Laser powder bed fusion (LPBF) is a cutting-edge metal additive manufacturing technology with promising applications in aerospace, biomedicine, and industrial automation. Its ability to fabricate intricate geometric shapes, achieve high surface precision, and deliver comprehensive results renders it highly advantageous. In LPBF process, several factors such as the interference of laser processing fluctuations, rapid cooling rate, and environmental gas, contribute to the initiation and expansion of defects including pores and cracks, limiting the application of LPBF components. Laser ultrasonic testing (LUT) is a promising non-destructive evaluation method that can accurately detected defects in LPBF manufactured components by non-contact generation and detection. In this paper, a multi-physical field LUT model for the pores and cracks in LPBF additively manufactured Ti6Al4V alloy is proposed. The interaction of ultrasound with defects produces defect reflection echo wave, diffracted wave, and transmission wave. The transmission and diffraction phenomena occur in the longitudinal sound waves at defects. Furthermore, the echo wave reflected at crack exhibited enhanced prominence and an irregular shape. Clear differences were observed in the effects of laser ultrasonic detection on different defect types, pore depths and sizes. Finally, the LUT technology achieved the detection of 90 μm pore defects in LPBF manufactured Ti6Al4V alloy.