Abstract Snap-through mechanism is employed to harvest electricity from random vibration through piezoelectricity. The random excitation is assumed to be Gaussian white noise. The snap-through piezoelectric energy harvester possesses the bistability. For small-amplitude vibration in a potential well, the Ito stochastic differential equation of the electromechanical coupling system is derived from the Taylor approximation at a stable equilibrium point. The method of the moment differential equations is applied to determine the statistical moments of the displacement response and the output voltage. The effects of the system parameters on the output voltage and the output power are examined. The approximate analytical outcomes are qualitatively and quantitatively supported by the numerical simulations. For large-amplitude interwell motion, the effects of the parameters on the output voltage and the output power are numerically investigated. Nonlinearity produced by the snap-through improves energy harvesting so that the snap-through piezoelectric energy harvester can outperform the linear energy harvester in the similar size under Gaussian white noise excitations.