There is increasing interest in experiences of urban forests because relevant studies have revealed that forest settings can promote mental well-being. The mental response to a forest experience can be evaluated by facial expressions, but relevant knowledge is limited at large geographical scales. In this study, a dataset of 2824 photos, detailing the evaluated age (toddler, youth, middle-age, and senior citizen) and gender of urban forest visitors, was collected from Sina Weibo (a social media application similar to Twitter in China) between 1–7 October 2018, in 12 randomly chosen cities in China. Happy and sad expressions were rated as scores by FireFACE software V1.0, and the positive response index (PRI) was calculated by subtracting sad scores from happy scores. Regional environmental factors were collected to detect driving forces using regression analyses. Happy scores were higher in forests than in urban settings, while sad scores for toddlers were lower in forests than in promenades and squares. Females showed more positive emotional expressions than males. Increases in happy scores were driven by the increase of daily minimum temperature; while PRI declined with increases in latitude. Overall, an urban forest experience can evoke positive emotions, which is likely due to comfortable feelings in warm temperatures.