Interfacial Coupling Research Articles

Triboelectric potential tuned oxide artificial tactile sensory platform with ultra-low power consumption

Sophistiated cognitive platform calls for multifunctional intelligent sensory devices with ultra-low power consumption. Triboelectric nanogenerator (TENG) provides an energy-efficient strategy to gate neuromorphic transistor with multiple sensing applications. To this end, a self-powered artificial tactile sensory neuron is proposed. Fish gelatin (GEL) and carboxylated-chitosan (CCs) are cross-linked to gate indium tin oxide (ITO) neuromorphic transistor. Thanks to the extremely strong protonic/electronic interfacial coupling at GEL-CCs based hydrogel/channel interface, good electrical performances are obtained at low voltage of only ∼0.8 V. The device demonstrates fundamental synaptic behaviors. Moreover, it exhibits ultra-low energy consumption of only ∼31.1 aJ for a single synaptic response with a good sensitivity of ∼4.65 dB. TENG is fabricated using polydimethylsiloxane elastomer and polytetrafluoroethylene, demonstrating good sensitivity of ∼8.0 V/kPa and good stabilities under pressure of 400 Pa. Thus, a tactile sensory platform is built with co-substrate configuration, integrating TENG and ITO neuromorphic transistor. Image edge detection is conceptually demonstrated by adopting Sobel algorithm. Furthermore, a wearable arterial pulse monitor is proposed based on the haptic sensory platform. The present work provides a candidate solution for realizing environment-friendly, energy-saving neuromorphic system and tactile perception system, demonstrating potentials in portable intelligent platform, prosthetics and human-machine interface.

The muphyII code: Multiphysics plasma simulation on large HPC systems

Collisionless astrophysical and space plasmas cover regions that typically display a separation of scales that exceeds any code's capabilities. To help address this problem, the muphyII code utilizes a hierarchy of models with different inherent scales, unified in an adaptive framework that allows stand-alone use of models as well as a model-based dynamic and adaptive domain decomposition. This requires ensuring excellent conservation properties, careful treatment of inner-domain model boundaries for interface coupling, and robust time-stepping algorithms, especially with the use of electron subcycling. This multi-physics approach is implemented in the muphyII code, tested on different scenarios of space plasma magnetic reconnection, and evaluated against space probe data and higher-fidelity simulation results from literature. Adaptive model refinement is highlighted in particular, and a hybrid model with kinetic ions, pressure-tensor fluid electrons, and Maxwell fields is appraised.

Plasmonic synergism in tailored metal–carbon interfaces for real-time single molecular level sniffing of PFOS and PFOA

Generating plasmonic hot-spots through engineering of nanoscale interfaces offers exciting opportunities towards point-of-care analytical detection. The mutual trade-off between ultra-high sensitivity, specificity and reliability are major drawbacks for practical applicability with real-time samples. Fundamentally these originate from low photonic mode density, high ohmic losses, temporally fluctuating and chemically indistinguishable nature of electromagnetic hot-spots. This work describes synergism of metallic plasmons from tailored interfaces of Ag-Au nanoalloys with conical nanocavities of nanocarbon florets (NCF), leading to strong metal-dielectric interfacial coupling. Such, Ag-Au-NCF nanohybrid delivers an unprecedented 1517-fold enhancement in surface-plasmon coupled directed emission (SPCE) of Rhodamine B (RhB) leading to robust (relative standard deviation, RSD < 10 %) single-molecular-level detection of spectroscopically-silent perfluoroalkyl substances (PFAS). The limit-of-detection demonstrated (PFOS = 0.005 ppt) is one-thousand times better than WHO recommendation and surpasses all existing reports. The specific cation–anion interactions between RhB and PFAS are substantiated through density functional calculations that concur with experimental findings. Finally, the emission from this SPCE platform can be visually tracked through a smartphone camera over wide range of PFOS concentrations (0.005–5000000 ppt) in water samples (lake, river, tap, drinking and ocean) and blood-plasma, offering transformative opportunities in analytical sciences.

HAZniCS – Software Components for Multiphysics Problems

We introduce the software toolbox HAZniCS for solving interface-coupled multiphysics problems. HAZniCS is a suite of modules that combines the well-known FEniCS framework for finite element discretization with solver and graph library HAZmath. The focus of this article is on the design and implementation of robust and efficient solver algorithms which tackle issues related to the complex interfacial coupling of the physical problems often encountered in applications in brain biomechanics. The robustness and efficiency of the numerical algorithms and methods is shown in several numerical examples, namely the Darcy-Stokes equations that model the flow of cerebrospinal fluid in the human brain and the mixed-dimensional model of electrodiffusion in the brain tissue.

Modulation of coaxial cone-jet instability in active co-flow focusing

The breakup of coaxial cone-jet interfaces to compound droplets in axisymmetric co-flow focusing (CFF) upon actuation is studied through numerical simulations. Due to the coupling effect of double interfaces, the response behaviours of coaxial cone-jet flow to actuation are more complex than those of a single-layered interface structure. Particularly, the coaxial jet presents totally different response modes between weak and strong interface coupling situations. In this work, the phase diagrams of response modes for coaxial jet breakup are depicted, considering the effect of perturbation frequency, amplitude and liquid flow rates. In particular, the breakup of a coaxial jet can be synchronized with actuation within a frequency range containing the natural breakup frequency, resulting in uniform compound droplets with a single core inside the shell, and the size of droplets can be adjusted by frequency. As the perturbation frequency exceeds the upper critical value, the external perturbation is unable to dominate the jet breakup, while below the lower critical frequency, the jet breaks up with multiple droplets generated in one period. The perturbation amplitude mainly affects the jet breakup length and also leads to the transition between different response modes. The coaxial cone upstream of the orifice can act as a buffer layer, regulating the perturbation amplitude of the coaxial jet downstream. The degree of buffering effect is affected by the perturbation frequency and amplitude. As the perturbation amplitude approaches unity, the decrease of perturbation frequency leads to the intermittent jet behaviour from the cone tip with a vibrating manner of the coaxial cone. Based on the linear instability analysis on the simplified single jet models for weak-coupled and strong-coupled jets, scaling analyses are carried out, which predict the jet breakup length and the natural frequency and critical frequency for the synchronized breakup. Finally, a strong pulse is added on the perturbation to produce compound droplets with a controllable number of cores. The present work provides valuable guidance for the practical application of on-demand compound droplet generation through active CFF.

Growth of 2D Cr2 O3 -CrN Mosaic Heterostructures with Tunable Room-Temperature Ferromagnetism.

2D magnets have generated much attention due to their potential for spintronic devices. Heterostructures of 2D magnets are interesting platforms for exploring physical phenomena and applications. However, the controlled growth of 2D room-temperature ferromagnetic heterostructures is challenging. Here, one-pot chemical vapor deposition growth of stable 2D Cr2 O3 -CrN mosaic heterostructures (MHs) is reported with a controlled ratio of components that possess robust room-temperature ferromagnetism. The 2D MHs consist of Cr2 O3 flakes with embedded CrN subdomains and the CrN:Cr2 O3 ratio can be tuned from 0% to 100% during growth. By changing the CrN:Cr2 O3 ratio, the ferromagnetism of the MHs (e.g., saturation magnetization, coercive field), which originates from the interfacial coupling between Cr2 O3 and CrN, can be controlled. Importantly, the obtained Cr2 O3 -CrN MHs are stable in air at elevated temperatures and have robust ferromagnetism with Curie temperature >400K. This work presents a facile method for fabricating 2D MHs with tunable magnetism which will benefit high-temperature spintronics.

Strategic design of NiS2/Co3S4 heterojunction for enhanced electrocatalytic hydrogen evolution in acidic media

The construction of heterogeneous interface significantly contributes to the boosted electrocatalytic activity for hydrogen evolution reaction (HER). This enhancement is achieved through the modulation of the electronic structure, facilitation of electron redistribution, and optimization of the electrocatalyst's chemisorption towards the reaction intermediates. Herein, NiS2/Co3S4 heterojunction was synthesized using a straightforward one-pot hydrothermal method, and the impact of heterogeneous interface on the electrocatalytic HER performances was investigated. The heterogeneous interface and strengthened interfacial effects between NiS2 and Co3S4 were confirmed by HRTEM and XPS. The NiS2/Co3S4 heterojunction demonstrate significantly enhanced HER performance in acidic solutions, owing to their clever structural design and the robust interfacial coupling effects within the heterogeneous interface structure, surpassing that of single-component NiS2 materials. The optimum NiS2/Co3S4 heterojunction presents a low overpotential of 253 mV and a Tafel slope of 62.0 mV dec−1 at 10 mA cm−2 toward HER. Density functional theory (DFT) calculation indicates that NiS2/Co3S4 heterostructure exhibit lower ΔGH* values compared to NiS2 and Co3S4. This suggests that the creation of heterogeneous interface can significantly optimize the adsorption capacity for hydrogen intermediates, thereby enhancing the HER in acidic media.

Interfacial coupling efficiency of functionalised rubbers on silica surfaces

Understanding filler-polymer interactions at the interfaces is an important aspect for rubber reinforcement development. Recent technology in the field of silica-rubber reinforcement has led to an increasing interest in functionalised rubbers, since they can directly react and enhance interactions with silica filler, and hence improved rubber reinforcement. The present work aims to better understand the role of different reaction variables, i.e. time, temperature, rubber concentration, solvent, surfactants, sonication, specific surface area of silica, rubber type, and catalyst, on rubber deposition on silica surface in a model reaction in solution of silica and functionalised rubbers. Results from the Design of Experiments (DoEs) study, i.e. One-Factor-At-a-Time (OFAT), Plackett-Burman (P-B) and Full-Factorial (FF) designs showed that all studied factors have a negligible effect on interfacial coupling efficiency of rubber to silica surface. Accessibility of the functional groups at the rubber molecules and the steric hindrance due to large polymeric molecular chains seem to be the most limiting factors, resulting in low coupling efficiency. Effects of the investigated reaction parameters and plausible mechanisms involved in rubber-silica coupling reactions are elucidated.

Interface coupling of Ni2P@Cu3P catalyst to facilitate highly-efficient electrochemical reduction of nitrate to ammonia

Electrochemical reduction of nitrate pollutants to ammonia is quite attractive in the context of the energy crisis and sustainable development, and developing efficient electrocatalysts with high NH3 yield rate and FE is particularly important and imminent. Herein, an efficient catalyst, Ni2P@Cu3P, for electrochemical reduction of nitrate to ammonia (NRA) was successfully constructed in situ on a copper foam. The interface coupling in Ni2P@Cu3P significantly optimized its surface electronic structure and induced the exposure of more metal-P bonds on the catalyst surface, resulting in its brilliant NRA performance with NH3 FE of 96.97 %, yield rate of 0.2784 mmol·h−1·cm−2, selectivity rate of 98.07 % and NO3− conversion rate of 99.35 %. DFT theoretical calculations indicated that optimization of the catalyst surface electronic structure by interface electron coupling significantly regulated the adsorption intensities of NRA intermediates on the catalyst surface, improving the catalytic performance of the NRA. The present work has some reference significance for understanding the design principle of efficient electrocatalysts for the reduction of nitrate to ammonia.

Simultaneously tuning oxygen reduction pathway and charge transfer dynamics toward sacrificial agent-free photocatalytic H2O2 production for in-situ water disinfection

Developing effective dual-function photocatalyst for sacrificial agent-free superior H2O2 production and in-situ water disinfection is a great challenge. Herein, defect engineering and interfacial chemical coupling dual-strategy is established to fabricate Sv-MoS2/BN heterojunction. The superior photocatalytic activity of Sv-MoS2/BN ascribes to the synergistic advantages of optimized electronic structure, improved oxygen adsorption property and charge separation efficiency. The optimal Sv-MoS2/BN-5 exhibits excellent H2O2 generation rate of 428.17 μmol h−1 g−1 and complete in-situ E. coli disinfection (7.78-log). Density functional theory calculation and rotating disk electrode (RDE) tests revealing that the existence of sulfur vacancies can regulate the interfacial barrier by reducing the work function, which switch oxygen-reduction route from two-step single-electron to one-step two-electron. The switch of oxygen reduction route remarkably promote the generation of the primary bactericidal species, H2O2, leading to significantly improved in situ photocatalytic disinfection efficiency. Moreover, the synthesized material still maintains high catalytic activity in a wide pH range and actual water. This research provides insights by modulating interfacial oxygen reduction for sacrificial agent-free H2O2 generation and in-situ water disinfection.

Interfacial coupling of CuFe2O4 induced hotspots over self-assembled g-C3N4 nanosheets as an efficient photocatalytic bacterial disinfectant

Most bacterial disinfectants contain high levels of extremely toxic and environmental hazardous chemicals, which pose a significant threat to the ecosystem. Semiconductor photocatalysis exhibits attractive prospects as an emerging greener technology for waste water disinfection. However, the fast recombination of charge carriers limits its practical application. Herein, self-assembled polymeric feather-like g-C3N4 (GCN) nanosheets modified with ferromagnetic CuFe2O4 (CFO) nanospheres were successfully applied as a reusable visible light photocatalytic disinfectant. As expected, the g-C3N4/CuFe2O4 (GCF) nanohybrid displayed superior photocatalytic inactivation efficiency of 0.157log within 120 min towards Escherichia coli DH5α (E. coli) compared with pristine GCN and CFO. The characterization results revealed the synergistic heterostructure interfaces, high surface area, and the transformative self-assembly of GCN to feather-like structure providing a rich active site for improved charge separation efficiency, and wide spectral response, therefore the superior performance of GCF. The radical trapping assay proclaimed that both O2•- and •OH radical played major role in the photocatalytic inactivation among the other reactive oxygen species (ROS). Furthermore, the chemical oxygen demand (COD), protein estimation, and DNA estimation assay results validated the cell damage caused by the photocatalyst. Besides that, GCN showed applicability in real-time wastewater samples with improved efficiency than in the saline solution. The excellent magnetic characteristics facilitated the recycling of the catalyst with insignificant leaching, magnetic induction, and distinguished separation. The results of this work signify the well-designed GCF as a high-performance and reusable photocatalyst for real-world pathogenic bacterial disinfection operations.

Interface coupling and droplet size under various flow-focusing geometry dimensions in double emulsion formation

The application performance of droplets, including the size and core-shell volumetric ratio of a double emulsion droplet, is investigated under various geometric sizes and flow rates in a flow-focusing capillary device. This study uses three-dimensional (3D) printing to create a novel substrate to assemble capillaries and make the inner dimension of the device tunable. Droplet generation is separated into two regions (uniform or non-uniform) based on the interface coupling shapes, where different generation modes are classified based on the rupture form of the multilayer interfaces. A map of the generation modes is established based on geometric size and flow conditions. In the dripping mode, interface coupling and its effect on generation are analyzed by the interface necking process for the two generation sub-modes (with/without a ball). The local capillary number of the double emulsion droplet is established for these sub-modes to analyze variations in the inner droplet volume, which helps propose the volume predictive model of inner and outer droplets.

Defect-Regulated Two-Dimensional Superlattice of Holey g-C3N4-TiO2 Nanohybrids: Contrasting Influence of Vacancy Content on Hybridization Impact and Photocatalyst Performance.

Defect engineering provides an effective way to explore efficient nanostructured catalysts. Herein, we synthesize defect-regulated two-dimensional superlattices comprising interstratified holey g-C3N4 and TiO2 monolayers with tailorable interfacial coupling. Using this interfacial-coupling-controlled hybrid system, a strong interdependence among vacancy content, performance, and interfacial coupling was elucidated, offering key insights for the design of high-performance catalysts. The defect-optimized g-C3N4-TiO2 superlattice exhibited higher photocatalytic activity toward visible-light-induced N2 fixation (∼1.06 mmol g-1 h-1) than defect-unoptimized and disorderly assembled g-C3N4-TiO2 homologues. The high photocatalytic performance of g-C3N4-TiO2 was attributed to the hybridization-induced defect creation, facilitated hydrogenation of adsorbed nitrogen, and improvement in N2 adsorption and charge transport. A comparison of the defect-dependent photocatalytic activity of g-C3N4, g-C3N4 nanosheets, and g-C3N4-TiO2 revealed the presence of optimal defect content for improving photocatalytic performance and the continuous increase of hybridization impact with the defect content. Sophisticated mutual influence among defect, electronic coupling, and photocatalytic ability underscores the importance of defect fine control in exploring high-performance hybrid photocatalysts. Along with the DFT calculation, the excellent photocatalyst performance of defect-optimized g-C3N4-TiO2 can be ascribed to the promotion of the uphill *N hydrogenation step as well as to enhancement of N2 adsorption, charge transfer kinetics, and mass transports.

Isotropic exchange-bias in twinned epitaxial Co/Co3O4 bilayer

Exchange bias (EB) is a unidirectional anisotropy caused by interface coupling between a ferromagnet and an antiferromagnet. It causes a preferential direction of magnetization in the ferromagnet, which manifests as a shift of the hysteresis loop along the magnetic field axis. Here, we demonstrate a large EB of over 1000 Oe at 20 K in a twinned Co(111)/Co3O4(111) thin film epitaxially grown on sapphire(0001) with sixfold rotational lattice symmetry, which is among the highest values reported for Co/Co1−yO systems. In such systems, the effect intensity is largest along the magnetic easy axes, which usually results in an anisotropy of the EB in epitaxial interfaces. However, we observed identical EB values for 0°, 15°, and 30° angles between the magnetic field and the nearest Co[002] magnetic easy axes. The measurements imply a relaxation of the magnetization to the nearest easy axis, suggesting increasingly isotropic EB fields with higher orders of rotational lattice symmetry.

Enhancing Interfacial Ferromagnetism and Magnetic Anisotropy of CaRuO3/SrTiO3 Superlattices via Substrate Orientation.

Artificial oxide heterostructures have provided promising platforms for the exploration of emergent quantum phases with extraordinary properties. One of the most interesting phenomena is the interfacial magnetism formed between two non-magnetic compounds. Here, a robust ferromagnetic phase emerged at the (111)-oriented heterointerface between paramagnetic CaRuO3 and diamagnetic SrTiO3 is reported. The Curie temperature is as high as ≈155K and the saturation magnetization is as large as ≈1.3µB per formula unit for the (111)-CaRuO3/SrTiO3 superlattices, which are obviously superior to those of the (001)-oriented counterparts and are comparable to the typical itinerant ferromagnet SrRuO3. A strong in-plane magnetic anisotropy with six-fold symmetry is further revealed by the anisotropic magnetoresistance measurements, presenting a large in-plane anisotropic field of 3.0-3.6T. More importantly, the magnetic easy axis of the (111)-oriented superlattices can be effectively tuned from 〈 1〉 to 〈 〉 directions by increasing the layer thickness of SrTiO3. The findings demonstrate a feasible approach to enhance the interface coupling effect by varying the stacking orientation of oxide heterostructures. The tunable magnetic anisotropy also shows potential applications in low-power-consumption or exchange spring devices.

Graphitic carbon nitride supported trimeric metal clusters as electrocatalysts for N2 reduction reaction

As a cleaner and more energy-efficient alternative, the electrochemical reduction of N2 to NH3 under mild conditions has emerged as a promising avenue for environmental protection. However, developing catalysts with both high activity and selectivity has been a challenging task. The advent of atomically dispersed catalysts is revolutionizing the field of catalysis. Drawing inspiration from the successful fabrication of Ru trimer on graphitic carbon nitride (g-C3N4) nanosheets, herein, we adopted a series of trimeric metal clusters anchored on g-C3N4 monolayer (TM3@g-C3N4, TM = 3d, 4d and 5d transition metal atom), as well as utilized the criteria range to describe the stability, activity, energy cost and selectivity of supported trimers for N2 reduction reaction based on ab initio calculations combined with multi-level screening strategies. Finally, 5 candidate TM3@g-C3N4 (TM = Rh, Ru, V, Mo, and Re) exhibits decent catalytic activity with limiting potential ranging of –0.50 – –0.02 V. These spatially confined triatomic metal centers demonstrated proficiency in activating N2 molecules while exhibiting tunable surficial reactivity through modulation of the metal elements and interfacial electron coupling between trimers and underlying substrates. More importantly, a structure–activity relationship was established, which provides crucial insights for precise design of highly efficient atomically-precise catalysts at an atomic level for hydrogen fuel storage.

Interfacial lattice coupling engineering in all-inorganic coupled flexible films for dielectric energy storage

Hexagonal boron nitride (BN) was dispersed into the lattice of Sr2Bi4Ti5O18 (SBT) ferroelectrics to form all-inorganic flexible film capacitors. The interfacial lattice coupling in microscopic induces reconstruction of lattice and electron configuration. The electrons transfer interaction at the interfacial lattices results in the lattice stretching, thereby enhancing polyhedral dipole-dipole interactions. Meanwhile, the potential difference derived from the electron transfer provides driving force for the interfacial polarization. Above both effectively enhance the polarization without expense of breakdown strength. The interfacial lattice coupling greatly reduces the carrier generation rates under high electric field due to the ultra-high bandgap of BN, which further improves breakdown strength, thus, suppressing the inversed relationship. The recovery energy density of 119.7 J/cm3 and the efficiency of 71.2 % are obtained with a consecutive mechanical bending stability. This strategy provides an alternative to break through the inversed relationship between polarization and breakdown strength for all-inorganic flexible film capacitors.

Tuning the Inter-Nanoplatelet Distance and Coupling Strength by Thermally Induced Ligand Decomposition.

CdSe nanoplatelets (NPLs) are promising 2D semiconductors for optoelectronic applications, in which efficient charge transport properties are desirable. It is reported that thermal annealing constitutes an effective strategy to control the optical absorption and electrical properties of CdSe NPLs by tuning the inter-NPL distance. Combining optical absorption, transmission electron microscopy, and thermogravimetric analysis, it is revealed that the thermal decomposition of ligands (e.g., cadmium myristate) governs the inter-NPL distance and thus the inter-NPL electronic coupling strength. Employing ultrafast terahertz spectroscopy, it is shown that this enhanced electronic coupling increases both the free carrier generation efficiency and the short-range mobility in NPL solids. The results show a straightforward method of controlling the interfacial electronic coupling strength for developing functional optoelectronic devices through thermal treatments.

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

In this study, an efficient phase inversion-impregnation approach is developed for fabricating BaO-decorated Ni-8 mol% yttria-stabilized zirconia (YSZ) anode-supported tubular solid oxide fuel cells (SOFCs) toward anti-coking. This technique involves a simple phase-inversion process, along with the saturated barium nitrate solution as coagulation bath. Experimental results show that BaO nanoislands with particle size of less than 100 nm have been successfully and uniformly introduced inside the Ni-YSZ anode. The corresponding peak power densities are determined to be 0.30 W cm−2 and 0.22 W cm−2 at 800 °C in wet hydrogen and methane fuel, respectively. The long-term stability in methane fuel with the BaO-decorated anode is significantly improved with respect to the pristine one. Density functional theory (DFT) calculations suggest that the loading of BaO nanoislands can efficiently capture and dissociate the H2O molecules to generate OH, which subsequently serves as effective carbon elimination medium. The OH diffusion from BaO to BaO/Ni interface coupling with the formation of COH is the key step involved in the carbon elimination mechanism. The as-proposed phase inversion-impregnation approach exhibits advantage in time and cost savings compared to traditional impregnation methods, providing a new route for fabricating anti-coking SOFC anodes.

The effect of interfacial charge-induced multiferroic properties of Bi0.993La0.007FeO3/BaTiO3 bilayer thin films: Performance modulation and energy storage applications

Multifunctional and multiferroic materials assure a tantalizing perspective of applications in next-generation microelectronics, memory, energy harvesting, and energy storage technologies. The current study aims to deposit a bilayer thin film of BLFO/BTO with varying top layer (BLFO) thickness on n-type Si and Pt/Ti/SiO2/Si (Pt-Si) substrate by the PLD technique. Bilayer films with dense and packed microstructures show evidence of both tetragonal (T) and rhombohedral (R) symmetry. The bilayer films exhibit remarkably enhanced saturation magnetization of 35.9 emu/cm3 and improved maximum polarization of 34 μC/cm2 at RT compared to single-layer films. Moreover, the higher top layer thickness (BTO/BLFO3) hetero-structures achieved a high recoverable energy storage density of 11.65 J/cm3 with an energy efficiency of 85 % simultaneously. These films display excellent energy storage performance and produce a maximum power density of 0.9 MW/cm3 at 100 Hz. Further, the leakage current density of BLFO/BTO3 film is found ∼102 times lower than the monolayer BTO thin film suggesting the lower oxygen vacancies, defects, and impurities in the bilayer stacked films with higher top layer thickness. The drop in leakage current density, slim hysteresis loop, and enhancement in large saturation polarization for BTO/BLFO3 highlight the improved result demonstrating the interface effect and coupling between ferroelectric and magnetic properties. Hence, the acquired ferroelectric and magnetic properties are promising for spintronic devices and energy storage capacitor applications.