Ion Distribution Profiles Research Articles

Depth profile analysis of 100 keV Ni ions in Si 〈100〉 substrate

Nickel implanted silicon substrate shows potential applications for the fabrication of infrared detectors, solar cells, spintronic devices as well as for the synthesis of an embedded nickel silicide layer inside Si substrates. Emerging applications of the transition metal implanted silicon structures for the fabrication of intermediate band materials motivated us to study the in-depth distribution profile of Ni ions as well as the structural changes that occur at the top of silicon substrate surface before and after annealing process. In the present work, we have carried out detailed study on the crystalline silicon substrates, implanted with Ni− ions comprising ion dose value of 5 × 1016 ions/cm2 at 100 keV implantation energy followed with the post implantation annealing at 800 °C temperature for a time duration of 2 h. The distribution profile of nickel ions inside the silicon substrate was estimated using the non-destructive simultaneous XRR-GIXRF measurements and were also compared with results obtained from the RBS and SIMS measurements. The in-depth concentration profile of Ni ions inside Si substrate derived from XRR-GIXRF measurements was found to be in close agreement with that of obtained from the RBS measurements. Furthermore, our investigations clearly showed that the annealing process causes the inward and outward diffusion of the Ni atoms inside the Si substrate, thus significantly changing the in-depth concentration profile of Ni ions in the Si matrix. The XANES and EXAFS results also demonstrate the formation of NiSi2 phase around Ni atoms in the implanted region of Si 〈100〉 substrate.

The Dramatic Effect of Water Structure on Hydration Forces and the Electrical Double Layer

Forces between hydrophilic surfaces mediated by water are important in various systems from lipid membranes and solid surfaces to colloids and macromolecules, first discovered as a significant addition to DLVO forces at the nanoscale. These “hydration forces” have been studied in great detail experimentally using osmotic stress measurements, surface force apparatus, and AFM, and they have also been the subject of multiple theories and simulations. One spectacular feature observed in experimental and simulation studies was the nonmonotonic, oscillatory decay in the forces between atomically smooth surfaces. Forces between “rougher” surfaces exhibit only quasi-exponential, monotonic decay. Here we revisit this hydration force problem by exploring the consequences of an extended phenomenological Landau–Ginzburg approach that describes nonlocal correlations in water, linking them with the key features of the wave-number k-dependent nonlocal dielectric function of water. With corresponding boundary conditions, this theory predicts the observed oscillatory decay in hydration force between ideally flat surfaces, the oscillatory mode disappearing with just a tiny roughness of the surfaces (of mean height ca. of the size of a water molecule). This study also brings an important side message. Explanation of these observations appears only possible under an assumption of two modes of polarization in water, consistent with the behavior of the response function, i.e., Lorentzian at small k and resonance-like at higher k. This resolves the “force oscillation–non-oscillation” paradigm, which is a strong, although indirect indication of the existence of these two modes. We also consider other important subjects, such as how the distribution of ions near a charged surface reacts to the propensity for overscreening oscillations due to polarized water. This is important not only for the interactions between charged surfaces but also for the fundamental understanding of the structure of the electrical double layer at electrochemical interfaces. We show that even in dilute electrolytes, the distribution of ions in the vicinity of the polarized interface follows, although not literally, preferential positions corresponding to the potential wells caused by “resonance” water layering. For a sharp interface, the theory predicts that the decaying spatial oscillation profiles extend over a 1 to 2 nm distance from the interface. With the smearing of the interface and the corresponding suppression of the resonance water layering, oscillations in the spatial distribution of ions subside, resulting in a familiar Gouy–Chapman–Stern picture. At longer distances from the interface, whether smeared or not, the ion distribution profiles become Gouy–Chapman-like. The effect of the boundary conditions on water polarization at the interface goes beyond a trivial shift of the potential of zero charge. We show that they can dramatically affect the ion distribution near the charged surface. Last, but not least, we study how the interfacial water layering influences the double layer capacitance and show the effect of the boundary conditions on the slopes of Parsons–Zobel plots, resolving some recently discussed puzzles.

In situ mapping of ion distribution profiles and gene expression reveals interactions between hypoxia and Mn2+/Fe2+ availability in barley roots

Flooding stress affects soil properties thus altering the availability, uptake, and transport of mineral nutrients in plant roots. Flooding stress also increases the amount of soluble Mn2+ and Fe2+ in the soil and their uptake by plants, causing elemental toxicity. However, as oxygen profiles in plant roots are not uniform, it is still unclear how soil flooding will affect Mn2+/Fe2+ absorption and distribution in different cell types and tissues. In this study, waterlogging sensitive barley variety NasoNijo (NN) and tolerant variety TX9425 (TX) were exposed to hypoxia, metal (Mn2+ and Fe2+), and combined hypoxia + metal treatment to map the in situ ion profiles at different regions of barley root. We found that combined hypoxia and metal stress causes significantly more reduction in plant biomass compared with the single submergence or metal stress. Despite this, more Fe and Mn were accumulated under metal stress condition than those under combined stress, regardless of variety. Cultivar NN absorbed more Fe and Mn than TX in the cortical cells of the root meristem and in the mature zone under metal stress which was also verified by histochemical detection. In the mature zone, the expressions of Fe and Mn transporter genes including HvADPRibase-Mn (Manganese-dependent ADP-ribose), HvZIP1 (zinc-regulated transporter /Fe-regulated transporter-like protein 1), HvYS1 (yellow stripe 1), HvNRAMP5 (Natural Resistance-Associated Macrophage Protein 5) were significantly downregulated under all three treatments in both barley varieties except HvADPRibase-Mn HvZIP1 cortex of TX were unchanged under metal stress. Interestingly, the transcripts of HvMTP1 (metal tolerance protein 1) were significantly downregulated by metal and combined stress in stele and upregulated by hypoxia and metal stress in cortex of TX, but not affected in NN. It is concluded that Fe and Mn absorption involving HvMTP1is associated with the extent of waterlogging tolerance in barley.

Non-invasive probing of dynamic ion migration in light-emitting electrochemical cells by an advanced nanoscale confocal microscope

In this study, we firstly propose an optical approach to investigate the ion profile of organic films in light-emitting electrochemical cells (LECs) without any invasive sputtering processes. In contrast to previous literatures, this pure optical strategy allows us to record clear and non-destructive ion profile images in the (Ru(dtb-bpy)3(PF6)2) consisted organic layer without interferences of complex collisions from the bombardment of secondary sputter induced ions in a conventional time-of-flight secondary ion mass spectrometry. By using the advanced position sensitive detector (PSD)-based Nanoscale Confocal Microscope, ion distribution profiles were successfully acquired based on the observation of nanoscale optical path length difference by measuring the refractive-index variation while the thickness of the LEC layer was fixed. Dynamic time-dependent ion profile displayed clear ion migration process under a 100 V applied bias at two ends of the LEC. This technique opens up a new avenue towards the future investigations of ion distributions inside organic/inorganic materials, Li-ion batteries, or micro-fluid channels without damaging the materials or disturbing the device operation.

TI-ION IMPLANTATION EFFECTS ON THE ELECTRICAL RESISTIVITY, HARDNESS AND MICROSTRUCTURE OF BRASS ALLOY

Extensive progress in brass alloys has been done in surface properties and microstructure. Ti-ion implantation is studied for its effects on electrical resistivity, hardness and microstructure by using scanning electron microscopy, X-ray diffractometer, four-point probe apparatus and Vickers microhardness tester. Ion distribution profile and stopping powers were calculated by Stopping and Range of Ions in Matter (SRIM) code. Nonuniformity in shape, and agglomeration of defects were observed at the surface in SEM micrographs. XRD analysis of (2 0 0) plane for crystallite size, strain, stress and dislocation density is also done. The peak intensity of (2 0 0) is found to be increased by increasing the ion fluence and tensile stresses were also found generated. Increase in the lattice parameter values from 3.681 Å to 3.686 Å appeared as a change in crystallite size, which, in turn, caused an increase in hardness. An increment in electrical resistivity from 7.9[Formula: see text][Formula: see text] to 18[Formula: see text][Formula: see text] (127.85%) is also observed. For a maximum ion fluence of [Formula: see text] ions/cm2, the surface turned out to be amorphous, which helped in making the brass more reliable in its practical usage.

Stability of Al and Ag metallic thin film mirrors in a space environment under the implantation of low energy helium ions

The stability of aluminum (Al) and silver (Ag) metallic thin films (MTFs) under helium ion bombardment has been investigated in the laboratory to replicate the effect of alpha particle bombardment on spacecrafts and satellites in a space environment. The implanted helium ions have varying fluence and energies ranging from 0.5 - 3 keV. The helium ion fluence in the present study has been chosen according to 4 and 6 years journey of a solar orbiter. The reflectivity of Al and Ag MTFs is investigated over a wide range of electromagnetic radiation covering ultraviolet to near infrared (200 - 2500 nm), prior and post helium ion implantation. It is observed that the degradation in the reflectivity of the above-mentioned MTFs is reasonably low for helium ion implantation and no significant impact is observed on reflectivity of both (Al and Ag) MTFs in the investigation. This opens a channel of utilization of these MTFs to provide better protection for the optical components used in spacecrafts. Surface characterization such as surface roughness is carried out to investigate the surface morphology of MTFs prior and post implantation using atomic force microscopy (AFM). It is observed that the effect of implantation on surface morphology is in accordance with the experimental results of reflectivity. SRIM/TRIM simulations help to obtain the distribution profile and penetration depth of helium ions inside the Al and Ag MTFs.

Photoluminescence of ion-synthesized 9R-Si inclusions in SiO2/Si structure: Effect of irradiation dose and oxide film thickness

The study of hexagonal silicon polytypes attracts special attention due to their unique physical properties compared to the traditional cubic phase of Si. Thus, for some hexagonal phases, a significant improvement in the emission properties has been demonstrated. In this work, the luminescent properties of SiO2/Si structures irradiated with Kr+ ions at different doses and annealed at 800 °C have been systematically investigated. For such structures, a photoluminescence line at ∼ 1240 nm is observed and associated with the formation of hexagonal 9R-Si phase inclusions. It is found that the variation in the thickness of oxide film and the relative position of ion distribution profile and film/substrate interface leads to a regular change in the luminescence intensity. The nature of the observed dependencies is discussed as related mainly to the interplay between the factors contributing to the formation of 9R-Si inclusions and the generation of radiation defects in the Si substrate—centers of nonradiative recombination. The revealed regularities suggest optimal ion irradiation conditions for synthesis of optically active 9R-Si phase in diamond-like silicon.

Explanation of core ion cyclotron emission from beam-ion heated plasmas in ASDEX Upgrade by the magnetoacoustic cyclotron instability

Bursts of ion cyclotron emission (ICE), with spectral peaks corresponding to the hydrogen cyclotron harmonic frequencies in the plasma core are detected from helium plasmas heated by sub-Alfvénic beam-injected hydrogen ions in the ASDEX Upgrade tokamak. Based on the fast ion distribution function obtained from TRANSP/NUBEAM code, together with a linear analytical theory of the magnetoacoustic cyclotron instability (MCI), the growth rates of MCI could be calculated. In our theoretical and experimental studies, we found that the excitation mechanism of core ICE driven by sub-Alfvénic beam ions in ASDEX Upgrade is MCI as the time evolution of MCI growth rates is broadly consistent with measured ICE amplitudes. The MCI growth rate is very sensitive to the energy and velocity distribution of beam-injected ions and is suppressed by the slowing down of the dominant beam-injected ion velocity and the spreading of the fast ion distribution profile. This may help to account for the experimental observation that ICE signals disappear within ∼3 ms after the NBI turn-off time, much faster than the slowing down times of the beam ions.

Fine-scale in-situ measurement of lead ions in coastal sediment pore water based on an all-solid-state potentiometric microsensor

Methods for in-situ measurements of heavy metal ions in coastal sediment pore water to elucidate fine-scale biogeochemical and environmental processes are highly required but have rarely been reported. In this work, an all-solid-state lead-selective microelectrode (Pb2+-ISμE) based on a poly(3,4-ethylenedioxythiophene)-poly(sodium 4-styrenesulfonate) (PEDOT/PSS) modified gold wire with a diameter of 14 μm has been fabricated. The proposed Pb2+-ISμE is capable of in-situ measurement of Pb2+ in coastal sediment pore water at millimeter depth intervals. The Pb2+-ISμE shows a Nernstian response for Pb2+ within the activity range of 2.1 × 10−9-2.1 × 10−4 M (S = 28.1 ± 1.3 mV/dec, R2 = 0.998) in 0.5 M NaCl, and the detection limit is 6.4 × 10−10 M. By lowering the microelectrode into a coastal sediment core with a micro-manipulator, the proposed Pb2+-ISμE allows the direct measurement of the vertical distribution profile of Pb2+ in the pore water. The in-situ measurement of Pb2+ using the microsensor could avoid the problems of sample handling. Moreover, the detection system can be extended to assess the vertical distribution profiles of other heavy metal ions in sediment pore water by using different ion-selective microelectrodes.

Achieving high gating performance for ion mobility spectrometry by manipulating ion swarm spatiotemporal behaviors in the vicinity of ion shutter

Ion shutter is one of the key components of the drift-tube types of ion mobility spectrometer, which affects both the resolving power and sensitivity of an ion mobility spectrometer. In this work, a spatiotemporal model was built to understand the behaviors of the ion swarms around the ion shutter. For simplicity, a Tyndall-Powell gate (TPG) was chosen as the gating disturbance to the field on the two sides of ion shutter could be separated. It can be inferred from the spatiotemporal model that the ion swarm could be diluted in front of the TPG when the gate closing voltage (GCV) was superposed on the grid facing the ionization region, while it could be compressed behind the TPG when the GCV was superposed on the other grid. These inferences conformed to the narrower and higher ion peaks obtained at GCV superposed on the latter grid and were further verified by the ion distribution profiles obtained at a wide gate opening pulse width. Finally, the product of the resolving power and the gating efficiency was proposed to evaluate the gating performance of an ion shutter. At GCV superposed on the grid facing the drift region, the best gating performance of 42 was obtained with peak height of 1.63 nA and resolving power of 57.2, and was almost twice as high as the optimal gating performance at GCV superposed on the other grid.

Imaging Mass Spectrometry of Endogenous Polypeptides and Secondary Metabolites from Galls Induced by Root-Knot Nematodes in Tomato Roots.

Nematodes are devastating pests that infect most cultivated plant species and cause considerable agricultural losses worldwide. The understanding of metabolic adjustments induced during plant-nematode interaction is crucial to generate resistant plants or to select more efficient molecules to fight against this pest. Matrix-assisted laser desorption/ionization mass spectrometry imaging (MALDI-MSI) has been used herein for in situ detection and mapping endogenous polypeptides and secondary metabolites from nematode-induced gall tissue. One of the major critical features of this technique is sample preparation; mainly, the generation of intact sections of plant cells with their rigid cell walls and vacuolated cytoplasm. Our experimental settings allowed us to obtain sections without contamination of exogenous ions or diffusion of molecules and to map the differential presence of low and high molecular weight ions in uninfected roots compared with nematode-induced galls. We predict the presence of lipids in both uninfected roots and galls, which was validated by MALDI time-of-flight tandem mass spectrometry and high-resolution mass spectrometry analysis of lipid extracts. Based on the isotopic ion distribution profile, both esters and glycerophospholipids were predicted compounds and may be playing an important role in gall development. Our results indicate that the MALDI-MSI technology is a promising tool to identify secondary metabolites as well as peptides and proteins in complex plant tissues like galls to decipher molecular processes responsible for infection and maintenance of these feeding sites during nematode parasitism.

Insights into the Role of Counterions on Polyelectrolyte-Modified Nanopore Accessibility.

Nanopores play a decisive role in different technologies from oil production, separation, and sensing to drug delivery or catalysis and energy conversion. In recent years, abilities to functionalize nanopores have advanced significantly. Thereby, nanopores functionalized with polyelectrolytes or responsive polymers show fascinating transport properties, such as gated or gradually controlled ionic permselectivity. Nonetheless, understanding the influence of external parameters such as ion type or concentration on nanopore performance, and thus on the mentioned applications, remains a challenge but is crucial for applications. In this work, the effect of different counterions on the wetting and ionic transport in poly(2-(methacryloyloxy)ethyltrimethylammonium chloride)-functionalized silica mesopores (pore diameter <10 nm) was experimentally and theoretically investigated. Static contact angles covered a range from 45 to almost 90° by exclusively changing the counterion. Ionic pore accessibility was also strongly dependent on the counterion present and was found to gradually change from accessible pores up to complete, pH-independent ion exclusion. On the basis of molecular theory calculations, these experimental observations were rationalized on the basis of ion binding between the [2-(methacryloyloxy)ethyl]trimethylammonium chloride monomers and the counterions. In addition, the theoretical framework provided a nanoscopic view into the molecular organization inside the pores, showing a strong dependence of ion concentration and ion distribution profiles along the pore radius in dependence of the present ions. The obtained insights on the role of counterion type and ion binding in nanopores are expected to have direct impact on the above-mentioned applications.

Correction: Characterization of hydroxypropyl-beta-cyclodextrins used in the treatment of Niemann-Pick Disease type C1.

[This corrects the article DOI: 10.1371/journal.pone.0175478.].

A Benzimidazole Proton Pump Inhibitor Increases Growth and Tolerance to Salt Stress in Tomato.

Pre-treatment of tomato plants with micromolar concentrations of omeprazole (OP), a benzimidazole proton pump inhibitor in mammalian systems, improves plant growth in terms of fresh weight of shoot and roots by 49 and 55% and dry weight by 54 and 105% under salt stress conditions (200 mM NaCl), respectively. Assessment of gas exchange, ion distribution, and gene expression profile in different organs strongly indicates that OP interferes with key components of the stress adaptation machinery, including hormonal control of root development (improving length and branching), protection of the photosynthetic system (improving quantum yield of photosystem II) and regulation of ion homeostasis (improving the K+:Na+ ratio in leaves and roots). To our knowledge OP is one of the few known molecules that at micromolar concentrations manifests a dual function as growth enhancer and salt stress protectant. Therefore, OP can be used as new inducer of stress tolerance to better understand molecular and physiological stress adaptation paths in plants and to design new products to improve crop performance under suboptimal growth conditions.Highlight: Omeprazole enhances growth of tomato and increases tolerance to salinity stress through alterations of gene expression and ion uptake and transport.

Study of the distribution profile of iron ions implanted into silicon

Iron ions with energies of 90 and 250 keV and a dose of 1016 cm–2 are implanted into a silicon single crystal with the (110) orientation. The method of Rutherford backscattering in combination with channeling is used to study the distribution profiles of the introduced impurity and also the profiles of the distribution of radiation-induced defects in the crystal lattice. Experimental data are compared with the results of simulation performed using the TRIM software package. It is shown that, at an energy of 4.6 keV/nucleon, the average projected ranges coincide; however, at an energy of 1.6 keV/nucleon, the difference amounts to 35%. In addition, it is shown that the calculation incorrectly takes into account the dose dependence at energies of 1.6–4.6 keV/nucleon.

Characterization of hydroxypropyl-beta-cyclodextrins used in the treatment of Niemann-Pick Disease type C1.

2-Hydroxypropyl-beta-cyclodextrin (HPβCD) has gained recent attention as a potential therapeutic intervention in the treatment of the rare autosomal-recessive, neurodegenerative lysosomal storage disorder Niemann-Pick Disease Type C1 (NPC1). Notably, HPβCD formulations are not comprised of a single molecular species, but instead are complex mixtures of species with differing degrees of hydroxypropylation of the cyclodextrin ring. The degree of substitution is a critical aspect of the complex mixture as it influences binding to other molecules and thus could potentially modulate biological effects. VTS-270 (Kleptose HPB) and Trappsol® Cyclo™ are HPβCD products under investigation as novel treatments for NPC1. The purpose of the present work is to compare these two different products; analyses were based on ion distribution and abundance profiles using mass spectrometry methodology as a means for assessing key molecular distinctions between products. The method incorporated electrospray ionization and analysis with a linear low-field ion mobility quadrupole time-of-flight instrument. We observed that the number of hydroxypropyl groups (the degrees of substitution) are substantially different between the two products and greater in Trappsol Cyclo than in VTS-270. The principal ions of both samples are ammonium adducts. Isotope clusters for each of the major ions show doubly charged homodimers of the ammonium adducts. In addition, both products show doubly charged homodimers from adduction of both a proton and ammonium. Doubly charged heterodimers are also present, but are more intense in Trappsol Cyclo than in VTS-270. Based on the analytical differences observed between VTS-270 and Trappsol Cyclo with respect to the degree of substitution, the composition and fingerprint of the complex mixture, and the impurity profiles, these products cannot be considered to be the same; the potential biological and clinical implications of these differences are not presently known.

Low toxicity and accumulation of zinc oxide nanoparticles in mice after 270-day consecutive dietary supplementation.

The toxicity and accumulation of zinc oxide nanoparticles (ZnO-NPs), ZnO microparticles (ZnO-MPs) and Zn ions were evaluated after long-term feeding with zinc-replenished food (1600 mg zinc equivalent per kg food) for 270 consecutive days. It was difficult for ZnO-NPs, ZnO-MPs and Zn ions were difficult to pass through the intestine barrier, and most of them were excreted mainly through feces. The distribution results showed that there was no noticeable difference among the distribution profiles of ZnO-NPs, ZnO-MPs and Zn ions in mice. Zn accumulated only in the digestive tract organs after the exposure to all three samples. However, the biomedical parameters and pathological investigations showed liver lesions induced by ZnO-MPs, but fewer by ZnO-NPs or Zn ions. The reason for the remarkably low in vivo toxicity of ZnO-NPs is discussed. Our findings suggest that ZnO-NPs are relatively biocompatible as the nutritional additive at the commonly used dose.

Ionic Behavior in Highly Concentrated Aqueous Solutions Nanoconfined between Discretely Charged Silicon Surfaces.

Through molecular dynamics simulations considering thermal vibration of surface atoms, ionic behaviors in concentrated NaCl solutions confined between discretely charged silicon surfaces have been investigated. The electric double layer structure was found to be sensitive to the density and distribution of surface charges. Due to the discreteness of the surface charge, a slight charge inversion appeared which depended on the surface charge density, bulk concentration, and confinement. In the nanoconfined NaCl solutions concentrated from 0.2 to 4.0 M, the locations of accumulation layers for Na(+) and Cl(-) ions remained stable, but their peak values increased. The higher the concentration was, the more obvious the charge inversion appeared. In 4.0 M NaCl solution, Na(+) and Cl(-) ions show obvious alternating layered distributions which may correspond to the solidification found in experiments. By changing surface separation, the confinement had a large effect on the ionic distribution. As both surfaces approached each other, many ions and water molecules were squeezed out of the confined space. Two adjacent layers in ion or water distribution profiles can be forced closer to each other and merge together. From ionic hydration analysis, the coordination number of Na(+) ions in highly confined space was much lower than that in the bulk.

Numerical study of hypersonic flows over reentry configurations with different chemical nonequilibrium models

Effects of two different 11-species chemical reaction models on hypersonic reentry flow simulations are numerically investigated. These two models were proposed by Gupta (1990) and Park (1990) [12,15], respectively. In this study, two typical configurations, the RAM-C II vehicle and FIRE II capsule, are selected as test cases, whose thermo-chemical nonequilibrium flowfields are computed by a multi-block finite volume code using a two-temperature model (a translational-rotational temperature and a vibrational-electron-electronic temperature). In the RAM-C II case, it is indicated that although electron number density distributions of the two reaction models appear in a similar trend, their values are distinctively different. Results of the Gupta's model show a better agreement with the electrostatic probe data, while those of the Park's model are more consistent with the reflectometers data. Both models give similar temperature distributions. In the FIRE II case, the two models yield significantly different distribution profiles of ions and electrons, whose differences could reach an order of magnitude. In addition, an abnormal nonequilibrium relaxation process in the shock layer is found in the FIRE II flowfield simulated by the Gupta's model, which proves to be a consequence of electron impact ionization reactions.

Interaction of rhyolite melts with monazite, xenotime, and zircon surfaces

The interfacial contact region between a rhyolite melt and the accessory minerals monazite, xenotime, and zircon is investigated using molecular dynamics simulations. On all surfaces, major structural rearrangement extends about 1 nm into the melt from the interface. As evidenced by the structural perturbations in the ion distribution profiles, the affinity of the melt for the surface increases in going from monazite to xenotime to zircon. Alkali ions are enriched in the melt in contact with an inert wall, as well as at the mineral surfaces. Melt in contact with zircon has a particularly strong level of aluminum enrichment. In xenotime, the enrichment of aluminum is less than that in zircon, but still notable. In monazite, the aluminum enrichment in the contact layer is much less. It is expected that the relative surface energies of these accessory minerals will be a strong function of the aluminum content of the melt and that nucleation of zircon, in particular, would be easier for melts with higher aluminum concentration. The crystal growth rate for zircon is expected to be slower at a higher aluminum concentration because of the effectiveness of aluminum in solvating the zircon surface. The variable interfacial concentration profiles across the series of accessory minerals will likely affect the kinetics of trace element incorporation, as the trace elements must compete with the major elements for surface sites on the growing accessory minerals.