Interelectrode Distance Research Articles

High-Speed Removal Process for Organic Polymers by Non-Thermal Atmospheric-Pressure Spark Discharge at Room Temperature and Its Mechanism

Heel marks (HMs) are a type of dirt stain consisting of polyester-based urethane rubber on polyvinyl chloride (PVC) floor surfaces. The rapid removal of HMs was achieved by using non-thermal atmospheric-pressure plasma technology. Mimetic HMs were prepared by coating PVC floor samples with HMs to a thickness of 13.9 μm. The removal area, thickness, and volume were measured after applying spark discharges at high voltage and a repetition rate of 50 kHz. The treated surfaces were analyzed by using X-ray photoelectron spectroscopy (XPS) and pyrolysis–gas chromatography with time-of-flight mass spectrometry (Py-GC/TOFMS). Removal rates of 20 mm2/min in area, 52 mm3/min in volume, and 7 μm/min in depth were achieved with an inter-electrode distance of 10.0 mm and an air flow rate of 20 standard liters per minute. A removal depth of 10 μm/min was achieved without air supply. The mechanism of stain removal by spark discharge was modeled by decomposing the original high-molecular-weight molecules in polyester-based urethane rubber into low-molecular-weight molecules, such as methylene diisocyanate (MDI) components. The results of this study may facilitate the development of a novel electric vacuum cleaner capable of removing floor stains.

Electrolysis for ammonia removal and hydrogen generation in urban wastewater: Innovative approaches to the water crisis

The global water crisis poses significant challenges, with millions lacking access to clean drinking water and increasing water scarcity affecting urban areas worldwide. This study explores the electrolysis of urban wastewater as a two-fold solution for ammonia (un-ionized NH3, and ionized NH4+) removal and hydrogen gas (H2) production. Traditional treatment methods often fail to remove ammonia efficiently, underscoring the need for innovative approaches. Electrolysis, known for its versatility, energy efficiency, and environmental friendliness, emerges as a promising solution in wastewater treatment applications. This research utilized a dimensionally stable electrode (DSA) comprising a Ru-Ir anode and a stainless-steel cathode to electrochemically oxidize ammonia and produce H2. The study investigates the effects of current density, J (83.33–416.6 A/m2) on the treatability of urban wastewater. Maximum H2 production was achieved at J of 416.6 A/cm2 after 300 min reaction time. Under optimal conditions (333.3 A/m2, 0.5 mm inter-electrode distance, and 300 min of operation), the process achieved removal efficiencies of 98.94 % for ammonia, 78.18 % for total suspended solids (TSS), 50.73 % for chemical oxygen demand (COD), and complete removal (∼100 %) of total coliforms. Gas chromatography (GC) assessed the composition of gases of interest generated during electrolysis. This approach addresses environmental pollution and freshwater scarcity and generates an energy resource, presenting a scalable solution for cities worldwide facing similar challenges.

Study and scaling-up of multi-tip pulsed-corona air discharges for degradation of paracetamol

Abstract This study investigates the paracetamol removal efficiency by multi-tip pulsed corona discharges, highlighting the conditions avoiding mutual effects between two consecutive streamer branching discharges generated by each tip. The results show that the production of reactive oxygen and nitrogen species (RONS) in the liquid phase and the efficiency of paracetamol removal are influenced by the distance between two contiguous tips due to the mutual effects for small inter-tip distances between 4 mm and 8 mm in the case of a fixed inter-electrode distance of 5 mm (i.e. distance between the tip summit and the water surface). Beyond an inter-tip distance of 12 mm (over twice the gap distance), the mutual effects of branching discharges were no longer observed since the field lines did not overlap, making the production and absorption of liquid-phase species more efficient. Furthermore, RONS production was almost linear when moving from one to four tip electrodes: [H2O2]1tip: 0.52 mg l–1 versus [H2O2]4tips: 1.99 mg l–1, a ratio of 3.82. Optimum values were reached for an inter-tip distance of 16 mm. In this case, the enhancement factor in this reactor configuration is the surface integration between the plasma and the liquid surface to be treated. Furthermore, the results show a quasi-exponential increase in the percentage of paracetamol degradation as a function of the number of electrodes, from 4% with a mono-tip configuration to over 78% for a treatment with a four tip one.

Volumetric lesion analysis and validation of various bipolar configurations in radiofrequency ablation of ventricular myocardium in a bovine model.

The bipolar radiofrequency ablation(B-RFA) strategy was increasingly used to target deep intramural re-entrant foci responsible for the arrhythmia not ablated by conventional unipolar RFA / sequential unipolar RFA. Lesional characteristics of various bipolar configurations were largely unknown. To investigate the lesional geometry in relation to various factors to determine the most effective ablation strategy that minimises steam pops and achieves transmurality. To assess the temperatures at the return electrode. A custom-made validated ex-vivo bipolar ablation model was used to assess lesion formation. The myocardial sample was placed between two ablation catheters in four different orientations. Lesions were created using different power (30W, 40W, 50W) and time settings(30, 40 and 50s) with different catheter orientations. Data was analysed using binary logistic regression and multiple linear regression. Among 107 lesions, The volume of the active catheter lesion (266 +/- 137mm^3) significantly differed from their return electrode counterparts (130 +/- 91.8mm^3) (p < 0.001), and the temperatures at the return electrode end were lower than at the active electrode (p = 0.004). Higher power and longer duration application led to more frequent steam pops (p < 0.001), while true parallel configuration resulted in fewer steam pops (p < 0.001). A custom model without ground electrode temperature monitoring is safe and cost-effective. The safest strategy is a true parallel configuration with an inter-electrode distance of at least 15mm and a power of 30W to 40W, which generates lower steam pops and better transmurality.

Electrochemical removal of ethylene glycol monobutyl ether in aviation industry wastewater using a porous Ti4O7/Ti electrode

Titanium alloy chemical milling wastewater contains a significant amount of ethylene glycol monobutyl ether (EGBE), which is toxic and difficult to be degraded by microorganisms, and the emission will lead to severe environmental pollution. To solve this problem, the electrocatalytic oxidation method was employed to remove EGBE in the wastewater, in which a porous Ti4O7/Ti electrode were prepared and employed as the anode, while stainless steel acted as the cathode. The effects of current density, interelectrode distance, and stirring mode on the COD removal rate were also investigated. Results show that the COD of the wastewater significantly decreases from 12410 to 15 mg L−1 after 16 h of electrolysis at 10 mA cm−2 and electrode spacing of 1.0 cm as well as aeration stirring at 100 mL min−1. Moreover, pilot-plant scale testing reveals that the COD decreasing from 11980 to 183 mg L−1 after 24 h of electrolysis. Consequently, the utilization of porous Ti4O7/Ti electrode as anode in the electrocatalytic oxidation method presents significant potential in removal of EGBE in aviation industry wastewater.

Machine learning assisted prediction and process validation of electrochemically induced phosphorus recovery from wastewater

The disturbance in the natural phosphorus cycle has enhanced the problem of depletion of phosphorus rocks and its overabundance in the wastewater, leading to various environmental problems. Electrochemical phosphorus recovery from wastewater has gained attention due to the production of high-purity phosphorus precipitates that can be utilized to relieve the pressure on natural sources. However, its commercialization needs to be planned and predicted using modern machine learning algorithms. Hence, this study aims to predict electrochemical phosphorus recovery using different machine learning (ML) models: Linear regression, Lasso regression, Ridge regression, Adaboost, eXtreme Gradient Boost (XGB), Random Forest, and Support Vector Regression. The dataset for 16 input parameters considering the wastewater parameters, reactor, and reaction characteristics from the literature was used to envisage its influence on electrochemical phosphorus recovery. XGB was the robust ML model that outperformed other models in testing with R2 (0.98) and RMSE (33.54). The influence of the input parameters was studied using the feature importance, dependence plot and summary plot. Current density, pH, inter-electrode distance, electrolysis time and initial phosphorus concentration were some of the most influential input parameters affecting the phosphorous recovery. The process validation shows the R2 of 0.78 between the predicted values from the model and the experimental result. Overall, this study could help to predict electrochemical phosphorus recovery from the wastewater to facilitate optimization, upscaling, and commercialization of the technology to close the phosphorus loop.

Steady state stability features of the electron–positron plasma diode in a mode with particle reflection from potential extrema

Steady state stability features of a diode with electrons and positrons entering from opposite boundaries and moving without collisions in plasma are numerically studied. The most complex regime when charged particles are reflected from potential barriers is considered. This problem arises, in particular, when modeling pulsar diodes. A small perturbation evolution is studied. It has been established that at the initial stage of the process the perturbation amplitude changes in time according to an exponential law. It is shown that stationary solutions with a potential barrier for electrons located near the electron-emitting electrode and a potential barrier for positrons located near the opposite electrode are stable when the inter-electrode distance is below a certain threshold. As the inter-electrode distance increases, the solutions become unstable. Solutions of another type when barriers reflecting particles are located in the opposite to the emitting electrode parts of the gap are also studied. However, these solutions turned out to be unstable.

Wire-to-two-drop plasma thruster: Experimental and numerical investigation of electroaerodynamic jet flow for micro aerial vehicle propulsion

Conventional micro aerial vehicles (MAVs) have primarily relied on complex, flapping-wing mechanisms for propulsion, often exhibiting limitations in terms of reliability and efficiency. To overcome these challenges, this study explores the potential of electroaerodynamic (EAD) thrusters as a novel propulsion system. By accelerating air molecules through ion collisions, EAD jet flow generates thrust, offering advantages such as noiseless operation and zero emissions due to its moving-part-free design. This research presents a comprehensive experimental and numerical investigation of a wire-to-two-drop thruster configuration to elucidate its electromechanical performance, plasma flow dynamics, and EAD jet characteristics. Experimental measurements of key parameters, including current, thrust, power, and effectiveness, were correlated with numerical simulations, demonstrating excellent agreement with a maximum error below 5%. These findings align strongly with established theoretical frameworks, revealing an inverse square root relationship between effectiveness and thrust. To optimize thruster performance, optimal operating voltages were identified at approximately 8.2, 9.4, and 11.6 kV for inter-electrode gap distances of 10, 15, and 20 mm, respectively, achieving a balanced trade-off between thrust and effectiveness. Detailed numerical visualizations of the plasma flow field, including velocity distribution, jet morphology, potential distribution, and electric field lines, provided valuable insights into the thruster's operation. Building upon these insights, a proof-of-concept EAD flier was constructed and tested, incorporating a serrated emitter electrode and lightweight materials. This flier achieved a mass of 0.5 g and generated a thrust of 0.77 g at 15 kV, resulting in a thrust-to-weight ratio of 1.54 and successful liftoff. This demonstration highlights the potential of EAD propulsion for practical MAV applications.

The effect of common parameters of bipolar stimulation on brain evoked potentials

ObjectiveTo identify optimal bipolar stimulation parameters for robust generation of brain evoked potentials (BEPs), namely the interelectrode distance (IED) and the intensity of stimulation (IS), in cortical and axonal stimulation. MethodsIn 15 patients who underwent awake surgery for brain tumor removal, BEPs were elicited at different values of IED and IS, respectively: 5 mm-5 mA, 5 mm-10 mA, and 10 mm-10 mA. The number of BEPs elicited by stimulation, as well as the delays and amplitudes of the N1 waves were compared between the different groups of stimulation parameters and according to the stimulated brain structure (cortical vs. axonal). ResultsThe amplitudes of N1 increased with the intensity of bipolar stimulation, either in cortical or axonal stimulation, while N1 peak delays were not affected by the stimulation parameters. Furthermore, axonal stimulation produced more N1s than cortical stimulation, with lower latencies. ConclusionsUnderstanding the relationship between stimulation parameters and BEP is of utmost importance to determine whether the generated N1 waves accurately reflect the underlying structural anatomy. Other factors, such as stimulation frequency or pulse width and shape, may also play a role and warrant further investigation. SignificanceThis study represents the first step in describing the influence of common bipolar stimulation parameters on robustness of BEPs by examining the impact of IED and IS on the N1 wave.

Removal of Ammonia and Colour from Landfill Leachate using Integrated Electrocoagulation-Zeolite Adsorption Processes

The amount of waste generated in Malaysia had increased annually due to both economic and population accelerations. This resulted in an increase in leachate production that contains a high amount of ammonia nitrogen (NH3-N) and colour, which is a severe problem for both environments as well as for human health. Therefore, this study aimed to determine the potential of Electrocoagulation (EC) – zeolite adsorption for removing NH3-N and colour from landfill leachate. In the experimental works, two batch studies consist of batch EC using aluminium (Al) cylindrical electrode and batch adsorption study using clinoptilolite zeolites adsorbent were conducted using leachate sample collected from Pulau Burung Sanitary Landfill (PBSL). The batch EC experiment was carried out to determine the optimum removal of NH3-N and colour by the effect of current density (7 - 35 mA/mm2), initial pH (5 - 9), electrolysis time (0 - 90 minutes) and inter-electrode distance (5 - 25 mm). An integrated EC - zeolite adsorption was carried out under the optimum condition of 2.0 g/150 mL adsorbent dosage, contact time of 100 minutes and an initial pH value of 8. Based on the experiment, almost 50% of NH3-N and 95% of colour were removed using a single EC under the optimum current density of 14.0 mA/mm2, pH 5, electrolysis time of 75 minutes and 15 mm of inter-electrode distance. A comparison of colour removal between single EC and EC-Zeolite showed the same degradation performance. The interaction of hydrogen ion (H+) with aluminium hydroxide ion (Al (OH)3) produces during EC stabilises small particles forming larger sludge that reduces colour concentration. The removal of NH3-N increased from 50.0% to 93% when EC was integrated with clinoptilolite zeolite adsorption. In conclusion, the results show that both processes can potentially remove colour while the integrated process effectively removes NH3-N from landfill leachate. The proposed treatment helps optimise process performance while minimising the operational cost of the treatment. Thus, the proposed integrated EC – zeolite adsorption processes can be an alternative to landfill leachate treatment which aligns with the 12thMalaysia Plan to reduce pollution and carbon emissions to become a carbon neutral nation as early as 2050.

Flow-Engineered 3-D Printed Electrodes for Alkaline Water Electrolysis

Initially, industrial alkaline electrolyzers had 2-D bipolar plates as electrodes in a configuration in which there is an important physical gap between the electrodes (e.g., 2 mm). This setup presented a high ohmic resistance and is commonly limited to a current density in the order of 0.5 A·cm-2 due to gas screening, i.e., the produced gases form a non-conductive layer over the entire electrode surface, limiting current density. The more advanced designs of today include the use of a zero-gap cell where the interelectrode distance is limited to the thickness of the separator (hundreds of micrometers for diaphragms and tens of micrometers for membranes). Commonly, 2-D electrodes such as perforated plates or an expanded metal mesh are used. As the electrode is pressed against the separator, the gases are forced to be evacuated at the backside of the electrode, avoiding the screening effect. As a consequence, much higher current densities can be achieved. More recently, there has been an increasing interest in the integration of 3-D electrodes in the zero-gap configuration, as they present higher surface areas than their counterpart 2-D electrodes. Nevertheless, bubbles can get trapped inside the intricate 3-D electrode structures. Several strategies are used to mitigate bubble entrapment, including the use of a forced electrolyte flow.The current study aims to investigate the possible electrochemical performance improvement of a single alkaline water electrolysis cell by using 3-D printed electrodes with graded structures, engineered to enhance bubble removal under the effect of a forced electrolyte flow. As the majority of the current is concentrated near the separator, the tailored 3-D printed electrodes present low strut distances and, consequently, a high surface area in this region. Further away from the separator, the distance between the struts gradually increases, decreasing flow-related energy dissipation and avoiding bubble entrapment. This tailored laterally graded structure promotes a difference in pressure along the direction perpendicular to the separator, allowing to extract bubbles from the region near the separator and to evacuate them towards the region with higher strut distances more efficiently. Furthermore, our flow cell was designed to promote a homogeneous upstream flow at the entrance of the electrode. Based on previous findings [1], a Schwarz triply periodic minimum surface was chosen as electrode geometry, as this geometry can channel the flow and reduce bubble-induced ohmic resistance. This geometry is defined by the following mathematical equation: t = sin(2·π·z/L)·sin(2·π·x/L) - 0.4·sin(2.4·π·y/L)·cos(2·π·z/L)·cos(2·π·x/L)with L the periodicity (e.g., an L = 1 mm means that the structure repeats itself in the space at each 1 mm), and t relates to void fraction.Different electrodes with a Schwarz geometry were analyzed in a combined experimental and simulation approach. Electrodes were 3-D printed using selective laser melting, and a strut in the order of 500 μm was achieved. Explicit computational fluid dynamics simulations were performed to estimate bubble residence time and path. Experimental analyses were conducted in a flow-through setup operating under industrial standard conditions of 30 wt% KOH electrolyte at 70°C to elucidate the performance disparities between these structures. Our findings indicate that such tailored 3-D printed electrodes are capable of significantly outperforming previously reported performances in the literature using more stochastic 3-D electrodes like foams. Furthermore, results show that the printed structures are more sensitive to electrolyte flow, presenting an important overvoltage reduction with increase in electrolyte flow rate. We also identified the most critical structural parameters controlling bubble evacuation, thereby significantly reducing the cell's ohmic resistance. Ultimately, this study also emphasizes the critical role of efficient gas evacuation for high-rate alkaline electrolysers using a zero-gap design.[1] Rocha F, Delmelle R, Georgiadis C, Proost J. Electrochemical Performance Enhancement of 3D Printed Electrodes Tailored for Enhanced Gas Evacuation during Alkaline Water Electrolysis. Advanced Energy Materials 2022;13:2203087.

(Invited) Understanding Potential Losses and pH Distribution in Electrochemical Nitrate Reduction Reaction to Ammonia

Electrochemical nitrate reduction reaction (NO3 -RR) to ammonia is a promising route to eliminate one of the major pollutants in surface and groundwater. When powered by renewable electricity, electrolysis provides a sustainable method to generate ammonia from nitrate ions, facilitating the transition from a linear to a circular economy. Optimizing the physical and chemical properties of electrolysis cells is crucial to make this process economically viable for widespread implementation. Here, we explore how the choice of current density, conductivity, pH, inter-electrode distance, membrane, catalyst, and buffer solution affect nitrate removal performance and efficiency. We develop a modeling framework to investigate the cell characteristics and fluid dynamics during electrochemical NO3-RR using both laminar and bubbly flows. To obtain more precise results, we employed the bubbly flow model (i.e., Multi-phase Fluid) to take into account how gas production near the electrode surface affects liquid velocity, pH distribution, and, ultimately, potential losses. We exploit mass transfer theory to include the current density effect on migration and diffusion. In the absence of a buffer solution, the Nernstian loss became a significant portion of the polarization loss, which increased with current density. We identified the positive effect of the membrane on energy efficiency to be more significant at smaller inter-electrode distances. This study provides insights into the origin of potential losses and pH distribution, enabling electrochemical cell optimization for renewable fuel synthesis. Next, we will discuss our recent work on designing single atom alloys (SAAs) for selective conversion of low concentration nitrate ions in natural wastewater streams from Dairy farm into ammonia. We benchmarked the catalyst's selectivity, activity, and stability following standard protocols established in the field of nitrogen fixation, including control experiments by using an electrolyte that does not contain nitrate ions and performing experiments under the same operating conditions using nitrogen isotopes (i.e., 14NO3 -, 15NO3 -).

Применение эволюционных и роевых методов для оптимизации многопараметрического управления процессом нанесения гальванического покрытия

One of the key parameters of the quality of ceramic coatings is its thickness, which must meet technical requirements and provide the necessary degree of corrosion protection, wear resistance and appearance of the coating. Ensuring the uniformity of the galvanic coating is one of the most important and complex tasks of high-tech machine-building production, for which a number of methods have been proposed, such as controlling current modes, the location of electrodes in the bath, and the electrolyte flow rate. However, in most cases, these methods require solving the problem of optimal multiparametric control. Prompt and accurate optimization when changing the conditions of electrolysis (electrode potentials, composition and properties of the electrolyte), as well as, if necessary, taking into account the multi-extreme nature of the dependence of the uniformity coefficient on the process parameters (current density, interelectrode distance, electrolyte flow rate) is a rather complex and ambiguous multifactorial task that limits the use of classical methods for- the claim of a global extreme. The article explores the possibility and expediency of using intelligent heuristic methods, such as evolutionary and swarm methods, to solve this problem. Objective. The objective of this study is to determine the effectiveness of using genetic algorithms and the particle swarm method to solve the problem of optimizing the multiparametric control of the electroplating process. Materials and methods. Methods of mathematical modeling, methods and software environment of numerical modeling and optimization were used to conduct the study. Results. The article investigates the effectiveness of the application of evolutionary and swarm optimization methods in relation to the process of applying chrome plating in a galvanic bath with many anodes with multiparametric control of current density, interelectrode distance and electrolyte flow rate. The best approximation to the extreme of the uniformity coefficient can be achieved by genetic algorithms using the mutation operation and the particle swarm method, while achieving the extreme using the particle swarm method is achieved in fewer iterations. Conclusion. The results of the study substantiate the expediency of using evolutionary and swarm methods to solve the problem of optimizing the multiparametric control of the electroplating process, while it is possible to increase the efficiency of these methods due to additional tuning.

Endovascular stimulation of the pudendal nerve using a stent-mounted electrode array

Objective. Previous preclinical and clinical studies have demonstrated that pudendal nerve is a promising target for restoring bladder control. The spatial proximity between the pudendal nerve and its accompanying blood vessels in the pudendal canal provides an opportunity for endovascular neurostimulation, which is a less invasive approach compared to conventional chronically implanted electrodes. In this study, we investigated the feasibility of excitatory stimulation and kilohertz-frequency block of the compound pudendal nerve in sheep using a stent-mounted electrode array.Approach. In a set of acute animal experiments, a commercially available hexapolar electrode catheter was introduced in the unilateral internal pudendal artery to deliver bipolar electrical stimulation of the adjacent compound pudendal nerve. The catheter electrode was replaced with a custom-made stent-mounted electrode array and the stimulation sessions were repeated. Global electromyogram activity of the pelvic floor and related sphincter muscles was recorded with a monopolar electrode placed within the urethra concurrently.Main results. We demonstrated the feasibility of endovascular stimulation of the pudendal nerve with both electrode types. The threshold current of endovascular stimulation was influenced by electrode-nerve distance and electrode orientation. Increasing the axial inter-electrode distance significantly decreased threshold current. Endovascular kilohertz-frequency nerve block was possible with the electrode catheter.Significance. The present study demonstrated that endovascular stimulation of the pudendal nerve with the stent-mounted electrode array may be a promising less invasive alternative to conventional implantable electrodes, which has important clinical implications in the treatment of urinary incontinence. Endovascular blocking of pudendal nerve may provide an alternative solution to the bladder-sphincter dyssynergia problem in bladder management for people with spinal cord injury.

Comparison of modulation efficiency between normal and degenerated primate retina.

With electrical stimulation, retinal prostheses bypass dysfunctional photoreceptors and activate the surviving bipolar or retinal ganglion cells (RGCs). Therefore, the effective modulation of RGCs is crucial for developing retinal prostheses. Substantial research has been performed on the ability of an electrical stimulus to generate a reliable RGC response. However, different experimental conditions show varying levels of how well the electrical stimulation evokes RGC spikes. Therefore, in this study, we attempted to extract an indicator to understand how the electrical stimulation effectively evokes RGC spikes. Six cynomolgus monkeys were used: three as controls and three as an N-methyl-N-nitrosourea (MNU)-induced retinal degeneration model. The retinal recordings were performed using 8 × 8 multi-electrode arrays (MEAs). Electrical stimulation consisted of symmetrical biphasic pulses of varying amplitudes and durations. The number of stimulation conditions that resulted in significantly higher post-stimulation firing rates than pre-stimulus firing rates was defined as the modulation efficiency ratio (MER). The MER was significantly lower in degenerated retinas than in normal retinas. We investigated the relationship between the variables and the MER in normal and degenerated primate RGCs. External variables, such as duration and inter-electrode distance, and internal variables, such as average firing rates and statistics (mean, standard deviation, and coefficient of variation [CV]) of inter-spike intervals (ISIs) of spontaneous spikes, were used. External variables had similar effects on MER in normal and degenerated RGCs. In contrast, internal variables affected MER differently in normal and degenerated RGCs. While in normal RGCs, they were not related to MER, in degenerated RGCs, the mean ISIs were positively correlated with MER, and the CV of ISIs was negatively correlated with MER. The most important variable affecting MER was the mean ISI. A shorter ISI indicates hyperactive firing in the degenerated retina, which prevents electrical stimulation from evoking more RGCs. We believe that this hyperactivity in degenerated retinas results in a lower MER than that in the normal retina. Our findings can be used to optimize the selection of stimulation channels for in vitro MEA experiments and practical calibration methods to achieve higher efficiency when testing retinal prostheses.

Removal of formaldehyde from the air flow in an electrochemical process

This study employed an electrochemical process to eliminate formaldehyde from contaminated air streams. Various factors that influence the process, including electrode material, inter-electrode distance, air injection site, applied voltage, electrical power, current density, pH, reaction time, electrolyte type, concentration, and formaldehyde's initial concentration were investigated. Findings revealed optimal percentage decrease in concentration (χ), reaching 100 %, using aluminum (Al) electrodes with a 1 cm gap between them. Potassium Persulfate (PP) was found to have superior χ compared to sodium thiosulfate (STH). Regarding the air injection site, the higher χ was noted at the cathode (98.9 ± 0.85 %) than at the anode (95.2 ± 0.99 %). Efficiency escalated from 85.1 % at 7.5 volts to 100 % at 15 volts and, for current density, from 89.18 % at 0.042 amps to 100 % at 0.159 amps. Conversely, efficiency for air flow diminished from 100 % at 0.1 l/min to 27.32 ± 2.7 % at 4.4 l/min. Additional factors were also explored, including removing formaldehyde in the reactor's liquid phase and mineralization. Outcomes suggest that formaldehyde reacts with water, eventually transforming into carbon dioxide. Moreover, the reaction kinetics for both electrolytes demonstrated a tendency toward a second-order kinetic model.

Exploration of sulfamethoxazole removal triggered by copper slag-based geopolymer: Radical versus nonradical contributions

The advanced oxidation processes based on sulfate radicals offer environmental sustainability and exhibit potential for effectively breaking down antibiotics. Among various iron-based materials for activating peroxydisulfate, copper slags are iron-rich raw material and can serve as an excellent catalyst. In this study, acid-activated copper slag-based geopolymers were successfully synthesized using a 1:1 mass ratio of copper slag and metakaolin as raw materials. In the geopolymer based electrocatalytic system, the removal of sulfamethoxazole (SMX) was 99.1 % within 60 mins under the optimized operating conditon of initial pH 3.0, current density of 20 mA/cm2, inter-electrode distance of 3 cm, geopolymer dosage of 1 g/L, and electrolytic concentration of 75 mM/L. The presence of GP provided surface Fe(II) to further activate H2O2 and peroxydisulfate and hence promote the degradation of SMX. Electron paramagnetic resonance spectroscopy, quenching experiments, electrochemical techniques, and probe analysis, were employed to investigate the radical and nonradical pathways within the system. The reactive oxygen species identified in the proposed system included hydroxyl radicals (·OH), sulfate radicals (SO4·-), and singlet oxygen (1O2). SO4·- was the predominant reactive oxygen species, playing a crucial role in the radical pathway with a contribution of 62.1 %. 1O2 was the sole nonradical pathways involved, exerting limit influence on SMX degradation. Additionally, six potential intermediate pathways for SMX degradation were identified. This research not only systematically offers a comprehensive understanding of the oxidation mechanisms in heterogeneous electro-catalytic systems but also demonstrates a high-value utilization strategy of metallurgical industrial solid waste for resource recycling.

Optimization of electrocoagulation process parameters for the treatment of oil industry drill site wastewater.

The effluent from the oil drilling site is a complex mixture of hazardous chemicals that causes environmental impacts on its disposal. The treatment of oil drill-site wastewater has not been explored much, and understanding its characteristics and optimizing the treatment process are required. In the present study, we have optimized the electrocoagulation process with aluminum electrodes for drill-site wastewater treatment. A multi-level factorial center composite design using response surface methodology is applied to optimize the effect of current density (CD), pH, and inter-electrode distance (IED) on chemical oxygen demand (COD) removal. The increasing current density shows a significant increase in COD removal, and a similar trend was observed with a decreased pH. It was found that with current density and inter-electrode distance, the maximum COD removal achieved was 70% at the CD of 19.04mAcm-2 and IED 2.6cm. By varying pH and current density, the COD removal reached up to 90% at pH 6 and CD 19.04mAcm-2. The study shows that the current density is the dominant factor for the process's energy consumption and operating cost, followed by pH. This study's findings could be effectively used to develop large-scale treatment processes through electrocoagulation.

Portable and affordable cold air plasma source with optimized bactericidal effect

The paper reports a low-cost handheld source of a cold air plasma intended for biomedical applications that can be made by anyone (detailed technical information and a step-by-step guide for creating the NTP source are provided). The plasma source employs a 1.4 W corona discharge in the needle-to-cone electrode configuration and is an extremely simple device, consisting basically of two electrodes and a cheap power supply. To achieve the best bactericidal effect, the plasma source has been optimized on Escherichia coli. The bactericidal ability of the plasma source was further tested on a wide range of microorganisms: Staphylococcus aureus as a representative of gram-positive bacteria, Pseudomonas aeruginosa as gram-negative bacteria, Candida albicans as yeasts, Trichophyton interdigitale as microfungi, and Deinococcus radiodurans as a representative of extremophilic bacteria resistant to many DNA-damaging agents, including ultraviolet and ionizing radiation. The testing showed that the plasma source inactivates all the microorganisms tested in several minutes (up to 105–107 CFU depending on a microorganism), proving its effectiveness against a wide spectrum of pathogens, in particular microfungi, yeasts, gram-positive and gram-negative bacteria. Studies of long-lived reactive species such as ozone, nitrogen oxides, hydrogen peroxide, nitrite, and nitrate revealed a strong correlation between ozone and the bactericidal effect, indicating that the bactericidal effect should generally be attributed to reactive oxygen species. This is the first comprehensive study of the bactericidal effect of a corona discharge in air and the formation of long-lived reactive species by the discharge, depending on both the interelectrode distance and the discharge current.

Spatially resolved capacitance-based stress self-sensing in concrete

Spatially resolved capacitance-based stress self-sensing in unmodified concrete has been demonstrated. The spatial resolution is 45 mm in one dimension, which is in the direction of the capacitance measurement. Parallel coplanar component electrodes (aluminum, 5-mm wide), attached to the concrete using double-sided adhesive tape) separated by 45 mm are used to measure the in-plane capacitance in the direction perpendicular to the length of the electrodes. Combinations of component electrodes are electrically connected to form an electrode. The capacitance ranges from ∼200 pF to ∼750 pF. The greater is the number of component electrodes in an electrode, the higher is the capacitance. The compressive loading is applied at selected areas located between adjacent component electrodes. The stress (defined as load divided by the 300 ×300-mm2 concrete area) is up to 3000 Pa. The load decreases the capacitance monotonically and reversibly. The fractional decrease in capacitance ranges from ∼0.1 % to ∼0.5 %. More spatially concentrated loading, as for loading near the edges of the specimen, gives greater fractional decrease in capacitance. The capacitance decreases with increasing inter-electrode distance. Embedded steel rebars with a 20.0-mm concrete cover do not affect the capacitance or capacitance-based sensing.