Interaction Mechanism Research Articles

Poly(Acrylic Acid)-Based Polymer Binders for High-Performance Lithium-Ion Batteries: From Structure to Properties.

Poly(acrylic acid) (PAA) and its derivatives have emerged as promising candidates for enhancing the electrochemical performance of lithium-ion batteries (LIBs) as binder materials. Recent research has focused on evaluating their ability to improve adhesion with silicon (Si) particles and facilitate ion transport while maintaining electrode integrity. Various strategies, including mixing modifications and copolymerization methods, are highlighted and the structural and physicochemical properties of these binders are examined. Additionally, the interaction mechanisms between PAA-based binders and active materials and their impact on key electrochemical properties such as initial Coulombic efficiency (ICE) and cycle stability are discussed. The findings underscore the efficacy of tailored PAA-based binders in enhancing the electrochemical properties of LIBs, offering insights into the design principles and practical implications for advanced battery materials. These advancements hold promise for developing high-performance lithium batteries capable of meeting future energy storage demands.

Sulcardine, an investigational multichannel blocker for atrial fibrillation with uniquely intense JTp inhibition to enhance safety

Abstract Background Sulcardine is a multi-ion channel blocker for treating atrial fibrillation (AF) with similar inhibitory potency on peak/late sodium, L-type calcium, and rapidly activating delayed-rectifier potassium (IKr) currents. The therapeutic effect of inhibiting IKr includes QT prolongation (accompanied by a proportional J to T peak [JTp] interval prolongation), which, when excessive, may cause malignant arrhythmias. As previously reported, sulcardine strongly mitigates the JTp increase that may contribute to excessive QT prolongation by inhibiting late sodium and L-type calcium currents, an intrinsic mechanism to protect from excessive IKr block. Purpose We explored the JTp mechanism, pharmacokinetics (PK), electrocardiogram (ECG) changes, safety, and drug-drug interaction (DDI) of a single sulcardine (as HBI-3000) intravenous (IV) infusion in healthy subjects. Methods An open-label Phase 1 study evaluated the PK interaction between sulcardine, dosed as a 350 mg 30-minute infusion of the sulfate salt HBI-3000, and a cytochrome P450 CYP2D6 enzyme inhibitor (paroxetine). Triplicate ECGs were extracted from continuous 12-lead Holter ECG recordings at baseline and 10 time points thereafter. Mean baseline-subtracted and heart rate-corrected QTcF (dQTcF), JTpc (dJTpc), and other ECG changes were calculated at each time point. Left ventricular ejection fraction (LVEF) was assessed at baseline, 30-, and 120-minutes post-infusion start by transthoracic echocardiography (TTE). Results 39 subjects received HBI-3000, 33 in the paired PK population. Expected ECG parameter changes proportional to sulcardine plasma concentrations were observed in the HBI-3000-alone portion of the study, including modest QTcF prolongation (Fig 1, blue slope, confidence band) and JTpc inhibition (Fig 1, red). The usual JTpc increase associated with IKr blockers, even those with mitigating channel block (such as the late sodium current), was not only reduced but actually reversed. We calculated the dQTcF change that would have been observed in the absence of JTpc reduction by sulcardine (Fig 1, green). Sulcardine reduced the QTcF increase that might have occurred by about 21 msec at the highest concentrations, and this mitigating effect was observed at all concentrations. No clinically significant safety findings or arrhythmias were observed. The most frequent TEAEs were nausea and headache (n=2 each [5.1%]). No LVEF changes were clinically significant. Sulcardine had minimal metabolic interactions. Conclusion Acute IV HBI-3000 administration resulted in no clinically significant safety findings, LVEF depression, or DDI with CYP2D6. Sulcardine facilitates QT prolongation, which has a therapeutic benefit in terminating AF, with simultaneous uncoupling and reversing of the JTpc interval increase, a potential mechanism for reducing proarrhythmic risk due to excessive QT prolongation.Figure 1.ECG Intervals vs Sulcardine Conc

Transcriptomic analysis of the gonads of Locusta migratoria (Orthoptera: Acrididae) following infection with Paranosema locustae.

Paranosema locustae is an environmentally friendly parasitic predator with promising applications in locust control. In this study, transcriptome sequencing was conducted on gonadal tissues of Locusta migratoria males and females infected and uninfected with P. locustae at different developmental stages. A total of 18,635 differentially expressed genes (DEGs) were identified in female ovary tissue transcriptomes, with the highest number of DEGs observed at 1 day post-eclosion (7141). In male testis tissue transcriptomes, a total of 32,954 DEGs were identified, with the highest number observed at 9 days post-eclosion (11,245). Venn analysis revealed 25 common DEGs among female groups and 205 common DEGs among male groups. Gene ontology and Kyoto Encyclopaedia of Genes and Genome analyses indicated that DEGs were mainly enriched in basic metabolism such as amino acid metabolism, carbohydrate metabolism, lipid metabolism, and immune response processes. Protein-protein interaction analysis results indicated that L. migratoria regulates the expression of immune- and reproductive-related genes to meet the body's demands in different developmental stages after P. locustae infection. Immune- and reproductive-related genes in L. migratoria gonadal tissue were screened based on database annotation information and relevant literature. Genes such as Tsf, Hex1, Apolp-III, Serpin, Defense, Hsp70, Hsp90, JHBP, JHE, JHEH1, JHAMT, and VgR play important roles in the balance between immune response and reproduction in gonadal tissues. For transcriptome validation, Tsf, Hex1, and ApoLp-III were selected and verified by quantitative real-time polymerase chain reaction (qRT-PCR). Correlation analysis revealed that the qRT-PCR expression patterns were consistent with the RNA-Seq results. These findings contribute to further understanding the interaction mechanisms between locusts and P. locustae.

Distributed feather-inspired flow control mitigates stall and expands flight envelope

Multiple rows of feathers, known as the covert feathers, contour the upper and lower surfaces of bird wings. These feathers have been observed to deploy passively during high angle of attack maneuvers and are suggested to play an aerodynamic role. However, there have been limited attempts to capture their underlying flow physics or assess the function of multiple covert rows. Here, we first identify two flow control mechanisms associated with a single covert-inspired flap and their location sensitivity: a pressure dam mechanism and a previously unidentified shear layer interaction mechanism. We then investigate the additivity of these mechanisms by deploying multiple rows of flaps. We find that aerodynamic benefits conferred by the shear layer interaction are additive, whereas benefits conferred by the pressure dam effect are not. Nevertheless, both mechanisms can be exploited simultaneously to maximize aerodynamic benefits and mitigate stall. In addition to wind tunnel experiments, we implement multiple rows of covert-inspired flaps on a bird-scale remote-controlled aircraft. Flight tests reveal passive deployment trends similar to those observed in bird flight and comparable aerodynamic benefits to wind tunnel experiments. These results indicate that we can enhance aircraft controllability using covert-inspired flaps and form insights into the aerodynamic role of covert feathers in avian flight.

Cow Dung Biostabilized Earth Mortars: Reusability and Influence of Cow Dung Processing and Cow Diet

Historically, cow dung has been widely used as a biostabilizer in earth building, although the scientific research on this subject is still limited. The available research provides evidence of the positive effects of this bioaddition on earthen blocks and plasters, as it improves their physical and mechanical properties and durability in water contact. The present research does not aim to characterize biostabilized earthen mortars or to explain the interaction mechanisms between the earth and cow dung components, because this topic has already been investigated. Instead, it aims to investigate strategies to optimize the collection and processing of cow dung so as to optimize their effects when used in earth-plastering mortars, as well as considering the effects of using them fresh whole, dry whole, and dry ground (as a powder); the effects of two different volumetric proportions of cow dung addition, 20% and 40% (of the earth + added sand); the effects of 72 h (fermentation–humid curing) before molding the biostabilized mortar; the influence of the cow diet; and the potential of reusing cow dung stabilized mortars. The results show that as the freshness of the cow dung increases, the mortar’s durability increases under water immersion, as well as the mechanical and adhesive strength. Collecting cow dung fresh and drying (composting) it in a plastic container is more efficient than collecting cow dung that is already dry on the pasture. The cow diet and the use of dry (composted) cow dung, whole or ground into a powder, does not result in a significant difference. A 72 h period of humid curing fermentation increases the adhesive strength and durability under water. The proportion of 40% promotes better durability under water, but 20% offers greater mechanical and adhesive strength. Finally, cow dung addition does not reduce the reusability of the earth mortar. The new mortar obtained by remixing the mortar with water presents increased properties in comparison to the original reference mortar with no cow dung addition. Therefore, the contributions of this research are innovative and important, offering technical support in the area of biostabilized earth-plastering mortars. Furthermore, it is emphasized that cow dung addition can be optimized as an efficient traditional solution to increase the mechanical resistance, but especially to increase the durability of earth mortars when in contact with water. This effect is particularly important for communities lacking financial resources, but also reveals the possibility of using eco-efficient waste instead of binders obtained at high firing temperatures.

A “WEST” Theory in the East: Decoupling and synergistic evolution of water utilization, economy, and society in China

AbstractTo attain a thorough examination of the dynamic interaction mechanism between China's utilization of water resources and its economic and social development, this paper innovatively introduces a Western theoretical framework within an Eastern context. The aim is to quantify the process of decoupling and synergistic evolution from 2006 to 2020. Decoupling signifies achieving economic growth while reducing resource use or mitigating environmental impacts, whereas synergy denotes enhancing economic efficiency while contributing to environmental protection. This paper employs the Tapio elastic coefficient method to construct a decoupling model. A collaborative model, based on the entropy weight Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) and weighted average methods, also assesses the organization and coordination of subsystems within the complex water‐economic‐social system. The findings reveal a strong decoupling between China's water resource management and economic and social systems, as indicated by a consistently negative decoupling index. Similarly, the economic system exhibits a degree of inefficiency influenced by factors like economic cyclicality and resource allocation. In contrast, the social system experienced a decline, particularly during the pandemic (2019–2020), leading to a social instability. This study provides valuable policy formulation and sustainable development insights, contributing to a comprehensive understanding of the intricate dynamics between water utilization, economy, and society.

Discrete-Event Simulation Integrates an Improved NEH Algorithm for Practical Flowshop Scheduling Problems in the Satellite Industry

The production of multiple types of satellites based on a common manufacturing platform represents a permutation flowshop scheduling problem (PFSP) with complex constraints. This is a highly complex scheduling problem, yet there is still a gap between theoretical research and practical application, particularly in the satellite industry. Therefore, we propose a more practical method that integrates discrete-event simulation modelling and an improved NEH algorithm to solve a more realistic PFSP. The discrete-event simulation-based method includes the following three main components: a flexible PFSP simulation modelling approach, an improved NEH algorithm, and an interaction mechanism between the simulation model and the optimisation algorithm. The proposed method allows automatic and flexible simulation modelling according to the characteristics of the actual satellite manufacturing workshop, which determines the practical nature of the approach proposed in this paper and then achieves excellent scheduling results based on the special interaction mechanism. The computational results demonstrate that this is a 9.18% improvement over the initial NEH algorithm and a 1.40% improvement over the best current improved NEH algorithm.

The effect of unhealthy lifestyle on the pathogenesis of sick sinus syndrome: A life-guiding review.

Sick sinus syndrome (SSS), also known as sinoatrial node dysfunction, has been widely concerned by the medical community. The incidence rate of SSS is increasingly, which poses a great threat to public health. Through decades of repeated research in the medical field, great progress has been made in the pathogenesis of SSS and the interaction mechanism between SSS and other cardiovascular diseases. In this paper, we pay special attention to the mental stimulation factors under various pressures such as society and work, and the influence of smoking, drinking, and unhealthy diet on the pathogenesis of SSS. It also explains the mechanism of negative factors in the pathogenesis of SSS. These unhealthy lifestyle will lead to the occurrence of sinoatrial node disease and arrhythmia, and then induce SSS. Therefore, in the premise of increasing incidence rate of SSS and difficult to cure, how to avoid these harmful factors and ensure a healthy lifestyle is extremely important for preventing and treating SSS. This study also has guiding significance for the daily life of high-risk population of SSS and reducing the mortality of SSS patients.

Research progress of nanoscale zero-valent iron in synergistic combinations of denitrifying bacteria for nitrate removal

Nitrate (NO3--N) is a common inorganic nitrogen pollutant in water. Excessive NO3--N can lead to water eutrophication and threaten human health. Nanoscale zero-valent iron (nZVI) has attracted much attention in NO3--N removal due to its high specific surface and excellent electron donor properties. The combination of nZVI and denitrifying bacteria (DNB) demonstrates high efficiency in converting NO3--N into N2. This approach not only substantially enhances the removal rate of NO3--N but also exhibits superior environmental sustainability compared with conventional chemical denitrification methods. Accordingly, it holds substantial promise for mitigating NO3--N pollution and warrants further exploration in the pollution control. Therefore, it is necessary to understand the interaction mechanism between nZVI and DNB for NO3--N removal. This paper details the factors affecting the removal of NO3--N by nZVI combined with DNB, reviews the latest research progress in this field, elaborates on the interaction mechanism between nZVI and DNB for NO3--N removal, and discusses the challenges and future research directions of NO3--N removal by nZVI combined with DNB. This review aims to provide a theoretical basis for the development of efficient approaches for the remediation of NO3--N pollution.

Computational Analysis of Sarin, Soman, and Their Water Mixtures in NU-1000: Interaction Mechanisms, Distribution Patterns, and Pairing Effects.

Due to their extraordinary structural stability under humid conditions, zirconium-based metal-organic frameworks (Zr-MOFs) have been widely investigated for the hydrolytic degradation of nerve agents. That said, mechanisms of hydrolysis in the solid state and the participation of environmental water are not well understood. This work utilizes computational techniques to evaluate the behavior of water and two organophosphorus nerve agents (sarin and soman) in NU-1000, a Zr-MOF with the characteristic attributes for hydrolytic efficiency under humid conditions. Density functional theory (DFT) calculations reveal that soman binds more favorably to NU-1000 active sites than sarin, resulting in different preferential locations of each nerve agent within the framework. The strength of nerve agent binding is also found to vary depending on the site environment, with more favorable binding of both nerve agents occurring in the c-pores of NU-1000 than in the mesopores. Molecular dynamics (MD) simulation results further illustrate that free water molecules in NU-1000 prioritize interactions with nerve agents. Given the variation in their affinity for active site interactions, the introduction of different nerve agents to the framework results in substantial differences in water distribution and behavior. The results give insight into potential variances in the functionality of NU-1000 toward the hydrolysis of each nerve agent. More importantly, they emphasize the significance of considering the role of environmental water in hydrolysis and the possibility of diverse reaction variables based on the type of nerve agent and the properties of the MOF.

Stimulated Raman scattering and enhancement mechanisms in alkali metal hydroxide aqueous solutions under laser-induced dynamic pressure

Stimulated Raman scattering (SRS) in lithium hydroxide-water/heavy water (LiOH-H2O/D2O) solutions with varying concentrations was investigated under laser-induced high-pressure conditions using an Nd: YAG laser. The spectra revealed a significant enhancement in SRS signals, characterized by the emergence of low-wavenumber Raman peaks and a shift of the main SRS peak of liquid water to lower frequencies, evolving from a single peak to two or three peaks, which suggested the formation of an ice-like structure. Additionally, the normalized SRS intensity was higher than that of pure water. The enhancement of SRS signals during LiOH dissolution was attributed to the cooperative modulation between hydrogen bonding (HB, O-H:O) by OH- and Coulombic electronic interactions generated by monovalent Li+, which strengthened HB interactions, increased the Raman gain coefficient, and induced structural modifications akin to pressure effects. Besides, the increased density amplified the dynamic high-pressure effects during the laser-induced breakdown (LIB) process, further boosting the SRS signals. This work provides valuable insights into the interaction mechanisms between alkali metal hydroxides and H2O/D2O under laser-induced pressure conditions, offering a comprehensive approach to understanding and enhancing the SRS effect in aqueous solutions.

Interaction and Diffusion Mechanism of Moisture in Power Capacitor Insulating Oil Based on Molecular Simulation

Interaction and Diffusion Mechanism of Moisture in Power Capacitor Insulating Oil Based on Molecular Simulation

The role of social interaction in farmers’ water-saving irrigation technology adoption: testing farmers’ interaction mechanisms

In rural areas, neighborly relationships are complex, and farmers’ behaviors are largely influenced by neighborly interactions. The promotion of agricultural technologies should not overlook the social interactions between farmers. Based on survey data from farmers in Minqin, China, this paper explores the role of overall social interaction and its various dimensions in farmers’ adoption of water-saving irrigation technology, focusing on the testing of three interactive mechanisms during the technology adoption process. The goal is to provide scientific policy suggestions for government when promoting agricultural technologies. The results show the following: social interaction promotes the adoption of water-saving irrigation technology among farmers; among the four dimensions of social interaction, the depth and frequency of social interaction facilitate the adoption of these technologies; social interaction promotes technology adoption through endogenous interaction mechanism, situational interaction mechanism, and social norm mechanism, with situational interaction mechanism and social norm mechanism playing a more significant role; social interaction has a stronger impact on farmers with longer farming experience and higher irrigation costs. Therefore, the government should emphasize the important role of social interaction in the adoption of agricultural technologies and accelerate the diffusion of these technologies through fostering technical exchanges among farmers, cultivating demonstration households, and implementing differentiated promotion strategies.

Kinetics and Mechanism Study of Different Types of Surface‐Imprinted Polymers for CO2 Adsorption

ABSTRACTThe increased level of CO2 in the atmosphere has led to global warming and climate change. To mitigate these problems, solid adsorbents have become attractive materials for capturing excess CO2 in the post‐combustion method. Molecularly imprinted polymer (MIP) can be applied to prepare highly selective adsorbents that could capture CO2 molecules. The MIP was prepared using the surface imprinted polymer technique in this preliminary work. Only two types of support materials were used (graphite and silica gel) to screen the best support material that could enhance the CO2 adsorption capacity of the resulting adsorbent, which was analyzed using a fixed‐bed column reactor. Graphite‐imprinted polymer (GMIP) was found to be a good potential for CO2 adsorption. The Avrami model best described the adsorption system, while the fixed‐bed curve data fit the Yoon–Nelson model well. The semi‐empirical method was used to assess the interaction mechanism of the molecularly imprinted polymer with CO2 during adsorption. This investigation involved testing four different ratios of the template complex to functional monomers. The ratio of 1:4 (CO2:Allylthiourea) demonstrated the highest binding energy, with a higher formation of hydrogen bonds. Film diffusion and intraparticle diffusion were the main rate‐limiting steps that played vital roles at different stages of CO2 adsorption. This preliminary work has enhanced the development of MIP for CO2 adsorption and showcased the integration of computational approaches in tailoring specific MIPs.

Periodic Bonding Behaviors of Actinide Atoms (An = Th-Cm) with Negatively Curved Nanographene.

The nanographene with negative curvature has been extensively studied due to its interesting properties and potential applications. In the present work, we have performed all-electron scalar relativistic density functional theory (DFT) calculations to understand the periodic interaction mechanisms of actinide atoms (An = Th, Cm) with the TB8C nanographene. The encapsulated complexes (An@TB8C) were formed due to the octagonal vacancy in the TB8C nanographene. TB8C shows fairly high affinity toward An atoms, especially for Th and Pa. AIMD simulations further confirmed the effective trapping of An atom with TB8C. The partial covalent characters of An-C bonds in An@TB8C were revealed through various bond analysis methods. The 6d electrons of An play an important role in the participation of chemical bonds. The delocalization index (DI) is proposed as a useful descriptor in the study of bond strength involving the actinides. Electronic absorption spectra were simulated for further identification in the experiments. The current work has expanded the potential molecular properties and applications of nanographene.

Elucidating the diffusion and interaction mechanisms of Zn2+ and H+ in MnO2 for aqueous zinc-ion batteries: A DFT study

MnO2 is a promising cathode material for aqueous zinc-ion batteries (AZIBs) with potential applications in large-scale energy storage systems. However, its practical use is hindered by poor cyclic stability and slow diffusion kinetics. Despite considerable efforts, success has been limited due to an unclear understanding of the intrinsic properties of Zn2⁺ and proton (H⁺) insertion into MnO2. This study investigates the predominant phases of MnO2—α, β, δ, and γ—and elucidates their reaction mechanisms using first-principles computational methods based on density functional theory (DFT). Our research reveals that H⁺ ions exhibit a higher initial insertion voltage compared to Zn2⁺ ions, but their diffusion in MnO2 is significantly impeded by strong interactions with oxygen. Additionally, H⁺ insertion partially obstructs Zn2⁺ ion migration. Furthermore, the insertion of Zn2⁺/H⁺ and the adsorption of H⁺ on the MnO2 surface are intricately linked to the dissolution process of manganese. This work significantly enhances our fundamental understanding of MnO2 as a cathode material for AZIBs.

Viscoelastic Fluid Focusing Chip-ICP-MS Single-Cell Analysis Enables Elucidating the Effect of Extracellular Polymeric Substances on Bioaccumulation of Hg2+/HgS in Microcystis aeruginosa Cell.

Understanding the interactions between mercury and microalgae, especially the interactions between inorganic mercury (IHg) and extracellular polymeric substances (EPS, a protective barrier between cells and their external environment), is essential for elucidating mercury's toxicological mechanisms. Given the inherent cell heterogeneity, a novel analysis system of an online viscoelastic fluid focusing chip-time-resolved analysis inductively coupled plasma mass spectrometry has been developed to investigate the bioaccumulation of HgS nanoparticles and Hg2+ in single Microcystis aeruginosa (M. aeruginosa) cells, exploring the interaction mechanisms between HgS/Hg2+ accumulation in algal cells and EPS. The single-cell analysis results reveal minimal bioavailability of HgS within algal cells, with mercury's toxicity to M. aeruginosa being species-dependent. Notably, algal cells exhibited more heterogeneity in HgS uptake than in Hg2+ uptake. Under Hg2+/HgS stress, M. aeruginosa cells with EPS removed (EPS-R algal cells) showed an increased level of bioaccumulation of mercury compared to those with EPS (EPS-C algal cells), highlighting the critical role of EPS in mercury bioaccumulation. Overall, the designed viscoelastic fluid microfluidic focusing chip integrates focusing and cleaning functions, featuring easy fabrication, simple operation, low sample loss, and relatively high throughput. Under the optimal conditions, the sample throughput is 1195 min-1 and the cell recovery is 90%. Besides, this research offers novel insights into the interaction mechanisms between Hg2+/HgS and EPS in microalgal cells and unveils the specific toxic effects of Hg2+/HgS on M. aeruginosa at the single-cell level, contributing to a deeper understanding of mercury's ecological and toxicological impact in aquatic environments.

A novel model of cardiovascular–kidney–metabolic syndrome combining unilateral nephrectomy and high-salt–sugar–fat diet in mice

The aim of this study was to explore biological interaction and pathophysiology mechanisms in a new mouse model of cardiovascular–kidney–metabolic (CKM) syndrome, induced by chronic moderate renal failure in combination with consumption of a customized Western diet rich in carbohydrates, fat and salt. Male C57BL/6J mice were subjected to unilateral nephrectomy, fed a customized Western diet rich not only in sugar and fat but also in salt, and followed for 12 weeks or 20 weeks. Sham-operated mice on a standard chow served as healthy controls. Body composition, weight gain, glucose metabolism, fat distribution, blood pressure, cardiac function, vascular reactivity, renal function, inflammation and mitochondrial function were measured and combined with biochemical and histopathological analyses. The novel triple-hit model of CKM syndrome showed signs and symptoms of metabolic syndrome, disturbed glucose metabolism, impaired adipocyte physiology and fat redistribution, cardiovascular dysfunction, renal damage and dysfunction, systemic inflammation, elevated blood pressure and cardiac remodeling. The pathological changes were more pronounced in mice after prolonged exposure for 20 weeks, but no deaths occurred. In the present mouse model of CKM syndrome, profound and significant metabolic, cardiac, vascular and renal dysfunctions and injuries emerged by using a Western diet rich not only in fat and carbohydrates but also in salt. This multisystem disease model could be used for mechanistic studies and the evaluation of new therapeutic strategies.

Fully Coupled Analysis of a 10 MW Floating Wind Turbine Integrated with Multiple Wave Energy Converters for Joint Wind and Wave Utilization

The study focuses on a semi-submersible wind-wave integrated power-generation platform, which consists of an OO-Star semi-submersible platform equipped with a DTU 10 MW wind turbine and a set of wave energy converters. A hydrodynamic model was established using ANSYS-AQWA (2023 R1), and by incorporating upper wind loads and utilizing the open-source program F2A, a fully coupled time-domain model of the integrated power-generation platform was constructed. The primary objective is to explore the interaction mechanisms between the upper wind turbine and the lower wave energy devices under the combined effects of irregular waves and turbulent wind through a series of operational conditions. Additionally, the safety of the mooring system was assessed. The results indicate that, compared to the wave period, the power generation of the lower wave energy devices is more significantly affected by wave height. Overall, the integrated power-generation platform demonstrates optimal performance under the third operational condition. In survival conditions, the introduction of oscillating buoys can improve the motion responses of the platform in terms of sway, roll, pitch, and yaw to a certain extent, but it also increases the surge and heave motion responses and the associated mooring loads. The mooring system can ensure the safety of the integrated power-generation platform under extreme sea conditions.

Insights into the phase behavior at interfaces using vibrational sum frequency generation spectroscopy.

Phase separation is ubiquitous at the interface between two distinct phases. Physical transformation during phase separation often plays a crucial role in many important mechanisms, such as lipid phase separation, which is fundamental for transport through biological membranes. Phase separation can be complex, involving changes in the physical state and the reorganization of molecular structures, influencing the behavior and function of materials and biological systems. Surface-sensitive vibrational sum frequency generation (VSFG) spectroscopy provides a powerful tool for investigating these interfacial processes. As a non-linear optical technique, VSFG spectroscopy is sensitive to changes in molecular orientation and interactions at interfaces, making it an ideal method for studying phase separation processes. Here, we review the molecular interaction mechanisms underlying phase separation. We also explore the application of VSFG spectroscopy in studying phase separation processes at different interfaces. In particular, we focus on oil-water interfaces, which are relevant in environmental and industrial contexts; polymer and lipid surfaces, important for materials science and biological membranes; and intrinsically disordered protein systems, which play key roles in cellular function and disease.