature-Resistant Polyimide Separators with Vertically Aligned Uniform Nanochannels for High-Performance Lithium-Ion Batteries.

Separator is an essential component of lithium-ion batteries (LIBs), playing a pivotal role in battery safety and electrochemical performance. However, conventional polyolefin separators suffer from poor thermal stability and nonuniform pore structures, hindering their effectiveness in preventing thermal shrinkage and inhibiting lithium (Li) dendrites. Herein, we present a robust, high-temperature-resistant polyimide (PI) separator with vertically aligned uniform nanochannels, fabricated via ion track-etching technology. The resultant PI track-etched membranes (PITEMs) effectively homogenize Li-ion distribution, demonstrating enhanced ionic conductivity (0.57 mS cm-1) and a high Li+ transfer number (0.61). PITEMs significantly prolong the cycle life of Li/Li cells to 1200 h at 3 mA cm-2. For Li/LiFePO4 cells, this approach enables a specific capacity of 143 mAh g-1 and retains 83.88% capacity after 300 cycles at room temperature. At 80 °C, the capacity retention remains at 85.92% after 200 cycles. Additionally, graphite/LiFePO4 pouch cells with PITEMs display enhanced cycling stability, retaining 73.25% capacity after 1000 cycles at room temperature and 78.41% after 100 cycles at 80 °C. Finally, PITEMs-based pouch cells can operate at 150 °C. This separator not only addresses the limitations of traditional separators, but also holds promise for mass production via roll-to-roll methods. We expect this work to offer insights into designing and manufacturing of functional separators for high-safety LIBs.

In Situ Gel Polymer Electrolyte with Rapid Li+ Transport Channels and Anchored Anion Sites for High‐Current‐Density Lithium‐Ion Batteries

AbstractIn situ formed gel polymer electrolytes (GPEs) have advantages in safety and adaptability to current high‐voltage lithium‐ion batteries (LIBs). However, it is challenging for GPEs to achieve stable cycling at high current densities. A flexible framework is proposed for stable in situ GPE, by introducing ─CF3 groups to the polymer network to establish rapid Li+ transport channels, and incorporating secondary amine N─H groups to anchor anion. The obtained GPE exhibits a high ionic conductivity of 2.6 mS cm−1 and a high Li+ transference number of 0.67. The assembled Li||NCM811 cell demonstrates excellent rate performance, with a discharging capacity of 112.3 mAh g⁻¹ at 10C, and capacity retention of 87.6% after 260 cycles at 1C. Furthermore, the assembled graphite||NCM811 cell demonstrates excellent long‐term cycling stability with impressive capacity retention of 73.2% after 300 cycles 3C (1.8 mA cm−2). This work presents a promising approach to enhancing the cycling stability of GPEs for high‐voltage LIBs at high current density.

Solar light driven photochromic membranes with viologen additives in PVDF/PVP matrix

This study explores the synthesis and characterization of photochromic Polyvinylidenefluoride/Polyvinylpyrrolidone (PVDF/PVP)-based membranes, prepared through an in situ thiol-ene click reaction by incorporating viologen derivatives with different counter ions. Viologens are well-known for their light-sensitive properties and ability to change color, making them useful in various optoelectronic applications. The membranes developed in this study exhibit significant improvements in their interactions with light as a result of improved morphology and enhanced ionic conductivity (≈4 × 10−4 S cm–1) with higher porosity (Ra: 11.26–33.76 nm) compared to conventionally prepared membranes. These membranes show the ability to block almost all ultraviolet (UV) and a 90% of visible light after irradiation. Thanks to these properties, the membranes undergo visible color changes when exposed to sunlight, making them suitable for photochromic and thermochromic applications. The findings of this study could contribute to the development of innovative coating materials that enhance energy efficiency, potentially being applied to buildings, automotive windows, and other surfaces.