Enhancing the electrical conductivity of metals remains a critical challenge, as it directly determines the transmission efficiency of power electronic systems. Graphene-reinforced metal matrix composites have garnered widespread attention due to their exceptional electrical conductivity and low-temperature coefficient of resistance. This review thoroughly examines the intrinsic physical properties of Graphene and Cu, identifying specific obstacles in developing highly conductive composite materials. Despite the weak van der waals interactions between Graphene and Cu, the work principle and interaction mechanism between Cu and Graphene are elucidated. The primary focus of this review is to explore methods for enhancing the electrical conductivity of Cu/Graphene composites through different design strategies and processing techniques. The more complex and critical factors encompass the quality of raw materials, processing techniques, dimensional precision, crystallographic orientation, and the interfacial properties between Graphene and Cu. The perspectives on the research gap and further development trends of Cu/Gr composites are also discussed.
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