Iodine Fluoride Research Articles

Iodine fluorides and their organo derivatives

Principally there are two ways to organo derivatives of iodine fluorides 1. the oxidative fluorination of alkyl- or aryl-iodides2. the substitution of fluoride in iodine fluorides.Arylbromine(V)tetrafluorides react with alkyl- or aryliodides in organic solvents. For this reaction we found relations between the basicity of the medium and the kind of fluorination products: RIF2 and RIF4 or other oxidation products. The conversion of the fluorination reaction strongly depended on medium basicity. R'bIF4 + RI → RIF2 + RIF4 + RI + R'BrIn contrast to alkyliodides C6F5I was not oxidatively fluorinated when BF3 was present, but electrophilically arylated under formation of [(C6F5)2]+. The same product was isolated when i-C3F7IF2 reacted with Cd(C6F5)2 in presence of BF3.Using nucleophilic substitution-reaction IF5 and IOF3 could be reacted to the corresponding polyvalent aryl-iodine compounds.Presupposing correct Lewis acidity of the reaction medium IF5 itself can be used as specific oxidative fluorinating reagent e.g. for the preparation of acid fluorides.

Excitation of iodine fluoride(B3.PI.0+) by active nitrogen

Excitation of iodine fluoride(B3.PI.0+) by active nitrogen

The Diode Laser Spectrum of Iodine Fluoride (IF)in the Ground Electronic State

Abstract The infrared absorption spectrum of the gas phase IF molecule in its ground state has been observed for the first time, using a diode laser spectrometer. The wavenumbers of transitions in the v = 1←0, and v = 2 ←1 bands have been measured with a nominal accuracy of +0.001 cm-1. These data were fitted along with the recently published microwave spectrum to produce an improved set Dunham T-parameters. Also the coefficients of the Dunham potential function for the electronic state of IF were determined by a direct fit to the experimental data.

Direct aromatic iodination using iodine fluoride prepared from iodine and fluorine

Direct aromatic iodination using iodine fluoride prepared from iodine and fluorine

Synthesis and chemistry of perfluoro-2-iodo-2-methyl-alkanes

Two novel perfluoro-tert-alkyl iodides CF 3(CF 2) n+1 C(CF 3) 2I have been obtained from F-alkenes CF 3(CF 2) nCFC(CF 3) 2 (n = 0 and 1) by formal additions of iodine fluoride; these required substantial alterations of known procedure. The F-tert-alkyl iodides are the most reactive alkyl halides known so far, and they are also very toxic. The following types of reactions have been studied: (a) Nucleophilic attack of anions at the iodine, leading to F-alkenes, (b) elimination of iodine fluoride, caused by metals or metal complexes, (c) pyrolysis, to give very selectively F-isobutene and n-perfluoroalkyl iodides, (d) photolysis, and (e) thermally induced insertions into the carbon-iodine bond. Screening results on the inhalation toxicity of the iodides and of some other fluoro-compounds are also reported.

Nitrogen fluoride(b1.SIGMA.+) quenching rate constants by halogens and interhalogens and the excitation rate constant for iodine fluoride(B) formation

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNitrogen fluoride(b1.SIGMA.+) quenching rate constants by halogens and interhalogens and the excitation rate constant for iodine fluoride(B) formationHyungki. Cha and D. W. SetserCite this: J. Phys. Chem. 1987, 91, 14, 3758–3767Publication Date (Print):July 1, 1987Publication History Published online1 May 2002Published inissue 1 July 1987https://doi.org/10.1021/j100298a009RIGHTS & PERMISSIONSArticle Views39Altmetric-Citations10LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alerts

A novel method for constructing a difluoromethylene group via the reaction of alkynes with bromine fluoride and iodine fluoride prepared directly from the corresponding elements

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA novel method for constructing a difluoromethylene group via the reaction of alkynes with bromine fluoride and iodine fluoride prepared directly from the corresponding elementsShlomo Rozen and Michael BrandCite this: J. Org. Chem. 1986, 51, 2, 222–225Publication Date (Print):January 1, 1986Publication History Published online1 May 2002Published inissue 1 January 1986https://doi.org/10.1021/jo00352a017RIGHTS & PERMISSIONSArticle Views322Altmetric-Citations51LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (585 KB) Get e-Alerts Get e-Alerts

On the substitution-reaction of IF 5 by oxo-compounds

Fluorine in IF 5 can be replaced by oxogroups using silylated alcoholes, carboxylates or siloxane itself. Systematic investigations of the fluorine-monoalcoholate-exchange in solution [1] show that IF 4(OR) is the only stable exchange-product at room temperature. Higher substitution products are unstable and undergo bismutation- and elimination-reactions: IF 3(OR) 2 → IF 4(OR) + IF 2(OR) 3 IF 2(OR) 3 ▪ IF 2O(OR) IO 2OR as the final product of nucleophilic exchange results on different routes: ▪ α-Branching in the aliphatic alcoholic group results in higher instability (alkylfluoride-elimination) of the iodine(V)fluoride alcoholates. No stable iodine(V)fluoride phenolates can be prepared. Using di- and trialcoholates two competing reaction products can be observed: IF 4O(CRR′) nOIF 4 and IF 3[O(CRR′) nO] In addition higher exchange products are formed: IF[O(CRR′)nO]2 Expanding our exchange-concept to the IF 5-carboxylate-system it was possible to synthesize IO(O 2C-R) 3, IO 2(O 2C-R), and in the case of the oxalate-group: IF 3(O 2CCO 2) and IFO(O 2CCO 2).

Combined Effect of Iodine and Sodium Fluoride on Dental Caries in Rats and on Viability of Streptococcus mutans in vitro

The caries-preventive and antibacterial properties of topically applied solutions of iodine and sodium fluoride administered singly or in combination were investigated using the rat model and in vitro

ChemInform Abstract: THERMOCHEMISTRY OF FLUORINE COMPOUNDS. VI. IODINE(V) FLUORIDE

Chemischer InformationsdienstVolume 11, Issue 52 Physical Inorganic Chemistry ChemInform Abstract: THERMOCHEMISTRY OF FLUORINE COMPOUNDS. VI. IODINE(V) FLUORIDE A. FINCH, A. FINCHSearch for more papers by this authorP. N. GATES, P. N. GATESSearch for more papers by this authorM. A. JENKINSON, M. A. JENKINSONSearch for more papers by this author A. FINCH, A. FINCHSearch for more papers by this authorP. N. GATES, P. N. GATESSearch for more papers by this authorM. A. JENKINSON, M. A. JENKINSONSearch for more papers by this author First published: December 30, 1980 https://doi.org/10.1002/chin.198052020AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume11, Issue52December 30, 1980 RelatedInformation

Thermochemistry of fluorine compounds—VI. Iodine(V) fluoride

Thermochemistry of fluorine compounds—VI. Iodine(V) fluoride

Chemiluminescent reactions of oxygen fluoride. 2. Reactions producing excited bromine fluoride and iodine fluoride

Chemiluminescent reactions of oxygen fluoride. 2. Reactions producing excited bromine fluoride and iodine fluoride

Structures of hexacoordinate compounds of main-group elements. 2. A combined electron diffraction-microwave study of iodine fluoride oxide (IOF5)

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructures of hexacoordinate compounds of main-group elements. 2. A combined electron diffraction-microwave study of iodine fluoride oxide (IOF5)L. S. Bartell, F. B. Clippard, and E. Jean. JacobCite this: Inorg. Chem. 1976, 15, 12, 3009–3013Publication Date (Print):December 1, 1976Publication History Published online1 May 2002Published inissue 1 December 1976https://doi.org/10.1021/ic50166a013RIGHTS & PERMISSIONSArticle Views70Altmetric-Citations29LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (745 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

Electronic structure and chemistry of some iodine compounds

By means of ab initio LCGO-MO-SCF calculations on a series of iodine fluorides and oxyfluorides. an attempt is made to obtain some quantum chemical background for the chemistry of these molecules, The agreement of the calculated data with various experimental results is quite good, despite the small basis set and neglect of relativistic and correlation effects. Electronic structure and bonding of the compounds are discussed, leading to the conclusion, that the chemistry of iodine is determined almost exclusively by p-electrons. Some physical quantities and reaction energies are discussed in relation to the experimentally observed chemical behaviour of the molecules investigated, such as dissociation, disproportionation, association tendency and 19F chemical shifts.

Thermodynamic Properties of the Diatomic Interhalogens from Spectroscopic Data

The thermodynamic functions Cp0, S0, —(F0—E00)/T, and (H0—E00)/T of the six diatomic interhalogens, chlorine monofluoride, bromine monofluoride, iodine monofluoride, bromine monochloride, iodine monochloride, and iodine monobromide, have been evaluated as a function of temperature from 298.16°K to 2000°K by the application of statistical methods. These results have been combined with newly evaluated properties of the fluorine, chlorine, bromine, and iodine atoms and molecules to yield the heats and free energies of dissociation and dissociation constants for the equilibria between the interhalogens and their molecular and atomic dissociation products. The calculations are based on available experimental spectroscopic constants with the exception of the anharmonicity term and internuclear distance for bromine chloride and of the internuclear distances in iodine fluoride and iodine bromide. These quantities are estimated empirically.