Interconnect Architecture Research Articles

Tailored Design of a Nanoporous Structure Suitable for Thick Si Electrodes on a Stiff Oxide-Based Solid Electrolyte.

Oxide-based all-solid-state batteries are ideal next-generation batteries that combine high energy density and high safety, but their realization requires the development of interface bonding technology between the stiff solid electrolyte and electrode. Even if the interface could be bonded, it is difficult to hold the interface, because only the electrode expands/contracts unilaterally during charge/discharge reactions. In particular, silicon (Si), which has eagerly awaited as a next-generation negative-electrode material for many years, changes in volume by several hundred percent. To solve these problems, in this work, highly porous silicon oxide (SiOx) electrodes with different porous structures were fabricated on a stiff garnet-type Li7La3Zr2O12 solid electrolyte, the three-dimensional nanoporous structure was analyzed quantitatively, and the charge/discharge characteristics were investigated. The microscopic observation and electrochemical analysis revealed how we should control the porous structure, such as sizes of pores and SiOx, size distribution, and porosity, for repeated and stable charge/discharge cycles. In addition, the resultant porous SiOx electrodes demonstrated superior charge/discharge cycle performance even when it thickened to 5 μm, whereas non-porous SiOx easily peeled off from the solid electrolyte when its thickness exceeded 0.1 μm. The thick SiOx films greatly improved the energy density per unit area (mAh cm-2). Nanosized fine pores with an interconnected open-pore architecture effectively mitigated the internal and interfacial stress upon expansion (charge)/contraction (discharge) of Si, and as a result, the thick and porous SiOx electrode maintained the interfacial joint with the stiff solid electrolyte after repeated charge/discharge cycles. These results will provide useful insights for effectively designing more practical porous SiOx powder effectively.

Microstructural and biological characterization of 3D printed PEEK scaffolds coated with alginate/CNT for bone regeneration applications

The main aim of bone tissue engineering is to develop novel scaffold structures that integrate biological functionality with sufficient mechanical strength and properties. In this study, bone scaffolds were fabricated using polyether ether ketone (PEEK) via 3D printing, resulting in three different porous designs. To enhance their biological attributes, these scaffolds were coated with an alginate and carbon nanotube (CNT) composite using a freeze-drying technique. The biological characteristics of fabricated samples, such as biocompatibility and bioactivity, were evaluated in simulated body fluid (SBF). Field emission scanning electron microscopy (FE-SEM) analysis showed that the 3D-printed PEEK scaffolds had a porous, uniform, and interconnected architecture with pore sizes between 321–378 µm. Energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) confirmed the formation of hydroxyapatite (HA) and bioactive calcium phosphate (Ca-P) on the scaffold surfaces, indicating their bioactivity. Cell biocompatibility was assessed using the MTT assay, which revealed a high cell viability rate of approximately 97% and no significant toxicity. Consequently, the 3D-printed PEEK scaffold coated with Alginate/0.3%wt CNT demonstrated promising microstructure, bioactivity, and biocompatibility, making it suitable for bone tissue regeneration.Graphical abstract

HDF5 in the exascale era: Delivering efficient and scalable parallel I/O for exascale applications

Accurately modeling real-world systems requires scientific applications at exascale to generate massive amounts of data and manage data storage efficiently. However, parallel input and output (I/O) faces challenges due to new application workflows and the state-of-the-art memory, interconnect, and storage architectures considered in exascale designs. The storage hierarchy has expanded with node-local persistent memory, solid-state storage, and traditional disk and tape-based storage, thus requiring efficiency at each layer and much more efficient data movement among these layers. This paper discusses how the ExaHDF5 project improved the I/O performance and data management for exascale architectures by enhancing HDF5, a widely used parallel I/O library. The team developed an Asynchronous I/O Virtual Object Layer (VOL) connector that allowed overlapping I/O with computation. They also created a Cache VOL to complement asynchronous I/O by incorporating fast storage layers, such as burst buffer and node-local storage, into the parallel I/O workflow through caching and staging data. Additionally, the team enabled data aggregation and I/O at the node level by using a Subfiling Virtual File Driver (VFD). To demonstrate superior I/O performance with HDF5 at exascale, the ExaHDF5 team collaborated with several exascale applications. In this paper, we show I/O performance improvements for three applications: Cabana (a particle-based simulation library), EQSIM (a regional earthquake simulation software), and E3SM (a climate system modeling library).

Rotation-invariant image recognition using interconnected floating-gate phototransistor

Rotational invariance is fundamental for robust image recognition systems, ensuring accurate analysis irrespective of image orientation. However, existing systems predominantly reliant on software often encounter challenges such as increased computational demands and compromises between processing speed and accuracy. In this study, we propose leveraging the interconnected floating-gate (FG) structure as an effective hardware-level solution to achieve rotational invariance in image recognition. Our design features a reconfigurable two-dimensional material FG phototransistor array, where each processing unit integrates four sensory devices sharing a common FG. This configuration facilitates uniform distribution of stored charges across the interconnected FG layer, which is typically made of metal, enabling consistent application of a single weight matrix to images across varied rotational conditions. The photoactive material, tungsten diselenide (WSe2), possesses a distinctive bipolar property that facilitates both hole and electron tunneling into the FG layer. This property directly contributes to the efficiency of state transition within the setup and improves its overall adaptability. In this manner, our design achieves stable and predictable outputs in recognizing identical digital numbers regardless of their rotation, while also demonstrating variable performance essential for accurately distinguishing between different digital numbers. This dual capability guarantees both the adaptability and precision required for rotation-invariant image recognition, suggesting that our work may open up a promising venue for exploring advanced hardware designs, such as optimized interconnected FG architectures, tailored for enhancing recognition accuracy and efficiency in the field of intelligent visual systems.

Unidirectional and hierarchical on-chip interconnected architecture for large-scale hardware spiking neural networks

Spiking Neural Networks (SNNs) exhibit the strong capability to address spatiotemporal dynamic problems. Recent research has explored the hardware SNN systems to solve the spatiotemporal problems in real-time. The Network-on-Chip (NoC) is an effective scheme for building large-scale hardware SNNs. However, for the existing NoC-based hardware SNNs, large area overhead and hardware power are consumed by their interconnections, because of complex topologies and router structures. Therefore, in this work a novel Unidirectional and Hierarchical on-Chip Interconnected Architecture (UHCIA) is proposed to address this problem. The proposed UHCIA mainly combines the novel hybrid topology of unidirectional multiple loops and rings, and uses a deflection router technique. Experimental results show that compared to other works, the UHCIA achieves ∼23.6X of area reduction and ∼6.4X of power reduction, with high system throughput and biological real-time computations.

Ruthenium Anchored Laser-Induced Graphene as Binder-Free and Free-Standing Electrode for Selective Electrosynthesis of Ammonia from Nitrate.

Developing effective electrocatalysts for the nitrate reduction reaction (NO3RR) is a promising alternative to conventional industrial ammonia (NH3) synthesis. Herein, starting from a flexible laser-induced graphene (LIG) film with hierarchical and interconnected macroporous architecture, a binder-free and free-standing Ru-modified LIG electrode (Ru-LIG) is fabricated for electrocatalytic NO3RR via a facile electrodeposition method. The relationship between the laser-scribing parameters and the NO3RR performance of Ru-LIG electrodes is studied in-depth. At -0.59 VRHE, the Ru-LIG electrode exhibited the optimal and stable NO3RR performance (NH3 yield rate of 655.9µgcm-2h-1 with NH3 Faradaic efficiency of up to 93.7%) under a laser defocus setting of +2mm and an applied laser power of 4.8W, outperforming most of the reported NO3RR electrodes operated under similar conditions. The optimized laser-scribing parameters promoted the surface properties of LIG with increased graphitization degree and decreased charge-transfer resistance, leading to synergistically improved Ru electrodeposition with more exposed NO3RR active sites. This work not only provides a new insight to enhance the electrocatalytic NO3RR performance of LIG-based electrodes via the coordination with metal electrocatalysts as well as identification of the critical laser-scribing parameters but also will inspire the rational design of future advanced laser-induced electrocatalysts for NO3RR.

Highly Compressible, Superabsorbent, and Biocompatible Hybrid Cryogel Constructs Comprising Functionalized Chitosan and St. John's Wort Extract.

Biobased porous hydrogels enriched with phytocompounds-rich herbal extracts have aroused great interest in recent years, especially in healthcare. In this study, new macroporous hybrid cryogel constructs comprising thiourea-containing chitosan (CSTU) derivative and a Hypericum perforatum L. extract (HYPE), commonly known as St John's wort, were prepared by a facile one-pot ice-templating strategy. Benefiting from the strong interactions between the functional groups of the CSTU matrix and those of polyphenols in HYPE, the hybrid cryogels possess excellent liquid absorption capacity, mechanical resilience, antioxidant performance, and a broad spectrum of antibacterial activity simultaneously. Thus, owing to their design, the hybrid constructs exhibit an interconnected porous architecture with the ability to absorb over 33 and 136 times their dry weight, respectively, when contacted with a phosphate buffer solution (pH 7.4) and an acidic aqueous solution (pH 2). These cryogel constructs have extremely high compressive strengths ranging from 839 to 1045 kPa and withstand elevated strains of over 70% without developing fractures. Moreover, the water-swollen hybrid cryogels with the highest HYPE content revealed a complete and instant shape recovery after uniaxial compression. The incorporation of HYPE into CSTU cryogels enabled substantial improvement in scavenging reactive oxygen species and an expanded antibacterial spectrum toward multiple pathogens, including Gram-positive bacteria (Staphylococcus aureus and Staphylococcus epidermidis), Gram-negative bacteria (Escherichia coli and Pseudomonas aeruginosa), and fungi (Candida albicans). Cell viability experiments demonstrated the cytocompatibility of the 3D cryogel constructs, which did not induce changes in the fibroblast morphology. This work showcases a simple and effective strategy to immobilize HYPE extracts on CSTU 3D networks, allowing the development of novel multifunctional platforms with promising potential in hemostasis, wound dressing, and dermal regeneration scaffolds.

Cryogel with Modular and Clickable Building Blocks: Toward the Ultimate Ideal Macroporous Medium for Bacterial Separation.

The lack of practical platforms for bacterial separation remains a hindrance to the detection of bacteria in complex samples. Herein, a composite cryogel was synthesized by using clickable building blocks and boronic acid for bacterial separation. Macroporous cryogels were synthesized by cryo-gelation polymerization using 2-hydroxyethyl methacrylate and allyl glycidyl ether. The interconnected macroporous architecture enabled high interfering substance tolerance. Nanohybrid nanoparticles were prepared via surface-initiated atom transfer radical polymerization and immobilized onto cryogel by click reaction. Alkyne-tagged boronic acid was conjugated to the composite for specific bacteria binding. The physical and chemical characteristics of the composite cryogel were analyzed systematically. Benefitting from the synergistic, multiple binding sites provided by the silica-assisted polymer, the composite cryogel exhibited excellent affinity toward S. aureus and Salmonella spp. with capacities of 91.6 × 107 CFU/g and 241.3 × 107 CFU/g in 0.01 M PBS (pH 8.0), respectively. Bacterial binding can be tuned by variations in pH and temperature and the addition of monosaccharides. The composite was employed to separate S. aureus and Salmonella spp. from spiked tap water, 40% cow milk, and sea cucumber enzymatic hydrolysate, which resulted in high bacteria separation and demonstrated remarkable potential in bacteria separation from food samples.

Preparation of Autoclavable and Injectable Silk Fibroin Cryogels for Tissue Engineering Applications.

A cryogel is a supermacroporous gel network that is generated at subzero temperatures by polymerizing monomers or gelating polymeric precursors. Since cryogels possess inherent characteristics such asinterconnectedmacroporous structures, excellent mechanical properties,and high resistanceto autoclave sterilization,they are highly desirable for tissue engineering and regenerative medicine. Silk fibroin, a natural protein obtainedfrom Bombyx morisilkworms, is an excellent raw material for cryogel preparation. The aim of this study is toestablish acontrolled method for preparing silk fibroincryogels with suitable properties for application as tissue engineering scaffolds. Using a dual crosslinking strategy consisting of low-temperature radical polymerization coupled with methanol-induced conformational transformation, porous cryogels are prepared. The cryogelsdisplay many unique characteristics, such as an interconnected macroporous structure, a high water absorption capacity, water-triggered shape memory, syringe injectability, and strong resilience to autoclave sterilization. Furthermore, the cryogels demonstrate excellent biocompatibility and cell affinity, facilitating cell adhesion, migration, andproliferation. The interconnected supermacroporous architecture resembling the nativeextracellular matrix, together with their unique physical properties and autoclaving stability, suggests that cryogels are promising candidate scaffolds for tissue engineering and cell therapy.

Large-Eddy Simulations of a Supersonic Impinging Jet Using OpenFOAM

Supersonic impinging jets are a versatile configuration that can model the compressible flows of cold-spray manufacturing and vertical take-off-and landing strategy. In this work, rhoCentralFoam, solver of the OpenFOAM framework, and a large-eddy simulation formulation were used to simulate an underexpanded supersonic jet of Mach 1.45 and nozzle pressure ratio of 4, impinging on a flat wall situated at 1.5 nozzle diameters away from the jet outlet. Care was taken in the mesh construction to properly capture the characteristic standoff shock and vortical structures. The grid convergence index was evaluated with three meshes of increasing spatial resolution. All meshes can generally be considered as sufficient in terms of results focused on time-averaged values and mean physical properties such as centerline Mach number profile. However, the highest resolution mesh was found to capture fine shear vortical structures and behaviors that are absent in the coarser cases. Therefore, the notion of adequate grid convergence may differ between analyses of time-averaged and transient information, and so should be determined by the user’s intention for conducting the simulations. To guide the selection of mesh resolution, scaling analyses were performed, for which the current rhoCentralFoam solver displays a good weak scaling performance and maintains a linear strong scaling up to 4096 cores (32 nodes) for an approximately 40 million-cell mesh. Due to the internode communication bottlenecks of OpenFOAM and improvements in central processing units, this work recommends, for future scaling analyses, adopting a “cells-per-node” basis over the conventional “cells-per-core” basis, with particular attention to the interconnect speed and architecture used.

Ru nanocrystals modified porous FeOOH nanostructures with open 3D interconnected architecture supported on NiFe foam as high‐performance electrocatalyst for oxygen evolution reaction and electrocatalytic urea oxidation

The construction of binder-free electrodes with well-defined three-dimensional (3D) morphology and optimized electronic structure represents an efficient strategy for the design of high-performance electrocatalysts for the development of efficient green hydrogen technologies. Herein, Ru nanocrystals were modified on 3D interconnected porous FeOOH nanostructures with open network-like frameworks on NiFe foam (Ru/FeOOH@NFF), which were used as an efficient electrocatalyst. In this study, a 3D interconnected porous FeOOH with an open network structure was first electrodeposited on NiFe foam and served as the support for the in-situ modification of Ru nanocrystals. Subsequently, the Ru nanocrystals and abundant oxygen vacancies were simultaneously incorporated into the FeOOH matrix via the adsorption-reduction method, which involved NaBH4 reduction. The Ru/FeOOH@NFF electrocatalyst shows a large specific surface area, abundant oxygen vacancies, and modulated electronic structure, which collectively result in a significant enhancement of catalytic properties with respect to the oxygen evolution reaction (OER) and urea oxidation reaction (UOR). The Ru/FeOOH@NFF catalyst exhibits an outstanding OER performance, requiring a low overpotential (360 mV) at 200 mA cm−2 with a small Tafel slope (58 mV dec-1). Meanwhile, the Ru/FeOOH@NFF catalyst demonstrates more efficient UOR activity for achieving 200 mA cm−2 at a lower overpotential of 272 mV. Furthermore, an overall urea electrolysis cell using the Ru/FeOOH@NFF as the anode and Pt as the cathode (Ru/FeOOH@NFF||Pt) reveals a cell voltage of 1.478 V at 10 mA cm−2 and a prominent durability (120 h at 50 mA cm−2). This work will provide a valuable understanding of the construction of high-performance electrocatalysts with 3D microstructure for promoting urea-assisted water electrolysis.

CoS2/carbon network flexible film with Co-N bond/π-π interaction enables superior mechanical properties and high-rate sodium ion storage

Flexible electrodes based on conversion-type materials have potential applications in low-cost and high-performance flexible sodium-ion batteries (FSIBs), owing to their high theoretical capacity and appropriate sodiation potential. However, they suffer from flexible electrodes with poor mechanical properties and sluggish reaction kinetics. In this study, freestanding CoS2 nanoparticles coupled with graphene oxides and carbon nanotubes (CoS2/GO/CNTs) flexible films with robust and interconnected architectures were successfully synthesized. CoS2/GO/CNTs flexible film displays high electronic conductivity and superior mechanical properties (average tensile strength of 21.27 MPa and average toughness of 393.18 KJ m−3) owing to the defect bridge for electron transfer and the formation of the π–π interactions between CNTs and GO. In addition, the close contact between the CoS2 nanoparticles and carbon networks enabled by the Co-N chemical bond prevents the self-aggregation of the CoS2 nanoparticles. As a result, the CoS2/GO/CNTs flexible film delivered superior rate capability (213.5 mAh g−1 at 6 A g−1, better than most reported flexible anode) and long-term cycling stability. Moreover, the conversion reaction that occurred in the CoS2/GO/CNTs flexible film exhibited pseudocapacitive behavior. This study provides meaningful insights into the development of flexible electrodes with superior mechanical properties and electrochemical performance for energy storage.

"Extending Amdahl's and Gustafson Baris's Laws by Adding Communication Overheads"

The extension of Amdahl's law and Gustafson-Barsis' law presented in this article provides insight into the relationship between communication costs and network topology in parallel computing. By considering communication latency in parallel computation execution time, these extensions can help researchers and developers optimize the interconnected network architecture of processing nodes and improve the performance of parallel computing systems. Today, parallel computer systems consisting of hundreds and thousands of processing nodes based on multiprocessor chip technology, high-speed optical transmission such as supercomputers are being researched, developed, and applied in many fields many areas. Although chip technology has progressed to the 3 nm process, the network architecture connecting processing nodes continues to be a problem that greatly affects the communication delay in the parallel computation time of the applications. In this paper, extensions of Amdahl's law and Gustafson-Barsis' law are presented with the addition of communication costs depending on the topology of the topology. These extensions provide insight into the relationship between communication costs and network topology in parallel computing. By considering communication latency in parallel computation execution time, these extensions can help researchers and developers optimize the interconnected network architecture of processing nodes and improve the performance of parallel computing systems.

Ligand-Induced Electronic Structure Modulation of Self-Evolved Ni3S2 Nanosheets for the Electrocatalytic Oxygen Evolution Reaction.

Modulating the electronic structure of the electrocatalyst plays a vital role in boosting the electrocatalytic performance of the oxygen evolution reaction (OER). In this work, we introduced a one-step solvothermal method to fabricate 1,1-ferrocene dicarboxylic acid (FcDA)-decorated self-evolved nickel sulfide (Ni3S2) nanosheet arrays on a nickel foam (NF) framework (denoted as FcDA-Ni3S2/NF). Benefiting from the interconnected ultrathin nanosheet architecture, ligand dopants induced and facilitated in situ structural reconstruction, and the FcDA-decorated Ni3S2 (FcDA-Ni3S2/NF) outperformed its singly doped and undoped counterparts in terms of OER activity. The optimized FcDA-Ni3S2/NF self-supported electrode presents a remarkably low overpotential of 268 mV to achieve a current density of 10 mA cm-2 for the OER and demonstrates robust electrochemical stability for 48 h in a 1.0 M KOH electrolyte. More importantly, in situ electrochemical Raman spectroscopy reveals the generation of catalytically active oxyhydroxide species (NiOOH) derived from the surface construction during the OER of pristine FcDA-Ni3S2/NF, contributing significantly to its superior electrocatalytic performance. This study concerns the modulation of electronic structure through ligand engineering and may provide profound insight into the design of cost-efficient OER electrocatalysts.

Injectable and rapidly expandable thrombin-decorated cryogels achieve rapid hemostasis and high survival rates in a swine model of lethal junctional hemorrhage

Effective therapies are urgently needed to stabilize patients with marginally compressible junctional hemorrhage long enough to get them to the hospital alive. Herein, we report injectable and rapidly expandable cryogels consisting of polyacrylamide and thrombin (AT cryogels) created by cryo-polymerization for the efficient management of lethal junctional hemorrhage in swine. The produced cryogels have small pore sizes and highly interconnected porous architecture with robust mechanical strength. The cryogels exhibit rapid shape memory properties and prove to be resilient against fatigue. These cryogels also show high water/blood absorption capacity, fast blood clotting effect, and enhanced adhesion of red blood cells and platelets in vitro. Further, in vivo, hemostatic efficacy tests in a lethal swine junctional hemorrhage model suggest that treatment with AT cryogels, especially AT-2 cryogels, achieves the least blood loss and the highest survival rate (100 %) compared to currently employed products such as XStat® and combat gauze. The high hemostatic performance of the cryogels may be attributed to highly interconnected porous architecture with small pore size and the use of thrombin as a pro-coagulant agent. Collectively, injectable and rapidly expandable thrombin-decorated polyacrylamide-based cryogels show significant promise as hemostatic material, offering effective management of marginally compressible junctional hemorrhages in prehospital settings.

Design of an Interconnection Architecture and Sizing of Two (2) EPC Core Networks: The Case of Orange-Guinea

Design of an Interconnection Architecture and Sizing of Two (2) EPC Core Networks: The Case of Orange-Guinea

Binder-Free Three-Dimensional Porous Graphene Cathodes via Self-Assembly for High-Capacity Lithium-Oxygen Batteries.

The porous architectures of oxygen cathodes are highly desired for high-capacity lithium-oxygen batteries (LOBs) to support cathodic catalysts and provide accommodation for discharge products. However, controllable porosity is still a challenge for laminated cathodes with cathode materials and binders, since polymer binders usually shield the active sites of catalysts and block the pores of cathodes. In addition, polymer binders such as poly(vinylidene fluoride) (PVDF) are not stable under the nucleophilic attack of intermediate product superoxide radicals in the oxygen electrochemical environment. The parasitic reactions and blocking effect of binders deteriorate and then quickly shut down the operation of LOBs. Herein, the present work proposes a binder-free three-dimensional (3D) porous graphene (PG) cathode for LOBs, which is prepared by the self-assembly and the chemical reduction of GO with triblock copolymer soft templates (Pluronic F127). The interconnected mesoporous architecture of resultant 3D PG cathodes achieved an ultrahigh capacity of 10,300 mAh g-1 for LOBs. Further, the cathodic catalysts ruthenium (Ru) and manganese dioxide (MnO2) were, respectively, loaded onto the inner surface of PG cathodes to lower the polarization and enhance the cycling performance of LOBs. This work provides an effective way to fabricate free-standing 3D porous oxygen cathodes for high-performance LOBs.

Implementations of efficient non-blocking crossbar network with novel multiplexer design in quantum-dot cellular automata

As an emerging nanotechnology, Quantum-dot Cellular Automata (QCA) has attracted extensive attentions due to its characteristics of high density, high speed, and low energy consumption. Modern high-performance System-on-Chips (SoCs) with multiple processors require interconnection networks to connect each core for improving data throughput and reducing latency, while the crossbar network is broadly used as a non-blocking interconnection architecture with high efficiency. In this paper, a method to design an efficient QCA-based N × N crossbar network utilizing optimally designed N:1 multiplexers (MUXs) is proposed, followed by a multi-layer and a single-layer implementation of its 8 × 8 design. A simplified matrix model is then introduced to provide a concise and intuitive switch control strategy, and expressions for cell count, area, latency, QCA cost, and QCA complexity of the proposed crossbar networks are derived according to the size N. Experimental results manifest that the proposed 8 × 8 crossbar networks have significant advantages on most performance parameters compared with other existing QCA-based networks.

Robust and multifunctional MXene/rGO composite aerogels toward highly efficient solar-driven interfacial evaporation and wastewater treatment

Given the ever-growing global water resource crisis, exploiting multifunctional materials featuring with high interfacial solar steam generation efficiency and good purification capability to achieving seawater desalination and wastewater treatment simultaneously are highly desired, yet it still remains a huge challenge to date. Herein, robust and multifunctional MXene/rGO (MRGA) and polydopamine & chitosan @ MRGA (CS&PDA@MRGA, CPM) three-dimensional composite aerogels with distinct interconnected cellular architecture were developed via a facile ice template-assisted chemical reduction self-assembly technology and subsequent sequential deposition modification. Due to the favorable graphene oxide-assisted assembly behavior, the resultant aerogels displayed a desirable mechanical robustness along with an excellent lightweight property. Benefiting from the strong electrostatic interaction deriving from aerogel surface moieties and dye molecules, MRGA-12 exhibited a prominent adsorption capability towards various dyes and achieved a superb adsorption capacity of up to 396.05 mg/g for malachite green (MG). Moreover, by virtue of the synergistic effect between the intentionally regulated low reduction degree of rGO and the integration of PDA and CS, CPM-12 achieved a dramatically reduced evaporation enthalpy of water from 2256 to 1617.18 J/g. Accordingly, this distinct feature resulted in an extraordinary solar-driven interfacial evaporation performance with a remarkable evaporation rate of 1.86 kg/m2/h and a high evaporation efficiency of 83.28 % under 1 sun illumination. Therefore, together with the terrific oil/water separation capability, these novel MXene-based aerogels hold a great potential for high-performance solar-driven interfacial evaporation and wastewater treatment.

Unlocking the potential of optimal etching and ion exchange concentration in post-synthesis of binder-free NiCo-MOFs for high-performance supercapacitors

In this study, we synthesized binder-free NiCo-MOFs electrodes on a flexible stainless-steel substrate (abbreviated as NCMS) using a post-synthesis approach that involves etching and an ion-exchange method. Herein, different concentrations of the nickel precursor, specifically 0.01 M (NCMSA), 0.05 M (NCMSB), 0.10 M (NCMSC), and 0.15 M (NCMSD), were employed to optimize the concentrations of the nickel precursor involved in etching and ion exchange method for Supercapacitors (SCs). Structural, morphological, compositional, and electrochemical characteristics of NCMS electrodes were studied. Morphological investigation unveiled a porous interconnected sheet-like architecture of NiCo-MOFs electrodes which is highly advantageous for SCs. Notably, the NCMSB electrode exhibited outstanding electrochemical performance, achieving a highest specific capacity (Csp) of 206 mAh/g (1487 F/g) at 5 mV/s; along with a 54.42 % retention rate after 3000th cycles at 100 mV/s. Additionally, NCMSB demonstrated superior power density (Pd) and energy density (Ed) of 2500 W/kg and 43.68 Wh/kg respectively. The power law was employed to examine the charge storage kinetics of the NCMSB electrode. Moreover, a symmetric aqueous device fabricated and evaluated for its electrochemical performance, exhibiting maximum Cs of 22 F/g (9.01 mAh/g) at 10 mV/s. The device exhibited a good Pd of 389 W/kg and Ed of 3.14 Wh/kg at 1 A/g, maintaining 69 % retention over 3000th cycles at 15 A/g. The current findings highlight the significance of etching and ion-exchange concentrations of nickel precursor during the post-synthesis of NiCo-MOFs electrode to achieve high supercapacitive performance.