Ion Deposition Research Articles

Fabrication of engineered biochar-iron oxide from date palm frond for the effective removal of cationic dye from wastewater

Wastewater containing dye is harmful to the environment. Methylene blue (MB) dye can be removed from wastewater using low-cost, renewable adsorbents. In this study, modified biochar (Biochar-FexOy), pristine biochar and FexOy were fabricated, characterized, and investigated for their performance to remove MB dye from wastewater. The Biochar-FexOy (85.1 mg/g) showed increased adsorption capacity in comparison to biochar (60.1 mg/g) and FexOy (50 mg/g) at an optimum pH of 8 due to the increase in surface area, porosity, and deposition of metal ions on its surface for adsorption. The enhanced MB adsorption by the Biochar-FexOy can be attributed to electrostatic attraction, hydrogen bonding, π-π interactions, and possible cationic exchange as evidenced by the result of the FTIR, EDX, and XRD analysis. Moreover, the adsorption of MB dye by the Biochar-FexOy showed an antagonistic effect in the presence of NaHCO3− and NaCl salt but showed a synergistic effect in the presence of Cu (II) ions. The Langmuir and pseudo-second-order isotherm model best describe the adsorption process of MB dye over the Biochar-FexOy. The adsorption capacity was still high after 4 regeneration cycles for the Biochar-FexOy which concludes that modified biochar can be effectively utilized for dye wastewater treatment. Finally, the fixed-bed column adsorption performance demonstrated that Biochar-FexOy could be used to polish real secondary textile industry effluents prior to treatment.

Ion current density on the substrate during short-pulse HiPIMS

A probe method for measuring the ion current density and theoretical calculations of the dynamics of neutral and charged plasma particles using the ionization region model (IRM) is used to study short and ultra-short pulse high-power impulse magnetron sputtering (HiPIMS). This paper studies reasons for the increase in the average ion current density on the substrate at shorter pulses, when the average discharge power does not change. HiPIMS pulses are applied to the copper target at constant values of average discharge power (1000 W) and peak current (150 А), respectively, while the pulse time of the discharge voltage ranges from 4 to 50 µs. A power supply with low output inductance is designed to generate ultra-short pulses. It is shown that shorter discharge pulses lead to a multiple growth (from 2 to 7 mA cm−2) in the average ion current density on the substrate and a growth in the peak intensity of Ar+, Cu+ and Cu2+ recorded by optical emission spectroscopy. A theoretical model of this effect is based on the spatially averaged IRM, which considers afterglow effects. According to theoretical calculations, the increase in the average ion current density on the substrate is determined by the plasma dissipation in the ionized region after the pulse ends. Also, a decrease in the copper deposition rate from 180 to 60 nm min−1 with decreasing pulse time from 40 to 4 µs is explored. A comparison of experimental data with those obtained earlier shows that the suggested dependences of the ion current density and deposition rate on the HiPIMS pulse time are typical for discharge systems with different cathode materials and configurations, i.e., for single- and dual-magnetron systems. This indicates a common nature of the phenomena observed and additionally confirms the results obtained.

ELECTROCHEMICAL REDUCTION OF CADMIUM IONS FROM ETHYLENE GLYCOL ELECTROLYTE

The work is devoted to the study of the process of cathodic reduction of Cd ions from anhydrous ethylene glycol electrolyte. The mechanism of the process of cadmium reduction was studied by taking linear and cyclic potentiodynamic polarization curves. The influence of cadmium chloride concentration, potential sweep rate and temperature on the process of electrochemical deposition of cadmium ions was studied. With an increase in the concentration of cadmium in the electrolyte, the rate of its release at the cathode increases. Precipitates of good quality are obtained at current densities of 25 mA/sm2. It has been established that the cadmium deposition potential almost does not change with increasing potential sweep rate. The dependence of cadmium electrodeposition from ethylene glycol electrolyte on temperature was studied, which made it possible to establish the optimal deposition temperature, which was 363–373 K, and to conclude that the deposition process is controlled by electrochemical polarization. The diffusion coefficient of cadmium ions to the cathode surface has been calculated

Positron annihilation spectroscopy of thermally annealed hydrogenated amorphous carbon films

Hydrogenated amorphous carbon (a-C:H) films are prepared using a bipolar-type plasma-based ion implantation and deposition system, followed by thermal annealing of the films at 200 °C-800 °C. The structural and compositional changes are examined by Raman spectroscopy, Rutherford backscattering spectrometry, and elastic recoil detection analysis (ERDA). Positron annihilation spectroscopy (PAS) is also conducted to investigate the behavior of voids in the films. The results of Raman and ERDA measurement clearly show that the sp2 ring clusters increase, and hydrogen content apparently decreases at temperatures between 400 °C and 800 °C. Uncorrelated behaviors between positron lifetimes and line-shape parameters are observed in the PAS results, which can be attributed to several competing effects, such as hydrogen release, bond reconstruction, and electronic-state change of voids. Furthermore, it is suggested that the graphitization of the films begins from the surface to the inside, accompanied by the hydrogen release that is related to the void behavior.

Safe and Durable Treatment of Dentin Hypersensitivity via Nourishing and Remineralizing Dentin Based on β-Chitooligosaccharide Graft Derivative.

Dentin hypersensitivity (DH) is a common symptom of various dental diseases that usually produces abnormal pain with external stimuli. Various desensitizers are developed to treat DH by occluding dentine tubules (DTs) or blocking intersynaptic connections of dental sensory nerve cells. However, the main limitations of currently available techniques are the chronic toxic effects of chemically active ingredients and their insufficiently durable efficacy. Herein, a novel DH therapy with remarkable biosafety and durable therapeutic value based on β-chitooligosaccharide graft derivative (CAD) is presented. Particularly, CAD indicates the most energetic results, restoring the amino polysaccharide protective membrane in DTs, significantly promoting calcium and phosphorus ion deposition and bone anabolism, and regulating the levels of immunoglobulin in saliva and cellular inflammatory factors in plasma. Exposed DTs are occluded by remineralized hydroxyapatite with a depth of over 70µm, as shown in in vitro tests. The bone mineral density of Sprague-Dawley rats' molar dentin increases by 10.96%, and the trabecular thickness of bone improves to about 0.03µm in 2 weeks in the CAD group compared to the blank group. Overall, the ingenious concept that modified marine biomaterial can be a safe and durable therapy for DH is demonstrated by nourishing and remineralizing dentin.

Tuning the distribution of zinc ions by manganese dioxide ion sieve to realize the uniform deposition of zinc ions on Zn metal anode of aqueous zinc-ion batteries

Zinc (Zn) metal, as a promising anode for aqueous zinc-ion batteries (AZIBs), has attracted much attention owing to its reasonable redox potential and fabulous theoretical capacity. Notwithstanding, Zn dendrites and side reactions generated during charging/discharging seriously inhibit the reversibility of Zn anode of AZIBs. Herein, ultra-long manganese dioxide (MnO2) nanowires with low cost and easy synthesis have been designed as a high-efficiency zinc ion shunt to achieve uniform Zn deposition. The Zn coated with MnO2 protection layer possesses good water wettability, high ionic conductivity (1.3 mS cm−1) and low activation energy (38.2 kJ mol−1). As a result, the Zn@MnO2||Zn@MnO2 symmetric cell exhibits an ultra-long lifespan over 3800 h at 0.5 mA cm−2/0.25 mAh cm−2; for the Zn@MnO2||Zn@MnO2 symmetric cell, the accumulative discharge capacity surpasses 1600 mAh cm−2 and the depth of discharge (DOD) is 34.2% at the harsh conditions of 20 mA cm−2/20 mAh cm−2; and the average coulombic efficiency (CE) of the Zn//Cu@MnO2 asymmetric cell achieves 99.6%. In addition, the Zn@MnO2//NVO full cell possesses an excellent reversible discharge capacity of 176.3 mAh g−1 after 1000 cycles at 2 A g−1. This investigation provides a useful reference for designing high-efficiency zinc ion shunt to realize highly reversible Zn anode for AZIBs.

Effects of Ti ion deposition on corrosion resistance of WE43 alloy

AbstractTi films with different thicknesses were successfully deposited on the surface of WE43 alloy by filtered cathode vacuum arc technology, and the microscopic morphology, structural composition, and corrosion resistance of the films were studied by means of X‐ray diffractometer, X‐ray photoelectron spectroscopy and scanning electron microscope. The results show that when the deposition time of Ti ions is 800 s, the thickness of the Ti film is 2.35 μm, the surface of the film is dense, and there are few defects. Meanwhile, Ti800 alloy has the best corrosion resistance among the four modified alloys. It has a corrosion current density (Icorr) of 2.9 μA·cm−2, which is about 50 times lower than that of unmodified alloy. This conclusion is also confirmed by the complete film layer of Ti800 alloy and the tight bonding with the substrate after immersion experiments. Good corrosion resistance is attributed to a dense and relatively chemically stable TiO2/Ti structure in simulated body fluid corrosive media.

Effect of substrate bias on structure and properties of (AlTiCrZrNb)N high-entropy alloy nitride coatings through arc ion plating

This study mainly focused on the effects of different substrate bias on the microstructure, elemental composition, mechanical and tribological properties of (AlTiCrZrNb)N coatings. (AlTiCrZrNb)N high-entropy nitride coatings with different substrate bias parameters were deposited on cemented carbide and silicon wafers using arc ion plating. The results showed that the bias voltage created a high-energy particle bombardment effect to reduce the number and volume of macroparticles brought by arc ion deposition technology; this optimized the surface quality of the coating. (AlTiCrZrNb)N coatings at different bias voltages exhibited a single-sided cubic solid solution structure. Substrate bias can significantly change the preferred orientation of coatings. As bias voltage increased from 0 V to −100 V, the preferred orientation of coatings changed from (111) to (200), and when negative voltage further increased to 200 V, the preferred orientation changed from (200) to (111). Appropriate substrate bias parameters can improve the residual stress, mechanical properties, and tribological properties of coatings. The highest hardness of the coating reached 34.85 ± 2.05 GPa. The lowest average friction coefficient was 0.26, and the lowest wear rate was 8.86 ± 1.05 × 10−6 mm3 ∙ N−1 ∙ m−1.

Interface engineering strategy construction of covalent organic framework for promoting highly reversible zinc metal

Zn-ion energy storage devices will play important roles in the future energy storage field. However, Zn-ion device development suffers significantly from adverse chemical reactions (dendrite formation, corrosion, and deformation) on the Zn anode surface. Zn dendrite formation, hydrogen evolution corrosion, and deformation combine to degrade Zn-ion devices. Zincophile modulation and protection using covalent organic frameworks (COF) inhibited dendritic growth by induced uniform Zn ion deposition, which also prevented chemical corrosion. The Zn@COF anode circulated stably for more than 1800 cycles even at high current density in symmetric cells and maintained a low and stable voltage hysteresis. This work explains the surface state of the Zn anode and provides information for further research.

Application of Herbal Medicine in Cu2+ Removal from Water and Comparison of its Detection Methods

In order to utilize discarded herbal medicine to treat heavy metal pollution in water, various herbal medicines were selected to explore their abilities of metal ions removal. In this experiment, copper ion was used as targeted heavy metal ion and two different treatments of several herbal medicines were compared on the effect of the copper ion removal ability. At the evaluating stage, four metal ion detection methods were employed and analyzed in this herbal medicine Cu2+ removal application. The results showed that directly soaking herbal medicine in the copper aqueous solution was more effective and easier to operate. Iodometry method and EDTA complexometric titration with xylenol orange as indicator were accurate and time-saving in the measurement of copper removal rate. In addition, the EDTA complexometric titration is also applicable in the detection of other metal ions. This experiment provided a basis for the implementation and application of herbal medicine in the deposition of metal ions in polluted water.

Printing 3D mesh-like grooves on zinc surface to enhance the stability of aqueous zinc ion batteries

Aqueous zinc ion batteries (AZIBs) are receiving broad attention owing to their high safety and low cost. However, the high mechanical strength and irreversible growth of zinc dendrites limit the practical application of AZIBs. Herein, regular mesh-like gullies are built on the surface of zinc foil (M150 Zn) by using simple model pressing method and stainless steel mesh as a mold. Due to the charge-enrichment effect, zinc ion deposition and stripping will be preferentially carried out in the grooves to keep the outer surface flat. In addition, zinc is exposed to 002 crystal surface in the gully after being pressed, and the deposited zinc is more inclined to grow at a small angle, so that it has a sedimentary morphology parallel to the basement. Consequently, at a current density of 0.5 mA cm−2, the M150 zinc anode has a voltage hysteresis of only 35 mV and a cycle life of up to 400 h (relative to a zinc foil of 96 mV and 160 h). Even more imposing is that the full cell has a capacity retention of approximately 100% after 1000 cycles at 2 A g−1 and a specific capacity of almost 60 mAh g−1 when activated carbon is used as the cathode. It is a promising method to improve the stable cycle performance of AZIBs by using a simple method to realize the non-prominent dendrites on the surface of zinc electrode.

Regulating the solvation sheath of zinc ions by supramolecular coordination chemistry toward ultrastable zinc anodes

AbstractAqueous zinc‐ion batteries (ZIBs) have attracted extensive interest for the next‐generation batteries, which, however, are facing great challenges due to the poor reversibility of zinc (Zn) anodes and side reactions of water decomposition. Herein, we demonstrated a strategy that the solvation sheath of Zn ions could be facilely regulated by supramolecular coordination chemistry by adding small amounts of cyclodextrins (CDs) and, hence, inhibited the side reactions and side products, widened the electrochemical window, facilitated the homogenous deposition of Zn ions, refined the Zn grains, and enhanced the stability of Zn anodes. Importantly, we demonstrated that compared with α‐ and β‐CD, the γ‐CD showed the best regulation effect of the solvation sheath of Zn ions either at the same molar ratio or at the same mass concentration, which could be ascribed to their difference in supramolecular coordination chemistry and the strongest interaction of γ‐CD with Zn ions. As a result, with γ‐CD, the Zn//Zn symmetric cells showed ultrahigh stability with a cycling lifespan of over 2400 h at a current density of 1 mA/cm2. These results highlight the regulation of solvation sheath by supramolecular coordination chemistry for highly stable Zn anodes and pave a new way to realize high‐performance ZIBs.

Modeling of the pressure drop effect using membrane distillation in the desalination process

The desalination process using membrane distillation (MD) has recently attracted wide attention in the last few years around the world. Especially, membranes that have an asymmetric geometry, for their performance to filtrate the salt water and the high salt rejection. In this paper, the Langevin dynamics model was adopted as a simulation method to investigate the transport of salt water through the sloping membrane under a pressure drop. The surface of the used membrane is considered as a hydrophilic sloping surface. Thus, the pressure drop effect on the fluid flux was observed, which leads to attracting the salt water into pores that are randomly distributed. The influence of deposition and accumulation of the ions into pores, the incline angle of the membrane surface, and the thickness of the formed layer on the surface were investigated. In addition, the impact of biofouling is caused by the accumulation and the variation of the fluid velocity as a function of pressure drop values. The obtained results show that the relationship between the fluid velocity and the pressing force is a power law. Moreover, the increase in fluid flow velocity in the porous medium is severe in the earlier time regime, but it becomes almost constant in the second regime. However, the time desalination process increases linearly with the pressure drop. Moreover, the accumulation and deposition of ions into the pores cause a decrease in the water flow through the pores resulting in a higher pressure drop in the less inclined direction. Finally, the influence of deposition and accumulation of the salt phase into the pores on the membrane performance was remarked, resulting in a high desalination rate. The obtained results explain the salt water behavior through a porous membrane, which provides ideas for making a high membrane performance.

Enhancement of the CO2 Sensing/Capture through High Cationic Charge in M-ZrO2 (Li+, Mg2+, or Co3+): Experimental and Theoretical Studies.

The capture and storage of CO2 are of growing interest in atmospheric science since greenhouse gas emission has to be reduced considerably in the near future. The present paper deals with the doping of cations on ZrO2, i.e., M-ZrO2 (M = Li+, Mg2+, or Co3+), defecting the crystalline planes for the adsorption of carbon dioxide. The samples were prepared by the sol-gel method and characterized completely by different analytical methods. The deposition of metal ions on ZrO2 (whose crystalline phases: monoclinic and tetragonal are transformed into a single-phase such as tetragonal for LiZrO2 and cubic for MgZrO2 or CoZrO2) shows a complete disappearance of the XRD monoclinic signal, and it is consistent with HRTEM lattice fringes: 2.957 nm for ZrO2 (101, tetragonal/monoclinic), 3.018 nm for tetragonal LiZrO2, 2.940 nm for cubic MgZrO2, and 1.526 nm for cubic CoZrO2. The samples are thermally stable, resulting an average size of ∼5.0-15 nm. The surface of LiZrO2 creates the oxygen deficiency, while for Mg2+ (0.089 nm), since the size of the atom is relatively greater than that of Zr4+ (0.084 nm), the replacement of Zr4+ by Mg2+ in sublattice is difficult; thus, a decrease of the lattice constant was noticed. Since the high band gap energy (ΔE > 5.0 eV) is suitable for CO2 adsorption, the samples were employed for the selective detection/capture of CO2 by using electrochemical impedance spectroscopy (EIS) and direct current resistance (DCR), showing that CoZrO2 is capable of CO2 capture about 75%. If M+ ions are deposited within the ZrO2 matrix, then the charge imbalance allows CO2 to interact with the oxygen species to form CO32- which produces a high resistance (21.04 × 106 (Ω, Ohm)). The adsorption of CO2 with the samples was also theoretically studied showing that the interaction of CO2 with MgZrO2 and CoZrO2 is more feasible than with LiZrO2, subscribing to the experimental data. The temperature effect (273 to 573 K) for the interaction of CO2 with CoZrO2 was also studied by the docking method and observed the cubic structure is more stable at high temperatures as compared to the monoclinic geometry. Thus, CO2 would preferably interact with ZrO2c (ERS = -19.29 kJ/mol) than for ZrO2m (22.4 J/mmol (ZrO2c = cubic; ZrO2m = monoclinic).

Reactive Polymer as Artificial Solid Electrolyte Interface for Stable Lithium Metal Batteries

AbstractLithium (Li) metal anodes have the highest theoretical capacity and lowest electrochemical potential making them ideal for Li metal batteries (LMBs). However, Li dendrite formation on the anode impedes the proper discharge capacity and practical cycle life of LMBs, particularly in carbonate electrolytes. Herein, we developed a reactive alternative polymer named P(St‐MaI) containing carboxylic acid and cyclic ether moieties which would in situ form artificial polymeric solid electrolyte interface (SEI) with Li. This SEI can accommodate volume changes and maintain good interfacial contact. The presence of carboxylic acid and cyclic ether pendant groups greatly contribute to the induction of uniform Li ion deposition. In addition, the presence of benzyl rings makes the polymer have a certain mechanical strength and plays a key role in inhibiting the growth of Li dendrites. As a result, the symmetric Li||Li cell with P(St‐MaI)@Li layer can stably cycle for over 900 h under 1 mA cm−2 without polarization voltage increasing, while their Li||LiFePO4 full batteries maintain high capacity retention of 96 % after 930 cycles at 1C in carbonate electrolytes. The innovative strategy of artificial SEI is broadly applicable in designing new materials to inhibit Li dendrite growth on Li metal anodes.

Reactive Polymer as Artificial Solid Electrolyte Interface for Stable Lithium Metal Batteries.

Lithium (Li)metal anodes have the highest theoretical capacity and lowest electrochemical potential making them ideal for Li metal batteries (LMBs). However, Li dendrite formation on the anode impedes the proper discharge capacity and practical cycle life of LMBs, particularly in carbonate electrolytes.Herein, we developed a reactive alternative polymer namedP(St-MaI) containing carboxylic acid and cyclic ether moieties which would in-situform artificial polymeric solid electrolyte interface (SEI) with Li. This SEI can accommodate volume changes and maintain good interfacial contact. The presence of carboxylic acid and cyclic ether pendant groups greatly contribute to the induction of uniform Li ion deposition. In addition, the presence of benzyl rings makes the polymer have a certain mechanical strength and plays a key role in inhibiting the growth of Lidendrites. As a result, the symmetric Li||Li cell with P(St-MaI)@Li layer can stably cycle for over 900 h under 1 mA cm-2without polarization voltage increasing, while their Li||LiFePO4full batteries maintain high capacity retention of 96% after 930 cycles at 1C in carbonate electrolytes.The innovative strategy of artificialSEI is broadly applicable in designing new materials to inhibit Li dendrite growth on Li metal anodes.

Inhibition of dendrite growth and side reactions using histidine as electrolyte additive for aqueous Zn-ion batteries

Aqueous Zn-ion batteries have attracted wide attention in the field of energy storage due to their low cost and high safety. However, the problems of dendrite growth and side reactions of Zn anode have been puzzling them and become the main factors limiting their development and application. Herein, we introduce histidine additive into the ZnSO4 electrolyte to inhibit dendrite growth and side reactions. The histidine is preferentially adsorbed on the surface of Zn anode to form a shield molecular layer, guiding the uniform deposition of Zn ions and inhibiting the side reactions. Consequently, an long cycle life of 4180 h for Zn||Zn symmetric battery can be achieved at 2 mA cm–2 (1 mAh cm–2), and even at the ultra-high current density of 10 mA cm–2 (5 mAh cm–2) for more than 1000 h. The capacity retention of Zn-MnO2 full battery with His/ZnSO4 retains 64% after 800 cycles of charge/discharge at 0.5 A g–1, while 47% for the full battery with pure ZnSO4 electrolyte. This work provides an effective electrolyte additive to address the dendrite growth and side reactions in Zn-ion batteries.

Environmental Impact Assessment of Heavy Metals Pollution in the ‎Surface Soil Surrounding the Shwan Private Oil Refinery, Northeastern‏ ‏Kirkuk

The current study included finding the concentrations of heavy elements (Co, Ni, Cu, As, Zn, Cd and Hg) in the surface soil and studying the environmental effects of Shwan Refinery within Kirkuk Governorate. Twenty surface soil samples were collected with a depth of 0-20 cm. The samples were prepared in the laboratory and sent to the laboratories of the Geology Department at the Faculty of Engineering, Ankara University for the purpose of conducting chemical analyzes using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The results of heavy element concentrations in the surface soil of the Shwan Refinery showed that the mean value of Co, Ni, Cu, Zn, As, Cd, and Hg was 33.99 mg/kg, 149.33 mg/kg, ‎24.62 mg/kg, ‎‎57.44 mg/kg, 6.18 mg/kg, 0.04 mg/kg, 0.95 mg/kg, respectively. The analyzes of heavy elements in the volumetric fractions (sand, silt and clay) indicated that most of the heavy metals increased their concentrations in the clay fraction (Cd, As, Zn, Cu, Ni, Co) with a value of (1.13 mg/kg 9.23 mg/kg ,87.15mg/kg ,35.23 mg/kg ,189.2 mg/kg ,48.02 mg/kg) respectively. Except for mercury, which was concentrated in the coarse sandy part, whose value reached (49.4 mg/kg), may be due to the role of clay minerals that are characterized by the processes of ion exchange, absorption and deposition of heavy elements on their surfaces compared to the alluvial and sandy fractions. The geo-accummelation index (Igeo) in the study area showed that there is high pollution with the elements Co and Ni and the average pollution index for the elements a As and low pollution with the Zn, Cu, (Cd) and (Hg) which are attributed to the wind and to the public road and the parallel road for transporting petroleum products.

Terrestrial neutron induced failure rate measurement of SiC MOSFETs using China spallation neutron source

The atmospheric neutron induced single event burnout (SEB) is observed for SiC MOSFETs by conducting irradiation at China Spallation Neutron Source (CSNS) with maximum energy close to 1.6 GeV. The failure is manifested as a sudden loss of voltage blocking ability during irradiation and a melting region is observed for the device with SEB. The SEB failure rates of SiC MOSFETs are calculated based on the experimental results. It shows that the failure rates increase exponentially with operating voltages. The measured failure rates are consistent with the results obtained at the other spallation neutron sources, which proves that the neutron beam line at CSNS is suitable for SEB testing. The information of the secondary ions produced by neutron is obtained through Monte Carlo simulations and the contributors to SEB are analyzed. A simulation method is also applied to calculate SEB failure rate by considering ionization energy deposition of secondary ions in the sensitive region of SiC devices. The simulated failure rates are also consistent with the experimental results.

Ultra-long cycle life flexible quasi-solid-state alkaline zinc batteries enabled by PEDOT:PSS encapsulated Ni3S2 nanorods

Alkaline nickel-zinc (Ni-Zn) batteries are considered as one of the most promising rechargeable battery systems. However, the poor cycling stability of the Ni cathode limit their service life. Herein, a conductive polymer (PEDOT:PSS) encapsulated Ni3S2 hollow nanorod structure via facile immersion is proposed. PEDOT:PSS coating layer can not only provide adhesion for Ni3S2 nanorods to prevent Ni3S2 from falling off the substrate during cycling, but also facilitate electron transfer via the complete conductive pathway. The hollow nanorods structure of Ni3S2 is beneficial to mitigate the volume change and accelerate the rapid transport of ions. Besides, a gel electrolyte with double network porous structure in our battery system is well designed. The ionic association of sodium alginate on Zn2+ can effectively reduce the activity of bound water molecules in the solvation sheath of Zn2+, inhibit the side reaction and dendrite generation through the ion-confinement effect, to achieve uniform deposition of zinc ions. As a consequence, the as-designed quasi-solid-state flexible Ni-Zn battery demonstrates a high specific capacity of 1.06 mAh cm−2 (276.04 mAh g−1) at 8 mA cm−2 and an ultra-long cycle stability over 10,000 cycles with a capacity retention of 88.96% at 30 mA cm−2.