{101̄2} twinning occurs extensively in Mg to accommodate plastic deformation. With multiple active twin variants, twin–twin interaction occurs and this often forms twin–twin boundaries. In this work, the {112̄2} twin–twin boundary is studied using electron backscatter diffraction (EBSD) analysis and atomistic simulations. EBSD data show that many of the twin–twin boundaries align well with {112̄2} or {112̄6} planes. Further, atomistic simulations reveal dynamically the formation of {112̄2} boundary via the interaction of two non-co-zone {101̄2} twin variants. Moreover, the twinning mode of the {112̄2} boundary is found to be an extension twin with second undistorted plane of {112̄6}. In addition, the {112̄2} boundaries contribute significantly to the 60°〈011̄0〉 peak in the misorientation histogram; they also play an essential role in the unique strong strain hardening under c-axis tension. Our findings are crucial for completing the twinning theories for Mg.
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