Intensity Values Research Articles

Alleviating the Hubble tension using the Barrow holographic dark energy cosmology with Granda–Oliveros IR cut-off

ABSTRACT In this study, we investigate the Barrow holographic dark energy (BHDE) model with the Granda–Oliveros(G–O) infrared (IR) cut-off in the presence of neutrino masses, utilizing the latest observational data to address the Hubble tension. The GO cut-off is defined as $L_{\mathrm{ IR}}=(\alpha H^2 + \beta \dot{H})^{-1/2}$. We place constraints on the total neutrino mass $\sum m_{\nu }$ using data from Type Ia supernovae (SN) Pantheon, cosmic chronometers (CC), cosmic microwave background (CMB), Baryon Acoustic Oscillation (BAO) data sets, and Planck Lensing. Specifically, the comprehensive CMB + BAO + CC + Pantheon data set provides a total neutrino mass of $0.118\, \text{eV}$. The parameters for the Barrow-GO model are determined to be $\Delta = 0.0055^{+0.0086}_{-0.0086}$, $\alpha = 0.997^{+0.060}_{-0.060}$, and $\beta = 0.598^{+0.080}_{-0.080}$, showing good agreement with previous studies. One of the key findings of this study is the model’s ability to alleviate the Hubble tension, as evidenced by the comparison of $H_0$ measurements. Specifically, the tension value for the combination of data set (CMB + BAO + CC + Pantheon + Lensing) is $1.5\sigma$ with the Planck 2018 and $1.4\sigma$ with R22. These results underscore the importance of multi-data set integration in refining constraints on neutrino properties and highlight the model’s efficacy in probing fundamental aspects of neutrino physics. Our results demonstrate that the BHDE model with the GO cut-off can effectively address the Hubble tension, offering a coherent framework that reconciles local and cosmological measurements of the Hubble constant.

A new strategy for systematically classifying HLA alleles into serological specificities: Update and refinement.

HLA antigens were historically defined according to the unique reactivity pattern of cells expressing HLA molecules with distinctive clusters of allo-antisera and/or monoclonal antibodies. Subsequently, amino acid residues determining epitopes (DEP) in the HLA molecule were correlated with reactivity patterns. In current clinical practice, the presence of allo-antibodies is assessed using Luminex-based solid phase single antigen bead (SAB) assays for transplantation. Recently, novel antigens were proposed for HLA molecules with DEP patterns that do not match any serologically defined antigens recognised by the WHO Nomenclature Committee. To validate the antigens, mean fluorescence intensity values of SABs tested on >13,000 patients' sera were extracted from clinical databases and analysed by scatter plots using a linear regression model. We found that when two proteins were considered as the same antigen in the original study, for example, HLA-A*02:01 and -A*02:06, their correlation ranked among the highest values at each locus. In contrast, discrete asymmetric outliers were observed when there were different antigens, for example, HLA-A*30:01 and -A*30:02, allowing validation and confirmation of 20 novel antigens for HLA-A, -B, -C and -DR. The outliers were confirmed to be true or false by flow cytometric crossmatches. In addition to the previously defined residues for antigen assignments, findings suggest that further distinction should be made for common antigens by including the substitutions at residue 67 of HLA-B, 67 and 74 of -DR. These serologic analyses can be applied systematically to identify and confirm novel antigens. These developments will lead to designing optimal SAB panels and further improving virtual donor-specific antibodies assessment.

An eco-efficient European metal industry transition towards Circular Economy

The European metal industry can minimize carbon and energy intensity through Circular Economy (CE) solutions in order to achieve the Agendas’ 2030; 2050 targets. This paper evaluates the eco-efficiency in 21 European countries using hybrid window data envelopment analysis (WDEA) across two scenarios. The study compares short- and a meso-term policies by choosing different window widths. Inputs include gross fixed capital formation (GFCF), labor force, and energy intensity value added, with value added as desirable output and carbon intensity value added as undesirable output. Results show that the meso-term policy yields an average eco-efficiency of 47%, while the short-term policy achieves 55%, suggesting that short-term strategies are more effective for the metal industry in reaching the Net-Zero goals. Geographically, Western and Northern Europe exhibit better eco-efficiency than Eastern and Southern Europe. In essence, the European metal industry can reach a Net-Zero status through deep CE transformations in energy and carbon intensity via cleaner production.

Reconstructing the past environmental conditions of southwestern India using estuarine sediment core

Geological archives can be examined via multiple proxies to uncover significant information about historical environmental changes. In comparison to single proxy approach, the use of multiple proxies can provide better resolution of the paleoenvironmental record. Thus, in the present study, to understand the paleoenvironmental conditions in the Kali coast in southwestern India, sedimentological, geochemical and isotopic (210Pb, 137Cs) proxies were used. The findings demonstrated that, in previous decades, the sedimentation rate varied from 0.5 to 1.0 cm/year under conditions with relatively higher hydrodynamic energy that were more common and fluctuating, allowing for larger sand particle deposition. However, in more recent years, finer particle deposition towards the surface has been observed under conditions with lower and more stable hydrodynamic energy, with a sedimentation rate of 1.87 cm/year. Additionally, the finer fractions displayed a strong correlation with the metal distribution, which was mostly governed by Fe-Mn oxides. Furthermore, it can be revealed that the environment was warm, humid, and marine-like between 1995 and 2000 based on chemical weathering intensity values and Rb/K ratios. A subtle shift to a freshwater habitat with relatively less warm, less humid climate occurred between 2000 and 2020. Therefore, similar research with longer depositional histories coupled with multiple proxies can help predict the future climatic shifts in decadal time scales.

Mid-spatial frequency reduction via zero-depth of cut rapid-feed passes in face-turning

The single point diamond turning process (SPDT) is used widely in creating optical grade mirror surfaces on several engineering materials ranging from polymers, and metals, to brittle materials such as silicon and germanium. In visual optic mirror applications, mid-spatial frequency (MSF) errors generated during the SPDT process interfere with the visible spectrum of light thereby affecting the image quality. To overcome these errors, a post-processing operation of polishing the optical mirrors is required. The post-processing step not only increases the complexity of the manufacturing process but also leads to minor geometrical form changes in the mirror which affects performance. To avoid post-processing and minimize MSFs formed during turning- a novel method to modify the toolpath during the machining process has been proposed in this paper. The suggested toolpath strategy comprises two consecutive operations: i) employing variable low feed rates with the specified depth of cut (DoC) and ii) executing rapid traverse rates with zero depth of cut for a predetermined number of passes. The effectiveness of the proposed strategy is tested by carrying out facing experiments in a micro-precision CNC lathe. The power spectral density (PSD) content of the machined surface is then analyzed to check for any improvement in the frequency characteristics. The results show that the frequency errors generated by the toolpath in normal turning operations can be minimized, distributing the resulting PSD peak over a wide range of spatial frequencies. From the PSD plots, it is observed that there is a decrease of 77% and 85.82% in the peak intensity values when compared with surfaces machined at constant feedrates of 150 μm/rev and 200 μm/rev respectively. This method can be applied to nanoprecision SPDT machines to improve the surface quality and to eliminate the MSF errors of the visual optical grade mirrors without the need for post-processing.

Comparison of Climatology of Precipitation Diurnal Cycle in Kalimantan Deduced from Rain Gauge and IMERG Data

Abstract The diurnal cycle is repetitive pattern of changes in weather factors on land and oceans due to the Earth rotation. Kalimantan Island as the largest island in the Maritime Islands region has a complex rainfall pattern that is influenced by local factors and global circulation. The research was conducted to find out the climatological comparison of the diurnal cycle of rain in Kalimantan based on rain gauge data and Integrated Multi-SatellitE Retrievals for GPM Version 07 (IMERG V07) data for the period 2016 - 2022. Data validation using rain gauge data to validate and calibrate IMERG satellite data, improving the accuracy and reliability of satellite rainfall estimates. The diurnal cycle is evaluated through a Precipitation Amount (PA), Precipitation Frequency (PF), and Precipitation Intensity (PI) every hour. The results show that the maximum rainfall occurs in the afternoon and evening along the coast, and in the middle of the night and morning on the Kalimantan plains. Kalimantan has high rainfall intensity values at short rainfall durations, i.e. rain lasting less than 3 hours. This is expected to improve the quality of hydrometeorological disaster mitigation in Kalimantan.

Quantitative analysis of human blood glucose by dynamic optical rotation angle of multiple wavelengths based on the polarization camera

Measurement of blood glucose concentration is important in the prevention and treatment of diabetes. To improve the measurement signal-to-noise ratio and accuracy, using a polarization camera as the sensor, this paper proposes a multi-wavelength dynamic optical rotation angle method to quantitatively analyze human blood glucose. First, this paper utilizes a split-time approach to drive nine different wavelengths of light sources to work separately to achieve the collection of multiple different wavelengths of data and increase the amount of information. Second, to capture images with an array sensor such as a camera, using space-for-accuracy, this paper uses the cumulative value of the gray values of all pixel points in the image at each angle as the light intensity value to improve the amplitude (light intensity) resolution. Third, the extraction method of the dynamic optical rotation angle in this paper is to extract the difference between the maximum and minimum values of the optical rotation angle from each cycle of the signal of the continuous cyclic change of the length of the optical path, and the accumulated value of the difference of multiple cycles is recorded as the dynamic optical rotation angle, which not only reduces the errors caused by the individual differences, the external environment and the measuring instrument, but also has the effect of averaging and improves the signal-to-noise ratio of the optical rotation angle. To prove the effectiveness of the proposed methods, human finger real and simulation experiments are carried out, respectively. Firstly, the polarization camera is used to collect the image data of elliptically polarized light of nine different wavelengths of linearly polarized light after passing through the human body’s finger, and obtains the optical rotation angle under each wavelength that changes with the photoplethysmography (PPG) through data processing, and extracts the dynamic optical rotation angles of the nine wavelengths by the extraction method, and the human body’s blood glucose can be quantitatively analyzed. Secondly, this paper builds a simulation model to simulate the blood volume conversion of the human finger, and uses the simulation experimental system to collect the dynamic optical rotation angles of nine wavelengths of a total of 137 human serum samples, and uses partial least squares regression to establish a model between the dynamic optical rotation angles and blood glucose concentration. In the results of predicting all samples using the model, the correlation coefficient and root mean square error were 0.7960 and 2.16 mmol/L, respectively, both of which improved by 137.26 % and decreased by 35.33 %, respectively, compared to the existing method. The experimental results show that the method in this paper has high accuracy in detecting the blood glucose concentration in human beings, which is of great significance in realizing the noninvasive quantitative analysis of human blood glucose components by the polarized light method.

Study of Natural Daylighting Houses in Coastal Area (Case Study: Pasar Bengkulu Village)

Abstract Sunlight is an important thing that humans need to see, recognize and learn certain things in their environment. Sunlight helps humans carry out daily activities indoors. The aim of this research is to examine the intensity of natural lighting in houses in the coastal area of the case study RT 3, Pasar Bengkulu Village. This research is quantitative research by obtaining data from observations and Dialux software simulations. The measurement data will be compared with the lighting standards set out in SNI No. 03-2396-2001. From the simulation results, it was found that there were several rooms that had not reached natural lighting standards, namely, there were 3 rooms in house A, 2 rooms in house B and 3 rooms in house C. Simulation of the optimal light intensity value in house A in room 1 was 508 lux, room 2 is 217 lux and room 3 is 235 lux. At house BThe average value is 220 lux in room 1, the value is 230 lux in room 2, 229 lux in room 3, 235 lux in room 4 and room 5 gets a value of 213 lux. Meanwhile, in house C there is room 1 with a value of 141 lux, room 2 with a value of 197 lux, room 3 with a value of 163 lux, room 4 with a value of 292 lux and room 5 with a value of 242 lux.

DETERMINATION OF OPTIMAL PARAMETERS OF SINTERING OF ROLLING SCALE

This article presents the results of studies conducted to determine the optimal parameters of sintering of rolled scale in a mixture with iron-containing steelmaking waste. The conducted studies of sintering of rolled scale have shown that the gas permeability of the charge depends on a number of physical properties, the size and shape of the grains, the amount of return, the height of the charge layer, and the moisture content of the charge. The initial gas permeability strongly depends on the degree of humidification of the agglomeration charge, especially when sintering small classes of materials under study. The maximum gas permeability of the charge is ensured with an optimal granulometric composition of the charge, which is characterized by an average equivalent diameter: the higher this indicator, the higher the gas permeability of the charge. The value of the surface tension reaches its maximum at a certain moisture content of the charge, which is the optimal moisture for this charge. By increasing the amount of return during agglomeration, the vertical sintering rate increases and the quality of the agglomerate improves. These factors lead to an increase in the productivity of sintering plants. According to the results of the study, the optimal parameters of the sintering sintering process of rolled scale in a mixture with iron-containing steelmaking waste were worked out. It is established that the optimal amount of return is the use of 20 % of the mass of the sintering charge at the optimal height of the sintered layer of 300 mm. As a result of the conducted research, the following optimal indicators were achieved: mechanical strength – 70.2 %, sintering rate – 28.7 mm/min, specific productivity – 1.75 t/m2·hour. Keywords: Rolling scale, agglomeration, optimal parameters, sintering, return, layer height.

RESISTANCE OF HEAT-RESISTANT YTTRIUM-CONTAINING SEALING COATINGS TO MECHANICAL FRACTURE WHEN FORMING CUTTING PATHS

According to the results of tribotechnical tests of coatings made of KNA-82 alloy ligatures with the addition of yttrium of 0.1%, 0.3%, 0.5%, data were obtained that allowed us to establish the nature of changes in the dynamic coefficient of friction over the test period and numerous values of the energy intensity of material wear. The evaluation of coatings formed by the gas-flame and ion-plasma method was based on the following premise. The maximum resistance to mechanical fracture is determined by the manifestation of a constant minimum value of the dynamic coefficient of friction. This serves as an indicator of reduced friction force before reaching the fatigue limit. Another key factor is the number of separated particles produced per unit of integral work during the friction process. These evaluation parameters are lined up in a row by the number of points from 1 to 4. The maximum score corresponds to the maximum resistance, i.e., a lower value of the energy intensity of material wear and the minimum value of the stable friction coefficient. It has been determined that the same coincidence of these parameters according to the scores is almost at all stages of testing (I-III) was the coating formed by the gas-flame method with a yttrium concentration of 0.3%-0.5%. The exception was the coating formed by the ion-plasma method with a yttrium concentration of 0.1% at the fourth stage of testing.

Response of submarine braided channels to varying inflow hydrographs: Geomorphic experiments and stratigraphic implications

AbstractSubmarine channels on the seafloor experience a range of turbidity current‐flood hydrographs. The characteristics of the flood hydrograph influence channel dimensions, the number of channel threads (i.e. braiding intensity) and the depositional properties of sandbars within the channels. However, the morphodynamic response of submarine braided channels to different hydrograph patterns is poorly understood. In this study, six geomorphic experiments are used to test how varied flood hydrographs affect the braiding intensity and sandbar geometry within submarine channels. Three experiments represent the control group with constant density‐current inflow, and three experiments use different time‐varying hydrograph patterns. The experiments show that, as the inflow‐to‐sediment discharge ratio increases, multiple small channels coalesce into a few main channels, causing a decrease in active braiding intensity defined by the channel threads with flow. When the flow returns to the initial low flow rate, active braiding intensity increases again. These observations show that the inflow‐to‐sediment discharge ratio determines the value of active braiding intensity. Additionally, active braiding intensity is directly proportional to dimensionless sediment‐stream power and dimensionless stream power, in agreement with previously established trends for both submarine and fluvial braided channels. In contrast to active braiding intensity changes, the measured sandbar aspect ratio and compactness ratio (i.e. ratio of planform area to perimeter) of submarine braided channels is insensitive to changes in the hydrograph. However, when inflows reach peak discharge, the higher transport capacity erodes pre‐existing deposits, forming noticeable erosional surfaces, and subsequently depositing thicker sandbars during that stage. These observations imply that sandbar planform morphology is largely insensitive to hydrograph, but hydrograph variability induces a greater variability in the resultant stratigraphic packages. The experimental results predict that field‐scale stratigraphy should be dominated by strata deposited during intervals of high flow, but that these strata will also exhibit reduced lateral continuity compared to formation scenarios with constant discharge.

Numerical Simulation Study of an Artificial Percolation Riverbed and Its Hydraulic Characteristics under Different Reynolds Numbers

The direct extraction of clear water from a sandy river is a difficult task and can only be achieved through specific engineering measures. This paper proposes an artificial percolation riverbed structure for extracting clean water from sandy rivers, using a numerical simulation to study the flow field distribution characteristics of the structure under clean water conditions. The main conclusions are as follows: When the percolation vortex tube opening rate is 1.4%, the vortex tube with or without opening the percolation hole has little influence on the distribution characteristics of the flow field in the artificial riverbed, and the purpose of water extraction can be achieved while constructing a helical flow field. The axial flow velocity and circumferential flow velocity of the vortex tube cross-section under different Reynolds numbers show the distribution of a low-flow velocity close to the center of the vortex tube, and a high-flow velocity close to the vortex tube side-wall area. The average axial flow velocity and average circumferential flow velocity of the vortex tube show a trend of increasing and then decreasing distribution along the axial axis of the vortex tube in the direction of the sediment transport flume. The mean axial flow velocity of the vortex tube along the axis of the vortex tube toward the sediment transport flume and the mean circumferential flow velocity both show a distribution trend of increasing and then decreasing. At the junction of the vortex tube and the sediment transport flume, there are obvious pressure changes, and the pressure changes drastically under the same horizontal line. Along the direction of the bottom line of the vortex tube, the pressure at the vortex tube is obviously greater than that at the sediment transport flume. The vortex of the artificial percolation riverbed is mainly concentrated in the vicinity of the vortex tube, and the maximum value of the vortex intensity generally occurs at the junction of the vortex tube and the sediment transport flume. With the increase in the Reynolds number, the vortex intensity has an overall increasing trend, and the distribution of the vortex is more complex. This study helps to elucidate the distribution characteristics of the flow field in the artificial percolation riverbed, and it provides a reference basis for the future study of the flow field of artificial percolation riverbeds of sandy rivers.

The influence of anisotropy on the character of hardening in additive high-strength alloys

The purpose of this work is to establish the dependence of the coefficients of planar anisotropy on the intensity of localized deformations in various loading ranges of transverse and longitudinal sections of samples of heat-resistant powder alloy Inconel 718 manufactured using SLM technology. The role of technological anisotropy of samples characteristic of SLM technology and its effect on the hardening of Inconel 718 alloy products is evaluated. Methods. To achieve this goal, the deformation diagrams of Inconel 718 powder alloy samples manufactured using SLM technology, measured during their stretching according to GOST 11701-84, were analyzed. Flat samples with a dividing grid applied to their surface were subjected to loading. During the tests, localized deformation of the samples in different sections was determined by measuring the geometry of the images of the dividing grid. A specially developed photo and video recording technology was used to capture these images. Results. The statistical analysis of the type and parameters of the deformation diagrams made it possible to determine the nature of changes in the intensity of stresses and deformations of the samples of the studied material. The linear character of its tensile hardening in the region of small values of strain intensity and the power-law character of hardening in the range of strain intensity from 0.03 to 0.17 were established. Conclusion. A significant effect of the technological anisotropy of Inconel 718 heat-resistant powder alloy samples obtained using SLM technology on the intensity of deformations is shown. The necessity of taking this fact into account in the development of technological processes for the production of responsible products from the studied material has been revealed.

Proposal for a New Method for Evaluating Polymer-Modified Bitumen Fatigue and Self-Restoration Performances Considering the Whole Damage Characteristic Curve

Fatigue performance and self-repairing activity of asphalt binders are two properties that highly influence the fatigue cracking response of asphalt pavement. There are still numerous gaps in knowledge to fill linked with these two characteristics. For instance, current parameters fail to accommodate these two bitumen phenomena fully. This study aims to propose a new procedure to address this issue utilizing the linear amplitude sweep (LAS) test, LAS with rest period (RP) (LASH) test, and simplified viscoelastic continuum damage (S-VECD) model. This research work used four different types of asphalt binders: neat asphalt (NA), self-healing thermoplastic polyurethane (STPU)-modified bitumen (STPB), self-healing poly (dimethyl siloxane) crosslinked with urea bond (IPA1w)-modified bitumen (IPAB), and styrene–butadiene–styrene (SBS)-modified bitumen (SBSB). Before the testing process, all the materials were subjected to short-term and long-term aging. The new procedure showed a superior capacity to analyze and accommodate all bitumen fatigue performances and self-repairing activities compared to the current method. Another finding proved that asphalt binders with a higher self-restoration behavior failed to show a better fatigue performance. Moreover, the higher fatigue performance increments produced by STPU and IPA1w in NA concerning the control bitumen were 123.7% and 143.7%, respectively. Those values were obtained with 1.0% STPU and 0.5% IPA1w in NA. A breakthrough finding demonstrated that asphalt binder fatigue response is augmented when the RP was applied at a higher damage intensity (S) value. STPB and IPAB reached their highest increments of fatigue response, containing 1.0% of STPU and 0.5% of IPA1w, respectively. Those augmentations were 207.54% and 232.64%, respectively.

Development of an ESP32 Microcontroller-based Colorimeter with an Android App for the Verification of Roasting Degree of Coffee Beans

A lo w-cost and portable colorimeter was developed using an ESP32 microcontroller and a TCS34725 color sensor to monitor the degree of coffee roast, crucial for maintaining flavor consistency and controlling product quality across different batches. The colorimeter detected color recognition resulting in RGB color intensity values, which could be displayed on the device’s TFT LCD touchscreen. Additionally, colorimetric data was transmitted in real-time via WiFi and stored in a MySQL database using an Android app created with the MIT App Inventor platform. The colorimeter was powered by a rechargeable lithium phosphate battery. The consistency of coffee roasting was ensured by self-identifying the standard RGB values of the roasted coffee beans at five degrees (light, light-medium, medium, medium-dark, and dark) with the app. The darker the color of the roasted coffee, the lower the RGB values were gained. The color detection was highly precise, with a relative standard deviation of less than 5%.

Spatial Simulation and Optimization of Cropping Structure Under Climate and Land Use Change Conditions Considering Synergistic Economic Benefits and Carbon Reduction in Crop Growth Processes

AbstractThe climate and land use changes caused by the natural environment and socioeconomic development have potential impacts on the green and sustainable development of agriculture. To accommodate agricultural production under multiple scenarios of future climate and land‐use change, this study proposes a “simulation–optimization” modeling approach based on a crop growth model with a synergistic “carbon emission–economic benefit” approach. This approach is based on climate change conditions and it accurately simulates future land use changes and crop growth processes, establishes a carbon emission intensity optimization model, and generates a spatial planting structure optimization and regulation scheme based on intelligent optimization algorithms under changing scenarios. The results of the model application show that the planting structure option in the future scenario can increase economic benefit by up to 14.8% compared to the current scenario while simultaneously reducing total greenhouse gas emissions by 6.77%. Correlation analysis of planting area, irrigation water volume, carbon intensity value and unilateral water use efficiency can be used to obtain the coordination level of each county under different regulation scenarios. This “simulation–optimization” modeling approach provides an effective approach to achieve synergistic and coordinated development of regional agricultural benefits and carbon reduction by fine‐tuning the planting structure, which promotes low‐carbon and high‐quality development of regional agriculture.

Development of a µPAD for the point-of-care testing of serum glutamic oxaloacetic transaminase (SGOT).

A wax-patterned paper analytical device (µPAD) has been developed for point-of-care colourimetric testing of serum glutamic oxaloacetic transaminase (SGOT). The detection method was based on the transamination reaction of aspartate with α-ketoglutarate, leading to the formation of oxaloacetate which reacts with the reagent Fast Blue BB salt and forms a cavern pink colour. The intensity of the cavern pink colour grows as the concentration of SGOT increases. UV-visible spectroscopy was utilized to optimize reaction conditions, and the optimized reagents were dropped onto the wax-patterned paper. The coloured PADs, after the addition of SGOT, have been photographed, and a colour band has been generated to correlate the SGOT concentration visually. The images were used to calculate the intensity values using ImageJ software, which inturn was used to calculate the SGOT concentration. The PADs were also tested with serum samples, and SGOT spiked serum samples. The PAD could detect the SGOT concentration ranging from 5 to 200 U/L. The analysis yielded highly accurate results with less than 6% relative error compared to the clinical sample. This colourimetric test demonstrated exceptional selectivity in the presence of other biomolecules in the blood serum, with a detection limit of 2.77 U/L and a limit of quantification of 9.25 U/L. Additionally, a plasma separation membrane was integrated with the PAD to directly test SGOT from finger-prick blood samples.

Surface activity of herniariasaponin and non-saponin fractions of Herniaria L. species

The study investigated the surface activity of aqueous extracts from three Herniaria L. species, namely H. glabra, H. polygama, and H. incana. The three crude extracts exhibited similar chromatographic saponin profiles and equilibrium surface tension values (46–47 mN/m at 1 % concentration). The adsorbed layers were predominantly elastic, with a high compression storage modulus, E'. However, they also showed the ability to dissipate mechanical energy over the aqueous-air interface, as evidenced by fairly high values of the surface compression loss modulus, E'' (45–50 mN/m). The extract of H. glabra exhibited a particularly high E' value (>150 mN/m). To analyze its complex chemical composition, the crude extract was fractionated using liquid chromatography. The sugar fraction was found to be dominant (∼65 % of the extract mass), but exhibited the lowest surface activity. As the acetonitrile content in the eluent increased, the subsequently eluted fractions showed an increasing ability to lower surface tension. The HGW30–70 fraction, which constitutes approximately 20 % of the crude extract mass, was the main contributor to the surface properties of the extract due to its herniariasaponins content. The HGW20–25-A fraction, which showed the second highest surface activity, was further separated into two sub-fractions: non-flavonoid and pure-flavonoid. The former components were primarily responsible for the surface activity and their composition resembled that of a more polar HGW10 fraction (terpene glycosides and C9-C12 fatty acids). The non-flavonoid subfraction was also responsible for solubilization of otherwise poorly water-soluble components, like flavonoids.

Analytical Spectral Semi-quantitative Dating Method of Printed Text Toner Using Raman Spectroscopy and the Fluorescence signal of Paper Sheet Cellulose

Abstract: The chemical processes that occur during the surface degradation of document paper under the influence of external factors were studied by Raman spectroscopy. The possibility of comparing the same processes occurring on clean free paper and under printed text toner letters is of interest. It is assumed that the transformation of cellulose can occur at different rates in the areas of paper exposed to direct atmospheric and light exposure and in the areas containing an intermediate layer of the toner. The most stable temporal changes occur in the region of C–C–C and C– C–O vibrations of glycosidic rings in the short-wavelength region of the Raman spectrum. Background: The main areas of research in the field of document dating, mainly focused on chromatographic methods. These methods are based on studying the dynamics of evaporation of volatile ink components. There is also a variety of chromatography techniques, including gas chromatography, ion chromatography, high performance liquid chromatography, thin layer chromatography and gas chromatography-mass spectrometry. This indicates the wide range of approaches and techniques used to determine the age of written materials. However, all these methods are used mainly during the first two years after writing the document details, which does not allow examining documents that are more than two years old. Methods: Raman spectroscopy was used as the main research method. The object of the study was sheets of white A4 paper with printed text printed on them, produced on a laser printer. The subject of the study was areas of paper free of text, as well as areas of paper under toner. The integrated fluorescence of a paper optical brightener based on stilbene was studied in the wavelength range of 400–500 nm. Also, all objects were studied using optical microscopy. Results: The comparison of peak intensity values averaged over 10 brands over the years made it possible to reveal the following regularities: – the ratio of peaks in the paper spectra from which the toner was removed is greater than in the blank paper spectra, and the difference becomes less noticeable as the age of the paper decreases. The ratio of the intensity of the 330 cm-1 peak to the intensity of the 1603 cm-1 peak: the older the document becomes, the lower the average ratios of these peaks in both the blank paper spectra and in the spectra of paper from which the toner has been removed. –the intensity of the peak in the region of 280 cm-1 and 1 086 cm-1 of the Raman shift increases with decreasing the age of the toner-free paper.– a gradual increase in the intensity of the 380 cm-1 peak is observed when comparing the paper samples from which the toner was removed for 2016, 2018, 2020, and 2022. Regularity was also found in the change in the ratio of the average statistical values of the peak at 280 cm-1 in the spectra of the paper under the toner to a similar peak in the spectra of the paper free from text: the value of this ratio decreases with decreasing the paper age. At the same time, the paper fluorescence signal is an informative parameter that makes it possible to establish some facts from the document’s history. With artificial document aging, a significant broadening of the dispersion region and the appearance of its “splitting” into two or three strata are observed in the distribution of the fluorescence signal level of a paper sheet relative to the average value. The average fluorescence signal of a naturally aged sheet decreases with the age of the document. Conclusion: As a result of research, it has been established that Raman spectroscopy can be successfully used as a method for dating documents. When comparing the degree of degradation of the surface of open areas of paper and areas protected by toner of printed text, different effects of external factors on these areas were established, leading to different rates of degradation processes. The use of Raman peak intensity ratios for paper components in exposed areas compared to peaks under printed text further expands the methodology. The emphasis on spectral methods, in particular fluorescence signal distribution and Raman spectroscopy, to detect surface changes is well justified. It demonstrates a holistic approach to document analysis, taking into account both the chemical changes observed using Raman spectroscopy and the fluorescence signal distribution that may indicate signs of artificial aging through light exposure. This combination of methods appears to be reliable for assessing the age of documents and can make significant contributions to the field of forensic document examination.

Smart Farm Control System Using IoT

This paper presents a way to do smart agriculture by using the advances in technology and information today, especially the Internet of Things (IoT) to help control the environment to change according to the needs of plants automatically. Which this research used the method of making a closed house or Greenhouse size 6m x 9m x 4m in number of 2 houses and using various types of sensor equipment. To detect parameters that affect the environment such as: Temperature sensor, Humidity sensor, Soil moisture sensor, pH sensor and Light sensor. To bring those values ​​forward to the microcontroller to process and order the electrical equipment to work, such as solenoid valves or water pumps; As well as send the parameter value to display the results to the application on the smartphone and the website through the wireless Internet system (WiFi) using the Blynk platform or Blynk cloud. From the results of the design and experiment, it was found that the system can control electrical equipment in the farm system, such as solenoid valves, water pump, and read various values ​​according to the set goals and objectives. We can order control Turn on and off the water system or the fog system anywhere at any time according to the conditions of the internet connection or direct control through the control box at any place or choose to have the system work automatically such as watering and misting according to the conditions we want and the system can also monitor or check the temperature, touch moisture, soil moisture, light intensity and pH value of the water at any time through the platform of the brand that can be used on both smartphones and computers.