Ion Population Research Articles

On Alfvénic turbulence of solar wind streams observed by Solar Orbiter during March 2022 perihelion and their source regions

It has been recently accepted that the standard classification of the solar wind solely according to flow speed is outdated, and particular interest has been devoted to the study of the origin and evolution of so-called Alfvénic slow solar wind streams and to what extent such streams resemble or differ from fast wind. In March 2022, Solar Orbiter completed its first nominal phase perihelion passage. During this interval, it observed several Alfv\'enic streams, allowing for characterization of fluctuations in three slow wind intervals (AS1-AS3) and comparison with a fast wind stream (F) at almost the same heliocentric distance. This work makes use of Solar Orbiter plasma parameters from the Solar Wind Analyzer (SWA) and magnetic field measurements from the magnetometer (MAG). The magnetic connectivity to the solar sources of selected solar wind intervals was reconstructed using a ballistic extrapolation based on measured solar wind speed down to the (spherical) source surface at 2.5 R$_s$ below which a potential field extrapolation was used to map back to the Sun. The source regions were identified using SDO/AIA observations. A spectral analysis of in situ measured magnetic field and velocity fluctuations was performed to characterize correlations, Alfv\'enicity, normalized cross-helicity, and residual energy in the frequency domain as well as intermittency of the fluctuations and spectral energy transfer rate estimated via mixed third-order moments. A machine learning technique was used to separate proton core, proton beam, and alpha particles and to study v--b correlations for the different ion populations in order to evaluate the role played by each population in determining the Alfvénic content of solar wind fluctuations. The comparison between fast wind and Alfvénic slow wind intervals highlights the differences between the two solar wind regimes: The fast wind is characterized by larger amplitude fluctuations, and magnetic and velocity fluctuations are closer to equipartition of energy. In fact the Alfv\'enic slow wind streams appear to be on a spectrum of wind types, with AS1, originating from open field lines neighboring active regions and displaying similarities with the fast wind in terms of fluctuation amplitude and turbulence characteristics, but not with respect to the alpha particles and proton beams. The other two slow streams differed both in their sources as well as plasma characteristics, with AS2 coming from the expansion of a narrow coronal hole corridor and AS3 from a region straddling a pseudostreamer. The latter displayed the coldest and highest density but the slowest stream with the smallest fluctuation amplitude and greatest magnetic energy excess. It also showed the largest scatter in proton beam speeds and the greatest difference in speed between proton beam and alpha particles. This study shows how the old fast--slow solar wind dichotomy, already called into question by the observations of slower Alfv\'enic solar wind streams, should further be refined, as the Alfv\'enic slow wind, originating in different solar wind regions, show significant differences in density, temperature, and proton and alpha-particle properties in the inner heliosphere. The observations presented here provide the starting point for a better understanding of the origin and evolution of different solar wind streams as well as the evolving turbulence contained within.

Evaluating deuterated-xylene for use as a fusion neutron spectrometer.

The spectrum of neutrons emitted by thermonuclear plasmas encodes information about the fuel ion distribution function. Measuring these fast neutron spectra with sufficient resolution allows for the measurement of plasma properties such as the ion temperature and strength and energy of fast ion populations. Liquid organic scintillators are a commonly used fast neutron detection technology because of their high detection efficiency and ability to discriminate between neutrons and gammas. However, performing detailed spectroscopy with these detectors is difficult because of the isotropic nature of neutron scattering on protons, the dominant mechanism of interaction. Deuterium-based scintillators have shown promise as a superior spectrometer technology because of the anisotropic nature of neutron scattering on deuterium, which significantly improves the condition number of the detector response matrix [Lawrence et al., Nucl. Instrum. Methods Phys. Res., Sect. A 729, 924 (2013)]. Deuterated-xylene, now available commercially, has advantages in light output and safety over benzene-based deuterated scintillators [Becchetti et al., Nucl. Instrum. Methods Phys. Res., Sect. A 820, 112 (2016)]. We present experimental spectrum unfoldings made by 2 in. right cylindrical protiated-xylene and deuterated-xylene detectors with response matrices generated with Geant4 and additional data from the literature. We compare their performance by measuring the neutron spectrum produced by an AmBe source and deuterium-tritium (DT) neutron generators. We find that the deuterated scintillator outperforms the protiated one for AmBe and DT spectra, suggesting deuterated-xylene should be considered for future fusion neutron spectrometry applications.

Universal Nonthermal Power-law Distribution Functions from the Self-consistent Evolution of Collisionless Electrostatic Plasmas

Collisionless systems often exhibit nonthermal power-law tails in their distribution functions. Interestingly, collisionless plasmas in various physical scenarios (e.g., the ion population of the solar wind) feature a v −5 tail in their velocity (v) distribution, whose origin has been a long-standing puzzle. We show this power-law tail to be a natural outcome of the collisionless relaxation of driven electrostatic plasmas. Using a quasi-linear analysis of the perturbed Vlasov–Poisson equations, we show that the coarse-grained mean distribution function (DF), f 0, follows a quasi-linear diffusion equation with a diffusion coefficient D(v) that depends on v through the plasma dielectric constant. If the plasma is isotropically forced on scales larger than the Debye length with a white-noise-like electric field, D(v) ∼ v 4 for σ < v < ω P/k, with σ the thermal velocity, ω P the plasma frequency, and k the characteristic wavenumber of the perturbation; the corresponding quasi-steady-state f 0 develops a v −(d + 2) tail in d dimensions (v −5 tail in 3D), while the energy (E) distribution develops an E −2 tail independent of dimensionality. Any redness of the noise only alters the scaling in the high v end. Nonresonant particles moving slower than the phase velocity of the plasma waves (ω P/k) experience a Debye-screened electric field, and significantly less (power-law suppressed) acceleration than the near-resonant particles. Thus, a Maxwellian DF develops a power-law tail, while its core (v < σ) eventually also heats up but over a much longer timescale. We definitively show that self-consistency (ignored in test-particle treatments) is crucial for the emergence of the universal v −5 tail.

Decoding the formation of hammerhead ion populations observed by Parker Solar Probe

In situ observations by the Parker Solar Probe (PSP) have revealed new properties of the proton velocity distributions (VDs), including hammerhead features that suggest a non-isotropic broadening of the beams. The present work proposes a very plausible explanation for the formation of hammerhead proton populations through the action of a proton firehose-like instability triggered by the proton beam. We investigated a self-generated firehose-like instability driven by the relative drift of ion populations using a simplified moment-based quasi-linear (QL) theory. While simpler and faster than advanced numerical simulations, this toy model provided rapid insights and concisely highlighted the role of plasma micro-instabilities in relaxing the observed anisotropies of particle VDs in the solar wind and space plasmas. The QL theory proposed here shows that the resulting transverse waves are right-hand polarized and have two consequences on the protons: (i) They reduce the relative drift between the beam and the core, but above all, (ii) they induce a strong perpendicular temperature anisotropy specific to the observed hammerhead ion beam. Moreover, the long-run QL results suggest that these hammerhead distributions are rather transitory states that are still subject to relaxation mechanisms, in which instabilities such as the one discussed here are very likely involved. This foundational work motivates future detailed studies using advanced methods.

Equatorial Source of Oblique Electromagnetic Ion Cyclotron Waves: Peculiarities in the Ion Distribution Function

AbstractElectromagnetic ion cyclotron (EMIC) waves are important for Earth's inner magnetosphere as they can effectively drive relativistic electron losses to the atmosphere and energetic (ring current) ion scattering and isotropization. EMIC waves are generated by transversely anisotropic ion populations around the equatorial source region, and for typical magnetospheric conditions this almost always produces field‐aligned waves. For many specific occasions, however, oblique EMIC waves are observed, and such obliquity has been commonly attributed to the wave off‐equatorial propagation in curved dipole magnetic fields. In this study, we report that very oblique EMIC waves can be directly generated at the equatorial source region. Using THEMIS spacecraft observations at the dawn flank, we show that such oblique wave generation is possible in the presence of a field‐aligned thermal ion population, likely of ionospheric origin, which can reduce Landau damping of oblique EMIC waves and cyclotron generation of field‐aligned waves. This generation mechanism underlines the importance of magnetosphere‐ionosphere coupling processes in controlling wave characteristics in the inner magnetosphere.

On Velocity Stopbands in Electrostatic Solitary Wave Propagation in Magnetospheric Plasma in the Presence of an Ion Beam—Application in the Solar Wind

Satellite observations in the Earth’s magnetosphere suggest a coexistence of different types of ion populations, such as protons and heavier helium ions (alpha particles) transported by the solar wind. We have undertaken an investigation, from first principles, of the conditions for the occurrence of electrostatic solitary waves in such a multi-ion plasma environment. Nonlinear analysis has been employed to explore the effect of an ion beam on the occurrence of stopbands in a multicomponent plasma consisting of Boltzmann electrons and two ion species, modeled as cold and warm (adiabatic) ions. A “stopband” is an interval of pulse speed (mach (Mach number) values in which solitary waves cannot propagate. Such stopbands are known to exist in relation to fast ion-acoustic solitary waves (exclusively). Our parametric analysis reveals that the stopband widens over the range of cold ion charge density (values) upon increasing speed of a hot ion beam moving along the direction of wave propagation. However, the stopband becomes narrower in the case of a counterpropagating beam. Similarly, the streaming of a cold ion beam fluid along (or antiparallel) to the wave direction leads to the narrowing (or widening, respectively) of the stopband. The fast soliton existence (velocity) domain is characterized by two critical points (a crossover and a turning point), which are affected by the beam. Our study could be relevant to understanding energy dissipation processes in the fast solar wind associated with relative drifts between the major (protons) and minor (alpha particles) ions which results in the heating of both species.

Experimental and numerical investigation of the Doppler-shifted resonance condition for high frequency Alfvén eigenmodes on ASDEX Upgrade

Abstract The Doppler-shifted resonance condition for high frequency Alfvénic eigenmodes has been extensively studied on ASDEX Upgrade in the presence of one or a combination of two neutral beam injected (NBI) fast ion populations. In general, only centrally deposited NBI sources drive these modes, while off-axis sources globally stabilize the mode activity. For the case of a single central NBI source, the observed trend is: the highest frequency modes are driven by the lowest energy and lowest pitch angle NBI sources, in line with the expectation from the Doppler-shifted resonance condition. The expected mode frequencies are determined analytically from the two-fluid cold plasma dispersion relation and the most unstable frequency relation, while the mode growth rates are estimated using the fast ion slowing down distribution functions from the ASCOT code. The overall mode frequency trend in a source-to-source variation is tracked, although a systematic overestimate of ∼1 MHz is observed. Possible causes of this overestimate include the finite size of the resonant fast ion drift orbit and non-linear effects such as mode sideband formation. Alternatively, the expected mode frequencies are determined by tracking the growth rate maxima trajectories, this method improves the agreement with the experimentally measured values. A combination of two central mode-driving NBI sources results in the suppression of the mode driven by the lowest energy and the lowest pitch angle NBI source. Computing the analytically expected mode frequency following the method outlined above, again, generally tracks the experimentally observed trend. The mode’s Alfvénic nature allows for a practical application to track the core hydrogen fraction by following the mode frequency changes in response to a varying ion mass density. Such application is demonstrated in a discharge where the average ion mass is varied from ∼2m p to ∼1.5m p (where m p is the proton mass) via a hydrogen puff in a deuterium plasma, in the presence of a strong mode activity. The expected mode frequency changes are computed from the existence of the resonance condition, and the values track the measured results with an offset of ∼0.5 MHz. Overall, the results suggest an intriguing possibility to monitor and control the D-T ion fraction in the core of a fusion reactor in real time using a non-invasive diagnostic.

A simplified coaxial ion trap mass analyzer: Characterization of the simplified toroidal ion trap with a rectilinear ion guide

A new miniature coaxial ion trap mass analyzer with a rectilinear ion guide has been constructed using a combination of planar and cylindrical electrodes. The results reported here focus on characterizing the performance of the rectilinear ion guide and simplified toroidal ion trap components. The simplified toroidal ion trap was found to have an ion capacity in excess of 105 ions and mass spectral resolution of 0.5–0.6 when used as a mass analyzer. The ion storage efficiency within the toroidal trapping region was evaluated and found the stored ion population decreased exponentially with storage time. Ion losses depended slightly on the stored βz condition. Ion losses within the toroidal region are attributed primarily to field instabilities at the intersection point of the two components while charge exchange reactions were observed but considered a minor loss mechanism. The ability to mass selectively ejection ions of a specific mass from the toroidal trapping region was characterized and found to approach 100 % efficiency under appropriate ejection conditions.

The consequences of tritium mix for simulated ion cyclotron emission spectra from deuterium-tritium plasmas

Abstract Measurements of ion cyclotron emission (ICE) are obtained from most large magnetically confined fusion (MCF) plasma experiments, and may be used in future to quantify properties of the fusion-born alpha-particle population in deuterium-tritium (DT) plasmas in ITER. ICE is driven by spatially localised, strongly non-Maxwellian, minority energetic ion populations which relax collectively under the magnetoacoustic cyclotron instability (MCI). ICE spectral peaks are typically observed at, near, or separated by, integer harmonics of the energetic ion cyclotron frequency. Here, for the first time, we study how simulated ICE spectra from DT plasmas vary with tritium concentration and compare with an observed JET DT ICE spectrum. We incorporate a population of thermal tritons, in addition to thermal deuterons and an energetic minority population of fusion-born alpha-particles, in simulations with the kinetic particle-in-cell (PIC) code EPOCH. This code has previously been used extensively for interpretation of ICE observations in terms of the self-consistent gyro-resolved collective Maxwell-Lorentz dynamics of tens of millions of simulation particles. Our simulation parameters are relevant to the ICE-generative outer midplane edge region of JET DT plasma 26148, which included 11% tritium. Quantifying the variation of simulated ICE power spectra with tritium concentration reveals that our simulation with 11% tritium concentration most accurately represents the observed ICE spectrum from this plasma. This outcome is encouraging for the diagnostic application of ICE to fusion plasmas containing two thermal ion species, including future DT plasmas.

Operando tracking of ion population changes in the EDL electrode of a lithium-ion capacitor during its charge/discharge

This study elucidates in-pore ion population changes in an activated carbon (AC)-based electrode operating within an extended potential range, akin to the positive electrode of a lithium-ion capacitor (LIC). Molecular dynamics (MD) simulations applied to a battery-type electrolyte (1 mol L−1 LiPF6 in EC:DMC), both in bulk and adsorbed within a model porous carbon, reveal partial solvation of Li⁺ cations within the pores and complete desolvation of PF6⁻ anions in both states. Operando electrochemical dilatometry (ECD), in situ potentiostatic electrochemical impedance spectroscopy, and operando Raman spectroscopy on AC electrodes confirm: (i) ionic exchange followed by anion adsorption during initial hole injection from the point of zero charge (PZC) to 4.5 V vs. Li/Li⁺; (ii) desorption and peak liberation of trapped PF6⁻ at 3.2 V vs. Li/Li⁺ during hole withdrawal; (iii) perm-selective adsorption of partially solvated Li⁺ during electron injection down to 2.2 V vs. Li/Li⁺; (iv) cation desorption during electron withdrawal up to PZC followed by similar ionic exchange and anion adsorption (as described in (i)) at potentials above the PZC, however with peak liberation of trapped Li⁺ at 3.8 V vs. Li/Li⁺. The high polarization required to extract trapped ions from the pores may explain the reduced lifespan of LICs, requiring further work to eliminate trapping by optimizing porous texture.

Size polydisperse model ionic liquid under confinement: A molecular dynamics study

The performance of an electric double-layer capacitor is strongly influenced by the choice of electrolyte, and the use of ionic liquid (IL) mixtures as an electrolyte has shown great promise. In this study, a model IL made of a mixture of anions and size-polydisperse cations in equal numbers and confined between two electrodes is investigated by means of molecular dynamics simulations. In particular, using the extent of size-polydispersity (characterized by polydispersity index, δ) as a control parameter, we systematically explore its effect on the local structure, charge profile, ion size distribution in the vicinity of electrode surfaces, and differential capacitance. It is observed that the charge density profiles near cathode, i.e., region comprising both Stern and diffused layers, are significantly affected under the variation of δ in addition to the electrode charge density. Ion population, ordering of different-size cations, and its effective size in the vicinity of electrodes under neutral and applied potential conditions are also quantified. An interesting observation is that the effective cation size in the Stern layer decreases with increasing value of δ in the case of moderate to strong electrode surface charge density. This behaviour can be qualitatively understood from the interplay of enthalpic and entropic forces in the system. Finally, a non-monotomic dependence of capacitance on δ is observed with maximum value of capacitance at a rather small value of δ(≈3%) for the model system.

Role of Cairns–Gurevich ion distribution on nonlinear wave propagation in negatively charged dusty plasma

The study of dust-acoustic (DA) nonlinear electrostatic waves in dusty plasma is crucial for understanding plasma behavior in both astrophysical and laboratory environments. Dusty plasmas, characterized by the presence of negatively charged dust particles, exhibit complex dynamics influenced by various factors, including nonthermal electron and ion populations following Cairns–Gurevich distributions. This study addresses the problem of understanding wave propagation under these specific conditions by employing a set of fluid hydrodynamic equations for dust fluid, alongside appropriate electron and Cairns–Gurevich ion distributions, to model the dynamics and propagation of DA nonlinear electrostatic waves under specific plasma conditions with negatively charged dust particles. We derived a nonlinear Zakharov–Kuznetsov (ZK) equation to model the evolution of these waves and further transformed it into the nonlinear Schrödinger (NLS) equation to analyze rogue wave formation and identify unstable and stable zones within the plasma. We focused our analysis on the effects of key parameters, such as the nonthermal index, magnetic field strength, negative dust temperature ratio, polarization force, and density ratio, on the behavior of dust-acoustic waves (DAWs). The results demonstrated that soliton waves, explosive waves, and kink waves exhibit distinct behaviors depending on these parameters and the spatial context of Earth's magnetosphere. These findings provide new insights compared to previous studies into the conditions under which these waveforms emerge and evolve, especially in magnetized environments where earlier models were less effective at accurately characterizing or predicting wave behavior. By applying two different analytical methods, a direct integration approach and a generalized Kudryashov method, we expanded our understanding of nonlinear wave phenomena in dusty plasmas. Our results not only advance theoretical knowledge but also have practical implications for interpreting space plasma observations and guiding experimental design in plasma physics research. This study thus contributes to a more comprehensive understanding of plasma dynamics, with potential applications to astrophysical observation and laboratory plasma experimentation.

CO2 Loss into Solution: An Experimental Investigation of CO2 Electrolysis with a Membrane Electrode Assembly Cell.

In pursuit of commercial viability for carbon dioxide (CO2) electrolysis, this study investigates the operational challenges associated with membrane electrode assembly (MEA)-type CO2 electrolyzers, with a focus on CO2 loss into the solution phase through bicarbonate (HCO3 -) and carbonate (CO3 2-) ion formation. Utilizing a silver electrode known for selectively facilitating CO2 to CO conversion, the molar production of CO2, CO, and H2 is measured across a range of current densities from 0 to 600 mA/cm2, while maintaining a constant CO2 inlet flow rate of 58 mL/min. The dynamics of CO2 loss are monitored through measurements of pH changes in the electrolyte and carbon elemental balance analysis. Employing the concept of conservation of elemental carbon, a chemical reaction analysis is conducted, identifying the critical role of the hydroxide (OH-) ion. At lower current densities below 125 mA/cm2, where CO2 reduction predominates, it is observed that CO2 loss is proportional to current density, reaching up to 0.18 mmol/min, and directly correlates with the rate of OH- ion production, indicative of HCO3 -/CO3 2- ion formation. Conversely, at higher current densities above 450 mA/cm2, where hydrogen evolution is the dominant process, CO2 loss is shown to decouple from the OH- ion production rate with a constant limit condition of 0.12 mmol/min, regardless of the current density. This suggests that electrolyte-induced cathode flooding restricts CO2 access to cathode sites. Additionally, pH change in the electrolyte during the electrolysis further infers differing ion populations in the CO2 reduction and hydrogen evolution regimes, and their movement across the membrane. Continued monitoring of the pH change after the cessation of electricity offers insights into the accumulation of HCO3 -/CO3 2- ion at the cathode, influencing salt formation.

THEMIS observations of compressional Pc5 pulsations in the dawn- and duskside magnetosphere

We present case and statistical studies of compressional Pc5 pulsations observed by the THEMIS spacecraft in the dawn- and duskside magnetosphere from 2007 to 2011. A case study provides evidence for compressional Pc5 pulsations in the dawnside magnetosphere following the arrival of particles injected by a substorm and the subsequent growth of the drift mirror instability on February 27, 2011. The statistical study shows that the Pc5 pulsations occur in a weak or moderately disturbed magnetosphere but rarely develop during strong magnetic activity (i. e., for Dst index below −25 nT). The most striking characteristic of the compressional Pc5 pulsations is their localization in latitude and longitude over many consecutive days. Dawnside Pc5 pulsations occur under quieter conditions, last longer, and attain greater amplitudes than duskside Pc5 pulsations. We attribute compressional pulsations in both sectors to the drift mirror instability, with a warmer, more energized, and gradient-curvature drifting population of substorm-injected ions on the duskside and a colder ExB drifting population of plasma sheet ions on the dawnside.

Numerical investigations of spatiotemporal dynamics of space-charge limited collisional sheaths

Electrostatic particle-in-cell (PIC) and direct simulation Monte Carlo (DSMC) methods are used to compare the plasma dynamics of collisionless with collisional emissive sheaths in partially ionized environments. Space-charge limited emissive sheaths submersed in a plasma with a density of ∼1017 m−3 are examined using a PIC-DSMC solver, CHAOS. Collisionless emissive sheaths with plasma domains sufficiently long (30 and 60 Debye lengths, λD) are subject to strong oscillations due to two-stream electron instability, whereas emissive sheaths in weakly collisional conditions with a short domain (15 λD) exhibit self-spike (sawtooth) oscillations in the plasma field due to the trapped charge-exchange (CEX) ion population within the virtual cathode (VC) region. The two-stream electron instability leads to strong temporal fluctuations in the total emission current, with maximum deviations of 60% and 100% from the time-averaged current for the long plasma domains, whereas CEX collisions cause strong spikes in the emission current if the domain size is short. Our PIC-DSMC simulations show for the first time that the interaction of the two types of instabilities causes the strength of the self-spike to be weakened due to the strong fluctuations caused by the two-stream instability when a sufficiently long computational domain with ion-neutral collisions is employed. By conducting a two-dimensional Fast Fourier Transform (FFT) on the collisional and collisionless sheaths with long domains, we show that the transient evolution of CEX entrapment in the VC increases frequency of sheath oscillations up to two times the ion-acoustic frequencies observed in the collisionless sheath. CEX collisions weaken the VC region and result in a total emission current more than that obtained from the collisionless case for the same domain length. With a more rarefied neutral environment of 1019 m−3 in the plasma sheath, the total emission current increases only 4% in comparison with 14% for one order of magnitude denser environment, within 20 μs. In addition, the spike period is tested with different neutral temperatures and densities. While we do not observe any self-spike in the more rarefied environment, the spike period increased from 5 to 7.5 μs when the neutral temperature is increased from 300 to 2000 K in the denser environment with the simulation time of 20 μs.

Hybrid Modeling of Miniaturized 50 W Annular Hall Thruster

A 50-W-class annular Hall thruster is studied with a hybrid axial–radial two-dimensional model. Ions are described by a kinetic approach, whereas fluid conservation equations are solved for electrons. In such models, additional (anomalous) contributions must be added to the momentum-transfer electron collision frequency to obtain realistic values of the cross-field electron mobility. First, a parametric study is performed, where anomalous transport is described with a simple two-region model based on constant empirical parameters. The simulated global performance is subsequently compared with experimental measurements. Then, laser-induced fluorescence ion velocity measurements are employed to infer a continuous profile of the anomalous electron collision frequency along the channel centerline. The model reproduces the performance, the acceleration structure, the current oscillations, and the doubly charged ion fraction of the laboratory thruster. Measurements of the ion velocity distribution function highlight the presence of a slow ion population in the near plume. The production of the slow ions and their growth for increasing distances from the thruster channel exit is qualitatively reproduced by the model. The results obtained suggest that the generation and dynamics of the observed slow ions can be attributed to the presence of energetic electrons in the plume.

Ion confinement and separation using asymmetric electrodynamic fields in structures for lossless ion manipulations.

TW-SLIM ion mobility separations have demonstrated exceptional resolution by leveraging long paths with minimal loss. All previously reported experiments have used electrode surfaces which are mirrored to generate symmetrically opposing electric fields for ion confinement. However, work with other planar ion optics indicates this may be unnecessary. This study explores conditions under which separations may be obtained using a SLIM with asymmetric electric fields. The asymmetric field configuration was defined by applying a uniform DC potential to all electrodes of the top PCB of a standard TW-SLIM board pair, with no electrode placement modifications. This configuration was simulated in SIMION to assess transmission through the SLIM. A benchtop TW-SLIM instrument outfitted with a Faraday plate detector was modified likewise, so the top PCB had a uniform DC potential applied to all electrodes, while the bottom board was operated normally. Simulations show full ion transmission for four different m/z ion populations over a range of DC biases applied to the "pusher" board. Likewise, the modified benchtop instrument is capable of transmitting, separating, and cycling ions with minimal losses. The effect of pusher strength on separation quality is explored, and comparisons between the standard and modified SLIM are made with respect to resolving the +2 and +3 charge states of neurotensin ions. A functional IMS instrument using asymmetric confining fields demonstrates additional field modifications may be a means to achieve additional functionality with limited interruption of the analysis. A TW-SLIM PCB specifically designed as a pusher board would benefit from minimized manufacturing cost, simplifying assembly, reducing drive electronics, and improved field consistency.

IRMPD spectroscopy of deprotonated selenocysteine - The 21st proteinogenic amino acid

The effect of deprotonation on the structure and stability of the 21st proteinogenic amino acid selenocysteine, generated as bare deprotonated species by electrospray ionization, has been investigated by infrared multiple photon dissociation (IRMPD) spectroscopy over an extended frequency range (700-3600 cm−1), encompassing both the fingerprint and X–H (X = C, N, O) stretching ranges. IRMPD spectra, interpreted by anharmonic DFT calculations, provide evidence of a thermally averaged ion population of two types of low-lying canonical conformers deprotonated at the selenol (Se–H) group and involved in different H-bonding motifs.The broadened and diffuse band structures observed in the H-stretching range are well interpreted by Born-Oppenheimer molecular dynamics computations that provide a valuable description of the flexible backbone arrangements of Sec and of the proton sharing dynamics in the Se–HO and Se–HN moieties.Other prototropic isomers, deprotonated at the carboxylic group or with a zwitterionic structure, should not be significantly populated, according to their higher free energy and calculated IR spectra inconsistent with experimental evidence.

Deep Entry of Low‐Energy Ions Into Mercury’s Magnetosphere: BepiColombo Mio’s Third Flyby Observations

AbstractAlthough solar wind‐driven convection is expected to dominate magnetospheric circulation at Mercury, its exact pattern remains poorly characterized by observations. Here we present BepiColombo Mio observations during the third Mercury flyby indicative of convection‐driven transport of low‐energy dense ions into the deep magnetosphere. During the flyby, Mio observed an energy‐dispersed ion population from the duskside magnetopause to the deep region of the midnight magnetosphere. A comparison of the observations with backward test particle simulations suggests that the observed energy dispersion structure can be explained in terms of energy‐selective transport by convection from the duskside tail magnetopause. We also discuss the properties and origins of more energetic ions observed in the more dipole‐like field regions of the magnetosphere in comparison to previously reported populations of the plasma sheet horn and ring current ions. Additionally, forward test particle simulations predict that most of the observed ions on the nightside will precipitate onto relatively low‐latitude regions of the nightside surface of Mercury for a typical convection case. The presented observations and simulation results reveal the critical role of magnetospheric convection in determining the structure of Mercury's magnetospheric plasma. The upstream driver dependence of magnetospheric convection and its effects on other magnetospheric processes and plasma‐surface interactions should be further investigated by in‐orbit BepiColombo observations.

Investigating Boundary Layer Properties at Jupiter's Dawn Magnetopause

AbstractWe survey crossings of Jupiter's dawn magnetopause during the Juno prime mission to identify and characterize Jupiter's magnetopause boundary layer. Using plasma and magnetic field observations from Jovian Auroral Distributions Experiment and Juno Magnetic Field investigation, we identify 53 boundary layer events from the 62 magnetopause crossings studied here. We find that the boundary layer generally exhibits mixed properties of magnetosheath and magnetosphere electron distributions, including lower characteristic electron energies and denser ion populations than in the magnetosphere, but higher characteristic electron energies and less dense ion populations than in the magnetosheath. Boundary layer proton speeds are on average slower than both the magnetosheath and magnetosphere. Other proton parameters in the boundary layer have intermediate values between the magnetosheath and magnetosphere. Through ion composition analysis in regions adjacent to the magnetopause, we find evidence of solar wind and magnetospheric plasma in the boundary layer that suggests plasma is transported across the magnetopause in both directions. This mass and energy transport may be the result of solar wind interactions such as magnetic reconnection and Kelvin‐Helmholtz instabilities. However, many boundary layer events do not exhibit local signatures of these solar wind interactions and plasma may be transported by a non‐local process or diffusively transported.