Intrinsic Physical Properties Research Articles

(Invited) Suspended 1D/2D Nanomaterials: Progress on a Waferlevel Technology and Applications

The use of 1D and 2D nanomaterials in emerging electronics and sensor technologies is becoming increasingly important due to their unique properties. Here we would like to highlight a scalable process for suspended nanomaterials that provides additional scope for the development of device properties that can be used in advanced concepts ranging from molecular sensing to quantum applications [1]. For example those applications benefit from arrangements as CNT-based nanoresonators with extremely high quality factors [2] usable for quantum bits with long coherence time [3] or suspended sensing nanomaterials for ultra-low power and extremely sensitive gas sensors [4]. Moreover, straining allows to tune intrinsic physical properties of nanomaterials. Thus, the strain-dependence of the band gap (e.g. CNTs <100meV/% [5], MoS2 ~60meV/% [6],) paves the way for integrated-, highly-efficient-, and tunable light sources for on-chip spectrometry in the context of photonic integrated circuits (PICs), as recently reviewed in [7].Our technological solution to manufacture suspended nanomaterials is aligned with established semiconductor processing chains on 200 mm wafer level and is developed to be modular integrable and compatible with MEMS, MEOMS or CMOS technologies [8]. Along the process chain, we demonstrate wafer-validated deposition processes for semiconducting CNT films which properties can be adjusted with respect to density and even alignment. In particular, for straining aligned CNTs as well as any transferable 2D nanomaterial, we implemented a stressed functional SiO2/SiN layer stack arranged on embedded sacrificial Cu-structures on the wafer surface. After contacting of the nanomaterial and release of sacrificial elements, stressed layers relax, strain and suspend the nanomaterial. This surface engineering approach greatly simplifies the introduction of strain into nanomaterials and makes it accessible for arbitrary device numbers on wafers as well as for monolithic 3D electronic concepts. Unique features include in-plane strains that are applicable in multiaxial directions and can be controlled by designing only two lithography planes. We show that devices with CNTs strained up to 1% determined from Raman spectral analysis, have a positive impact on sensor operation. We show application examples such as a mechanical stress sensor with extremely low on-set sensitivity.

Crystal Growth of the R2SiO5 Compounds (R = Dy, Ho, and Er) by the Floating Zone Method Using a Laser-Diode-Heated Furnace

In recent years, rare earth silicate compounds have attracted the extensive attention of researchers owing to their potential for applications in scintillation crystals in gamma ray or X-ray detectors, as well as in thermal or environmental barrier coatings. Large high quality crystals of three members of the rare earth monosilicates family of compounds, R2SiO5 (with R = Dy, Ho, and Er), have been grown by the floating zone method, using a laser-diode-heated floating zone furnace. Crystal growths attempts were carried out using different parameters in order to determine the optimum conditions for the growth of these materials. The phase purity and the crystalline quality of the crystal boules were analysed using powder and Laue X-ray diffraction. Single crystal X-ray diffraction experiments were carried out to determine the crystal structures of the boules. The optimum conditions used for the crystal growth of R2SiO5 materials are reported. The phase purity and high crystalline quality of the crystals produced makes them ideal for detailed investigations of the intrinsic physical and chemical properties of these materials.

Time-Domain View of Polaron Dynamics in Metal Oxide Photocatalysts.

The polaron is a fundamental physical phenomenon in transition metal oxides (TMOs), and it has been studied extensively for decades. However, the implication of a polaron on photochemistry is still ambiguous. As such, understanding the fundamental properties and controlling the dynamics of polarons at the atomistic level is desired. In this Perspective, we seek to highlight the recent advances in studying small polarons in TMOs, with a particular focus on nonadiabatic molecular dynamics at the ab initio level, and discuss the implications for photocatalysis from the aspects of the structure, intrinsic physical properties, formation, migration, and recombination of small polarons. Finally, various methods were proposed to advance our understanding of manipulating the small-polaron dynamics, and strategies to design high-performance TMO-based photoelectrodes were discussed.

Novel wet transfer technology of manufacturing flexible suspended two-dimensional material devices

With the rise of two-dimensional (2D) materials, their excellent optical, electronic, and thermal properties different from bulk materials make them increasingly widely studied and commercialized. 2D materials’ exceptional physical properties and unique structures make them an ideal candidate for next-generation flexible and wearable devices. In this work, we created a manufacturing method to successfully transfer monolayer, bilayer, and trilayer graphene onto the flexible substrate, with trenches of micron size to suspend graphene. Thermal transport measurements have been characterized to prove the suspended region. The achievement of manufacturing 2D materials in suspended condition will allow us to study their intrinsic physical properties at a mechanical strain, as well as contribute to novel flexible and wearable electronic devices and sensors.

Exceptionally flexible and stable quasi-solid-state supercapacitors via salt-in-polyampholytes electrolyte with non-freezable properties

Hydrogel electrolytes have been intensively studied for a decade, due to their outstanding intrinsic physical properties, such as good flexibility, high stretchability, and high ionic conductivity. However, due to their low mechanical strength (<103 Pa) and poor ionic conductivity (<1 mS/cm) at low temperatures, many researchers have been focusing on improving these issues. Thus, in our study, we prepared salt-in-polyampholytes (SIPAs) that have two different counterions (Li+ and Cl-) in an aqueous medium via facile one-step UV radical polymerization. Polyampholyte (PA) improves the toughness and elongation by inducing strong ionic interactions between opposite charges in the polymer chains, but also exhibits excellent recovery ability under periodically changing strain and strong adhesion with electrodes. Furthermore, the incorporation of LiCl salt into our PA results in SIPA with high ionic conductivity at 25 °C (134 mS/cm) and even at sub-zero temperatures (15 mS/cm). Consequently, the non-freezable SIPA-based quasi-solid-state supercapacitor (QSS), assembled with activated carbon electrodes, exhibits a wide operating voltage window as high as 2.0 V, a high specific capacitance of 241 F/g, and high energy (34 Wh/kg) and power (598 W/kg) densities, along with excellent cycling stability, retaining 91 % of the initial capacitance even after 20,000 cycles at 1 A/g. Besides, the QSS electrochemical performance remains unaffected under bending and rolling deformations at a low temperature, demonstrating excellent mechanical, thermal, and electrochemical stability of our system. This work provides an effective strategy for designing energy storage devices that are both foldable and reliable, making them suitable for use in extreme environments.

Properties of isolated galaxies in the Digital Survey Isolated Galaxies (DSIG) catalogue within a redshift range (0.005 &amp;lt; z &amp;lt; 0.080)

ABSTRACT Evolution of galaxies is known to be influenced by a number of factors such as the environment that hosts the galaxy as well as the galaxies intrinsic properties. The environmental effects on galaxy properties have not been fully quantified. In our study, we analysed a sample of isolated galaxies within 0.005 &amp;lt; z &amp;lt; 0.080 from Sloan Digital Sky Survey data release 16, as part of a Digital Survey Isolated Galaxies catalogue. The aim was to investigate intrinsic physical properties of singly isolated galaxies in low-density environment. We investigated the galaxies morphology, colour, luminosity, stellar masses, and star formation rates (SFRs). A concentration index, Cr, of 2.65 separates our isolated sample into early and late types, with the late-types (spiral galaxies) dominating the isolated sample at 68 per cent as confirmed from the visually classified sample obtained from Galaxy Zoo. Our isolated ellipticals are redder, massive, and more luminous, while the isolated spirals are blue, less massive, and less luminous. Both the isolated spirals and ellipticals have steeper colour relations indicating a fast transition to the red sequence. In the colour–colour analysis, most ellipticals were quiescent with the majority of spirals being star forming. 5 per cent of the isolated ellipticals have recently quenched their star formation and are transiting to the red sequence. The isolated spirals experiences higher star-forming activities, with a small fraction of passively evolving high-mass isolated spirals. Similarly, isolated ellipticals exhibit low SFRs indicating passive evolution, with a fraction being actively star forming.

Preparation of a new calcite layer from calcium glycolate for the conservation of sulfated limestone artifacts

AbstractA novel preparation method of calcite layer was explored for the conservation purpose of the surface sulfation limestone artifacts. In this method, the alcoholic solution of calcium glycolate was used as a precursor of calcite layer. After application on the surface of gypsum crust on limestone by spraying, calcium glycolate can combine with the carbon dioxide spontaneously and form a compact calcite layer. The obtained calcite layer can act as a shelter and can prevent the gypsum crust from the dissolution damage of the natural precipitation. The protective properties of the calcite layer were investigated by scanning electron microscopy with energy dispersive X‐ray spectroscopy (SEM/EDS), X‐ray diffraction (XRD), infrared spectroscopy (FTIR), water erosion resistance, water absorption, colour difference, surface strength, and hardness test. The results revealed that the water erosion resistance, surface strength, and hardness of the treated sample were increased remarkably. Meanwhile, the intrinsic physical properties such as porosity, capillary absorption, and appearance were not affected obviously, indicating a good compatibility of the proposed protection method.

Cobalt-doped WSe2@conducting polymer nanostructures as bifunctional electrocatalysts for overall water splitting

Designing of high-performance, low-cost, and nonprecious metal-based bifunctional electrocatalysts is highly significant for the development of water splitting process and expanding the practical application of green hydrogen production. Transition metal dichalcogenides (TMDs) with intrinsic physical and chemical properties have been considered potential catalytic materials for electrode fabrication. However, it has remained challenging to develop TMD catalysts that have bifunctional properties for overall water splitting. Herein, WSe2, as a typical representative of TMDs, was utilized to design electrocatalysts using polypyrrole (PPy) or polyaniline (PANI) as a conducting polymer (CP) and cobalt doping. A facile hydrothermal preparation of WSe2 in the presence of CP enabled the construction of cobalt-doped WSe2@CP electrocatalysts. Morphological analysis indicated that the CP played an important role as a conductive template to enhance the distribution of WSe2 nanosheets, leading to higher surface area. In addition, cobalt doping led to the formation of defect structures and boosted the electrocatalytic activities of the catalysts for oxygen evolution reaction (OER). Owing to the increased electrochemical surface area and defect structures, the cobalt-doped WSe2@CP nanostructures exhibited enhanced electrochemical properties for hydrogen evolution reaction (HER) and OER in an alkaline medium. The cobalt-doped WSe2@PANI modified glassy carbon electrode (GCE) exhibited overpotentials down to 308 and 360 mV at a current density of 10 mA cm−2 for the HER and OER, respectively. Furthermore, the cobalt-doped WSe2@CP electrocatalysts demonstrated long-term stability and continuous cycling. More importantly, the Co–WSe2@PANI electrolyzer required cell voltage of 1.87 V at a current density of 10 mA cm−2 for overall water splitting process. This work provides new findings for designing efficient bifunctional electrocatalysts utilizing TMD materials and conducting polymers.

Determining the ratio of the jet to the unbeamed luminosities for γ-ray blazars

ABSTRACT The spectacular observational phenomena lying in blazars can be well explained and described by the relativistic beaming effect that the emission in the jet is highly boosted along the line of sight to observers. Aiming to reveal the intrinsic emission core dominance in γ-ray loud blazars, we collect a large sample including 226 blazars with available superluminal motion data and radio core-dominance parameters at 5 GHz, and calculate a crucial parameter, R⊥, defined as the ratio of the luminosity in the jet to the unbeamed luminosity when the viewing angle comes up to 90°. R⊥ is a better parameter than the well-known core-dominance parameter, R, to reveal more intrinsic physical properties behind the prominent observational characteristics within blazars. We primarily ascertain the updated median value of R⊥ = 0.032 at 5 GHz, illustrating around 97 per cent of the total radio emission are dominated by the jets in γ-ray loud blazars. We also make further discussion on the physical difference in BL Lacertae objects and flat-spectrum radio quasars.

Functionalization of Fabrics with Graphene-Based Coatings: Mechanisms, Approaches, and Functions

Due to their unique surface-active functionalities, graphene and its derivatives, i.e., graphene oxide (GO) and reduced graphene oxide (rGO), have received enormous research attention in recent decades. One of the most intriguing research hot spots is the integration of GO and rGO coatings on textiles through dyeing methods, e.g., dip-pad-dry. In general, the GO sheets can quickly diffuse into the fabric matrix and deposit onto the surface of the fibers through hydrogen bonding. The GO sheets can be conformally coated on the fiber surface, forming strong adhesion as a result of the high flakiness ratio, mechanical strength, and deformability. Moreover, multiple functions with application significance, e.g., anti-bacteria, UV protection, conductivity, and wetting control, can be achieved on the GO and rGO-coated fabrics as a result of the intrinsic chemical, physical, electronic, and amphiphilic properties of GO and rGO. On the other hand, extrinsic functions, including self-cleaning, self-healing, directional water transport, and oil/water separation, can be achieved for the GO and rGO coatings by the integration of other functional materials. Therefore, multi-scale, multifunctional, smart fabrics with programmable functions and functional synergy can be achieved by the design and preparation of the hybrid GO and rGO coatings, while advanced applications, e.g., healthcare clothing, E-textiles, anti-fouling ultrafiltration membranes, can be realized. In this review, we aim to provide an in-depth overview of the existing methods for functionalizing fabrics with graphene-based coatings while the corresponding functional performance, underlying mechanisms and applications are highlighted and discussed, which may provide useful insights for the design and fabrication of functional textiles and fabrics for different applications.

Controlled Synthesis and Accurate Doping of Wafer-Scale Two-Dimensional Semiconducting Transition Metal Dichalcogenides.

Two-dimensional (2D) semiconducting transition metal dichalcogenide (TMDCs) possess atomically thin thickness, dangling-bond free surface, flexible band structure, and silicon-compatible feature, making them one of the most promising channels for constructing state-of-the-art field-effect transistors in the post-Moore's era. However, the existing 2D semiconducting TMDCs fall short of meeting the industry criteria for practical applications in electronics due to their small domain size and the lack of effective approach to modulate intrinsic physical properties. Therefore, it is crucial to prepare and doping of 2D semiconducting TMDCs single crystals with wafer size. In this review, wesystematically summary the up-to-date progresses regarding the wafer-scale growth of 2D semiconducting TMDCs polycrystalline and single-crystal films. The domain orientation control of 2D TMDCs and the seamless stitching of unidirectionally aligned 2D islands by means of substrate design are proposed. In addition, the accurate and uniform doping of 2D semiconducting TMDCs and the effect on electronic device performances are also discussed. Finally, the dominating challenges pertaining to enhance electronic device performances of TMDCs are emphasized, and the further development directions are put forward. This review provides a systematically and in-depth summary for high-performance device applications of 2D semiconducting TMDCs. This article is protected by copyright. All rights reserved.

Multiband Image Fusion via Regularization on a Riemannian Submanifold

Multiband image fusion aims to generate high spatial resolution hyperspectral images by combining hyperspectral, multispectral or panchromatic images. However, fusing multiband images remains a challenge due to the identifiability and tracking of the underlying subspace across varying modalities and resolutions. In this paper, an efficient multiband image fusion model is proposed to investigate the latent structures and intrinsic physical properties of a multiband image, which is characterized by the Riemannian submanifold regularization method, nonnegativity and sum-to-one constraints. An alternating minimization scheme is proposed to recover the latent structures of the subspace via the manifold alternating direction method of multipliers (MADMM). The subproblem with Riemannian submanifold regularization is tackled by the projected Riemannian trust-region method with guaranteed convergence. The effectiveness of the proposed method is demonstrated on two multiband image fusion problems: (1) hyperspectral and panchromatic image fusion and (2) hyperspectral, multispectral and panchromatic image fusion. The experimental results confirm that our method demonstrates superior fusion performance with respect to competitive state-of-the-art fusion methods.

Room-Temperature Solvent Evaporation Induced Crystallization: A General Strategy for Growth of Halide Perovskite Single Crystals by Applying the Le Chatelier's Principle.

The growth of high-quality halide perovskite single crystals is imperative to study their intrinsic physical properties and to realize high-performance optoelectronic devices. Here, a room-temperature solvent evaporation-induced crystallization (RTSEIC) method is reported based on Le Chatelier's principle, which provides a general strategy to grow halide perovskite single crystals including 3D, 2D, 1D, and 0D, and either hybrid or all-inorganic halide perovskites. Taking 2D n-BA2 PbBr4 (n-BA = butylammonium) as an example, the room-temperature crystallization kinetics is demonstrated. The centimeter-sized n-BA2 PbBr4 single crystals exhibit an extremely small full width at half maximum (FWHM) of 0.024° in (0 0 2) plane rocking curve and a small trap density of 2.74× 1010 cm-3 . The superior crystalline quality endows the n-BA2 PbBr4 single crystal ultraviolet photodetectors with recorded performance among reported n-BA2 PbBr4 ultraviolet photodetectors, demonstrating a detectivity reaching 1.8× 1013 Jones, a fast response time of 55 µs and a high on-off ratio of 104 . The low-cost, simple, general, and efficient RTSEIC method is anticipated to promote the blossoming of halide perovskites single crystals.

Bio-templated energy transfer system for constructing artificial light-harvesting antennae, white light generation, and photonic nanowires

Developing environmentally friendly, sustainable, and biocompatible artificial light-harvesting systems has become an essential area of research to understand natural light-harvesting processes involving multistep resonance energy transfer and building efficient energy conversion systems related to energy and optoelectronic applications. In this direction, bio-scaffolded artificial energy transfer systems for panchromatic light collection and sequential energy transfer have fascinated the scientific community. In this review, we have discussed what the dynamic structure and intrinsic physical properties of biomolecules like deoxyribonucleic acid, proteins, and peptides can provide for the development of new optical devices, sustainable and environmentally friendly white emitting materials, and cascaded energy transfer systems for energy harvesting from light. In doing so, we have highlighted some of the recent advances in bio-scaffolds as a platform for the assembly of different types of donor–acceptor chromophores involved in fluorescence energy transfer.

Recent progress and perspectives of metal organic frameworks (MOFs) for the detection of food contaminants

Over the past decades, increasing research in metal-organic frameworks (MOFs) being a large family of highly tunable porous materials with intrinsic physical properties, show propitious results for a wide range of applications in adsorption, separation, electrocatalysis, and electrochemical sensors. MOFs have received substantial attention in electrochemical sensors owing to their large surface area, active metal sites, high chemical and thermal stability, and tunable structure with adjustable pore diameters. Benefiting from the superior properties, MOFs and MOF-derived carbon materials act as promising electrode material for the detection of food contaminants. Although several reviews have been reported based on MOF and its nanocomposites for the detection of food contaminants using various analytical methods such as spectrometric, chromatographic, and capillary electrophoresis. But there no significant review has been devoted to MOF/and its derived carbon-based electrodes using electrochemical detection of food contaminants. Here we review and classify MOF-based electrodes over the period between 2017 and 2022, concerning synthetic procedures, electrode fabrication process, and the possible mechanism for detection of the food contaminants which include: heavy metals, antibiotics, mycotoxins, and pesticide residues. The merits and demerits of MOF as electrode material and the need for the fabrication of MOF and its composites/derivatives for the determination of food contaminants are discussed in detail. At last, the current opportunities, key challenges, and prospects in MOF for the development of smart sensing devices for future research in this field are envisioned.

The GLASS-JWST Early Release Science Program. III. Strong-lensing Model of Abell 2744 and Its Infalling Regions

Abstract We present a new high-precision, JWST-based, strong-lensing model for the galaxy cluster Abell 2744 at z = 0.3072. By combining the deep, high-resolution JWST imaging from the Grism Lens Amplified Survey from Space–JWST and Ultradeep NIRSpec and NIRCam Observations before the Epoch of Reionization programs and a Director’s Discretionary Time program, with newly obtained Very Large Telescope/Multi Unit Spectroscopic Explorer (MUSE) data, we identify 32 multiple images from 11 background sources lensed by two external subclusters at distances of ∼160″ from the main cluster. The new MUSE observations enable the first spectroscopic confirmation of a multiple-image system in the external clumps. Moreover, the reanalysis of the spectrophotometric archival and JWST data yields 27 additional multiple images in the main cluster. The new lens model is constrained by 149 multiple images (∼66% more than in our previous model) covering an extended redshift range between 1.03 and 9.76. The subhalo mass component of the cluster includes 177 member galaxies down to m F160W = 21, of which 163 are spectroscopically confirmed. Internal velocity dispersions are measured for 85 members. The new lens model is characterized by a remarkably low scatter between the predicted and observed positions of the multiple images (0.″43). This precision is unprecedented given the large multiple-image sample, the complexity of the cluster mass distribution, and the large modeled area. The improved precision and resolution of the cluster total mass distribution provides a robust magnification map over a ∼30 arcmin2 area, which is critical for inferring the intrinsic physical properties of the highly magnified, high-z sources. The lens model and the new MUSE redshift catalog are released with this publication.

Visible-light-driven AgI/Bi4O5I2 S-scheme heterojunction for efficient tetracycline hydrochloride removal: Mechanism and degradation pathway

The existence of excessive tetracycline hydrochloride (TCH) in the ecological environment has seriously threatened human health, so there is an urgent need to develop a high-performance photocatalyst that can efficiently and greenly remove TCH. Currently, most photocatalysts have the problems of fast recombination of photogenerated charge carriers and low degradation efficiency. Herein, S-scheme AgI/Bi4O5I2 (AB) heterojunctions was constructed for TCH removal. Compared with the single component, the apparent kinetic constant of the 0.7AB is 5.6 and 10.2 time as high as the AgI and Bi4O5I2, and the photocatalytic activity only decreases by 3.0% after four recycle runs. In addition, to verify the potential practical application of the fabricated AgI/Bi4O5I2 nanocomposite, the photocatalytic degradation of TCH was performed under different conditions by regulating the dosage of photocatalyst, the TCH concentration, pH, and the existence of various anions. Systematical characterizations are conducted to investigate the intrinsic physical and chemical properties of the constructed AgI/Bi4O5I2 composites. Based on the synergetic characterizations by in situ X-ray photoelectron spectroscopy, band edge measurements, as well as reactive oxygen species (ROS) detections, the S-scheme photocatalytic mechanism is proved. This work provides a valuable reference for developing efficient and stable S-scheme AgI/Bi4O5I2 photocatalyst for TCH removal.

The mechanism of pyroelectricity in polar material hemimorphite

It is known that a crystal structure and symmetry determine the physical properties of materials. Lattice distortion can strongly affect the symmetry of the crystal structure. Polar materials show changes in polarization with temporal fluctuations of temperature due to the asymmetry. As a polar crystal, hemimorphite shows excellent pyroelectric properties. However, to date, there are a few studies on its intrinsic physical properties, and the mechanism of its pyroelectricity remains unclear. In this paper, single-crystal x-ray diffraction measurement was carried out to obtain the atomic positions at 100–400 K. Furthermore, the electric dipole moments of [ZnO4] and [SiO4] polyhedrons along a, b, and c axes have been calculated. The calculated pyroelectric coefficient derived from the intrinsic electric dipole moment was compared with the experimental measurement. The results indicate that the pyroelectric coefficients of hemimorphite at different temperatures mainly come from the variation of the electric dipole moment of [ZnO4] and [SiO4] polyhedrons along the c axis. The electric dipole moment changes as a function of temperature from 100 to 400 K, which is induced by the random lattice distortion. It is found that pyroelectricity is strongly correlated with the random lattice distortion. The establishment of the relationship between lattice distortion and pyroelectricity helps us to regulate the specific electrical parameters of the material, which may lead to future work in energy harvesting and further properties.

Correlation of Ground Penetrating Radar Data with Geotechnical Prospect Profiles: Reduto Case Study, Belém-PA, Brazil

The study presented in this manuscript aimed to relate the sedimentary strata imaged by the ground penetrating radar (GPR) method through numerical modeling with the mapping of sedimentary strata acquired through geotechnical surveys. The study aimed to expose how obtaining subsoil information through noninvasive/destructive electromagnetic waves is beneficial, as they are reliable and less costly than drilling holes beyond what is necessary to have a subsurface mapping. In this sense, physical-geological modeling was carried out. The information on the type of sediments, acquired through simple recognition surveys carried out in the city of Belém-PA, helped to create a model of a sedimentary package with its respective intrinsic physical properties. The result shows that the GPR recovered with good vertical and horizontal resolution at the beginning and end of the layers of the sedimentary package studied, proving to be very effective for locating geotechnical sounding points and safely reducing costs.

Effects of hexagonal boron nitride encapsulation on the electronic properties of Cu, Li, and O-doped black phosphorus monolayer

In this work, the structural and electronic properties of Cu, Li, and O-doped phosphorene/hexagonal boron nitride systems were studied based on density functional theory calculations. The intrinsic physical properties of the pristine phosphorene layer do not change with the addition of hexagonal boron nitride layers. While doping of phosphorene leads to strong binding energy at the interface, hence, improving the stability of the doped phosphorene/hexagonal boron nitride layers in systems. The electronic properties of the encapsulated systems change after doping. The band gap also decreases from 1.1200 eV in pristine encapsulated phosphorene to 0.3087, 0.0076, and 0.3100 eV in encapsulated phosphorene doped with Li, Cu, and O, respectively. The partial density of states and band structure diagrams show that the electronic properties of these systems shift from semiconductor to metallic behavior which can be exploited in electronic and optical applications.