Global warming and urban heat island effects negatively impact the development of urban thermal environments, making them very uncomfortable to live in. Green space plays an essential role in controlling and improving air pollution, regulating the microclimate, and enforcing compliance with public health requirements. Therefore, this study explored the relationship between green space and thermal comfort in the historical neighborhood of Dazhalan in Beijing through questionnaires, observational interviews, and numerical simulations. The current situation of the microclimate environment in the green space of the block was observed first. Then, the microclimate environment was simulated by the ENVI-met 5.6 software. The thermal comfort of the three types of space, such as enclosed space, strip space, and corner space, was also evaluated to explore the coupling relationship between different green space elements and microclimate evaluation factors. It was found that the thermal comfort PET had a positive correlation with the sky openness SVF. The green space morphology was quantitatively measured, and it was found that the thermal comfort PET had a negative correlation with the three-dimensional green quantity of green space. The paper developed managing strategies for optimizing the layout and construction mode of the green space. The ultimate goal was to rationally match the greening planting, improve the pavement of the underlying surface of the block, and optimize the design of the internal space topography.