Internal Olefin Sulfonate Research Articles

Favorable Attributes of Alkaline-Surfactant-Polymer Flooding

Summary A laboratory study of the alkaline-surfactant-polymer (ASP) process was conducted. It was found from phase-behavior studies that for a given synthetic surfactant and crude oil containing naph-thenic acids, optimal salinity depends only on the ratio of the moles of soap formed from the acids to the moles of synthetic surfactant present. Adsorption of anionic surfactants on carbonate surfaces is reduced substantially by sodium carbonate, but not by sodium hydroxide. The magnitude of the reduction with sodium carbonate decreases with increasing salinity. Particular attention was given to a surfactant blend of a pro-poxylated sulfate having a slightly branched C16–17 hydrocarbon chain and an internal olefin sulfonate. In contrast to alkyl/aryl sulfonates previously considered for EOR, alkaline solutions of this blend containing neither alcohol nor oil were single-phase micellar solutions at all salinities up to approximately optimal salinity with representative oils. Phase behavior with a west Texas crude oil at ambient temperature in the absence of alcohol was unusual in that colloidal material, perhaps another microemulsion having a higher soap content, was dispersed in the lower-phase microemulsion. Low interfacial tensions existed with the excess oil phase only when this material was present in sufficient amount in the spinning-drop device. Some birefringence was observed near and above optimal conditions. While this phase behavior is somewhat different from the conventional Winsor phase sequence, overall solubilization of oil and brine for this system was high, leading to low interfacial tensions over a wide salinity range and to excellent oil recovery in both dolomite and silica sandpacks. The sandpack experiments were performed with surfactant concentrations as low as 0.2 wt% and at a salinity well below optimal for the injected surfactant. It was necessary that sufficient polymer be present to provide adequate mobility control, and that salinity be below the value at which phase separation occurred in the polymer/surfactant solution. A 1D simulator was developed to model the process. By calculating transport of soap formed from the crude oil and injected surfactant separately, it showed that injection below optimal salinity was successful because a gradient in local soap-to-surfactant ratio developed during the process. This gradient increases robustness of the process in a manner similar to that of a salinity gradient in a conventional surfactant process. Predictions of the simulator were in excellent agreement with the sandpack results.

AOS — An anionic surfactant system: Its manufacture, composition, properties, and potential application

AbstractSeveral sulfonation parameters, believed to be critical to the manufacture of good quality a‐olefin sulfonate (AOS), are related to product color and conversion. The interfacial properties for single carbon number AOS and the major components comprising AOS are investigated. Results, based on surface activity, indicate that AOS in the molecular weight range from C14 through C18 should be of value in formulating efficient cleaning agents. The data show that AOS is more effective for lowering Crisco®/solution interfacial energy than the more commonly used surfactants. The alkene‐1‐sulfonate component of AOS was found to be most effective in lowering interfacial energy with the hydroxyalkane‐1‐sulfonate component being significantly less effective but still more effective than alcohol ether sulfate or linear alkylbenzene sulfonate of comparable molecular weight. Hand dishwashing efficacy was found greatest for the hydroxyalkane‐1‐sulfonate component of AOS, but combinations of hydroxyalkane‐1‐sulfonates and alkene‐1‐sulfonates were shown to be synergistic for laundering applications. The presence of the ‐OH group in the hydroxyalkane sulfonate structure was shown to increase solubility and lower surface activity significantly more than the presence of unsaturation in the alkene sulfonate. Long, single branching in the a‐olefin sulfonate and random internal olefin sulfonate are shown to reduce drastically the surface activity. The hydroxyalkane and alkene‐1‐sulfonates were rapidly biodegraded. Disulfonates and long, singly branched sulfonate were more slowly degraded. Both 1,3‐sultones and 1,4‐sultones were found to biodegrade rapidly.