Using systematic sequences of the newly developed correlation consistent core-valence basis sets from cc-pCVDZ through cc-pCV6Z, the spectroscopic constants of the homonuclear diatomic molecules containing first row atoms, B–F, are calculated both with and without inclusion of 1s correlation. Internally contracted multireference configuration interaction (IC-MRCI) and singles and doubles coupled cluster (CCSD) theory with a perturbational estimate of connected triple excitations, CCSD(T), have been investigated. By exploiting the convergence of the correlation consistent basis sets, complete basis set (CBS) limits have been estimated for total energies, dissociation energies, equilibrium geometries, and harmonic frequencies. Based on the estimated CBS limits the effects of 1s correlation on D e (kcal/mol), r e (A), and ω e (cm−1) are: +1.1, −0.0070, +10 for B2; +1.5, −0.0040, +13 for C2; +0.9, −0.0020, +9 for N2; +0.3, −0.0020, +6 for O2; and −0.1, −0.0015, +1 for F2.