This study explored the model of urban impervious surface (IS) density, land surface temperature (LST), and comprehensive ecological evaluation index (CEEI) from urban centers to suburbs. The interrelationships between these parameters in Guangzhou from 1987 to 2019 were analyzed using time-series Landsat-5 TM (Thematic Mapper), Landsat-8 OLI (Operational Land Imager), and TIRS (Thermal Infrared Sensor) images. The urban IS densities were calculated in concentric rings using time-series IS fractions, which were used to construct an inverse S-shaped urban IS density function to depict changes in urban form and the spatio-temporal dynamics of urban expansion from the urban center to the suburbs. The results indicated that Guangzhou experienced expansive urban growth, with the patterns of urban spatial structure changing from a single-center to a multi-center structure over the past 32 years. Next, the normalized LST and CEEI in each concentric ring were calculated, and their variation trends from the urban center to the suburbs were modeled using linear and nonlinear functions, respectively. The results showed that the normalized LST had a gradual decreasing trend from the urban center to the suburbs, while the CEEI showed a significant increasing trend. During the 32-year rapid urban development, the normalized LST difference between the urban center and suburbs increased gradually with time, and the CEEI significantly decreased. This indicated that rapid urbanization significantly expanded the impervious surface areas in Guangzhou, leading to an increase in the LST difference between urban centers and suburbs and a deterioration in ecological quality. Finally, the potential interrelationships among urban IS density, normalized LST, and CEEI were also explored using different models. This study revealed that rapid urbanization has produced geographical convergence between several ISs, which may increase the risk of the urban heat island effect and degradation of ecological quality.
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