ABSTRACT Artificial Intelligence Learning Platform (AILP) plays a key role in AI education. However, there are few studies investigating the behavioral intentions of teachers and students on using AILP and the sample size is small. This study examines factors affecting the behavioral intentions of 299 teachers and 347 students from China on using AILP. “Perceived Playfulness” is integrated into the Unified Theory of Acceptance and Use of Technology (UTAUT) model as the theoretical framework. Moreover, this study analyzes the moderating effects of gender, age, experience, voluntariness of use, teachers’ teaching level, teaching experience, and students’ major. The results of research through two structural equation models show that: (1) Students focus more on performance expectancy, whereas teachers are more concerned with perceived playfulness. (2) Students are easily affected by social influence, while teachers are not. (3) Both teachers and students are impacted by effort expectancy and facilitating conditions. This research provides a scientific comparison of affecting factors about behavioral intentions on using AILP between teachers and students, which can be used by researchers and AILP designers to optimize AILP design for better AI education.