Intercept Age Research Articles

Late Neoarchean high-grade regional metamorphism in the eastern North China Craton: New constraints from monazite dating in northern Liaoning

Late Neoarchean tectono-thermal events in the eastern North China Craton have been comprehensively characterized in terms of mineralogy, petrology, geochemistry, metamorphic evolution, geophysics and geochronology. The Late Neoarchean metamorphic event is debated to correlate with vertical and/or horizontal tectonism, potentially an indicator as initiation of plate tectonics. With a growing number of zircon geochronological investigations, the precise timing of the Late Neoarchean metamorphic event should be questioned due to the complexity of post-Archean multiple tectono-thermal overprints. Here we demonstrate the capabilities of LA–ICP–MS U–Pb and LA–MC–ICP–MS Sm–Nd isotope measurements applied to monazite endowed with LREE-enriched geochemical peculiarities as well as zircon U–Pb–Hf isotope, to reevaluate the Late Neoarchean metamorphic event in northern Liaoning, eastern North China Craton. Monazites within the biotite two-feldspar gneiss from the Qingyuan greenstone belt are Ce-monazite in composition, with negligible amounts of the huttonite and brabantite components. The internally homogeneous and anhedral rounded granular monazites show textural equilibration in contact with plagioclase, quartz, and K-feldspar, indicating that monazite is a product of metamorphism. The apparent ages and Eu/Eu* values of monazite analyses show a positive correlation, which confirms the continuous formation of monazite and coeval feldspar during the metamorphic evolution. These metamorphic monazites yield a weighted mean 207Pb/206Pb age of 2493 ± 8 Ma and an upper intercept age of 2496 ± 8 Ma, consistent with the metamorphic zircon dates of 2492–2468 Ma. These results, along with monazite Sm–Nd isochron of 2459 Ma, thus provide a critical clue to understand the Late Neoarchean high-grade regional metamorphism in the eastern North China Craton. As a consequence, the Qingyuan greenstone belt was only partially influenced by the Paleoproterozoic tectono-thermal events, not largely as previously thought by some workers.

Exhumation of plutons controlled by boundary faults: Insights from the kinematics, microfabric, and geochronology of the Taibai shear zone, Qinling Orogen, China

Abstract The Taibai granitic plutons lie between the Taibai ductile shear zone to the north and the Shangdan suture to the south. The deformation mechanism of the ductile shearing is crucial to understanding the exhumation processes of the multiple plutons that formed after the Late Mesozoic period. Geological investigations, microstructures, and kinematic vorticity calculations indicate that the Taibai shear zone deformed in response to pure shear-dominated (54%–65%) transpression and top-to-NW shear sense as a result of NE–SW oblique contractional tectonics. The quartz crystallographic preferred orientations of the prism <a> slip system, the grain boundary migration, and sub-grain rotation dynamic recrystallization of quartz—combined with the plagioclase–hornblende thermometer—constrain the main deformation temperatures to a range of 400–650 °C, which suggests amphibolite to greenschist facies conditions. In addition, it is extremely likely that the mylonites experienced late-stage, lower temperature deformation as demonstrated by the sporadic bulging recrystallization, the quartz basal <a> slip system, and the two-feldspar geothermometer calculation. The samples collected from the weakly deformed mylonitic granite pluton and the undeformed quartz-feldspathic dike that intruded into the mylonites yield zircon U–Pb ages of 129 ± 1 Ma and 115 ± 1 Ma, respectively. This information, with the lower intercept ages of ca. 120 Ma obtained from the mylonite samples, suggests that the ductile shearing probably occurred from ca. 129 Ma to 115 Ma. Combined with the regional geological data, these findings suggest that the Taibai shear zone and the Shangdan suture accommodated the oblique upward extrusion of the Taibai plutons during Early Cretaceous time.

Mafic-ultramafic suite from the Karwar Block, SW India: Implications for Mesoarchean geodynamics

Archean mafic–ultramafic rocks provide important clues on the tectonic and crust building processes in the early Earth. The Western Dharwar Craton (WDC) and the Karwar Block (KB) in southern Peninsular India preserve some of the oldest records of craton building processes in the Archean Earth. The tectonic affinity of the Karwar Block that lies at the western periphery of the WDC remains uncertain. Here we present the results from an integrated study of a mafic–ultramafic rock suite from this block using petrology, whole-rock geochemistry, and zircon U–Pb and Lu-Hf data. These rocks occur as deformed and dismembered units within basement granitic gneiss. The primary igneous minerals such as pyroxene and plagioclase show variable degrees of alteration. The rocks show negative Nb anomalies and prominent Pb enrichment. The uniform enrichment of Th and U over Nb-Ta indicates the influence of metasomatic fluids in the mantle wedge. The geochemical data indicate that these rocks were derived from basaltic magmas generated within a subduction metasomatised mantle wedge in an intra-oceanic arc setting without any significant crustal contamination. U-Pb isotope analysis of zircon grains from the metapyroxenite shows upper intercept ages of 3172 to 3213 Ma and weighted mean ages of 3170 to 3203 Ma. A metagabbro sample yielded upper intercept age of 2792 Ma and the 207Pb/206Pb spot ages in another sample range up to 3202 Ma. Zircon U-Pb data suggest that the mafic–ultramafic suite formed at ca. 3.2 Ga and were overprinted by 2.7 Ga thermal event. The εHf(t) values are all positive and range between 0.73 and 6.02, suggesting that the magma was derived dominantly from Mesoarchean juvenile (depleted mantle) sources. We propose a tectonic model that involves a subduction-accretion stage followed by suturing of the ancient continental nuclei.

U-Pb isotopic dating of cassiterite: Development of reference materials and in situ applications by LA-SF-ICP-MS

Cassiterite, the economically most important tin mineral, typically has moderate U and variable common Pb contents, making it amenable for UPb dating. Cassiterite has extremely low Th/U ratios (Th/U < 0.01) and its 208Pb is dominantly common Pb. This is particularly helpful as there is significant interference of tungsten oxides on 202Hg and 204Pb. The feasibility of the 208Pb correction procedure is discussed in detail. The 208Pb corrected LA-SF-ICP-MS data are in good agreement with intercept ages in the Tera-Wasserburg diagram and 207Pb corrected ages.Twelve cassiterite samples were investigated using the ID-TIMS and LA-SF-ICP-MS methods. The ID-TIMS results of Pit-AB, Rond-A, RG-114, BB#7 and 19GX cassiterite are reported for the first time in this study. RG-114, BB#7 and 19GX cassiterite have very low common Pb contents and are recommended for use as primary reference materials for in situ cassiterite. Pit-AB, Rond-A and Yankee cassiterite contain a small amount of common Pb, produce reliable and consistent ages and are suitable as primary reference materials. The remaining five cassiterite samples (Kard, Zinnwald, Els, XBD-W and Y724) were only investigated using the LA-SF-ICP-MS method and produce ages consistent with published age data from the host rocks associated with the tin deposits and with published UPb ages of cassiterite from the same deposits. We present an ID-TIMS UPb of 154.3 ± 0.7 Ma for the commonly used cassiterite reference material AY-4. This age differs from previously reported ID-TIMS ages. This age discrepancy is caused by different initial common Pb compositions rather than age heterogeneity.

U-Pb VEIN CALCITE DATING REVEALS THE AGE OF CARLIN-TYPE GOLD DEPOSITS OF CENTRAL YUKON AND A CONTEMPORANEITY WITH A REGIONAL INTRUSION-RELATED METALLOGENIC EVENT

AbstractLaser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb dating of hydrothermal calcite associated with the waning stage of mineralization is used to constrain the age of Neoproterozoic-hosted Carlin-type gold deposits in central Yukon, Canada. Samples exhibiting minor textural complexity show low dispersion of individual spot analyses and define Tera-Wasserburg lower intercept ages between 75.1 ± 2.5 and 71.2 ± 4.3 Ma. Samples with U-rich microfractures and/or a second generation of calcite associated with vein reopening record the primary stage of calcite growth related to hydrothermal activity at ca. 74 Ma and a younger ca. 48 Ma event related to fluid-assisted U mobility. The minimum age for mineralization at ca. 74 Ma overlaps with a maximum age based on a zircon U-Pb date of 74.1 ± 1.0 Ma for a gabbro dike that is locally altered and mineralized. These time constraints indicate that mineralization is ca. 74 Ma and penecontemporaneous with dike emplacement. Furthermore, mineralization is contemporaneous with a regional gold-bearing, intrusion-related, metallogenic event in eastern Alaska and central Yukon. This temporal link between Carlin-type mineralization and other mineralization types bears similarities with world-class sedimentary rock-hosted gold deposits of Nevada. This study demonstrates the potential of using LA-ICP-MS U-Pb dating on calcite to constrain the age of mineral deposits lacking synmineralization minerals amenable to classic dating techniques.

Evolution of the Neoarchean lower crust beneath Western Liaoning of the North China Craton: Evidence from U-Pb-Hf-O isotopes in zircon

A comprehensive analysis of U-Pb geochronology and Hf-O isotopes of zircons from granulite xenoliths hosted in the Cretaceous basalt and zircon xenocrysts in the Jurassic andesitic volcanic rocks of Western Liaoning within the North China Craton (NCC) provides an opportunity to understand the evolution of the lower crust in the region. Zircons from these granulites yield 207Pb/206Pb ages of 1678–2646 Ma and consistent upper intercept ages of 2514–2544 Ma. In contrast, zircon xenocrysts yield two periods of 207Pb/206Pb ages of Neoarchean (2500–2591 Ma) and Paleoproterozoic (1733–2499 Ma), which produce consistent upper intercept ages of 2543–2549 Ma and lower intercept ages of 1761–1789 Ma, respectively. The Neoarchean zircons from the granulites and xenocrysts generally have similar positive εHf(t) values resulting in Hf depleted mantle model ages (TDM) of 2.5–2.9 Ga with a mode of 2.7 Ga and variable δ18O (5.05‰ to 8.81‰) values. However, the δ18O values of zircons from the xenocrysts are a little bit higher than those of zircons from granulites (peak of 8.00‰ for the xenocrysts and 6.00‰ for the xenoliths). Some Paleoproterozoic zircon xenocrysts have negative εHf(t) values (−12.8 to −9.39) and similar 176Hf/177Hf ratios and δ18O values to those of the Neoarchean zircons, whereas the other Paleoproterozoic zircons show chondritic εHf(t) (−4.34 to 1.16) and higher δ18O (7.70‰ to 10.19‰) values. All these data demonstrate that the primordial lower crust beneath Western Liaoning originally formed in the Neoarchean, perhaps around 2.6–2.7 Ga. The ubiquitous presence of ca. 2.5 Ga magmatic zircons illustrates that an important melting event indeed happened in the lower crust beneath Western Liaoning, similar to the thermal event throughout the entire NCC. In addition, the Neoarchean lower crust underwent another important thermal event during the Paleoproterozoic, which was considered to be associated with the final amalgamation of the Western and Eastern blocks of the NCC. Thus, we can conclude that there indeed existed an Archean lower crust beneath the Western Liaoning until to the Late Mesozoic, and this Archean lower crust underwent a similar multiple-stage (Neoarchean and Paleoproterozoic) evolutionary history as those throughout the NCC.

Experimental Annealing of Zircon: Influence of Inclusions on Stability, Intracrystalline Melt Migration, Common Lead Leaching, and Permeability to Fluids.

Zircon derived from crustal rocks can survive dissolution into hot basalts during magma hybridization and rock assimilation if it is shielded as an inclusion phase in early-formed phenocrysts or in minerals from non-disaggregated xenoliths. Under these conditions, zircon can be thermally shocked, triggering recrystallization of metamict domains and reaction with its hosted mineral inclusions. This work simulates this process by performing thermal annealing experiments on zircon grains with variable degrees of metamictization. These were embedded in cristobalite powder under a N2 atmosphere at 1 bar and 1300 °C. The thermal annealing produces recrystallization of metamict domains, melting of multi-phase mineral inclusions, nanopore formation, and microcrack propagation by thermo-elastic stress. The porosity enhances intracrystalline melt mobility, leaching out trace-element and mineral impurities. Baddeleyite was formed at temperatures below the thermal decomposition of pure zircon by two mechanisms: (i) recrystallization of metamict domains assisted by silica migration from the reaction site and (ii) incongruent zircon dissolution into molten mineral inclusions with a high CaO/SiO2 ratio. Highly metamict zircons with elevated common Pb and radiogenic Pb loss, which were impossible to date with SHRIMP, lost all their common Pb and some radiogenic Pb upon annealing, producing well-fitted discordias with a significant upper intercept age.

Late Miocene magmatic‐hydrothermal system and related Cu mineralization of the Arakawa area, Akita, Japan

AbstractThe Northeast Japan arc hosts a number of hydrothermal vein‐type copper deposits associated with Neogene felsic intrusions. The Arakawa area is underlain by Cretaceous granites and Tertiary sedimentary rocks, which were intruded by the Miocene Ushizawamata dacite. Zircon grains from the dacite intrusion yield a 206Pb/238U intercept age (laser ablation inductively coupled plasma mass spectrometry) of 8.10 ± 0.30 Ma, consistent with a previously reported K‐Ar illite age (8.1 ± 0.4 Ma) of the Ushizawamata lead and zinc prospect in the Arakawa area. The dacite intrusion and the surrounding Miocene sedimentary rocks were altered by hydrothermal activity on the surface, classified into four alteration zones: (1) biotite‐chlorite, (2) illite, (3) chlorite and (4) smectite, centered on the intrusion. About 20 major vertical sub‐parallel copper‐bearing quartz veins occur in the chlorite alteration zone on the west side of the dacite. The first vein stage is composed of chalcopyrite and chamosite with a minor amount of quartz in brecciated wall rocks, and the second‐stage is characterized by the presence of hematite in addition to the first‐stage mineral assemblage. The third‐stage consists of comb‐shaped quartz veins with a minor amount of chalcopyrite, sphalerite, galena and pyrite, and the fourth‐stage of barite and apatite present in druse in the third‐stage veins. Primary fluid inclusions in quartz of the first‐ and third‐stages are all liquid‐rich and two‐phase. Homogenization temperature and salinity of first‐stage quartz are 263–277°C and 5.7–7.5 wt% NaCl equivalent (eq.); in quartz of the third‐stage, 251–270°C and 2.7–4.2 wt% in the inner zone and 207–250°C and 2.7–3.7 wt% in comb‐shaped quartz on the vein margin. The fluid inclusions in quartz phenocrysts of the Ushizawamata dacite show two distinct assemblages, halite‐bearing polyphase inclusions that coexist with vapor‐phase inclusions and/or vapor‐rich two‐phase inclusions, and liquid‐rich two‐phase inclusions. Homogenization temperature and salinity of the polyphase inclusions are higher than 401°C and 46.7 wt%, respectively, and those of the vapor‐rich two‐phase inclusions report 393–419°C and 2.6–3.7 wt% NaCl, whereas the liquid‐rich two‐phase inclusions returned 344–403°C and 8.0–9.3 wt%, respectively. These results indicate that the ore forming fluid was slightly cooler and lower in salinity than the late‐stage hydrothermal fluid in the Ushizawamata intrusion. The spatial and temporal proximity between the Ushizawamata dacite and the hydrothermal veins indicates that the dacitic magma was genetically related to the vein copper mineralization in the Arakawa area.

Linking uplift and mineralisation at the Mount Novit Zn-Pb-Ag Deposit, Northern Australia: Evidence from geology, U–Pb geochronology and sphalerite geochemistry

The subeconomic Mount Novit Zn-Pb-Ag deposit is located approximately 20 km south of Mount Isa, Queensland. In contrast to the nearby Mount Isa, Hilton and George Fisher Zn-Pb-Ag deposits, mineralisation at Mount Novit is situated to the west of the regional-scale Mount Isa Fault and is hosted in the Moondarra Siltstone as opposed to the Urquhart Shale. Lower-grade (<4 wt.% Zn + Pb) Zn-Pb-Ag mineralisation primarily replaces pre-existing carbonate alteration and veining and consists of pyrrhotite, pyrite and sphalerite with lesser galena. Higher-grade (>10 wt.% Zn + Pb) mineralisation occurs as a matrix supported breccia dominated by sphalerite and pyrrhotite with galena, pyrite, and magnetite. In-situ U–Pb geochronology was completed on apatite and two textural varieties of monazite. Fine-grained (<50 µm) subhedral to anhedral monazite is located within highly foliated biotite alteration directly adjacent Zn-Pb-Ag mineralisation and yields a mean weighted 207Pb/206Pb age of 1527 ± 18 Ma (MSWD = 1.06). This age is consistent with the formation of highly foliated biotite alteration during D3 deformation of the Isan Orogeny. Apatite from the same fabric yields a lower intercept age of 1443 ± 29 Ma (MSWD = 1.30). Consistent with previous studies, this age is interpreted to represent the age of a major thrusting event along the Mount Isa Fault that resulted in the cooling of the Mount Novit area below ∼375 °C. Coarse-grained monazite is coeval with Zn-Pb-Ag mineralisation and yields a mean weighted 207Pb/206Pb age of 1457 ± 11 Ma (MSWD = 0.28). Sphalerite from Mount Novit has low concentrations (<1 ppm) of Ge and Ga and a relatively high concentration of In (5 to >10 ppm), possibly reflecting the leaching of the metals from an underlying basement unit. The GGIMFis geothermometer (Frenzel et al., 2016) produced a mean formation temperature of 345 ± 52 °C. The timing and temperature of Zn-Pb-Ag mineralisation is consistent with the age and cooling temperature of apatite presented in this study. Based on these correlations, we suggest that Zn-Pb-Ag mineralisation at Mount Novit was emplaced during an episode of major thrusting along the Mount Isa Fault, with the precipitation of Zn-Pb-Ag mineralisation driven by the cooling of the Mount Novit area below ∼375 °C. A key implication of this study is a new model for synorogenic Zn-Pb-Ag mineralisation to the south of Mount Isa, which contrasts with the widely accepted regional-scale syngenetic metallogenic model.

Metamorphism of retroeclogites from the Passos Nappe, Southern Brasília Orogen

High-pressure metamafic rocks from the Passos Nappe, Southern Brasília Orogen, have been traditionally interpreted as highly retrogressed eclogites, even though no reliable P-T conditions were available thus far. In this work, samples from the least retrogressed sample were studied using petrography, mineral and whole-rock chemical analysis, thermodynamic modelling, and rutile U–Pb geochronology, with the objective of unravelling its metamorphic history. The studied rocks are, descriptively, hornblende-garnet-clinopyroxene schists. Garnet and hornblende occur in a matrix composed of clinopyroxene-plagioclase symplectite, with garnet being surrounded by plagioclase-hornblende coronas. A combination of thermodynamic modelling, Zr-in-rutile and Ti-in-quartz thermobarometry suggests peak temperature to be 725 ± 30 °C, attained at a minimum pressure of ≈16 kbar, and data from rutile and quartz crystals included in garnet qualitatively indicate an earlier stage at higher P and lower T, constraining a clockwise P-T path. No evidences of UHP metamorphism were found thus far. A lower intercept age of 579 ± 23 Ma was calculated from rutile data, which is identical, within uncertainty, to rutile ages obtained previously in units immediately above the rocks studied here. The data suggests that these rocks were submitted to a different P-T path compared to the adjacent units, and that they were subducted to depths of at least ≈60 km and tectonically emplaced amid the surrounding metapelitic rocks before 579 Ma, which is compatible with current models for the evolution of the Southern Brasilia Orogen.

Apatite fingerprints on the magmatic-hydrothermal evolution of the Daheishan giant porphyry Mo deposit, NE China

Abstract Porphyry deposits are the main source for global Cu and Mo production. The generation of hydrous silicate magmas and subsequent separation of volatile-rich magmatic fluids with hydrothermal alteration are significant processes leading to the formation of porphyry deposits. However, a specific understanding of these processes has been limited by a lack of direct mineralogical records in the evolving magmatic-hydrothermal system. In this paper, we present an integrated textural and geochemical investigation on apatite from the giant Daheishan porphyry Mo deposit in NE China, illustrating that apatite can be a potential recorder of the magmatic-hydrothermal evolution of porphyry systems. Apatite from the ore-forming porphyry displays distinctive core-rim textures, with melt inclusions in the resorption cores (Type-A1) and co-existing of melt and fluid inclusions in the euhedral rims (Type-A2), indicating a magmatic-hydrothermal origin of apatite. This is also supported by both chemical and isotopic compositions obtained by in situ analyses using laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) and LA-multi collector-ICP-MS. The late Type-A2 apatite is relatively enriched in incompatible elements, such as rare earth elements (REE) and Th, but slightly depleted in fluid-mobile elements such as Na and S, compared to the early Type-A1 apatite. Relatively homogeneous (87Sr/86Sr)i ratios (0.70436–0.70504) of the Type-A1 and Type-A2 apatites indicate that they were formed in a relatively closed system without detectable contamination. Meanwhile, some apatite in the wall rock (biotite granodiorite) shows characteristics of secondary altered textures, resulting from the intensive alteration by hydrothermal fluids exsolved from the porphyry system. Apatite trapped in mineral phenocrysts of the wall rock is usually unaltered (Type-B1 apatite), with clear oscillatory growth zones in cathodoluminescence (CL) images. In contrast, the intergranular apatite is commonly altered (Type-B2 apatite), with chaotic zoning in CL images, abundant micro-fractures and secondary fluid inclusions. Compositionally, the Type-B2 apatite shows notable tetrad REE patterns, relatively lower light-REE and S contents, and elevated 147Sm/144Nd ratios compared to the Type-B1 apatite. LA-ICP-MS U-Pb dating yields a lower intercept age of 171.4 ± 2.3 Ma for Type-B2, which is consistent with the age of 171.5 ± 2.4 Ma for Type-A2, but is notably younger than the Type-B1 apatite (175.5 ± 1.3 Ma). It is suggested that the Type-B2 apatite has been significantly reset by hydrothermal fluids exsolved from the porphyry system. Therefore, we conclude that the textures and geochemistry of apatite in porphyry systems can be used as a potential proxy for recording fluid exsolution and hydrothermal alteration processes.

Three distinct Archean crustal growth events as recorded from 3.48 Ga migmatite, 2.70 Ga leucogranite, and 2.54 Ga alkali granite in the Bundelkhand Craton, Central India

Field relations, microstructures, phase petrology, elemental geochemistry, and zircon U-Pb geochronology of migmatites and (undeformed) granites (sensu lato) from the Central Bundelkhand Tectonic Zone (CBTZ) of the Bundelkhand Craton, central India are investigated to understand the age and origin of these rocks. Anatexis of felsic proto-crust produced in situ leucocratic melts with entrained residual assemblages, forming the metatexite and diatexite in the migmatite. The chemistry of biotite (XFe = 0.65–0.72) from the leucosome of migmatite supports its crystallization in a peraluminous felsic melt more likely in a syn-collisional tectonic setting. The residual amphibole in the leucosome from migmatites belongs to metaluminous (I-type) calc-alkaline protocrust source that originated in a subduction setting. Biotites (XFe = 0.80–0.81) and amphiboles (XFe = 0.84–0.87) from granites exposed proximal to the CBTZ, suggest alkaline (A-type) nature of the host magma, emplaced at mid-crustal depth (3.79–4.73 ± 0.5 kbar). Whole-rock geochemistry of migmatite reveals the magnesian nature of melt formed by differential degrees of melting of heterogeneous sources (i.e., TTG and mafic crust), at 12–14 kbar. The alkali granite was likely formed by the anhydrous melting of ancient felsic crustal rocks. U-Pb geochronology of inherited magmatic zircon cores (Th/U = 0.06–0.48) from migmatite yielded an upper intercept age of 3478 ± 48 Ma interpreted as zircon crystallization age in the protolith. The zircon rims of magmatic origin (Th/U = 0.06–0.72) grown over the 3.48 Ga old zircon cores provide an upper intercept age of 2700 ± 16 Ma; interpreted as zircon crystallization age in a leucocratic melt. This is synchronous with the timing of intense deformation/collision and the melting event in the CBTZ. Zircons (Th/U = 0.26–0.92) from alkali granite yielded a weighted mean crystallization age of 2539.9 ± 6.6 Ma without any noticeable zircon inheritance. The Bundelkhand Craton probably experienced at least two phases of collision-accretion orogens, the first one initiated at ca. 2.8 Ga with arc-related magmatism and ended with ca. 2.7 Ga collision-related felsic magmatic record. The second phase began with ca. 2.58 Ga subduction-related magmatism and culminated at ca. 2.54 Ga with a minor amount of post-collisional, alkali granite magmatism.

Metamorphic evolution of the juvenile Serrinha forearc basin in the southern Brasiliano Orogen

Understanding the accretion of an oceanic island arc to a craton is a major issue in unravelling the evolution of the continents. P-T-t conditions registered in metamorphic rocks, the boron isotopic compositions of tourmaline provide essential information to delimit the accretionary processes. The Tonian-Cryogenian São Gabriel Terrane is a prominent juvenile structure in the southern Brasiliano Orogen that records key information about accretionary processes. Limited previous studies have investigated the São Gabriel Terrane, with little presently known about the metamorphic conditions. To pursue the objective, we combined multiple methods, including pseudosection modeling, U-Pb garnet geochronology and δ11B isotopes of tourmaline applied to one key sample from the Serrinha Formation of the São Gabriel Terrane. The recorded peak P-T conditions occurred at 4.5–5.1 kbar and 536–555 °C. U-Pb dating of low-U (<1 ppm) garnet yielded a lower intercept age of 721 ± 14 Ma for the bulk garnet growth. Dravite isotopic δ11B (+0.51 to + 3.39) compositions indicate oceanic crust components present in the island arc rocks. The calculated P-T conditions correspond to the metamorphic peak from heat pulses during burial events. Collision and thrusting of the São Gabriel arc against and over the Rio de La Plata Craton occurred at 721 ± 14 Ma. The evaluation of the parameters obtained in this study indicate a Barrovian-type evolution and a Late Tonian age of metamorphism for the Serrinha Basin. The sedimentation of the Serrinha Basin occurred in a forearc basin of the São Gabriel island arc. Collision of the oceanic arc with the craton is thus better constrained. Our study contains one point in the evolution of the protracted, complex amalgamation of the supercontinent Gondwana during the Brasiliano Orogeny.

Geochemical and geochronological evidence of meteorite impact excavating the Archean basement at Lonar Crater, Central India

The effect of meteorite impact on basement rocks remains widely debated at Lonar Crater, Central India. We investigate an impact melt-bearing rock from the ejecta layer of Lonar to assess the potential interaction of the projectile with the underlying Archean basement. The investigated sample is a melanocratic, aphanitic melt rock comprising glassy inclusions, and plagioclase and quartz clasts. Plagioclase and quartz show shock-induced features including diaplectic glass and well-developed planar deformation features (PDFs), respectively. The decrease in shock pressure is thus established with the plagioclase of overlying basalt showing shock features like diaplectic glass whereas the quartz from lower Archean basement showing PDF development. Laser Raman spectroscopy reveals the presence of cristobalite. The impact melt-bearing rock shows major element geochemistry similar to that of Deccan basalt with a tholeiitic trend, but the Harker variation plots reveal an independent field for the melt rock between the two end members: Deccan basalt and Archean basement represented by Peninsular gneiss. The REE geochemistry also reveals more fractionation for the melt rock. Zircon U-Pb data indicate an upper intercept age around 3.0 to 3.1 Ga. Chondrite normalized zircon REE data display a positive Eu anomaly indicating a reheating during the impact event. This indicates that the melt rock sample was generated by the incorporation of Archean basement gneiss components, which is compatible with the estimated depth of excavation for an impact structure of this size. This specifies a depth to basement in the range between 522 and 570 m.

The Troia–Pedra Branca mafic–ultramafic complex, Borborema Province, Brazil: Record of 2.04 Ga post–collisional Alaskan–type magmatism and PGE mineralization

The Troia–Pedra Branca complex is the most extensive exposure of mafic–ultramafic rocks in the Borborema Province, northeastern Brazil. These rocks have been known for a long time, particularly because of their platinum group element (PGE) mineralization associated with chromitites. The Troia–Pedra Branca complex consists of a succession of serpentinites (after dunite), metachromitites, metaperidotites, hornblendites and metagabbros. PGE–bearing metachromitites are hosted by the serpentinite–peridotite unit, occurring as dispersed blocks, well preserved from weathering. However, host metadunites are poorly preserved, and are only accessed by drill core samples. Scanning Electron Microscopy (SEM) analysis in thin sections of selected metachromitite samples revealed that most of the platinum group minerals (PGM) occur in the chlorite–serpentine matrix, generally in contact with chromite grains. The main PGM are sperrylite (PtAs2), cooperite (PtS), irarsite ((Ir,Pt,Rh)AsS) and hollingworthite ((Rh,Pd,Pt,Ru)AsS). Within chromite grains, very few PGM were found, and sulfide inclusions are mainly chalcopyrite (CuFeS2), pentlandite ((Fe,Ni)9S8) and bornite (Cu5FeS4). Whole–rock geochemical data reveal that metagabbros are LILE–enriched and show subduction–related signature similar to that of Alaskan–type intrusions. Mineral chemistry of chromite and olivine is also compatible with arc–related Alaskan–type complexes. The U–Pb SHRIMP zircon age for a metachromitite sample yielded an upper intercept age of 2036 ± 27 Ma, which we interpret as the crystallization age. However, dispersion in the data implies that zircons lost variable amounts of radiogenic Pb at around 749 ± 54 Ma (lower intercept), which may be related to Neoproterozoic metamorphism. The age obtained for the Troia–Pedra Branca metachromitites (2036 Ma) is younger than the 2190–2130 Ma arc–related plutons of the area, and it is closely related in age to the 2.10–2.04 Ga syn– to late–collisional plutonism and high–temperature metamorphism. Therefore, this Alaskan–type mafic–ultramafic magmatism may be related to the post–collisional setting of the 2.2–2.0 Ga Eburnean/Transamazonian orogeny.

Corundum (ruby) growth during the final assembly of the Archean North Atlantic Craton, southern West Greenland

We investigate the petrogenesis and tectonic significance of corundum (ruby)-bearing late Neoarchean rocks from the Maniitsoq region of southern West Greenland using petrology, thermobarometry, phase equilibrium modelling, and carbon isotopes as well as U–Pb zircon and rutile geochronology. Corundum was generated by amphibolite-facies metamorphism of an aluminosilicate schist. Thermobarometry and phase equilibrium modelling constrain the P–T conditions of corundum growth to ~ 600–700 °C at ~ 4–7 kbar. The presence of graphite suggests corundum growth in the presence of a mixed hydrous–carbonic fluid; this fluid was responsible for the transfer of SiO2 out of the precursor rock generating quartz-undersaturated conditions that enabled corundum growth. Carbon isotope values of graphite from corundum-bearing schist indicate a biogenic origin and are inconsistent with the fractionation of non-biogenic carbon. Zircon U–Pb geochronology documents regional metamorphism at c. 2.72–2.60 Ga. U–Pb rutile geochronology yields an upper intercept age of c. 2.5 Ga, which is interpreted as the best age estimate of corundum growth. The growth of corundum in southern West Greenland reflects heating associated with post-tectonic magmatism after the assembly of the North Atlantic Craton.

Provenance, nature, and U–Pb zircon geochronology of Ngaye rocks (Adamawa‐Yadé Shield, Central Cameroon): New insights into the evolution of Archean crust within the Pan‐African belt

Petrographical, geochemical, and geochronological data obtained from Ngaye high‐grade metasedimentary rocks have contributed to determine the provenance, nature, and evolutionary history of the Adamawa‐Yadé Domain from the Archean to Pan‐African events. The rocks are migmatites formed after TTG and granitic crusts were reworked by partial melting at T = 683–994°C. Geochemical features, for example, low Rb/Sr ratio (0.03–0.53), high Cr/V, and Cr/Th ratios (9.91–100.75; 28.41–686.15), respectively, indicate that these samples were derived predominantly from a mafic crust source. The primordial mantle‐normalized spidergrams are characterized by negative Nb‐Ta anomalies, suggesting melting of crustal rocks. REE fractionation shown (La/Yb)N = 8.48–197.89) indicate melting of crustal source rocks (meta‐TTGs). Low Hf and Zr contents (0.95–5.65 ppm and 23–262.85 ppm, respectively), low Sr/Y ratios (9.17–200.65), and a positive correlation between Th/Sc and Zr/Sc, point to crustal reworking. U–Pb ages on detrital zircon in tonalitic and granodioritic gneisses indicate contribution of Mesoarchean and Paleoproterozoic sources and suggest a maximum deposition age during the Early Paleoproterozoic for their magmatic protoliths. Magmatic zircon grains of granodiorite, with a round shape, Th/U ratio values ranging from 0.02 to 1.23, and an oscillatory zonation yield post emplacement metamorphic ages at 2,077 Ma. The lower intercept ages obtained in this study, match the tectonic reworking of the crust during the Pan‐African event associated with partial melting due probably to regional‐scale shear zone activities and magmatic accretion of juvenile magmas.

Ocean Plate Stratigraphy of a long-lived Precambrian subduction-accretion system: The Wutai Complex, North China Craton

Ocean Plate Stratigraphy (OPS) is the travelogue of the oceanic lithosphere from its birth at the Mid Ocean Ridge to its demise at the subduction zone in convergent plate margins. Here we present an OPS succession preserved onland in the Wutai Complex of the North China Craton (NCC), representing a prolonged subduction-accretion-collision system and continental growth during the Neoarchean-Paleoproterozoic. The OPS succession in Wutai includes metabasalts and banded iron formation representing the pelagic sequences together with intercalated metacarbonates. Phyllite, greenschist, and mica schist represent the hemipelagic sequence. Quartzite and conglomerate correspond to the turbidite sequence, with a progressive southward accretion towards a magmatic arc in the north. We present results from petrological, geochemical, zircon U-Pb, REE, and Lu-Hf studies from representative rocks in the OPS sequence of the Wutai Complex. The trace elements including the rare-earth element (REE) data of the metabasalt show transitional features between normal mid-ocean ridge basalt (N-MORB) and enriched mid-ocean ridge basalt (E-MORB). The REY (lanthanide elements and Y) data of the banded iron formation (BIF), greenschists, and phyllite suggest the interaction of high-temperature hydrothermal fluids and seawater. Magmatic zircon grains from the quartzite show 206Pb/207Pb upper intercept age of 2443 ± 21 Ma, whereas zircon grains in the phyllite show upper intercept age of 2494 ± 32 Ma, with minor xenocrysts with older ages of 2726 ± 46 Ma and 2672 ± 48 Ma. Zircon grains in the metaconglomerate show upper intercept age of 2569 ± 32 Ma. Those from the siliceous and intercalated bands in the BIF yield upper intercept ages of 2583 ± 34 Ma and 2524 ± 49 Ma. The zircon Lu-Hf data on zircon grains from the BIF, phyllite, quartzite, and metaconglomerate all show positive εHf(t) values (+1.3 to +7.4) in the range of depleted mantle to new crust, suggesting Neoarchean intra oceanic arc subduction. Combined with the zircon U-Pb and Hf isotopic data previously reported from the Wutai Complex, we infer the following four tectonic evolution stages: ca. 2800 Ma subduction initiation, ca. 2750–2300 Ma arc-accretionary complex, ca. 2300–2100 Ma back-arc rifting, and ca.1900–1750 Ma arc-continent collision. The metavolcanics and part of the metasedimentary rock assemblages in the Wutai Complex represent a deformed and dismembered OPS sequence generated through northward subduction and closure of the Wutai Ocean.

LA-ICPMS, TEM and Raman study of radiation damage, fluid-induced alteration and disturbance of U-Pb and Th-Pb ages in experimentally metasomatised monazite

Experimentally metasomatised monazite was studied in terms of preservation of U-Pb and Th-Pb ages during alkali-bearing fluid-induced alteration over a broad range of temperature conditions 250–750 °C. Starting materials for experiments included Burnet monazite (Concordia age 1100.5 ± 11.6 Ma, 2σ), albite, K-feldspar, biotite, muscovite, SiO2, CaF2, Na2Si2O5 and H2O. Monazite from experiments at 250–550 °C is partially replaced by secondary REE-rich fluorapatite [(Ca,LREE,Si,Na)5(PO4)3F], fluorcalciobritholite [(Ca,REE)5(SiO4,PO4)3F] and REE-rich steacyite [K1−x(Na,Ca)2(Th,U)Si8O20], and developed patchy zoning, whereas partial replacement by fluorcalciobritholite and cheralite [CaTh(PO4)2] occurred at 650 and 750 °C, with no signs of compositional alteration based on EPMA data and BSE imaging. Raman microspectroscopy results show narrowing of the ν1(PO4) stretching band in unaltered domains, which indicates advancing annealing of the monazite structure with increasing temperature, and narrow ν1(PO4) band with low FWHM values in altered domains. TEM investigations revealed that unaltered domains of monazite from experiments at 250–550 °C have mottled diffraction contrast, similar to the starting Burnet monazite, which indicates low to moderate degree of metamictization. On the contrary, the altered domains of monazite (patchy zones) show no mottled contrast, suggesting an ordered crystalline structure. TEM imaging demonstrated low degree of metamictization in monazite from the experiment at 650 °C; fluid-aided alteration along the cleavage planes resulted in the development of nanoporosity or partial replacement by fluorcalciobritholite and cheralite. Monazite from the experiment at 750 °C has crystalline structure with no signs of metamictization and shows significant development of nanoporosity and formation of secondary cheralite nanocrystals across the grain. For comparison, TEM and Raman evaluation of xenotime from similar experiments at 350 and 650 °C revealed that both starting xenotime and xenotime from experimental products are crystalline with no signs of radiation damage or fluid-induced alteration affecting internal domains on submicron scale, which could result in compositional alteration of the xenotime.The unaltered domains of monazite from runs at 250–550 °C yielded U-Pb and Th-Pb dates similar to the age of Burnet monazite, whereas altered domains yielded discordant dates due to various degree of Pb-loss (up to 99.4%). Linear regressions on the Concordia diagrams show lower intercept ages from −266 ± 160 Ma (run 350 °C, 200 MPa) to −1 ± 48 Ma (450 °C, 800 MPa), which reflect the “true age” of experimental alteration. The monazite from runs at 650 and 750 °C yielded data indicating initial disturbance of the U-Th-Pb system, ranging from 8.4% Pb-gain to 18.6% Pb-loss. Linear regressions with lower intercepts of −53 ± 420 Ma and −55 ± 610 Ma roughly correspond to the timing of the experiments. Furthermore, LA-ICPMS results demonstrate discrepancy between Th-Pb and U-Pb dates suggesting higher mobility of 208Pb than that of 207Pb and 206Pb.To summarize, TEM and Raman data indicate increasing annealing of the radiation damaged monazite with increasing temperature. Alteration processes induced by alkali-bearing fluid can result in recrystallization of monazite and various degrees of the age disturbance at temperatures 250–550 °C, whereas isotopic U-Th-Pb microanalysis provide an opportunity to constrain the age of the metasomatic processes as the lower intercept in the Concordia diagram. The particular importance of this study lies in submicron alteration of monazite at 650–750 °C induced by alkali-bearing fluid and/or melt, which remains unnoticed using common electron microscopy BSE imaging. Such alteration, however, induces substantial disturbance of U-Pb and Th-Pb ages, which can cause misinterpretations in reconstructions of geological processes.

Insights into characterization and genesis of the Tieshanmiao banded iron formation deposit, China: Evidence from zircon U–Pb dating and geochemistry

The Tieshanmiao hosted by the metamorphosed Paleoproterozoic Upper Taihua Group, is a large-scale BIF–hosted Fe deposit in the southern margin of the North China Craton. The formation age, BIF type, depositional condition as well as the genesis of pyroxene–rich BIF is under heated debate. In this study, we present petrology, whole–rock geochemistry, zircon U–Pb geochronology and Lu–Hf isotope analyses on the Tieshanmiao Fe deposit. The Fe ore of the deposit can be divided into two sub-types, including banded pyroxene–magnetite quartzite (BMQ) and disseminated magnetite pyroxenite (DMP). The hanging wall rock pyroxene biotite gneiss yields an upper intercept age of 2406 ± 24 Ma, interpreted as the lower limited age for BIF deposition. The foot wall rock garnet–bearing biotite plagioclase gneiss yields a weighted mean 207Pb/206Pb age of 2739 ± 12 Ma, interpreted as its maximal depositional age. Lu-Hf isotope systematics indicates that pyroxene biotite gneiss is derived from the Paleoproterozoic mantle contaminated by the crust, and the provenance of garnet–bearing biotite plagioclase gneiss is derived from a Mesoarchean crust.The primary mineral assemblages of the pyroxene–rich Tieshanmiao Fe deposit are Fe–silicate, Ca/Mg–carbonate, ferrihydrite, and minor quartz. The BMQs have high and variable Y/Ho ratios (40–80), recording periodic alkaline hydrothermal injection that is progressively diluted by seawater, while the DMPs have low and constrained Y/Ho ratios, archiving well–supplied alkaline hydrothermal injection. We propose a REY (lanthanide elements and Y) modelling of multi–Fe sources for the Tieshanmiao BIF deposit. The BMQs are sourced from seawater and high–T hydrothermal fluid, while the DMPs are sourced from seawater, high–T hydrothermal fluids and one or several additional Fe fluxes (e.g. high-Fe dissolved riverine fluxes, low–T hydrothermal fluids or benthic Fe shuttles driven by dissimilatory iron reduction).The basic gneisses as metabasalts associated with the Tieshanmiao Fe deposit are characterized by high–Fe assay, variable LREE enrichment, relatively depletion in Nb, Ta, Zr, Ti, Y, and Th. The geochemistry of the basic gneisses shows affinities to both MORBs and volcanic–arc basalts, indicating a back–arc basin setting of the BIF deposition. It is most likely a Superior–type BIF–hosted Fe deposit, which is formed in a back–arc basin along the craton–side continental shelf.