Nano-clay has the potential to improve the properties of cement-based materials. However, the effectiveness of this improvement is influenced by the dispersion of the nano-clay. The effects of different nano-clay dispersion techniques on cement-based material properties and pore structure complexity were studied. The samples were prepared using manual and mechanical dispersion methods. The mechanical properties of the specimens were evaluated, and the pore characteristics of the cement-based materials were analysed using mercury intrusion porosimetry. The study investigated the effect of the dispersion method on the nano-clay dispersion. The complexity of the pore structure was evaluated using a fractal model, and the relationship between the fractal dimension, mechanical properties, and pore structure was analysed. The findings indicate that mechanical dispersion results in better dispersion than manual dispersion, and the mechanical properties of mechanical dispersion are superior to those of manual dispersion. Nano-clay particles can improve the internal pore structure of cement materials. Through mathematical calculation, the surface fractal dimension is between 2.90 and 2.95, with good fractal characteristics. There is a good correlation between the surface fractal dimension and the mechanical properties. The addition of nano-clay can reduce the complexity of the pore structure, and the fractal dimension has an excellent linear relationship with the pore structure.