Intermediate Components Research Articles

Effects of fluorine and phosphorus-based flame retardants addition on the lower flammability limit of dimethyl carbonate

This study initially examines the alteration pattern of the lower flammable limit (LFL) of dimethyl carbonate (DMC), a typical electrolyte component in lithium batteries, under the influence of inhibitors, namely di(2,2,2trifluoroethyl) carbonate (DtFEC), perfluorohexanone (C6F12O), and trimethylphosphate (TMP), through experimental investigation. Additionally, the critical inhibitory concentration required for complete inhibition is investigated. Subsequently, numerical simulations and chemical kinetic path analyses reveal how these inhibitors control combustion. Results show that C6F12O and DtFEC initially decrease and then increase the LFL of DMC, while TMP causes a monotonic increase. This is due to the competition between reaction-thermal and reaction-radical effects. Reaction kinetic analysis reveal that when small amounts of C6F12O and DtFEC are added, the fluorine-containing components decomposed by the reaction undergo oxidation, thereby promoting combustion. However, with increased amounts, these components combine with H and OH radicals to form stable substances like HF, inhibiting the combustion process. In the case of TMP, the phosphorus-containing intermediate components produced by cleavage catalyze the recombination of H and OH radicals, thereby inhibiting DMC combustion. The research findings offer a theoretical foundation for the development of safer lithium batteries and provide crucial data references for enhancing battery safety and prevention measures.

Design and optimization of reaction-separation-recycle systems using a pseudo-transient continuation model

The reaction-separation-recycle (RSR) systems are an important part of chemical processes. Due to the interaction between reaction and separation sections, the behavior of RSR processes becomes highly complex and non-linear, posing different challenges for their design and optimization. The purpose of this study is to design and optimize RSR processes for irreversible liquid phase reaction systems using the pseudo-transient continuation (PTC) approach within an equation-oriented programing environment. This approach was applied to investigate one binary system and four ternary systems. The differential-algebraic models of the proposed process flowsheets were solved until the steady-state conditions were reached. The tray bypass efficiency method was incorporated into the PTC to circumvent the need for discrete optimization. The results demonstrated that in those cases where the product was heavier than the reactants, employing a stripping column was more economical than using a conventional distillation column for both the binary and ternary systems. In the ternary systems with two recycle streams, when the product was the intermediate component in terms of boiling point, the utilization of a divided-wall distillation column (DWC) resulted in a total annual cost saving of 35 % and 41 % compared to direct and indirect separation methods, respectively.

Investigating Different Dynamic pHP1α States in Their KCl-Mediated Liquid-Liquid Phase Separation (LLPS) Using Solid-State NMR (SSNMR) and Molecular Dynamic (MD) Simulations.

Chromatin phase separation is dynamically regulated by many factors, such as post-translational modifications and effector proteins, and plays a critical role in genomic activities. The liquid-liquid phase separation (LLPS) of chromatin and/or effector proteins has been observed both in vitro and in vivo. However, the underlying mechanisms are largely unknown, and elucidating the physicochemical properties of the phase-separated complexes remains technically challenging. In this study, we detected dynamic, viscous, and intermediate components within the phosphorylated heterochromatin protein 1α (pHP1α) phase-separated system by using modified solid-state NMR (SSNMR) pulse sequences. The basis of these sequences relies on the different time scale of motion detected by heteronuclear Overhauser effect (hetNOE), scalar coupling-based, and dipolar coupling-based transfer schemes in NMR. In comparison to commonly utilized scalar coupling-based methods for studying the dynamic components in phase-separated systems, hetNOE offers more direct insight into molecular dynamics. NMR signals from the three different states in the protein gel were selectively excited and individually studied. Combined with molecular dynamics (MD) simulations, our findings indicate that at low KCl concentration (30 mM), the protein gel displays reduced molecular motion. Conversely, an increase in molecular motion was observed at a high KCl concentration (150 mM), which we attribute to the resultant intermolecular electrostatic interactions regulated by KCl.

Dynamic modeling and modification of ternary semicontinuous distillation without a middle vessel for improved controllability and energy performance

Ternary distillation conventionally requires two sequential columns. In a process intensification technique, the second column is eliminated by operating the first column in a cyclic manner, where the intermediate component is withdrawn periodically from a side stream. This process, called semicontinuous distillation (SCD) without a middle vessel, can lower the separation costs significantly. However, it exhibits controllability challenges due to the periodic recycling of the side stream. In this work, the process controllability is improved by adding a surge tank in the side stream recycle path. The modification increases significantly the process robustness without changing the operation recipe. Also, the modified SCD can lower maintenance costs as the manipulated variables experience milder oscillations. Moreover, it is shown to have a faster startup than the original design, yielding about 13 % energy saving per feed processed and processing about 25 % more feed during the startup compared with the original design. The case studies show the surge tank volume should be chosen based on the trade-off between attenuation of undesired disturbances and slow-down of desired control actions. Also presented in this article is detailed hybrid discrete-continuous dynamic modeling of the SCD and how the resulting model is implemented in the open-source software OpenModelica.

Molecular insights into CO2 enhanced hydrocarbon recovery and its sequestration in multiscale shale reservoirs

CO2 huff-n-puff (HNP) is an attractive enhanced oil recovery (EOR) technique in shale development due to its low cost, high efficiency, and environmentally friendly feature. Molecular dynamics (MD) simulations have been widely used to investigate the mechanisms of CO2 HNP process. However, the process of CO2 HNP is highly complex, involving the CO2 adsorption and transport in multiscale porous media, while considering the effect of different hydrocarbon compositions of shale oil. In this work, we developed a novel multiscale model (nano + bulk) with the modified Eagle Ford shale oil and water as the reservoir fluid. We investigated the adsorption behaviors and transport dynamics of CO2 in the CO2 HNP process. We quantitatively evaluated the CO2 swelling effect and its miscibility with hydrocarbons. Our results show the preferential adsorption to the graphene wall is pentane < CO2 < octane. CO2 can effectively desorb the light and intermediate hydrocarbons from the graphene wall. In addition, CO2 has good swelling effect and miscibility with the light and intermediate components. Due to the large molecular diameter and the strong interactions with the nanopore wall, the heavy components tend to be trapped in the nanopore after the CO2 HNP process. However, CO2 has similar swelling effect on the light and heavy components, indicating that the heavy components in the bulk pore can be effectively swelled and produced. Different from the unstable diffusion edge in the inorganic nanopores, CO2 has a stable diffusion edge in the organic nanopores. From the adsorption perspective, CO2 has favorable sequestration performance in the inorganic nanopores in shale gas reservoirs. This work provides a comprehensive understanding of the CO2 HNP process and practical implications for CO2 sequestration in shale reservoirs.

Electromagnetic and thermal performance study on a canted stack of REBCO tapes

Abstract Due to the critical current limitation of a single REBCO tape, stacking methods are generally employed to increase the current carrying capacity in practical high-temperature superconducting (HTS) applications. However, the overall critical current is strongly dependent on the self-magnetic field, which is influenced by the geometrical arrangement of conductors in the stack. Due to the brittle ceramic property, REBCO tapes are conventionally bent along the thickness side of the tape. However, the difference in bending radii of the outer and inner tape surfaces in the stack may lead to fracture deformation, thereby limiting the stacking number of REBCO tapes. To balance the stacking number with the bending issue, canted stack is proposed as a variant of normal stack for REBCO tapes. As a potential HTS intermediate component, it is imperative to conduct a comprehensive study on electromagnetic and thermal performance of canted stack. The unique geometrical arrangement of canted stack introduces new factors that affect critical current and transport AC loss. This paper concludes the special influencing factors of canted stack, including canted angle, stacking number, tape width, and spatial structure. The metal interleaving method is introduced for spatial distribution changing and thermal stability. Furthermore, orthogonal analysis is performed to elucidate the comprehensive correlation among these multiple factors. This study provides insights into the overall critical current and transport AC loss for different combinations of canted stack and establishes a predicting function for critical current to support the structural design of canted stack. Based on the specific case study, the improvement effect of canted stack is confirmed by both experiments and simulations.

Factor of safety analysis for mine pillar considering the influence of the intermediate principal stress component

Failure of mine pillars, especially in deep underground mines, significantly threatens the safety of miners and equipment. Previous studies on mine pillar stability design have used classical constitutive models that ignore the intermediate principal stress component when determining the factor of safety. In this study, we develop and implement a three-dimensional modified Hoek–Brown (HB) constitutive model that incorporates the intermediate principal stress component into the numerical simulation tool FLAC3D. Furthermore, we propose and apply a strength-reduction technique to determine a more accurate factor of safety for mine pillars. This novel approach provides a more comprehensive and realistic method for geomechanical analysis and pillar design, enhancing our understanding of pillar stability. Through numerical analysis, we illustrate the impact of the intermediate principal stress component on mine pillar plasticity. The factor of safety is calculated via the strength reduction method, revealing a substantial improvement from 1.7 with the classical HB model to 2.0 with the 3D HB model. Including the intermediate principal stress component reduces the evolution of plasticity in the mine pillar. For instance, the volume of plastic zones diminishes, and the factor of safety increases as the width-to-height ratio increases. Exemplary simulations show that ignoring the effect of the intermediate principal stress component, including underestimating safety levels, designing suboptimal pillar design, and misinterpreting in situ observations and measurements, can lead to severe consequences.

EFFECT OF ADDING N2/H2O TO ETHYLENE LAMINAR DIFFUSION FLAME ON SOOT FORMATION

Abstract The method of adding exhaust gas to fuel to reduce soot and NOX is called Exhaust Gas Recirculation (EGR). This paper was carried out to investigate the effect of adding N2 and H2O to the fuel side to dilute ethylene on soot generation in laminar diffusion flame by combining experiment and numerical simulation. In the experiment, the flame was optically detected, and the volume fraction of soot and temperature was reconstructed. The numerical simulation adopts a simplified GRI-Mech 3.0 ethylene 23-step combustion reaction mechanism. It introduces virtual species FX (F1H2O, F2H2O, F3H2O) to isolate the effects of H2O addition on thermal, transport, chemical, and density effects. The results show that the numerical values agree well with the experimental results. At the same dilution ratio, the direct involvement of H2O in the reaction affects the flame temperature and intermediate products, leading to a more significant suppressing effect on soot than N2 dilution. After decoupling the effects of H2O, it was found that there are two main reasons for the decrease of soot caused by the addition of H2O. The first is the dilution effect and thermal effect, which hinder the HACA reaction by reducing the concentration of intermediate component C2H2, greatly inhibiting the surface growth rate of soot, and playing a decisive role in reducing the formation of soot. The second is the chemical effect, which mainly enhances the oxidation process of soot by increasing the concentration of OH free radicals during combustion through the elementary reaction OH+H2↔H+H2O. Additionally, the degree of influence of various effects on soot was qualitatively determined as follows: dilution effect &amp;gt; chemical effect &amp;gt; thermal effect &amp;gt; density effect &amp;gt; transport effect.

Refractive index measurement for plane parallel plate using fiber point diffraction lateral interference and numerical modeling

A plane-parallel-plate (PPP) refractive index (RI) measurement method based on fiber point diffraction lateral interferometry and numerical modeling is proposed. Two fiber point light sources (PLSs) generate lateral interference through PPP, and the interferograms are collected by a linear array camera (LAC). Employing ray tracing of an ideal PLS and numerical simulation, the theoretical model of RI measurement is established by polynomial fitting with the RI of PPP as the output, the PPP thickness and the phase change at specific positions of the LAC detector as the inputs. To enhance measurement accuracy, the theoretical model is further corrected using PPP samples with known RI, measured thicknesses and phase changes. The experimental results indicate that the RI measurement accuracy can reach 10−4. Remarkably, this method features a simple structure and eliminates the intermediate optical components, except for the fiber PLSs, PPP samples, and LAC. We demonstrate how to simulate an ideal PLS with fiber PLSs and correct the numerical simulation model to improve the accuracy of RI measurement. Furthermore, this approach can be extended to other optical measurements.

Composite hemangioendothelioma of breast: A case report with review of literature

Composite hemangioendothelioma (CHE) is an intermediate grade neoplastic tumor of vascular origin. It consists of a varied mixture of benign, intermediate and malignantvascular components. Only few cases of CHE occurring in different soft tissue areas of the body and rarely in internal organs have been reported in literature till now. We report a case of CHE presenting as lump in the breast in a 42 year old female. A review of literature is also presented to create awareness of this entity which can be misleading in breast where angiosarcoma is also known to occur.

Evaluation of candidate International Standards for meningococcal capsular polysaccharide groups W and Y

Two candidate International Standards for meningococcal capsular group W and Y (MenW and MenY, respectively) polysaccharides were assessed for their suitability as quantitative standards in various physicochemical assays. The study was designed to evaluate the intended purpose of these standards, namely, to standardize the quantification of the respective polysaccharide content in meningococcal polysaccharide and conjugate vaccines and their intermediate components. Twelve laboratories from eleven different countries participated in the collaborative study of candidate preparations for International Standards for MenW and MenY polysaccharide (coded 16/152 and 16/206, respectively). Unitage was assigned using the Resorcinol assay. Our proposals, on the basis of data from the Resorcinol assay were: 1) candidate standard for MenW polysaccharide (16/152) to be assigned a content of 1.015 ± 0.071 mg MenW polysaccharide per ampoule (expanded uncertainty with coverage factor k = 2.13, corresponding to a 95 % level of confidence) and 2) candidate standard for MenY polysaccharide (16/206) be assigned a content of 0.958 ± 0.076 mg MenY polysaccharide per ampoule (expanded uncertainty with coverage factor k = 2.26, corresponding to a 95 % level of confidence). The amount of polysaccharide per ampoule remained consistent under all stability conditions over a 36-month period.

Experimental Study on Oil-Gas Interaction Mechanism during Offshore Heavy Oil Gas Injection.

Offshore heavy oil injection gas extraction is a highly scrutinized area in today's petroleum industry. However, the interaction mechanisms between oil and gas are not clear. To elucidate these mechanisms, an indoor experimental setup was established for research purposes. The effects of different types of gases on heavy oil expansion, mass transfer mechanisms between gas and heavy oil, the influence of gas injection on heavy oil phase behavior, and the testing of minimum miscibility pressures are investigated in this study. The results indicate that CO2 yields the best reduction in the heavy oil viscosity. Both forward and backward multiple contact mass transfer processes demonstrate nonmiscible multiple contact dynamic displacement mechanisms involving CO2 dissolution and condensation, as well as C1 extraction and coextraction. Nonmiscible multiple contact dynamic displacement of natural gas primarily involves limited dissolution and condensation of light hydrocarbon components and intermediate hydrocarbon components, with an extremely weak extraction effect. The minimum miscibility pressures are in the order of CO2 < natural gas < N2. This research provides important experimental evidence and theoretical guidance for further improving offshore heavy oil injection gas technology and practice.

Presentation of microstructural diffusion components by color schemes in abdominal organs.

Development of a color scheme representation to facilitate the interpretation of tri-exponential DWI data from abdominal organs, where multi-exponential behavior is more pronounced. Multi-exponential analysis of DWI data provides information about the microstructure of the tissue under study. The tri-exponential signal analysis generates numerous parameter images that are difficult to analyze individually. Summarized color images can simplify at-a-glance analysis. A color scheme was developed in which the slow, intermediate, and fast diffusion components were each assigned to a different red, green, and blue color channel. To improve the appearance of the image, histogram equalization, gamma correction, and white balance were used, and the processing parameters were adjusted. Examples of the resulting color maps of the diffusion fractions of healthy and pathological kidney and prostate are shown. The color maps obtained by the presented method show the merged information of the slow, intermediate, and fast diffusion components in a single view. A differentiation of the different fractions becomes clearly visible. Fast diffusion regimes, such as in the renal hilus, can be clearly distinguished from slow fractions, such as in dense tumor tissue. Combining the diffusion information from tri-exponential DWI analysis into a single color image allows for simplified interpretation of the diffusion fractions. In the future, such color images may provide additional information about the microstructural nature of the tissue under study.

The oxygen fugacity of intermediate shergottite NWA 11043: implications for Martian mantle evolution

Shergottite meteorites, classified as depleted, intermediate, or enriched based on incompatible trace elements and specific radiogenic isotope compositions (Sr, Nd, and Hf isotope ratios), point to multiple Martian mantle source regions. The oxygen fugacity (fO2) of these mantle regions, determined from early crystallizing minerals using the olivine-pyroxene-spinel oxybarometer, appears to correlate with incompatible trace element enrichment and isotope compositions. However, values derived from the vanadium-in-olivine oxybarometer challenge this correlation, hinting at potential biases in oxybarometry or complexities in the redox conditions of the Martian mantle. By analyzing the intermediate shergottite Northwest Africa (NWA) 11043 with various oxybarometers, this study deduced its origin from a reduced mantle source, with an average fO2 value of −0.77 ± 0.35 relative to the iron-wüstite (IW) buffer. Notably, these values coincide with those of depleted shergottites, which represent the depleted Martian mantle region. This redox similarity between intermediate and depleted shergottites contrasts with earlier notions that postulated intermediate shergottites as a mix of depleted and enriched mantle derivatives. Moreover, intermediate shergottites such as NWA 11043, Elephant Moraine (EETA) 79001A, and Allan Hills (ALH) 77005 display 176Hf/177Hf values akin to those of depleted shergottites, suggesting that intermediate mantle components can be separated from the depleted mantle source at approximately 2.2 Ga based on model age calculations. Therefore, there presents a consistent redox state between mantle magma sources of both intermediate and depleted shergottites since the Hesperian period, while enriched shergottites lean toward more oxidized conditions past source formation.This study prompts a reassessment of conventional theories, emphasizing the nuanced redox evolution of the Martian mantle across distinct mantle source regions and underscoring the complexity of the redox evolution of the Martian mantle. The emergence of chemically diverse mantle reservoirs might predominantly arise from early magma ocean differentiation processes, albeit with inherent oxidation nuances. The differences in fO2 observed between intermediate and depleted shergottites underscore the need for more in-depth studies to decipher Martian mantle differentiation and evolution.

A Novel SVM Strategy to Reduce Current Stress of High-Frequency Link Matrix Converter

High-frequency link matrix converter (HFLMC) can directly realize DC/AC conversion without intermediate energy storage components, reduce the power conversion stage, and improve efficiency and power density. With the conventional space vector modulation strategy, the secondary side voltage of the high-frequency transformer presents an asymmetric trapezoidal wave, which leads to the DC magnetic bias phenomenon and increases the current stress in secondary side switches. This paper proposes a novel SVM strategy for HFLMC. It optimizes the space vector distribution, makes secondary side voltage periodic and symmetric, and reduces the switching actions. The current stress is reduced, and the converter's efficiency is improved. Simulation and experiment results verify the advantages of the proposed modulation strategy.

Energy spectra of elemental groups of cosmic rays with the KASCADE experiment data and machine learning

We report the reconstruction of the mass component spectra of cosmic rays (protons, helium, carbon, silicon and iron) and their mean mass composition, at energies from 1.4 to 100 PeV. The results are derived from the archival data of the extensive air shower experiment KASCADE. We use a novel machine learning technique developed specifically for this reconstruction, and post-LHC hadronic interaction models: QGSJet-II.04, EPOS-LHC and Sibyll 2.3c. We have found an excess of the proton component and a deficit of intermediate and heavy nuclei components compared to the original KASCADE results. The spectra of protons and helium show a knee-like behavior at ∼ 4.4 PeV and ∼ 11 PeV, with significances 5.2σ and 3.9σ, respectively. The spectrum of the iron component has a hint (2.4σ) of a hardening at ∼ 4.5 PeV, which can be interpreted as a counterpart of a hardening in the proton spectrum at 166 TeV, recently reported by the GRAPES-3 experiment. The systematic uncertainties of our analysis were found to be smaller than those of the original KASCADE, as well as those of IceTop and TALE experiments, over the most part of the energy range studied. We also estimated separately the uncertainty related to the difference between the three mentioned hadronic interaction models. We also compute a mean logarithm mass of CR flux as a function of energy. It is in agreement with the results of IceTop, TALE and LHAASO within the uncertainties.

Removal of antibiotics, bacterial toxicity, and occurrence of antibiotic resistance genes in secondary hospital effluents treated with granular activated carbon and the impact of preceding chlorination

This comprehensive investigation highlighted the complex adsorption behaviors of antibiotics onto granular activated carbon (GAC), the effectiveness of this adsorption in reducing bacterial toxicity, and the reduction of antibiotic resistance genes (ARGs) and antibiotic resistant bacteria (ARB) in hospital wastewater (HWW) effluents. Six GACs were characterized for their physicochemical properties, and their ability to adsorb six antibiotics in the background matrix of actual HWW was evaluated. Coconut shell-derived GAC (Co-U), which had the highest hydrophobicity and lowest content of oxygen-containing acidic functional groups, demonstrated the highest adsorption capacities for the tested antibiotics. Bacterial toxicity tests revealed that GACs could eliminate the bacterial toxicity from antibiotic intermediates present in chlorinated HWW. By contrast, the bacterial toxicity could not be removed by GACs in non-chlorinated HWW due to the greater presence of intermediate components identified by LC-MS/MS. The intraparticle diffusion coefficient of antibiotics adsorbed onto Co-U could be calculated by adsorption kinetics derived from the linear driving force model and the homogenous intraparticle diffusion model associated with the linear adsorption isotherms (0–150 μg/L). Meropenem and sulfamethoxazole exhibited the highest adsorption capacities in a single-solute solution compared to penicillin G, ampicillin, cetazidime, and ciprofloxacin. However, the greater adsorption capacities of meropenem and sulfamethoxazole disappeared in mixed-solute solutions, indicating the lowest adsorption competition. GAC can eliminate most ARGs while also promoting the growth of some ARB. Chlorination (free chlorine residues at 0.5 mg Cl2/L) did not significantly affect the overall composition of ARGs and ARB in HWW. However, the accumulation of ARGs and ARB on GAC in fixed bed columns was lower in chlorinated HWW than in non-chlorinated HWW due to an increase in the adsorption of intermediates.

Geochemical indicators to constrain weathering, provenance and tectonic setting of the Pisha Sandstone (Early–Middle Triassic) in Northeast Ordos Basin, China

The Pisha Sandstone is widely exposed in the northeastern margin of the Ordos basin. Since the Mesozoic the basin was subjected to uneven uplift several times, strong weathering and erosion have been occurring and a large amount of sediments derived from these erosional strata are input into the lower Yellow River, posing a fragile ecological environment along the river. However, the geochemical characteristics of the Pisha Sandstone have remained poorly understood. In this study, we focus on the Pisha Sandstone from Early–Middle Triassic Liujiagou, Heshanggou and Ermaying Formation, present a very first petrographic and geochemical data together with detailed field geological characteristics, aiming to place geochemical indicators on weathering, provenance and tectonic setting of the Pisha Sandstone. The results show that sandstones in Pisha Sandstone are classified as arkose, litharenite and wacke. The geochemical proxies including Chemical Index of Alteration (CIA = 67.2), Chemical Index of Weathering (CIW = 80.1), Plagioclase Index of Alteration (PIA = 75.6) and Index of Compositional Variability (ICV = 1.6) indicate Pisha Sandstone experienced first–cycle deposit and moderate to strong chemical weathering. Trace element and rare earth element concentrations together with their ratios (La/Sc, La/Co, Th/Sc, Th/Co, Cr/Th) reveal a felsic provenance, and source rock compositions are predominantly granodiorite and granite from the north margin of the Inner Mongolia Paleo–Uplift (IMPU), with a small amount of mafic or intermediate components. The geochemical signatures and tectonic discrimination diagrams display a collision setting for the Pisha Sandstone and further reveal the sediments had been deposited in a continental island arc setting. The results of this work may provide new theoretical basis for environmental protection in the Pisha Sandstone area.

The Electronic Impact of Light-Induced Degradation in CsPbBr3 Perovskite Nanocrystals at Gold Interfaces.

The understanding of the interfacial properties in perovskite devices under irradiation is crucial for their engineering. In this study we show how the electronic structure of the interface between CsPbBr3 perovskite nanocrystals (PNCs) and Au is affected by irradiation of X-rays, near-infrared (NIR), and ultraviolet (UV) light. The effects of X-ray and light exposure could be differentiated by employing low-dose X-ray photoelectron spectroscopy (XPS). Apart from the common degradation product of metallic lead (Pb0), a new intermediate component (Pbint) was identified in the Pb 4f XPS spectra after exposure to high intensity X-rays or UV light. The Pbint component is determined to be monolayer metallic Pb on-top of the Au substrate from underpotential deposition (UPD) of Pb induced from the breaking of the perovskite structure allowing for migration of Pb2+.

Laminar flame speed measurement and combustion mechanism optimization for ethylene–air mixtures

AbstractEthylene plays a crucial role as an intermediate component in the cracking and combustion processes of large molecular alkane and olefins. In this article, the laminar flame speed of ethylene–air mixtures was measured using the heat flux method. The mechanism of ethylene was simplified by utilizing the error propagation directed relationship graph (DRGEP) and sensitivity analysis (SA), and the Arrhenius pre‐exponential factors for 20 selected reactions in the skeletal mechanism were optimized using the particle swarm optimization (PSO) algorithm. Finally, an ethylene optimization mechanism including 39 species and 85 reactions was obtained. The prediction results for flame speed, ignition delay time, and species concentration were compared with experimental data and other mechanisms, covering a wide range of temperatures (298–1725 K), pressures (1–22.8 atm), and equivalence ratios (0.5–2.0). The findings demonstrate that the optimization mechanism not only improves the prediction results of laminar flame speed in the rich combustion zone and low oxygen environment but also enhances the prediction accuracy of the ignition delay time at high pressure and in the lean combustion zone, as well as the prediction accuracy of C2H4 and H2O radicals. In conclusion, the optimized mechanism exhibits higher accuracy and broader applicability.