Composite Interface Research Articles

Pomegranate-like ZnMn2O4 nanospheres/carbon fiber network for interface enhancement structure-function PEEK composites with good electromagnetic interference shielding and thermal conductivity

The functionalization of structural carbon fiber reinforced polymer (CFRP) composites remains a significant challenge. In this work, the integration of structure-function was achieved in carbon fiber reinforced PEEK (CF/PEEK) composite by introducing a ZnMn2O4-based interface with the functionalities of electromagnetic interference (EMI) shielding and thermal conductivity (TC). The ZnMn2O4 nanospheres/CF network was constructed by introducing ZnMn2O4 nanospheres on the CF surface, realizing a significantly strengthened composite interface. Notably, the interlayer shear strength (ILSS) of the UCF-Z125/PEEK composite has reached 85.38 MPa, marking a 47.51 % increase over the Unsized CF/PEEK composite. In addition, the EMI shielding and the TC performances of the CF/PEEK composite have also improved, with the EMI shielding of the composite enhanced by 54.67 % and the through-plane TC increased by 47.17 %. This structure-function integrated composite can be used not only as structural materials in aerospace applications but also as high-performance bifunctional materials in semiconductor and artificial intelligence industries.

Phase interface engineering enables state-of-the-art half-Heusler thermoelectrics

In thermoelectric, phase interface engineering proves effective in reducing the lattice thermal conductivity via interface scattering and amplifying the density-of-states effective mass by energy filtering. However, the indiscriminate introduction of phase interfaces inevitably leads to diminished carrier mobility. Moreover, relying on a singular energy barrier is insufficient for comprehensive filtration of low-energy carriers throughout the entire temperature range. Addressing these challenges, we advocate the establishment of a composite phase interface using atomic layer deposition (ALD) technology. This design aims to effectively decouple the interrelated thermoelectric parameters in ZrNiSn. The engineered coherent dual-interface energy barriers substantially enhance the density-of-states effective mass across the entire temperature spectrum while preser carrier mobility. Simultaneously, the strong interface scattering on phonons is crucial for curtailing lattice thermal conductivity. Consequently, a 40-cycles TiO2 coating on ZrNi1.03Sn0.99Sb0.01 achieves an unprecedented zT value of 1.3 at 873 K. These findings deepen the understanding of coherent composite-phase interface engineering.

Experimental and numerical study on the loading rate dependent tensile behavior of carbon fiber/epoxy interface

A series of experiments and simulations were performed to explore the effect of loading rate on the tensile behavior of carbon fiber/epoxy composite interface via the fiber bundle tensile method. Varying velocities were used to test the stress‒time and stress‒displacement curves of the samples, and a high-speed camera was used to study the in situ failure behavior of the carbon fiber/epoxy interface. Increasing the loading rate from 5 × 10−6 m/s to 12.0 m/s leds to an increase in the interfacial tensile strength from 6.1 ± 0.9 MPa to 16.4 ± 0.3 MPa, an increase in the interfacial stiffness from 1.58 ± 0.3 N/m to 17.4 ± 3.1 N/m, and a decrease in the fracture displacement from 0.23 ± 0.03 mm to 0.10 ± 0.01 mm. Optical microscopy analysis revealed rougher crack surfaces at higher loading rates. The fracture mode of interface transitioned from fiber breakage and pull-out to brittle matrix cracking with increasing loading rate. The finite element method was employed to verify the effectiveness of the fiber bundle tensile method with a split Hopkinson tension bar and study the failure behavior of the interface under dynamic loading. The simulation results showed that the calculated failure stress was 20 % lower than the actual value, and the cohesive layer was found to have greater stress at the edge region. This investigation deepens the understanding of the effects of the loading rate on the interfacial tensile behaviors of carbon fiber/epoxy composites.

The rigid-flexible balanced molecular crosslinking network transition interface: An effective strategy for improving the performance of bamboo fibers/poly(butadiene succinate-co-butadiene adipate) biocomposites

The poor interfacial compatibility of natural fiber-reinforced polymer composites has become a major challenge in the development of industry-standard high-performance composites. To solve this problem, this study constructs a novel rigid-flexible balanced molecular crosslinked network transition interface in composites. The interface improves the interfacial compatibility of the composites by balancing the stiffness and strength of the fibers and the matrix， effectively improving the properties of the composites. The flexural strength and flexural modulus of the composites were enhanced by 38 % and 44 %, respectively. Water absorption decreased by 30 %. The initial and maximum thermal degradation temperatures increased by 20 °C and 16 °C, respectively. The maximum storage modulus increased by 316 %. Furthermore, the impact toughness was elevated by 41 %, attributed to the crosslinked network's efficacy in absorbing and dissipating externally applied energy. This innovative approach introduces a new theory of interfacial reinforcement compatibility, advancing the development of high-performance and sustainable biocomposites.

Impact of the Rare Earth Element La on the Microstructure and Mechanical Properties of the Al/Steel Bimetallic Composite Interface Fabricated by Liquid–Solid Casting

Impact of the Rare Earth Element La on the Microstructure and Mechanical Properties of the Al/Steel Bimetallic Composite Interface Fabricated by Liquid–Solid Casting

Polarization at the compositional interface in Nb-doped metastable TiO2-SnO2 solid solutions

Polarization architecture was incorporated into metastable Nb-doped TiO2-SnO2 to deliver electron accumulation at the localized TiO2-SnO2 compositionally fluctuating interface. Specimens were quenched from various holding temperatures to ambient temperatures in air to avoid bimodal decomposition into TiO2 and SnO2 endmembers. At the lowest sintering temperature of 1,400 °C, the mixed phase containing TiO2- and SnO2-rich compositions existed as an intermediate state to the single-phase solid solution. The phase boundary became more ambiguous with increasing sintering temperatures, and the compositional fluctuation size reduced to single nanometers at 1,500 °C. The permittivity due to the interfacial polarization, ε interface, increased steadily with increasing sintering temperature. The larger ε interface values at higher temperatures are attributed to the greater density of the compositionally fluctuating phase interface, which leads to greater electron accumulation at the energy barrier between the two semiconducting layers.

Optimization of garnet-type solid-state lithium batteries via synergistic integration of an advanced composite interface for elevated performance

Solid-state batteries (SSBs) represent a pivotal avenue of development owing to their superior energy density and enhanced safety profile. However, the widespread utilization about SSBs confronts challenges such as inadequate interfacial connectivity resulting in high resistance, dendrite formation, and volumetric fluctuations in the lithium metal anode during plating and stripping. In this study, we introduce an innovative and remarkably efficient approach, leveraging the transformative potential of TiN-induced conversion. This method yields a lithium-ion-conductive TiN material concurrently addressing pre-existing porosity. The LiTiN| LLZTO| LiTiN symmetric cell is particularly noteworthy for its remarkable long-term cycle stability, which exceeds 1000 h at 0.2 mA cm−2, and its remarkable critical current density of 1.4 mA cm−2 at 25 °C. By subjecting TiN, the formation of the Li-Ti-N phase is induced, thereby establishing an additional Li3N-conductive layer that significantly enhances battery performance. Of paramount significance is the validation of the exceptional attributes of the composite through the deployment of LiFePO4 (LFP) full cells. In this configuration, the LFP coupled full cell manifests a remarkable discharge rate capacity of about 147 mAh g−1 at 1C, along with a noteworthy discharge capacity retention rate of 90 % even following 1000 charge and discharge cycles. These outcomes underscore the material’s robust lithium affinity and uniform lithium-ion distribution, which together mitigate dendrite growth and enhance the cycle stability of lithium-metal batteries.

Influence of curing agent modified BN with different molecular structures on the heat conduction and electrical insulation property of epoxy composites

AbstractBoron nitride (hBN) serves as an outstanding high‐performance polymer organic filler. However, its hexagonal crystal structure renders it chemically inert, thus limiting its applications. This study proposes the modification of hBN using economical amine and anhydride curing agents to reduce aggregation and enhance the heat conduction of epoxy resin. Specifically, the DETA curing agent and methyl tetrahydrophthalic anhydride (MTHPA) curing agent were grafted onto the hBN surface via ball milling and eco‐friendly water scrubbing processes. Subsequently, the modified functionalized BNNS were uniformly dispersed in epoxy resin via a wet process to form composite materials. Results indicate that both modified fillers maintain good dispersion at the epoxy interface. Compared to epoxy resin, the heat conduction of the EP/MTHPA‐BNNS composite material with 10 vol% loading increased by 212%. The EP/DETA‐BNNS composite exhibited a relative thermal conductivity enhancement of 191%. Moreover, both of materials demonstrated significantly improved thermal stability, with slightly reduced breakdown strength. Mechanical property testing revealed a maximum increase of 187.5% in fracture elongation.Highlights Comprehensive study on curing agent modified hBN High dispersion of BNNS after wet ball milling Modified BNNS improves composite interface properties The thermal conductivity increases twice under 10 wt% BNNS loading Composite materials with outstanding electrical insulation and high fracture elongation

Effect of Magnetic Moment on Carrier Effective Mass and Transport in Magnetic Nd2Fe14B Composite Bi2Te3 Films.

A composite of magnetic and thermoelectric (TE) materials is one of the most popular methods to improve TE properties. However, the influential mechanism of the magnetic property on the carrier has not been clarified. In this study, Nd2Fe14B cylinders are used as the magnetic phase to regulate carrier behaviors in Bi2Te3 films. Roaming state Fe atoms in Nd2Fe14B provide some carriers. The VTe at the composite interface also provides carriers. These lead to the increase of carrier concentration and conductivity of the composite film. Meanwhile, the Lorentz force generated by the magnetic moment of Nd2Fe14B provides the carriers with a stronger energy, which results in the increase of carrier effective mass and thereby increases the Seebeck coefficient. Thus, the power factor of the magnetic composite film is improved by 366% compared with that of the pure Bi2Te3 film.

Investigation of Direct Electron Transfer of Glucose Oxidase on a Graphene-CNT Composite Surface: A Molecular Dynamics Study Based on Electrochemical Experiments.

Graphene and its variants exhibit excellent electrical properties for the construction of enzymatic interfaces. In particular, the direct electron transfer of glucose oxidase on the electrode surface is a very important issue in the development of enzyme-based bioelectrodes. However, the number of studies conducted to assess how pristine graphene forms different interfaces with other carbon materials is insufficient. Enzyme-based electrodes (formed using carbon materials) have been extensively applied because of their low manufacturing costs and easy production techniques. In this study, the characteristics of a single-walled carbon nanotube/graphene-combined enzyme interface are analyzed at the atomic level using molecular dynamics simulations. The morphology of the enzyme was visualized using an elastic network model by performing normal-mode analysis based on electrochemical and microscopic experiments. Single-carbon electrodes exhibited poorer electrical characteristics than those prepared as composites with enzymes. Furthermore, the composite interface exhibited 4.61- and 2.45-fold higher direct electron efficiencies than GOx synthesized with single-carbon nanotubes and graphene, respectively. Based on this study, we propose that pristine graphene has the potential to develop glucose oxidase interfaces and carbon-nanotube-graphene composites for easy fabrication, low cost, and efficient electrode structures for enzyme-based biofuel cells.

Bond Strength Assessment of Normal Strength Concrete-Ultra-High-Performance Fiber Reinforced Concrete Using Repeated Drop-Weight Impact Test: Experimental and Machine Learning Technique.

Ultra-high-performance concrete (UHPC) has been used in building joints due to its increased strength, crack resistance, and durability, serving as a repair material. However, efficient repair depends on whether the interfacial substrate can provide adequate bond strength under various loading scenarios. The objective of this study is to investigate the bonding behavior of composite U-shaped normal strength concrete-ultra-high-performance fiber reinforced concrete (NSC-UHPFRC) specimens using multiple drop-weight impact testing techniques. The composite interface was treated using grooving (Gst), natural fracture (Nst), and smoothing (Sst) techniques. Ensemble machine learning (ML) algorithms comprising XGBoost and CatBoost, support vector machine (SVM), and generalized linear machine (GLM) were employed to train and test the simulation dataset to forecast the impact failure strength (N2) composite U-shaped NSC-UHPFRC specimen. The results indicate that the reference NSC samples had the highest impact strength and surface treatment played a substantial role in ensuring the adequate bond strength of NSC-UHPFRC. NSC-UHPFRC-Nst can provide sufficient bond strength at the interface, resulting in a monolithic structure that can resist repeated drop-weight impact loads. NSC-UHPFRC-Sst and NSC-UHPFRC-Gst exhibit significant reductions in impact strength properties. The ensemble ML correctly predicts the failure strength of the NSC-UHPFRC composite. The XGBoost ensemble model gave coefficient of determination (R2) values of approximately 0.99 and 0.9643 at the training and testing stages. The highest predictions were obtained using the GLM model, with an R2 value of 0.9805 at the testing stage.

Investigation on the fatigue crack propagation of rock-concrete interface under fatigue loading below the initial cracking load

The fatigue crack propagation of the composite rock-concrete interface under constant-amplitude flexural fatigue loading below the initial cracking load was investigated in the present study. Fatigue pre-crack initiation and propagation tests were first conducted on three types of rock-concrete interfaces under three-point bend loading. It was shown that for the rock-concrete interface, the damage evolution throughout the fatigue loading process can be divided into deceleration and acceleration stages according to the rate curves of flexural stiffness, deformation and crack propagation. The crack propagation rate exhibited two distinct regions when plotted on a log scale, namely the small-crack growth region and the long-crack growth region. The small-crack growth region for the studied rock-concrete interfaces was not particularly pronounced. The long-crack growth region was the Paris’ law region and included both the acceleration and part of the deceleration stages. Based on the experimental results, the fatigue crack propagation rate in the Paris’ law region was then described using the empirical Paris’ law. The exponent m1 in the Paris’ law was found to be approximately constant, with a value of m1 ≈ 21 for the rock-concrete interface. The pre-factor C1 was found to be dependent on both the load ratio R and the type of the rock-concrete interface (represented by an elastic mismatch parameter α). By introducing R and α into the empirical Paris’ law, an adjusted Paris’ law was proposed. The adjusted Paris’ law can describe the fatigue crack propagation rate in a unified way for the same rock-concrete interface of different R and different interfaces in the scope of this research. Based on the adjusted Paris’ law, the fatigue cycles during the crack propagation and fatigue lifetimes of all tested rock-concrete interface specimens were reasonably predicted. For practical applications, an approach was suggested involving a combination of the adjusted Paris’ law and a material coefficient β (approximately β ≈ 0.143 in this study) to estimate the fatigue lifetimes of structures or specimens with existing pre-cracks at the rock-concrete interface.

Hygroscopic damage of fiber–matrix interface in unidirectional composites: A computational approach

The mechanical properties of fiber-reinforced composites are significantly affected by hygroscopic exposure. Recent experimental findings reveal that the diffusion of water molecules results in void formation at the fiber–matrix interface, contributing to ∼1% increase in porosity. This paper presents a computational micromechanics framework to analyze the damage behavior of unidirectional composites under hygroscopic aging and transverse loads. First, a mathematical relation for the porosity evolution with moisture content in the composite is obtained. Leveraging this correlation, the aged composite is modeled as a porous microstructure consisting of fiber, matrix, and voids at the fiber–matrix interface in finite element simulations. The fiber is considered elastic, and the matrix is modeled as an elastoplastic material using a pressure-dependent yield model to capture tension–compression asymmetry. A cohesive interface is considered between the fiber and matrix. Simulation results indicate that a void at the interface significantly influences plastic strain evolution and stress distribution, leading to early damage initiation and reduced strength. Previous works have indicated that matrix and inter-fiber voids do not have a significant impact on the strength of composites when their combined porosity is below 1%. On the contrary, this study demonstrates that a porosity of as low as 0.1% at the fiber–matrix interface can result in an 11% decrease in the transverse tensile strength of the composite. A parametric study is conducted to understand the fundamental effects of pore size, location, and relative position on the transverse tension, compression, and shear loading responses of a unidirectional composite. For a given moisture content, the predicted strength of the hygroscopic aged composite exhibits a lower and upper bound. The strengths observed in the experiments fall within the model-predicted range. Additionally, a computational method is proposed that incorporates the effects of porosity at the fiber–matrix interface into a modified cohesive strength. This method allows efficient computations and failure predictions for water or moisture-aged strength degradation of unidirectional composites.

Effect of the process parameters of liquid–solid cast-rolling on the microstructure and properties of 1070A/7075 composite sheets

The effects of casting temperature and cast-rolling speed on the microstructure and properties of the composite interface of 1070A/7075 aluminium alloy composite sheet were studied. The results showed that under the same process conditions, the diffusion distances of the Mg element and the Cu element were the greatest and smallest, while that of the Zn element was found between the diffusion distances of the two elements. Furthermore, the intermetallic compound Al23CuFe4 generated at the interface greatly affected the bonding and tensile properties of the composite sheet. When the casting temperature was 690 °C, the cast-rolling speed was 12 m/min. The shear strength, tensile strength, yield strength and elongation were determined as 86.2, 173.9 and 108.6 MPa and 24.9%, respectively.

Effect of Electrochemical Aryl Diazonium Salt Modification on Interfacial Properties of CF/PEEK Composites.

The interfacial properties between carbon fiber (CF) and thermoplastic resin are relatively weak, which can be problematic for composites in structural applications. Improving the surface roughness of CF is regarded as an effective way to enhance the interface of composites. However, most CF modifying methods are complex and time-consuming, which cannot meet the demand for industrial production. Therefore, it is of great significance to research a fast technique of CF surface modification to strengthen the interface of composites. Herein, a one-pot reaction based on the aryl diazonium salt modification was applied to enhance the interface between CF and poly ether ether ketone (PEEK) resin. Carbon nanotubes (CNTs) were linked to CF by p-phenylenediamine (PPD) via cyclic voltammetry (CV). The surface morphology, chemical characteristics and surface energy of modified CF illustrated the effectiveness of this method, and the interfacial properties of as-prepared modified CF/PEEK demonstrated the increased tendency. All the CF was treated within 5 min and the interfacial shear strength (IFSS) of CF/PEEK was increased to the maximum of 99.62 MPa by aryl diazonium salt modification. This work may shed some light on the industrialized application of CF reinforced high-performance engineering thermoplastic composites.

Study on the strength composition mechanism and interface microscopic characteristics of cold recycling asphalt mixture

Study on the strength composition mechanism and interface microscopic characteristics of cold recycling asphalt mixture

Self-organized composite morphologies and interface instability of immiscible alloy thin films during physical vapor deposition: Insights from phase-field simulations

In this paper, we carried out phase-field simulations for investigating self-organized composite morphologies formation and interface instability of two phase immiscible binary alloy thin-film growth during physical vapor deposition. Predicted results show that for lower the deposition rate the solid-gas interface keeps planar and the lateral composition modulation (LCM) configuration occurs. As the deposition rate increases, the self-organized composite morphology gradually transfers to vertical composition modulations (VCM) configuration and the random composition modulations (RCM) configuration with the decrease of the boundary layer of the incident vapor and the unsteady solid-gas interface. Results show that the nanoprecipitate concentration modulation (NCPM) depends strongly on the nominally phase fraction. Moreover, we found that the historical dependence of self-organized composite morphologies and solid-gas interface stability, i.e., the initial condition can strongly influence the microstructure of the thin film during physical vapor deposition. Finally, we provide an analysis method for interface instability based on fast Fourier transform (FFT), and the frequency characteristics of cellular and bump structures are identified.

Unveiling the Structure and Diffusion Kinetics at the Composite Electrolyte Interface in Solid‐State Batteries

AbstractThe “interface” between polymer and oxide within the polymer‐oxide composite electrolytes is widely acknowledged as a crucial factor influencing ionic conduction. However, a fundamental understanding of the precise composition and/or micro‐structure, and the ionic conduction mechanism at the complex interface has remained elusive, primarily due to a dearth of compelling experimental evidence. In this study, the intricate correlation between morphology and composition in composite electrolytes is discerned by leveraging advanced 1D and 2D exchange nuclear magnetic resonance spectroscopy (1D and 2D EXSY NMR) techniques. Notably, this research represents the inaugural elucidation of the microstructure of the interface. The findings underscore the pivotal role of the preparation conditions for polymer‐oxide composite electrolytes, particularly the solvent selection, in determining the formation of the interface structure. Direct insights into the lithium‐deficient surface of Li6.4La3Zr1.4Ta0.6O12 (LLZTO) are provided and elucidate the timescales of Li‐ion exchange processes among various components. Furthermore, a comprehensive investigation into the roles of individual components within the composite electrolyte on the Li‐ion conduction mechanism is conducted through the 6Li→7Li isotope tracer technique as a function of current density.

Cohesive failure analysis of carbon-fiber composite patch repair in perforated steel tubular elements

The use of composite materials to repair corroded steel structural components has expanded in the offshore oil and gas sector. The effective use of composites requires a meticulous process for choosing appropriate constituent elements. In this regard, numerical modeling is an efficient tool to better understand the impact of associated variables and enables the identification of failure causes and simulation of failure propagation. This study aims to assess the mechanical behavior of the adhesive layer at the steel - composite material interface in the repair of perforated tubular structures under bending, compression, and bending-compression. A numerical model is developed simplifying the examination and characterization of the cohesive failure mechanisms and modes occurring between the laminate patch repair and the perforated steel tubular element. The stress distribution and cohesive failure at the interface are then thoroughly investigated. The impacts of the inclusion of fillets at the patch repair ends to smoothen the transition between the composite material and the tube and the repair length are also evaluated. A Python subroutine is developed to identify the failure mode mechanisms to characterize the adhesive areas subjected to peel, shear, or mixed modes. Results suggest that pure shear mode is predominant in most of the repair locations across the three types of loading. For bending loads, the cohesive failure close to the cutout shows prominent shear mode. In the other loading conditions, the adhesive nearly fails in the vicinity of the cutouts (i.e., damage values are close to 1) in a predominant near pure shear failure mechanism. The use of fillets displaces the failure location for bending load, hence increasing the failure load level. Repairs were more extensive under Bending Moment load conditions compared to other load types. The mode ratio analysis and methodology presented in this work offer valuable tools for understanding the causes of failure modes.

Simultaneously improving interfacial adhesion and toughness of carbon fiber reinforced epoxy composites by grafting polyethyleneimine on the carbon fiber surface to construct a rigid‐flexible interface

AbstractChemical grafting is commonly employed to functionalize carbon fiber (CF) surface to enhance the interfacial properties of CF reinforced polymer composites (CFRP) by forming a robust interface. However, an overly rigid interface layer can result in relatively poor interface toughness. To balance interfacial strength and toughness, this paper proposes an effective method to simultaneously strengthen and toughen the interface of CF/epoxy composites by grafting branched polyethyleneimine (PEI) on CF surface using hexachlorophosphazene (HCCP) as active intermediate, which features a rigid ring structure and six active P‐Cl groups. The introduction of PEI provided a large number of amine and imine groups on CF surfaces, which were contributive to improving surface wettability and reactivity of CF, thus resulting in strong chemical bonding between CF and epoxy matrix. Additionally, the long and flexible molecular skeleton of PEI constructed a rigid‐flexible composite interface, which could effectively reduce stress concentration and absorb impact energy. After surface modification with PEI, the interfacial shear strength and fracture toughness of CF/epoxy composite were increased to 89.9 MPa and 200.3 J m−2, by 64.3% and 149.7%, respectively, in compared with desized CF reinforced epoxy composites.Highlights A rigid‐flexible interface was constructed between CF and epoxy resin. The interfacial strength and toughness of CFRP were synergistically improved. IFSS and interfacial toughness increased by 64.3% and 149.7%, respectively.