Ion And Neutral Mass Spectrometer Research Articles

Modeling of electron fluxes in the Enceladus plume

Observations by instruments onboard the Cassini spacecraft of Saturn's icy satellite Enceladus have shown that a plume containing water vapor and ice grains is present in the southern hemisphere. Energy distributions of electrons in this plume were measured by the electron sensor part of the Cassini plasma spectrometer (CAPS – ELS). A significant suprathermal electron population was detected. The nature of the electron population is important for understanding the composition and chemistry of the plume plasma because the electron‐ion recombination rate depends on the energy distribution and because ionizing collisions by energetic electrons creates new plasma. We present the results of a two‐stream electron transport model for plume electrons that includes neutral densities that agree with Cassini Ion and Neutral Mass Spectrometer (INMS) data. Electron production within the plume due to photoionization by solar radiation and by electron impact ionization was included, as were energy losses due to electron‐neutral collisions. Model cases were considered that both included and did not include electron inputs from outside the plume. Comparisons are made of model fluxes with measured fluxes by CAPS – ELS on October 9, 2008. The model‐data comparisons indicate that photoelectrons (10 eV–70 eV energies) locally produced within the plume can explain the data. The possible role of electron‐grain collisions was also explored and it was determined that nanograin densities in excess of 106 cm−3 would be needed to affect the electron distribution.

The abundance of H2 in Titan's troposphere from the Cassini CIRS investigation

We derived the mole fraction of H2 in the troposphere of Titan from an analysis of the H2–N2 dimer S0(0) rotational transition seen near 355cm−1 in spectra recorded by the Composite Infra-Red Spectrometer (CIRS) on the Cassini spacecraft between March 2006 and February 2007. We find a globally-averaged value of (9.6±2.4)×10−4, consistent with the earlier determination based on the Voyager IRIS dataset, and with the value obtained from the Gas Chromatograph Mass Spectrometer (GCMS) experiment on the Huygens probe, but a factor of ∼4 lower than that measured by the Ion and Neutral Mass Spectrometer (INMS) in the 1025–1475km altitude range. Interestingly, the latitudinal distribution of H2 appears to be non-uniform, with a mole fraction above 50°N in excess of 30–70% (±40%) relatively to the globally-averaged value. Such a non-uniform distribution is unexpected since H2 is thought to be chemically inert in the lower atmosphere of Titan. It is proposed that the observed enhancement in the north polar region is caused by downwelling occurring during the winter season in the polar vortex. This interpretation is dependent on the existence of a vertical gradient of the H2 concentration in the stratosphere, as suggested by the differences between the INMS values and those measured by GCMS and CIRS, although such a gradient is not consistent with the present understanding of dynamics and chemistry in Titan's atmosphere.

Titan's ionospheric composition and structure: Photochemical modeling of Cassini INMS data

Titan's upper atmosphere produces an ionosphere at high altitudes from photoionization and electron impact that exhibits complex chemical processes in which hydrocarbons and nitrogen‐containing molecules are produced through ion‐molecule reactions. The structure and composition of Titan's ionosphere has been extensively investigated by the Ion and Neutral Mass Spectrometer (INMS) onboard the Cassini spacecraft. We present a detailed study using linear correlation analysis, 1‐D photochemical modeling, and empirical modeling of Titan's dayside ionosphere constrained by Cassini measurements. The 1‐D photochemical model is found to reproduce the primary photoionization products of N2 and CH4. The major ions, CH5+, C2H5+, and HCNH+ are studied extensively to determine the primary processes controlling their production and loss. To further investigate the chemistry of Titan's ionosphere we present an empirical model of the ion densities that calculates the ion densities using the production and loss rates derived from the INMS data. We find that the chemistry included in our model sufficiently reproduces the hydrocarbon species as observed by the INMS. However, we find that the chemistry from previous models appears insufficient to accurately reproduce the nitrogen‐containing organic compound abundances observed by the INMS. The major ion, HCNH+, is found to be overproduced in both the empirical and 1‐D photochemical models. We analyze the processes producing and consuming HCNH+ in order to determine the cause of this discrepancy. We find that a significant chemical loss process is needed. We suggest that the loss process must be with one of the major components, namely C2H2, C2H4, or H2.

The water vapor plumes of Enceladus

[1] The Cassini E3, E5, and E7 encounters with Enceladus probed the south polar plumes, where the Ion and Neutral Mass Spectrometer (INMS) measured neutral H2O molecular densities up to ∼109 cm−3. We have constructed a physical model for the expected water density in the plumes, based on supersonic radial outflow from one or more of the surface vents. We apply this model to possible surface sources of water vapor associated with the multiple jets observed in the visible dust plumes. Our model predictions fit well with the INMS measurements of neutral H2O density along the E3, E5, and E7 trajectories. The fit is optimized by values of outflow velocity in the range ∼550–750 m/s and values of total source rate in the range ∼1.5 − 3.5 × 1028 H2O molecules/s. The model can be extended to incorporate the jet features within the plume observed during the E7 encounter.

Energetics of Titan's ionosphere: Model comparisons with Cassini data

[1] Observed electron and ion temperatures in planetary ionospheres are higher than the neutral temperature. Instruments on board the Cassini spacecraft have shown this is also true for Titan. The Radio and Plasma Wave Science Langmuir Probe (RPWS-LP) (Wahlund et al., 2005) has measured electron temperatures above 1000 K. Ionospheric ion temperatures were deduced from a combined analysis of data from the Cassini Plasma Spectrometer and Ion and Neutral Mass Spectrometer (INMS) (Crary et al., 2009). Elevated electron temperatures attributed to heating by suprathermal electrons were predicted by pre-Cassini models (e.g., Gan et al., 1992; Roboz and Nagy, 1994) and observed by the Cassini electron spectrometer. Models of the energetic electrons and ions are presented that include Cassini inputs (i.e., measured neutral densities from INMS). The results are compared between 800 and 1800 km with suprathermal electron fluxes and plasma temperatures measured by Cassini instruments emphasizing the thermal electron temperature. Using only solar inputs, the dayside model agrees well with electron temperatures measured by RPWS-LP (Ågren et al., 2009) between 1000 and 1400 km. At higher altitudes energy input from magnetospheric electrons is needed to reproduce the measured temperature. Incorporating typical magnetospheric electron fluxes into the dayside does not noticeably increase ion production near the ionospheric peak; however, effects can be seen near 1350 km. Joule heating effects are shown to be capable of contributing significantly to the ion temperature. Magnetospheric suprathermal electrons are shown to provide sufficient heating for the thermal electron population in the middle to upper ionosphere on the nightside.

Titan's thermospheric response to various plasma environments

[1] TheCassini‐HuygensmissionhasbeenobservingTitansinceOctober2004,resultingin over 70 targeted flybys. Titan’s thermosphere is sampled by the Ion and Neutral Mass Spectrometer (INMS) during several of these flybys. The measured upper atmospheric density varies significantly from pass to pass. In order to quantify the processes controlling this variability, we calculate the nitrogen scale height for a variety of parameters related to the solar and plasma environments and, from these, we infer an effective upper atmospheric temperature. In particular, we investigate how these calculated scale heights and temperatures correlate with the plasma environment. Measured densities and inferred temperatures are found to be reduced when INMS samples Titan within Saturn’s magnetospheric lobe regions, while they are enhanced when INMS samples Titan in Saturn’s plasma sheet. Finally the data analysis is supplemented with Navier‐Stokes model calculations using the Titan Global Ionosphere Thermosphere Model. Our analysis indicates that, during the solar minimum conditions prevailing during the Cassini tour, the plasma interaction plays a significant role in determining the thermal structure of the upper atmosphere and, in certain cases, may override the expected solar‐driven diurnal variation in temperatures in the upper atmosphere. Citation: Westlake, J. H., J. M. Bell, J. H. Waite Jr., R. E. Johnson, J. G. Luhmann, K. E. Mandt, B. A. Magee, and A. M. Rymer (2011), Titan’s thermospheric response to various plasma environments, J. Geophys. Res., 116, A03318,

Heavy ions, temperatures and winds in Titan's ionosphere: Combined Cassini CAPS and INMS observations

Multiple Titan encounters by the Cassini spacecraft have shown that ion chemistry in Titan's upper atmosphere is much more complex than previously thought. As well as showing a great variety of species present below 100 amu, they also include the detection of negative ions and of large abundances of ions above 100 amu. Here, we use data from two Cassini instruments, the Cassini plasma spectrometer's ion beam sensor (CAPS/IBS) and the ion and neutral mass spectrometer (INMS) during fourteen Cassini encounters with Titan's upper atmosphere. By simultaneous analysis of the combined data, we are able to determine the ion temperature, one component of the wind speed and spacecraft potential. Using these derived quantities, we are also able to extend the analysis of CAPS/IBS data to quantify the abundance of ions above 100 amu and to statistically estimate their composition.

Structure of Titan's ionosphere: Model comparisons with Cassini data

Solar extreme ultraviolet and X-ray radiation and energetic plasma from Saturn's magnetosphere interact with the upper atmosphere producing an ionosphere at Titan. The highly coupled ionosphere and upper atmosphere system mediates the interaction between Titan and the external environment. New insights into Titan's ionosphere are being facilitated by data from several instruments onboard the Cassini Orbiter, although the Ion and Neutral Mass Spectrometer (INMS) measurements will be emphasized here. We present dayside ionosphere models and compare the results with both Radio and Plasma Wave–Langmuir Probe (RPWS/LP) and INMS data, exploring the sensitivity of models to ionospheric chemistry schemes and solar flux variations. Modeled electron densities for the dayside leg of T18 and all of T17 (dayside) had reasonable agreement with the measured RPWS electron densities and INMS total ion densities. Magnetospheric inputs make at best minor contributions to the ionosphere for these flybys, at least for altitudes above about 1000 km. At lower (<1100 km) altitudes, the total ion densities measured by the INMS are less than the electron densities measured by the RPWS/LP which could be due to heavy (>100 daltons) ions, which the INMS is not able to detect. Qualitatively, INMS spectra exhibit the same ion species and 12 amu family separations for the dayside ionospheres of T17 and T18 as were seen in the mass spectra measured during T5 (nightside). However, the relative abundance of high-mass ( m>50) ion species is about 10 times less for the dayside T17 and T18 passes than it was for the polar nightside T5 flyby, which can perhaps be explained in several ways including differences in neutral composition, less dissociative recombination on the nightside than on the dayside (due to lower electron densities and affecting heavier ion species more than lighter ones), and transport of longer-lived high-mass species from day-to-night.

INMS-derived composition of Titan's upper atmosphere: Analysis methods and model comparison

The Cassini Ion and Neutral Mass Spectrometer (INMS) has recorded full altitude profile data from 20 low-altitude Titan encounters during the nominal mission (July 2004–2008). These encounters were TA, T5, T16, T18, T19, T21, T23, T25, T26, T28, T29, T30, T32, T36, T37, T39, T40, T41, T42, and T43. In this work we present an analysis of the data observed by INMS during these encounters to derive the neutral composition of Titan's upper atmosphere between 1000 and 1100 km. Analysis methods are described for the determination and correction of instrument effects as well as the composition derivation processes. Results are compared to independent INMS analysis efforts and a selected survey of photochemical models of Titan's upper atmosphere.

Plume ionosphere of Enceladus as seen by the Cassini ion and neutral mass spectrometer

The Cassini spacecraft passed within 168 km of the surface of Enceladus on 14 July 2005 during the E2 flyby and passed closer (50 km) during the E3 encounter on 13 March 2008. During both flybys the ion and neutral mass spectrometer (INMS) detected a plume atmosphere mainly composed of water. During the E3 flyby, the INMS measured an ion mass spectrum with a large peak at mass number of 19 Daltons (interpreted as H3O+ ions) but not at the mass numbers of other water group ion species (including H2O+, OH+, O+). In addition, the INMS observed ion species at mass numbers 36 and 37 ‐ possibly the water cluster ion species H2O+ ‐ H2O and H3O+ ‐ H2O. The INMS detection of cold H3O+ in the plume combined with the almost complete absence of cold H2O+ ions is attributed to an active ion‐neutral chemistry operating in a plume “ionosphere.”

Composition and chemistry of Titan's thermosphere and ionosphere

Titan has long been known to harbour the richest atmospheric chemistry in the Solar System. Until recently, it had been believed that complex hydrocarbons and nitriles were produced through neutral chemistry that would eventually lead to the formation of micrometre sized organic aerosols. However, recent measurements by the Cassini spacecraft are drastically changing our understanding of Titan's chemistry. The Ion and Neutral Mass Spectrometer (INMS) and the Cassini Plasma Spectrometer (CAPS) revealed an extraordinary complex ionospheric composition. INMS detected roughly 50 positive ions with m/z<100 and a density higher than 0.1cm-3. CAPS provided evidence for heavy (up to 350amu) positively and negatively charged (up to 4000amu) ions. These observations all indicate that Titan's ionospheric chemistry is incredibly complex and that molecular growth starts in the upper atmosphere rather than at lower altitude. Here, we review the recent progress made on ionospheric chemistry. The presence of heavy neutrals in the upper atmosphere has been inferred as a direct consequence of the presence of complex positive ions. Benzene (C6H6) is created by ion chemistry at high altitudes and its main photolysis product, the phenyl radical (C6H5), is at the origin of the formation of aromatic species at lower altitude.

Model-data comparisons for Titan's nightside ionosphere

Solar and X-ray radiation and energetic plasma from Saturn's magnetosphere interact with the upper atmosphere producing an ionosphere at Titan. The highly coupled ionosphere and upper atmosphere system mediates the interaction between Titan and the external environment. A model of Titan's nightside ionosphere will be described and the results compared with data from the Ion and Neutral Mass Spectrometer (INMS) and the Langmuir probe (LP) part of the Radio and Plasma Wave (RPWS) experiment for the T5 and T21 nightside encounters of the Cassini Orbiter with Titan. Electron impact ionization associated with the precipitation of magnetospheric electrons into the upper atmosphere is assumed to be the source of the nightside ionosphere, at least for altitudes above 1000 km. Magnetospheric electron fluxes measured by the Cassini electron spectrometer (CAPS ELS) are used as an input for the model. The model is used to interpret the observed composition and structure of the T5 and T21 ionospheres. The densities of many ion species (e.g., CH + 5 and C 2H + 5) measured during T5 exhibit temporal and/or spatial variations apparently associated with variations in the fluxes of energetic electrons that precipitate into the atmosphere from Saturn's magnetosphere.

Ion chemistry and N-containing molecules in Titan's upper atmosphere

High-energy photons, electrons, and ions initiate ion–neutral chemistry in Titan's upper atmosphere by ionizing the major neutral species (nitrogen and methane). The Ion and Neutral Mass Spectrometer (INMS) onboard the Cassini spacecraft performed the first composition measurements of Titan's ionosphere. INMS revealed that Titan has the most compositionally complex ionosphere in the Solar System, with roughly 50 ions at or above the detection threshold. Modeling of the ionospheric composition constrains the density of minor neutral constituents, most of which cannot be measured with any other technique. The species identified with this approach include the most complex molecules identified so far on Titan. This confirms the long-thought idea that a very rich chemistry is actually taking place in this atmosphere. However, it appears that much of the interesting chemistry occurs in the upper atmosphere rather than at lower altitudes. The species observed by INMS are probably the first intermediates in the formation of even larger molecules. As a consequence, they affect the composition of the bulk atmosphere, the composition and optical properties of the aerosols and the flux of condensable material to the surface. In this paper, we discuss the production and loss reactions for the ions and how this affects the neutral densities. We compare our results to neutral densities measured in the stratosphere by other instruments, to production yields obtained in laboratory experiments simulating Titan's chemistry and to predictions of photochemical models. We suggest neutral formation mechanisms and highlight needs for new experimental and theoretical data.

Understanding the escape of water from Enceladus

On 14 July 2005, Cassini passed within 175 km of Enceladus’ surface enabling a direct in situ measurement of water escaping from the surface by the Ion and Neutral Mass Spectrometer (INMS) and the observation of a stellar occultation by the Ultraviolet Spectrometer (UVIS). We have developed a three‐dimensional, Monte Carlo neutral model to simultaneously model the INMS and UVIS measurements of water gas density and column density, respectively. The data are consistent with a two‐component atmosphere; the first with a weak, distributed source on the surface which, if global, has a source rate of ∼8 × 1025 H2O/s, and the second with a much larger source localized at the south pole with a source rate ∼1028 H2O/s. This latter source is possibly coincident with the “tiger stripe” series of fractures revealed by the Imaging Science Subsystem instrument where the ice was measured to be warmer than the surrounding regions by the Composite Infrared Spectrometer instrument. We estimate the plasma mass loading rate due to interaction between the plume and magnetospheric plasma is 2–3 kg/s for a plume source of 1028 H2O/s. Pickup of water group ions in the plume slows down the plasma to ∼10 km/s relative to Enceladus in the region of, and downstream of, the south polar plume. This is consistent with the mass loading rate inferred from magnetic field perturbations detected during the Cassini flyby and suggests an additional source may be needed to explain the plasma flow deflections detected by the Cassini Plasma Spectrometer.

Composition of Titan's ionosphere

We present Cassini Ion and Neutral Mass Spectrometer (INMS) measurements of ion densities on the nightside of Titan from April 16, 2005, and show that a substantial ionosphere exists on the nightside and that complex ion chemistry is operating there. The total ionospheric densities measured both by the INMS and the Cassini Radio and Plasma Wave (RPWS) experiments on Cassini suggest that precipitation from the magnetosphere into the atmosphere of electrons with energies ranging from 25 eV up to about 2 keV is taking place. The absence of ionospheric composition measurements has been a major obstacle to understanding the ionosphere. Seven “families” of ion species, separated in mass‐to‐charge ratio by 12 Daltons (i.e., the mass of carbon), were observed and establish the importance of hydrocarbon and nitrile chains in the upper atmosphere. Several of the ion species measured by the INMS were predicted by models (e.g., HCNH+ and C2H5+). But the INMS also saw high densities at mass numbers not predicted by models, including mass 18, which we suggest will be ammonium ions (NH4+) produced by reaction of other ion species with neutral ammonia.

Cassini Ion and Neutral Mass Spectrometer: Enceladus Plume Composition and Structure

The Cassini spacecraft passed within 168.2 kilometers of the surface above the southern hemisphere at 19:55:22 universal time coordinated on 14 July 2005 during its closest approach to Enceladus. Before and after this time, a substantial atmospheric plume and coma were observed, detectable in the Ion and Neutral Mass Spectrometer (INMS) data set out to a distance of over 4000 kilometers from Enceladus. INMS data indicate that the atmospheric plume and coma are dominated by water, with significant amounts of carbon dioxide, an unidentified species with a mass-to-charge ratio of 28 daltons (either carbon monoxide or molecular nitrogen), and methane. Trace quantities (<1%) of acetylene and propane also appear to be present. Ammonia is present at a level that does not exceed 0.5%. The radial and angular distributions of the gas density near the closest approach, as well as other independent evidence, suggest a significant contribution to the plume from a source centered near the south polar cap, as distinct from a separately measured more uniform and possibly global source observed on the outbound leg of the flyby.

Titan's ionosphere: Model comparisons with Cassini Ta data

On October 26, 2004, during its first encounter with Titan (Ta), the Cassini Orbiter moved from the dayside to the nightside with a closest approach altitude of 1174 km. In situ measurements of the main part of Titan's ionosphere were made by the Langmuir probe on the Cassini Radio and Plasma Wave Experiment (RPWS), while the Ion and Neutral Mass Spectrometer (INMS) measured the main constituents of the neutral atmosphere. The results of model calculations of Titan's ionosphere for Ta encounter conditions (e.g., near the terminator) are presented in this paper. The paper includes comparisons of calculated and measured electron densities along the spacecraft track. Ionization both by solar radiation and by incoming energetic electrons from Saturn's magnetosphere are needed to obtain good agreement between the measured and calculated electron densities.

Oxygen Ions Observed Near Saturn's A Ring

Ions were detected in the vicinity of Saturn's A ring by the Ion and Neutral Mass Spectrometer (INMS) instrument onboard the Cassini Orbiter during the spacecraft's passage over the rings. The INMS saw signatures of molecular and atomic oxygen ions and of protons, thus demonstrating the existence of an ionosphere associated with the A ring. A likely explanation for these ions is photoionization by solar ultraviolet radiation of neutral O2 molecules associated with a tenuous ring atmosphere. INMS neutral measurements made during the ring encounter are dominated by a background signal.

The Cassini Ion and Neutral Mass Spectrometer (INMS) Investigation

The Cassini Ion and Neutral Mass Spectrometer (INMS) investigation will determine the mass composition and number densities of neutral species and low-energy ions in key regions of the Saturn system. The primary focus of the INMS investigation is on the composition and structure of Titan’s upper atmosphere and its interaction with Saturn’s magnetospheric plasma. Of particular interest is the high-altitude region, between 900 and 1000 km, where the methane and nitrogen photochemistry is initiated that leads to the creation of complex hydrocarbons and nitriles that may eventually precipitate onto the moon’s surface to form hydrocarbon—nitrile lakes or oceans. The investigation is also focused on the neutral and plasma environments of Saturn’s ring system and icy moons and on the identification of positive ions and neutral species in Saturn’s inner magnetosphere. Measurement of material sputtered from the satellites and the rings by magnetospheric charged particle and micrometeorite bombardment is expected to provide information about the formation of the giant neutral cloud of water molecules and water products that surrounds Saturn out to a distance of ~12 planetary radii and about the genesis and evolution of the rings.

A current stabilizer for a superconducting solenoid

The Cassini Ion and Neutral Mass Spectrometer (INMS) has recorded full altitude profile data from 20 low-altitude Titan encounters during the nominal mission (July 2004–2008). These encounters were TA, T5, T16, T18, T19, T21, T23, T25, T26, T28, T29, T30, T32, T36, T37, T39, T40, T41, T42, and T43. In this work we present an analysis of the data observed by INMS during these encounters to derive the neutral composition of Titan's upper atmosphere between 1000 and 1100 km. Analysis methods are described for the determination and correction of instrument effects as well as the composition derivation processes. Results are compared to independent INMS analysis efforts and a selected survey of photochemical models of Titan's upper atmosphere.