Internal Ice Research Articles

Study on ice-melting performance of gradient gas diffusion layer in proton exchange membrane fuel cell

In this study, a three-dimensional model was established using the lattice Boltzmann method (LBM) to study the internal ice melting process of the gas diffusion layer (GDL) of the proton exchange membrane fuel cell (PEMFC). The single-point second-order curved boundary condition was adopted. The effects of GDL carbon fiber number, growth slope of the number of carbon fibers and carbon fiber diameter on ice melting were studied. The results were revealed that the temperature in the middle and lower part of the gradient distribution GDL is significantly higher than that of the no-gradient GDL. With the increase of the growth slope of the number of carbon fiber, the temperature and melting rate gradually increase, and the position of the solid-liquid interface gradually decreases. The decrease in the number of carbon fibers has a similar effect as the increase in the growth slope of the number of carbon fibers. In addition, as the diameter of the carbon fiber increases, the position of the solid-liquid interface gradually decreases first and then increases.

DNA damage and repair responses to freezing and anoxia stresses in wood frogs, Rana sylvatica

Wood frogs, Rana sylvatica, endure the freezing of ∼65% of total body water while overwintering in cold climates, enduring not only internal ice formation but also long-term anoxia due to cessation of heartbeat and breathing. Thawing restores perfusion but rapid reoxygenation can increase vulnerability to reactive oxygen species and induce oxidative damage. This study provides a first assessment of antioxidant capacity, DNA damage, and DNA repair responses comparing freeze/thaw and anoxia/reoxygenation in liver and skeletal muscle of wood frogs. Oxidation of guanine resides in DNA did not change under either stress but total antioxidant capacity rose in both tissues under anoxia. Relative expression of eight proteins involved in double-stranded break repair (Mre11, Rad50, phospho-p95, XLF, DNA ligase IV, XRCC4, Ku70, Rad51) were assessed in both tissues. Freezing suppressed Ku70 and Rad51 in liver and Rad51 in muscle but levels rose again after thawing. Anoxia exposure suppressed XLF, Ku70 and Rad51 proteins in muscle. However, in liver, anoxia exposure led to elevated Mre11, Ku70 and DNA ligase IV, the former two belonging to the MRN complex that binds DNA and marks sites of double stranded breaks (DSBs). Large increases in Mre11 and Ku70 expression suggested DSB damage in liver under anoxia but not during freezing, whereas muscle was resistant to DSB damage under both stresses. These data indicate that DNA damage is minimal during whole body freezing due to tissue and stress specific regulation of antioxidant capacity and DNA damage repair to preserve genomic integrity.

Towards accurate quantification of ice content in permafrost of the Central Andes – Part 1: Geophysics-based estimates from three different regions

Abstract. Increasing water scarcity in the Central Andes due to ongoing climate change recently caused a controversy and debate on the significance of permafrost occurrences for the hydrologic cycle. The lack of comprehensive field measurements and quantitative data on the local variability in internal structure and ground ice content further exacerbates the situation. We present field-based data from six extensive geophysical campaigns undertaken since 2016 in three different high-altitude regions of the Central Andes of Chile and Argentina (28 to 32∘ S). Our data cover various permafrost landforms ranging from ice-poor bedrock to ice-rich rock glaciers and are complemented by ground truthing information from boreholes and numerous test pits near the geophysical profiles. In addition to determining the thickness of the potential ice-rich layers from the individual profiles, we also use a quantitative four-phase model to estimate the volumetric ground ice content in representative zones of the geophysical profiles. Our analysis of 52 geoelectrical and 24 refraction seismic profiles within this study confirmed that ice-rich permafrost is not restricted to rock glaciers but is also observed in non-rock-glacier permafrost slopes in the form of interstitial ice, as well as layers with excess ice, resulting in substantial ice contents. Consequently, non-rock-glacier permafrost landforms, whose role for local hydrology has so far not been considered in remote-sensing-based approaches, may be similarly relevant in terms of ground ice content on a catchment scale and should not be ignored when quantifying the potential hydrological significance of permafrost. We show that field-geophysics-based estimates of ground ice content, while more labour intensive, are considerably more accurate than remote sensing approaches. The geophysical data can then be further used in upscaling studies to the catchment scale in order to reliably estimate the hydrological significance of permafrost within a catchment.

Mechanism of shear strength deterioration of soil-rock mixture after freeze–thaw cycles

The growth and melting of internal ice crystals reorganizing the pore structure and internal skeleton of soil-rock mixture (S-RM), which leads to the deterioration of the S-RM shear strength after freeze–thaw cycles and its strength characteristics after the cycles are different from the normal temperature one. Due to unclear S-RM strength deterioration mechanism after freeze–thaw cycles, stability of S-RM cutting slopes in cold regions cannot be effectively evaluated. In this paper, particle flow code (PFC) simulation as well as direct shear and nuclear magnetic resonance (NMR) tests were carried to study strength degradation behaviors and pore structure changes of S-RMs containing various amounts of rock after freeze–thaw cycles. The results show that the shear strength and internal friction angle of S-RM are no longer positively correlated with the rock content after the cycles, and the strength parameters will decrease at rock contents of above 45%. Based on the simulation test, shear band thickness variation after the cycles was quantitatively evaluated, and an innovative method to obtain the fluctuation value of shear failure surface was proposed. It is found that the change laws of shear band thickness and failure surface fluctuation value with rock content after the cycles are consistent with that of shear strength, and they all reach the maximum value when the rock content is 45%. Fractal theory was introduced for quantitative evaluation of changes in S-RM pore structure after the cycles, and combined with the strength parameter attenuation, the strength deterioration mechanism of S-RM was revealed: The deterioration of shear strength in samples containing low rock content is mainly due to changes in the contact form between particles caused by internal inclusion structure formation after the cycles. The deterioration of S-RM with rock content of 55% and 65% is mainly due to attenuation of the internal skeleton effect caused by the appearance of overhead structures. The internal pores and skeleton structure of the sample with 45% rock content have little change, so the attenuation changes of the strength parameters and the undulation value of the failure surface are minimal.

Contrasting geophysical signatures of a relict and an intact Andean rock glacier

Abstract. In semi-arid Chile, rock glaciers cover more surface area than glaciers and are potentially important water reserves. To understand their current and future hydrological role, it is necessary to characterize their internal structure (e.g. internal boundaries and ice, air, water and rock content). In this study, we present the results and interpretations of profiles of electrical resistivity and refraction seismic tomography collected on two contrasting rock glaciers in the Chilean Andes located at the headwaters of the Elqui River within the Estero Derecho nature reserve. These geophysical measurements are interpreted both independently and jointly through a scheme of petrophysical four-phase inversion. These first in situ measurements in Estero Derecho confirm that El Ternero (intact rock glacier) contains a significant volume of ground ice, while El Jote contains little to no ice (relict rock glacier). Within our study, we highlight the strong differences in the geophysical responses between intact and relict rock glaciers and propose a diagnostic model that differentiates between them.

Decadal Observations of Internal Wave Energy, Shear, and Mixing in the Western Arctic Ocean

AbstractAs Arctic sea ice declines, wind energy has increasing access to the upper ocean, with potential consequences for ocean mixing, stratification, and turbulent heat fluxes. Here, we investigate the relationships between internal wave energy, turbulent dissipation, and ice concentration and draft using mooring data collected in the Beaufort Sea during 2003–2018. We focus on the 50–300 m depth range, using velocity and CTD records to estimate near‐inertial shear and energy, a finescale parameterization to infer turbulent dissipation rates, and ice draft observations to characterize the ice cover. All quantities varied widely on monthly and interannual timescales. Seasonally, near‐inertial energy increased when ice concentration and ice draft were low, but shear and dissipation did not. We show that this apparent contradiction occurred due to the vertical scales of internal wave energy, with open water associated with larger vertical scales. These larger vertical scale motions are associated with less shear, and tend to result in less dissipation. This relationship led to a seasonality in the correlation between shear and energy. This correlation was largest in the spring beneath full ice cover and smallest in the summer and fall when the ice had deteriorated. When considering interannually averaged properties, the year‐to‐year variability and the short ice‐free season currently obscure any potential trend. Implications for the future seasonal and interannual evolution of the Arctic Ocean and sea ice cover are discussed.

Parameterization of Submesoscale Mixed Layer Restratification under Sea Ice

Abstract Commonly used parameterization of mixed layer instabilities in general circulation models was developed for temperate oceans and does not take into account the presence of sea ice in any way. However, the ice–ocean drag provides a strong mechanical coupling between the sea ice and the surface ocean currents and hence may affect mixed layer restratification processes. Here we use idealized simulations of mixed layer instabilities to demonstrate that the sea ice dramatically suppresses the eddy-driven overturning in the mixed layer by dissipating the eddy kinetic energy generated during instabilities. Considering the commonly used viscous-plastic sea ice rheology, we developed an improvement to the existing mixed layer overturning parameterization, making it explicitly dependent on sea ice concentration. Below the critical sea ice concentration of about 0.68, the internal sea ice stresses are very weak and the conventional parameterization holds. At higher concentrations, the sea ice cover starts acting as a nearly immobile surface lid, inducing strong dissipation of submesoscale eddies and reducing the intensity of the restratification streamfunction up to a factor of 4 for a fully ice-covered ocean. Our findings suggest that climate projection models might be exaggerating the restratification processes under sea ice, which could contribute to biases in mixed layer depth, salinity, ice–ocean heat fluxes, and sea ice cover.

Supercooling points of freeze-avoiding bumble bees vary with caste and queen life stage

Bumble bees thrive in cold climates including high latitude and high altitude regions around the world, yet cold tolerance strategies are largely unknown for most species. To determine bumble bee cold tolerance strategy, we exposed bumble bees to a range of low temperatures and measured survival 72 h post-exposure. All bees that froze died within 72 h while only one bee died without freezing, suggesting that bumble bees are generally freeze-avoiding insects and may be slightly chill susceptible. We then assessed whether temperatures that cause internal ice formation (supercooling points, SCP) varied among bumble bee castes (drones, workers, and queens), or across queen life stages, collection elevation, species, or season. Males froze at significantly lower temperatures than workers or queens. Queens in pre-overwintering or overwintering states froze at significantly lower temperatures than queens stimulated to initiate ovary development by CO2 narcosis (i.e., “spring” queens). We also tested whether the presence of water (i.e., wet or dry) or ramping rate affected SCP. As expected, queens inoculated with water froze at significantly higher temperatures than dry queens. SCP tended to be lower, but not significantly so, at faster ramping rates (0.5 °C/min vs 0.25 °C/min). We also found no differences in SCP between queen bumble bees collected in spring and fall, between queens collected at two sites differing in elevation by 1100 m, or between three field-caught bumble bee species. Bumble bees appear to have relatively high, invariable SCPs, likely making them highly susceptible to freezing across all seasons. As bumble bees are not freeze-tolerant and appear to lack the ability to prevent freezing at temperatures much below 0 °C, they may rely on season- and caste-specific micro-habitat selection to thrive in cold climates.

EisNet: Extracting Bedrock and Internal Layers From Radiostratigraphy of Ice Sheets With Machine Learning

The ice–bedrock interfaces at the bottoms of ice sheets and the internal ice layers record the historical evolution of the ice sheets and are important indicators for inferring glacier dynamics and explaining subglacial topographies. Radar-detected bedrock and internal ice layers can be used to observe conditions in the interiors and bottoms of ice sheets. The low contrast of the internal layers’ feature in radar images, as well as the effects of ice flow, makes it challenging to automatically extract and trace the layers and interfaces of ice sheets. Manual or semiautomatic methods are extensively applied in bedrock and internal ice layers’ extractions. However, the conventional methods require large amounts of time. Especially when processing a large number of radar observation data, the accuracy and efficiency of conventional methods are untoward. Therefore, we propose EisNet, a fusion system consisting of deep neural networks, to extract the multiple types of internal layers. Because of the rareness of high-precision extraction of ice layers, it is virtually impossible to train EisNet in observational data with the corresponded label of ice layers. To train EisNet, we design a novel synthetic method for radar images based on artifact noise and characteristic textures that are similar to those in the observation data. The validation in synthetic data proves EisNet’s capacity for layer extraction and noise removal. The field data application shows the generalization and adaptation abilities of EisNet and indicates that EisNet can significantly improve the efficiency of the automatic processing of ice sheet radiostratigraphy.

Investigating the Intra-Annual Dynamics of Kunlun Glacier in the West Kunlun Mountains, China, From Ascending and Descending Sentinel-1 SAR Observations

Monitoring glacier dynamics is an effective approach for quantifying the response of the glaciers in cold arid mountainous areas to climate change. However, the quantification of short-term flow dynamics of the mountain glaciers in cold-dry climates has rarely been reported. This article investigated the intra-annual flow dynamics in terms of velocity and ice thickness changes on the Kunlun glacier, a mountain glacier in the cold-dry west Kunlun mountains, using spaceborne synthetic aperture radar (SAR) imagery. We applied the improved pixel-offset-tracking small-baseline-subset method (PO-SBAS) on ascending and descending Sentinel-1A SAR images acquired in 2017 and 2018 to estimate the three-dimensional (i.e., north–south, west–east, and vertical) velocity time series of the glacier. The vertical velocities were further decomposed into the surface-parallel-flow (SPF) and the nonsurface-parallel-flow (nSPF) components, which link glacier motion along glacier surface slope and internal ice deformation, respectively, to glacier thickness changes. Our findings show that the eastern branch of the glacier moved faster than the western branch. We inferred that a loss of ice thickness due to a previous surge on the western branch should be responsible for its slower flow. The nSPF rates are higher than the SPF rates in both branches, indicating that internal ice deformation primarily controls the changes in ice thickness. We also observed an apparent summer acceleration in the nSPF rates, which is likely caused by changes in subglacial hydrological conditions. This article highlights the potential uses of the improved PO-SBAS method of quantifying the flow dynamics of the glaciers in cold-dry mountain regions.

Greenland Ice Sheet Subsurface Temperature Estimation Using Ultrawideband Microwave Radiometry

Ice sheet subsurface temperature is important for understanding glacier dynamics, yet existing methods to obtain the temperature of the ice sheet column are limited to <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">in situ</i> sources at present. The ultrawideband software-defined microwave radiometer (UWBRAD) has been developed to investigate the remote sensing of ice sheet internal temperatures. UWBRAD measures brightness temperature spectra from 0.5 to 2 GHz using 12 subchannels and employs a sophisticated algorithm for detection and mitigation of radio frequency interference (RFI). The instrument was deployed during a flight over northwestern Greenland in September 2017 and acquired the first wideband low-frequency brightness temperature spectra over the ice sheet and coastal regions. The results reveal strong spatial and spectral variations that correlate well with internal ice sheet temperature information. In this article, the section of the flight path ranging from the Camp Century to NEEM to NGRIP boreholes is used for subsurface temperature estimation. A “partially coherent” forward model is applied along with a Robin model for the temperature profile and a two-scale model of ice sheet density variations to describe measured brightness temperatures. Using this model, vertical temperature profiles are retrieved along the flight path using a sequential Bayesian estimator; borehole measurements at the three campsites are used to obtain Bayesian priors. The retrieved temperature profiles show reasonable behaviors and demonstrate the potential of ultrawideband microwave radiometry for remotely sensing internal ice sheet temperatures.

Plasticity drives extreme cold tolerance of emerald ash borer (Agrilus planipennis) during a polar vortex

Invasive species must often survive combinations of environmental conditions that differ considerably from their native range; however, for a given species it is unclear whether improved tolerance is the result of phenotypic plasticity or genetic adaptation (or both). Agrilus planipennis (Coleoptera: Buprestidae; the emerald ash borer) is an invasive pest of Fraxinus trees in North America and Europe. Previous studies in SW Ontario, Canada, showed that A. planipennis is freeze avoidant, preventing internal ice formation by accumulating Molar concentrations of glycerol in its hemolymph and depressing its supercooling point (SCP, the temperature at which it freezes). The cold tolerance of these SW Ontario animals was used to predict potential distribution, revealing that some Canadian cities should be too cold to allow populations to persist. However, a small population of A. planipennis has persisted in Winnipeg, Manitoba, Canada, through several severe 'polar vortex' events. In 2018/19, we collected A. planipennis larvae and prepupae from Winnipeg, MB and Southern Ontario, and found that individuals from Winnipeg were extremely cold tolerant - with SCPs as low as -52°C in prepupae (compared to -32°C in SW Ontario), and observed survival of unfrozen individuals exposed to -50°C for one hour. This cold tolerance was accompanied by higher hemolymph osmolality and glycerol concentration than in the SW Ontario individuals. To distinguish between phenotypic plasticity and local adaptation, in 2020/21 we overwintered Winnipeg-sourced individuals either outdoors in SW Ontario or in a simulated Winnipeg winter. Simulated Winnipeg winter individuals had cold tolerance similar to those overwintered in Winnipeg, while SW Ontario overwintered individuals had cold tolerance similar to those collected previously in the region. The simulated winter individuals had higher hemolymph glycerol concentrations than SW Ontario overwintered animals, at least in part due to greater dehydration. Thus, A. planipennis are cold-tolerant enough to survive some of the harshest winters where their host trees can grow, and most likely attain this cold tolerance via phenotypic plasticity. These findings raise the importance of delineating sensitivity of conclusions to unexpected phenotypic plasticity when predicting potential distributions of new invasives or responses to climate change.

Internal Ocean Dynamics Control the Long-Term Evolution of Weddell Sea Polynya Activity

Open-ocean polynyas effectively couple the ocean and atmosphere through large ice-free areas within the sea-ice cover, release vast quantities of oceanic heat, and impact deep ocean ventilation. Changes in polynya activity, particularly in the Weddell Sea, may be key to longer time-scale climate fluctuations, feedbacks and abrupt change. While changes in the occurrence of Weddell Sea polynyas are generally attributed to changes in the atmospheric surface forcing, the role of internal ocean dynamics for polynya variability is not well-resolved. In this study we employ a global coupled ocean-sea ice model with a repeating annual atmospheric cycle to explore changes in Weddell Sea water mass properties, stratification and ocean circulation driven by open-ocean polynyas. During the 1300-year long simulation, two large polynyas occur in the central Weddell Sea. Our results suggest that Weddell polynyas may be triggered without inter-annual changes in the atmospheric forcing. This highlights the role of ocean processes in preconditioning and triggering open-ocean polynyas on multi-centennial time-scales. The simulated polynyas form due to internal ocean-sea ice dynamics associated with a slow build-up and subsequent release of subsurface heat. A strong stratification and weak vertical mixing is necessary for building the subsurface heat reservoir. Once the water column turns unstable, enhanced vertical mixing of warm and saline waters into the surface layer causes efficient sea ice melt and the polynya appears. Subsequent, vigorous deep convection is maintained through upwelling of warm deep water leading to enhanced bottom water formation. We find a cessation of simulated deep convection and polynya activity due to long-term cooling and freshening of the subsurface heat reservoir. As subsurface waters in the Southern Ocean are now becoming warmer and saltier, we speculate that larger and more persistent Weddell polynyas could become more frequent in the future.

Reversible glacial-periglacial transition in response to climate changes and paraglacial dynamics: A case study from Héðinsdalsjökull (northern Iceland)

The objective of this work is to chronologically establish the origin of the different glacial and rock glacier complex landforms deposited by Héðinsdalsjökull glacier (65°39′ N, 18°55′ W), in the Héðinsdalur valley (Skagafjörður fjord, Tröllaskagi peninsula, central northern Iceland). Multiple methods were applied: geomorphological analysis and mapping, glacier reconstruction and equilibrium-line altitude calculation, Cosmic-Ray Exposure dating (in situ cosmogenic 36Cl), and lichenometric dating. The results reveal that a debris-free glacier receded around 6.6 ± 0.6 ka, during the Holocene Thermal Maximum. The retreat of the glacier exposed its headwall and accelerated paraglacial dynamics. As a result, the glacier terminus evolved into a debris-covered glacier and a rock glacier at a slightly higher elevation. The front of this rock glacier stabilized shortly after it formed, although nuclide inheritance is possible, but its sector close the valley head stabilized between 1.5 and 0.6 ka. The lowest part of the debris-covered glacier (between 600 and 820 m altitude) collapsed at ca. 2.4 ka. Since then, periods of glacial advance and retreat have alternated, particularly during the Little Ice Age. The maximum advance during this phase occurred in the 15th to 17th centuries with subsequent re-advances, namely at the beginning of the 19th and 20th centuries. After a significant retreat during the first decades of the 20th century, the glacier advanced in the 1960s to 1990s, and then retreated again, in accordance with the local climatic evolution. The internal ice of both the debris-covered and the rock glacier have survived until the present day, although enhanced subsidence provides evidence of their gradual degradation. A new rock glacier developed from an ice-cored moraine from around 1940–1950 CE. Thus, the Holocene coupling between paraglacial and climatic shifts has resulted in a complex evolution of Héðinsdalsjökull, which is conflicting with previously proposed models: a glacier, which had first evolved into a debris-covered and rock glacier, could later be transformed into a debris-free glacier, with a higher sensitivity to climatic variability.

Maximum extent and readvance dynamics of the Irish Sea Ice Stream and Irish Sea Glacier since the Last Glacial Maximum

ABSTRACTThe BRITICE‐CHRONO Project has generated a suite of recently published radiocarbon ages from deglacial sequences offshore in the Celtic and Irish seas and terrestrial cosmogenic nuclide and optically stimulated luminescence ages from adjacent onshore sites. All published data are integrated here with new geochronological data from Wales in a revised Bayesian analysis that enables reconstruction of ice retreat dynamics across the basin. Patterns and changes in the pace of deglaciation are conditioned more by topographic constraints and internal ice dynamics than by external controls. The data indicate a major but rapid and very short‐lived extensive thin ice advance of the Irish Sea Ice Stream (ISIS) more than 300 km south of St George's Channel to a marine calving margin at the shelf break at 25.5 ka; this may have been preceded by extensive ice accumulation plugging the constriction of St George's Channel. The release event between 25 and 26 ka is interpreted to have stimulated fast ice streaming and diverted ice to the west in the northern Irish Sea into the main axis of the marine ISIS away from terrestrial ice terminating in the English Midlands, a process initiating ice stagnation and the formation of an extensive dead ice landscape in the Midlands.

Deriving Melt Rates at a Complex Ice Shelf Base Using In Situ Radar: Application to Totten Ice Shelf

AbstractA phase‐sensitive radar (ApRES) was deployed on Totten Ice Shelf to provide the first in situ basal melt estimate at this dynamic East Antarctic ice shelf. Observations of internal ice dynamics at tidal time scales showed that early arrivals from off‐nadir reflectors obscure the true depth of the ice shelf base. Using the observed tidal deformation, the true base was found to lie at 1,910–1,950‐m depth, at 350–400 m greater range than the first reflection from an ice‐ocean interface. The robustness of the basal melt rate estimate was increased by using multiple basal reflections over the radar footprint, yielding a melt rate of 22 ± 2.1 m a−1. The ApRES estimate is over 40% lower than the three existing satellite estimates covering Totten Ice Shelf. This difference in basal melt is dynamically significant and highlights the need for independent melt rate estimates using complementary instrumentation and techniques that rely on different sets of assumptions.

Coupled climate-ice sheet modelling of MIS-13 reveals a sensitive Cordilleran Ice Sheet

Previous modelling efforts have investigated climate responses to different Milankovitch forcing during Marine Isotope Stage (MIS) 13. During this time the climate has been highly variable at atmospheric CO2 concentrations of ~240 ppm. As yet, ice sheet-climate feedbacks were missing in previous studies. Therefore we use the state-of-the-art coupled climate-ice sheet model, AWI-ESM-1.2, to investigate the MIS-13 climate and corresponding Northern Hemisphere ice sheet (NHIS) evolution by performing simulations under three different astronomical configurations representing 495, 506 and 517 kyr BP. The simulated excess ice compared to present-day is mainly over the Cordillera, Arctic islands and Tibet. The global mean surface air temperature for the MIS-13 experiments have the same magnitude. At 506 kyr BP with boreal summer at perihelion, the Northern Hemisphere continents are warmer during summer than the other experiments, which could potentially inhibit the development of the ice sheets. The Cordilleran Ice Sheet is found to be especially sensitive to orbital (precession) forcing, at an intermediate CO2 level. This is probably due to its high elevation where the freezing point could be easily maintained. The other ice sheets over northeast America and Eurasia, however, are absent in our simulations. We propose that the alpine-based Cordilleran Ice Sheet is more sensitive and easier to build up than other NHISs in response to the astronomical controlled summer insolation. Dynamic surges are simulated for the Cordilleran Ice Sheet under fixed low orbital forcing. These surges due to internal ice sheet-climate feedbacks could potentially be the mechanism for the millennial scale H-like events.

Preliminary Analysis of a New Power Train Concept for a City Hybrid Vehicle

This research aims to test the feasibility of a prototype of a newly designed thermal engine for a hybrid propulsion vehicle. This study consists of the implementation of an innovative supercharger for city car internal combustion engine ICE (900 cc). The preliminary proposal presented here is to mechanically disconnect the compressor/turbine device, supporting the rotation of the compressor with a dedicated electric motor and connecting a turbine to a generator. Mechanical decoupling will allow both machines to be designed for operating closer to their maximum performance point, for most of the expected real field of operation. Specifically, the turbine is likely to have a lower rotation speed than the original group and will, therefore, be slightly larger. The advantage is that, while in the current supercharger groups the surplus at high regimes is discharged through the waste-gate valve without expanding in a turbine, in the configuration proposed, all the energy of the combustible gases is used by the turbine to generate electrical power that can be used where required. Once the motorization of the vehicle (999 cc) has been fixed, the two turbomachines will have to be studied and designed, looking where possible, for commercial components. Finally, a computational fluid dynamic CFD will be needed to verify the validity of the choice, followed by careful experimentation campaigns.

Impact of borate on structure of antifreeze glycoproteins

Antifreeze glycoproteins (AFGPs) facilitate the survival of various organisms in the polar region by preventing internal ice accumulation via an adsorption-inhibition mechanism. Inhibition of AFGP antifreeze activity by the borate buffers has been widely acknowledged as the direct experimental evidence supporting the hydroxyl, rather than methyl, binding mechanism. On the other hand, perturbation of borate binding on the AFGP configuration, which might have considerable influence on the binding efficiency of not only the hydroxyl but also the methyl groups, has rarely been quantitatively examined. Herein we studied, using molecular dynamics simulations, the perturbation on the configuration of a solvated AFGP8 protein induced by the binding of one single borate anion. Near the freezing point, this binding not only makes the disaccharide groups adjacent to the borate-binding disaccharide close to each other but also affects the entire AFGP8 conformation. The structural changes induced by the binding of borate on different disaccharide sidechains exhibit clear site-specificities and the effect of borate binding on the structural changes is significantly reduced at higher temperatures. Our study is valuable for further understanding the relationship between the structure and antifreeze activity of these antifreeze glycoproteins.

Rock glaciers in mixed lithologies: a case study from Northern Pirin

Rock glaciers are lobate or tongue-shaped assemblages of poorly sorted, angular-rock debris and ice, commonly found in high mountain environments, which move as a consequence of the deformation of internal ice (Giardino and Vitek, 1988; Barsch, 1996). However, in most research works, when discussing the formation of these features, the focus has been mainly on the past or present climatic conditions. The systematic observations of the distribution of relict rock glaciers in the mountains of the Balkan Peninsula indicate however that geological setting, represented by bedrock type and composition, and the pattern of fault lines, is not less important for the formation and evolution of these landforms. The present article is focused on rock glaciers in the high mountain zone of the Pirin Mounains (Bulgaria), which are formed in mixed lithology, with participation of both silicate rocks (granite, gneiss) and carbonate rocks (marble). In fact, these rock glaciers are the only ones of a typical morphology that exist in the glaciokarstic marble area of Northern Pirin. What is common for all locations where such rock glaciers are found is that the marble layer, which is on top, is quite thin (few metres to few hundreds of metres). In such conditions, the rock glacier formation occurred following the mechanism typical for silicate rocks, but using marble debris and block material instead. The observed forms are characteristic only for marginal zones, along the contact line between silicate and carbonate high mountain environments.