Intense Weathering Research Articles

Provenance shifts in bauxitic clay from Zibo, North China Craton, links tectonics and climate to environmental perturbation

Abstract In the eastern North China Craton, the Zibo bauxitic clay deposits are situated between Permian sandstones. These deposits exhibit distinct characteristics in two horizons. The lower horizon consists of disordered kaolinite with anhedral–subhedral, rounded morphologies that indicate a detrital origin. The upper horizon, however, contains ordered kaolinite. Detrital zircon grains in the lower horizon indicate a unimodal age spectrum with a mean age of ca. 290 Ma and εHf(t) values ranging from −20.8 to −6.0. These findings suggest a continental volcanic arc source on the northern margin of the North China Craton. In contrast, detrital zircon grains in the upper section exhibit a multi-modal detrital age spectrum with significant age peaks at 2500 Ma, 1850 Ma, and 310 Ma that originates from the local basement. The zircon dating establishes a maximum depositional age of ca. 280 ± 3 Ma, which indicates denudation of the source area in the northern North China Craton during the Artinskian stage. The relative abundance of detrital kaolinite indicates a warm and humid climate during the late Artinskian (ca. 283 Ma) to Early Kungurian (ca. 280 Ma), while cold and dry conditions prevailed during the mid–late Kungurian (ca. 277 Ma). The northern North China Craton, which supplied source material to the lower section of Zibo bauxitic clay, experienced rapid uplift and exhumation and underwent intense weathering under high humidity and warm temperatures during the late Artinskian to Early Kungurian. However, the source area shifted from the north to a more central region as the climate transitioned to cold and dry conditions in the mid–late Kungurian. Considering that detrital clay formation is indicative of specific climatic conditions, the Permian bauxitic clay deposits in Zibo provide a valuable record of environmental changes during the late Paleozoic ice age (LPIA; ca. 360–260 Ma).

Late Oligocene monsoonal climate in the Lunpola Basin, central Tibetan Plateau: evidence from palaeosol records

The Asian monsoon affects the natural patterns of climate in China and its origin and evolution have been a matter of much debate in palaeoclimatology. Results from recent studies indicate that the Asian monsoon had reached the subtropical zone by at least c. 41 Ma and expanded to the central Tibetan Plateau during the Late Oligocene, although more geological evidence is required to confirm its spatial and temporal evolution. The well-developed Late Oligocene palaeosol in the Lunpola Basin, central Tibetan Plateau is an ideal material for addressing the issue. Observations of various climatic indicators suggest that these palaeosols were forest cinnamon soils, as shown by the compound Bt and Bk horizons, abundant clay coatings and carbonate nodules, and the diagnostic chemical composition of clays in the Bt horizon. A high chemical weather index, the Rb/Sr ratios and high contents of illite/smectite mixed-layer minerals show that these palaeosols experienced intense weathering and leaching during pedogenesis. The mean annual temperature and mean annual precipitation during the developmental period of the palaeosols were 10.4–14.8°C and 615–1128 mm, respectively, as estimated by empirical formulas, which are comparable with those of cinnamon soils in current monsoon climates. This study provides important independent evidence from palaeosols for studies of the evolution of the Asian monsoon. Supplementary material: The data about the clay chemical composition and climatic indicators of palaeosol and modern soils are available at https://doi.org/10.6084/m9.figshare.c.6850703 Thematic collection: This article is part of the Mesozoic and Cenozoic tectonics, landscape and climate change collection available at: https://www.lyellcollection.org/topic/collections/mesozoic-and-cenozoic-tectonics-landscape-and-climate-change

A multiproxy approach to reconstruct the Late Holocene environmental dynamics of the semiarid Andes of central Chile (29°S)

Mountain ecosystems located in the Andes cordillera of central Chile (29–35°S) have been strongly affected by the ongoing Mega Drought since 2010, impacting the snow cover, the surficial water resources (and thereby water storage), as well as the mountain biota and ecosystem services. Paleoenvironmental records in this part of the semiarid Andes are key to estimating the effects of past climate changes on local communities helping to forecast the ecological and biological responses under the aridification trend projected during the 21st century. Here we present a 2400-year multiproxy paleoenvironmental reconstruction based on pollen, diatoms, chironomids, sedimentological and geochemical data (XRF and ICP-MS data) of Laguna El Calvario (29°S; 3994 m a.s.l), a small and shallow Andean lake. Four main hydrological phases were established based on changes in the lithogenic and geochemical results associated with allochthonous runoff input and the subsequent response of the biological proxies. Between 2400 and 1400 cal yrs BP, wetter than present conditions occurred based on the intense weathering of the lake basin and the dominance of upper Andean vegetation. A decrease in moisture along with sub-centennial discrete wet pulses and lake-level changes occurred until ~800 cal yrs BP followed long-term stable climate conditions between 1850 and 1950 AD as suggested by a drop in vegetation productivity and low lake levels. From 1950 AD to the present, a decline in moisture with a severe trend to drier conditions occurring in the last decades occurred as reflected by an upward vegetation belt displacement around Laguna El Calvario along with a turnover of diatom assemblages and high productivity in the water column.

Enhanced Denudation of the Emeishan Large Igneous Province and Precipitation Forcing in the Late Permian

AbstractHydroclimate is an important factor controlling landscape evolution. But establishing the impact of hydroclimate is complicated by the influences of other processes and is especially hard to prove for those in deep time from geological record. During the late Permian, voluminous basaltic sediments were derived from the erosion of the Emeishan large igneous province in western South China. They provide a unique record critical in understanding the responses of tropical basaltic erosion to hydroclimate change without impacts of orogenic uplift, lithologic variation, vegetational difference and glacial‐interglacial change. Sampled successions define a negative carbon isotope excursion capable of making regional and global stratigraphic correlations in the middle Wuchiapingian interval corresponding to the final phase of the late Paleozoic ice age. This interval is associated with a petrofacies shift and a decreasing source weathering intensity, a downward shift of erosion loci, and a reduced coastal water paleosalinity. Applying present‐day temperature dependence pattern of basaltic weathering and using land surface temperatures approximated from nearby paleo‐seawaters, denudation rates were calculated for the Emeishan basaltic province and shows an increase from ∼71 to ∼107 m/Ma. This erosional acceleration is temporally correlated with a decrease in paleosalinity and likely linked to enhanced freshwater discharge in the middle Wuchiapingian. Scaling and landscape erosion modeling suggest ∼80%–130% increase in catchment precipitation could have driven this acceleration in denudation. Our work provides a positive test for the hydroclimate forcing on landscape erosion in deep time and underlines the mechanistic linkage of sediments with erosion and climate change.

Composition and constraints of lithium isotopes in cryoconite from various remote glacier areas of the Tibetan Plateau

Lithium isotope is one of the most promising indicators for the study of continental silicate weathering, and lithium concentrations and its isotopic compositions in earth surface can provide a better understanding of the geochemical behavior and isotopic fractionation during weathering and erosion. This work focused on the composition and distribution of Li isotope in cryoconite deposited on various glacier areas in a large range of the Tibetan Plateau and surroundings, as well as its implications for cryoconite dust provenances. Results showed that δ7Li in cryoconite varied within the same order of magnitude (−2.14 ‰-7.74 ‰), which is characterized by geographic distribution of higher δ7Li value of cryoconite in northern glaciers (e.g. Yuzhufeng Glacier), and lower δ7Li value in southern glaciers. In comparison with other global materials, the cryoconite dust shows a lighter δ7Li isotopic composition due to constraints of climatic conditions and land surface weathering intensity. Compared with dust materials in the surrounding Asian dust sources (e.g. large deserts and Gobi), we find that, the primary sources of Li isotope in cryoconite of the northern locations were from both local dust/soils of the TP surface and the surrounding large deserts. Moreover, the products of anthropogenic activities (e.g. coal-burning) may also influence the isotopic composition of the cryoconite dust, and Li isotope may serve as potential tracers of anthropogenic source activities. Therefore, this work provides a complete view of the composition and distribution of Lithium isotopes in cryoconite from various glacier areas of the Tibetan Plateau, and the research significance of its transport processes and source constraints of Li isotopes in cryoconite is proposed.

Intensive chemical weathering in the Arctic during the Miocene Climatic Optimum

The Arctic today has shallow, chemically immature, and frost-dominated weathering regimes. At Sokli, Finland (68°N), a 70 m deep palaeo-weathering profile is developed in a Devonian carbonatite pipe that represents fundamentally different past weathering environments. Formation of the apatite-francolite P-ore likely began under Palaeogene warm, humid climates. Later, cryptomelane (K-Mn oxide) crusts developed within the ore that have yielded peak 40Ar/39Ar ages of 16.20 ± 0.13 Ma (2σ)., The crusts formed at the redox front during the Miocene Climatic Optimum (∼16.9–14.7 Ma) under mean annual temperatures ∼12–14 °C warmer than today. The presence of the cryptomelane crust at shallow depth (15 m) indicates very low erosion rates since formation, consistent with its position on a tectonically stable Archaean craton and in the cold-based ice-divide zone of successive Fennoscandian ice sheets. The Miocene Climatic Optimum triggered a pulse of intensive weathering in mid- and low latitudes; the Sokli cryptomelane ages demonstrate that intensive chemical weathering extended into the Arctic.

Способ экспериментального нахождения коэффициента склоновой эрозии

The article deals with the theory of slope erosion, developed on the basis of the phenomenological law, according to which the intensity vector of soil erosion from the slope is proportional to the absolute value of its height gradient vector and inverse in direction. Since the erosion model includes a phenomenological coefficient of proportionality between the intensity of soil weathering and the elevation gradient, it is necessary to provide a way to find such a coefficient experimentally. Comparison of changes in elevation data obtained during field monitoring with the results of theoretical calculations enables identifying it

Architecture of lacustrine deposits in response to early Carboniferous rifting and Gondwanan glaciation, Nova Scotia, south‐east Canada

AbstractUpper Palaeozoic lacustrine basin deposits not only record local tectonism but are also an archive to evaluate global palaeoclimate changes linked to the Late Palaeozoic Gondwanan ice age. The Tournaisian Horton Group of Nova Scotia, south‐east Canada, accumulated in rift basins following the final accretion of peri‐Gondwanan terranes to the Appalachians. Sedimentology, mineralogy and geochemistry of the well‐exposed sandstones and shales at the classic Blue Beach section (ca 353.5 to 352 Ma) reveal the interplay of local tectonism and global climatic controls on lacustrine sedimentation. The lacustrine depositional environment gradually transitioned from deep water offshore at the base of the section to wave‐dominated and fluvial‐dominated nearshore at the top. Multiple small transgressive–regressive sedimentation cycles have an average 21 ka duration, likely related to Milankovitch cyclicity. Unusually abundant soft‐sediment deformation structures and landslides are the sedimentary responses to frequent earthquakes during the most active phase of rift subsidence. The overall succession shows changes from a shallowing‐up balanced‐filled to an overfilled lacustrine basin. The chemical weathering intensity index and the Th/K ratio show a longer‐term trend from dry and cool conditions low in the section to humid and warm conditions near the top, with rapid change in the transition period. The section records the peak of the global mid‐Tournaisian carbon isotope excursion and the corresponding cooling event (354 Ma to approximately 351 Ma). The sedimentary succession is a response to long‐term and short‐term climatic cycles influencing lake level and sediment supply during the time of maximum rift basin subsidence recorded by the soft‐sediment deformation structures.

The impact of paleoclimatic on the structural strength of loess paleosol sequences and its implications for tillage on the Loess Plateau: A case study from Luochuan profile

The structural strength of the Loess-Paleosol Sequence (LPS) and the presence of paleosols within the LPS have significant implications for tillage and understanding past climate conditions. This research investigation sought to examine the structural strengths of the Luochuan (LC) LPS via both triaxial shear and oedometer tests, with the microstructure being further characterized through scanning electron microscopy. Results indicate that the LPS's structural strength tends to increase as burial depth increases. Additionally, the loess layer's structural strength is typically lower than that of the adjacent paleosol layer. The LPS's microstructure experiences considerable transformations with increased burial depth, particularly regarding changes in particle contact relationship, degree of cementation, and pore volume. This shift is characterized by a transition from an overhead structure to a matrix structure. These findings suggest that the loess layers' structural strength is associated with weaker pedogenic weathering occurring under cold and dry climatic conditions, whereas the paleosol layer exhibits a higher structural strength due to intense weathering during a warm and humid climate. Overall, this study establishes a link between paleoclimate and mechanical properties, using microstructure as a mediating factor, and provides a theoretical basis for tillage on the Loess Plateau.

Cation exchange controls riverine magnesium isotopes in extremely-high-erosion catchments

Carbonate weathering plays a significant role in regulating global carbon budget at short time scales, and thus needs to be better constrained in the context of global warming. Riverine magnesium isotopes (δ26Mg) have the potential to trace carbonate weathering intensity (CWI) but require further testing under various climatic and geological settings. Cation exchange is an important mechanism buffering river water chemistry, especially in catchments characterized by high erosion. However, field evidence on the influence of cation exchange on riverine δ26Mg is rare. In this study, spatial riverine δ26Mg variation within the Three Rivers (i.e., the Jinsha Jiang, the Lancang Jiang, and the Nu Jiang), three extremely-high-erosion catchments in the southeastern Tibetan Plateau, was investigated to address this issue. The results showed that riverine δ26Mg values present a wide range from –1.11 ‰ to –0.59 ‰ in the Jinsha Jiang, from –1.39 ‰ to –0.65 ‰ in the Lancang Jiang, and from –1.19 ‰ to –0.50 ‰ in the Nu Jiang. An inversion model was used to partition riverine Mg2+ sources and confirmed that the riverine Mg2+ budget was dominated by carbonate weathering, followed by evaporite dissolution. However, conservative mixing could not explain riverine δ26Mg variation within the Three Rivers catchments, because measured δ26Mg values (δ26Mgmeasured) systematically deviated from the modeled ones (δ26Mgmodeled), with Δ26Mgmeasured–modeled (δ26Mgmeasured – δ26Mgmodeled) up to 0.79 ‰. The positive correlations between Δ26Mgmeasured–modeled and suspended particulate matter (SPM) concentrations indicate Mg isotopic fractionation was related to high suspended loads owing to extremely-high erosion rates. Given the significant cation exchange capacity of SPM, Mg2+-Na+ exchange is proposed for the first time as an explanation for the observed δ26Mg variations in the rivers draining the Tibetan Plateau, although the role of carbonate precipitation could not be excluded. The strong positive correlations between riverine δ26Mg and exchangeable Mg/Na ratios in the Three Rivers further support that light Mg isotopes may be preferentially retained in the riverine exchange pool during Mg2+-Na+ exchange, driving riverine δ26Mg towards higher values. Expanding our finding to global rivers, the negative correlation between riverine δ26Mg and CWI can be interpreted by a competition between the fast dissolution of carbonates leading to the enrichment of 24Mg in waters and Mg isotope fractionation induced by cation exchange leading to the depletion of 24Mg in the residual waters. This study provides new insight into cation exchange as a regulator of riverine δ26Mg and Mg cycling, highlighting the robustness of riverine δ26Mg in tracing CWI and constraining the carbon cycle.

Physical weathering of Gobi Desert sediments under different temperature and humidity conditions

Physical weathering of the Gobi Desert surface sediments involves complex processes. However, our understanding of its main driving factors is still limited, and experimental observations on the weathering intensity of Gobi Desert surface sediments under changing environmental conditions are still insufficient. Surface samples were collected from the Gobi Desert, divided into 0.063–0.125 mm, 0.125–0.25 mm, 0.25–0.5 mm, 0.5–1 mm and 1–2 mm groups, and washed with deionized water. Physical weathering and salt weathering experiments of these groups were conducted under temperature (T) of −40 °C–40 °C and relative humidity (RH) of 20 %–100 %. Salt and mineral analyses, grain size distribution, and morphology analysis of each fraction group before and after the experiments were conducted. The results showed that mean grain sizes for the 0.063–0.125 mm, 0.125–0.25 mm, 0.25–0.5 mm, 0.5–1 mm, and 1–2 mm groups decreased by 0.49 ± 1.09 %, −0.27 ± 2.14 %, 0.41 ± 3.14 %, 2.96 ± 3.14 %, and 0.19 ± 1.29 %, respectively. The mean size of each group decreased ∼ 0.76 ± 1.13 % /10 days, demonstrating a higher physical weathering intensity than the previous estimations. The d0.1 size (i.e., the grain diameter for which 0.1 % of each grain group is smaller) was more sensitive to physical weathering, and the skewness was a good indicator of physical weathering for groups obeying a normal distribution. Physical weathering was still affected by salt weathering, and there was no regular pattern for physical weathering under variations in salt and mineral contents. At present, there are still difficulties in developing an accurate physical weathering intensity model.

Assessing hydrological controls on the lithium isotope weathering tracer

To investigate the impact of riverine discharge and weathering intensity on lithium isotopes (δ7Li) in a mono-lithological terrain, this study examines the dissolved load and leached suspended load (exchangeable, oxide, and clay fractions) from Icelandic rivers spanning a wide range of discharge, weathering rates, and weathering intensity. The δ7Lidissolved co-varies inversely with the discharge, confirming that water-rock interaction time is a primary control on the secondary mineral formation that fractionates Li isotopes. The “boomerang” shape observed in global rivers between the weathering intensity (i.e. W/D = weathering rate/denudation rate) and δ7Lidissolved also exists for these basaltic rivers at low to medium W/D. However, these rivers do not extend to such low δ7Lidissolved values as seen in the global compilation at low W/D, indicating that there is a lithological control on this relationship arising from the type of the lithology-specific secondary minerals forming and their precipitation rates. In addition, the Δ7Lix-dissolved between each leached solid phase and the dissolved load also co-varies with discharge. At low discharge (long water-rock interaction times), Δ7Lix-dissolved values agree with experimentally-determined equilibrium values, whereas less fractionated values are observed at higher discharge (shorter water-rock interaction times). As a result, there is a different relationship between W/D and Δ7Liclay-source in this basaltic terrain than previously reported from global multi-lithological river sediment samples, with clay leachates from Iceland more closely mimicking the boomerang shape of the dissolved load. However, the relationship between δ7Li and weathering processes is complicated because the fractionation between the clay fraction and the dissolved load is not constant but varies with both W/D and discharge. Overall, this study confirms the utility of Li isotopes as a tracer of modern and palaeo-weathering processes, and also has important implications for the specific interpretations of detrital δ7Li values, which may be more sensitive to weathering parameters than previously thought.

The influence of secondary weathering processes on dissolved nickel isotope compositions under cold climatic conditions – Observations from the Mackenzie Basin

Nickel (Ni) and its stable isotope signature (δ60Ni) have recently gained momentum as a tracer of nutrient cycling in the modern and past oceans. A robust understanding of Ni isotope cycling in the ocean rests on an accurate understanding of the Ni sources and sinks to and from the oceans. In particular, rivers, which are the dominant Ni source to the oceans, show significant variation in Ni isotopes compared to rocks, thought to reflect variable extents of formation of secondary phases that scavenge light Ni isotopes. The current estimate of the global isotope composition of riverine Ni is based on a few large rivers in warm climates, thus preventing the assessment of a potential climatic control on the Ni isotope flux to the ocean. In this contribution, we investigate the Ni elemental and isotope signatures of river catchments in cold climates, namely the Mackenzie Basin tributaries (Canada) and two rivers, the Nass and Skeena, draining the Western Cordillera.The river solid load in the Mackenzie Basin shows almost no resolvable variation in terms of Ni abundances and Ni isotopes, which are similar to silicate rocks. Furthermore, dissolved Ni and Ni isotopes do not show any relationship with source tracers. This suggests a minimal source control on variations in riverine Ni. This result is particularly intriguing as riverine chemistry in the Mackenzie Basin is often dominated by lithological controls, including rocks other than silicate, such as carbonate and black shale. Instead, the variations in dissolved Ni isotopes are related to the removal of dissolved Ni, reflecting the dominant control by secondary weathering processes. The Ni isotope fingerprint of these secondary weathering processes reflects Ni scavenging into metal oxides, consistent with the literature. The data presented here and literature data show that dissolved Ni and lithium isotopes (a tracer of clay formation) exhibit contrasting patterns between the Mackenzie and the Amazon basins. This suggests that climatic conditions might couple or decouple the formation of metal oxide and clay. In addition, the Ni isotope signatures of the river dissolved load vary with the specific weathering intensity of Ni (the fraction of riverine Ni exported as dissolved species). At high specific weathering intensity of Ni, the Ni isotope signature reflects that of silicate, consistent with the congruent release of Ni from the weathering of silicate. Lower specific weathering intensities of Ni are associated with heavier Ni isotope signatures, suggesting greater scavenging of Ni onto secondary metal oxide. Finally, at the lowest Ni weathering intensity, the dissolved Ni isotope composition is lower again, potentially implying limited metal oxide formation under such conditions. Therefore, and though more data are required to confirm the hypothesis from this initial data, while climate might play a role in the relative rate of Li- and Ni- scavenging phase formation, the specific weathering intensity of Ni may be more significant in controlling dissolved Ni isotope composition.

Tracing the source and transport of Hg during pedogenesis in strongly weathered tropical soil using Hg isotopes

Soil is one of the largest reservoirs and re-emission sources of mercury (Hg) on Earth’s surface. The accumulation and remobilization of Hg during pedogenesis affect how Hg is transported from terrestrial to aquatic environment and biota, but these processes are poorly understood. Here we present Hg concentration and isotope ratios of soil and bedrock samples from a latosol profile formed through intense weathering of Cenozoic basalts in Zhanjiang, Guangdong Province, China, to trace the sources, transport and transformation processes of Hg during pedogenesis, and to gain insights on the potential impact of tropical soils on global Hg cycling. The entire soil profile shows negative δ202Hg (−2.97‰ ± 0.08‰ to −2.54‰ ± 0.08‰) and negative Δ199Hg (−0.68‰ ± 0.04‰ to −0.43‰ ± 0.04‰), with a gradual downward positive shift of Δ199Hg below 35 cm. An isotopic mixing model based on Δ199Hg suggests a dominant Hg input from atmospheric Hg (HgAtm) and limited contribution (<36%) of geogenic Hg (HgGeo) from the bedrock. The strongly negative Δ199Hg throughout the latosol profile suggests that HgAtm was likely subject to substantial photoreduction on soil surface and migrated downward after incorporation into soils. Moreover, there is a distinct positive shift of δ202Hg alongside a rapid decrease of HgGeo from the bedrock to the weakly weathered basalt, indicating a substantial loss of HgGeo with the preferential release of lighter isotopes during the initial weathering, likely due to the dissolution of primary minerals. In addition, the δ202Hg shows a negative correlation with soil pH at some horizons, attributable to the isotopic fractionation during Hg(II) speciation change in soil solution and the selective complexation/adsorption of different Hg(II) species onto mineral surfaces, which are affected by surface charge properties and thus soil pH. Overall, our results provide direct evidence for the accumulation and downward migration of HgAtm in tropical soils during pedogenesis, as well as the loss of HgGeo during the weathering of bedrock, which may serve as an underappreciated source of Hg in tropical regions and have a potential impact on the Hg isotope signatures in aquatic environments.

Anomalous weathering trends during the Early Silurian warming: Implications for the biotic crisis and recovery

The Late Ordovician mass extinctions were divided into two distinct stages, with the second stage occurring during the Late Hirnantian. However, biotic recovery was delayed until the Aeronian and the triggering factors are still unknown. To comprehend the connections between paleoclimate, marine redox states, and biotic recovery in the Early Silurian, we analyzed temporal variations in chemical weathering intensity using multi-geochemical proxies for the shales of the Longmaxi Formation in South China. The results reveal a significant increase in chemical weathering intensity from the Rhuddanian warming phase to the Aeronian cooling phase. This increase is anomalous, considering it coincides with the Early Silurian's climate cooling. This study posits that Rhuddanian sediments exhibited low chemical weathering intensity and more congruent weathering, while Aeronian sediments were characterized by intermediate chemical weathering intensity and incongruent weathering. Given that the gradual enrichment of oxygen within bottom waters can be supported by Corg/P and Corg-S-Fe, this study suggests that congruent weathering-induced high paleoproductivity is the primary factor accelerating anoxia in the Rhuddanian. In summary, the persistent marine anoxia of seawater thus triggered the deposition of organic-rich shales and delayed biotic recovery in the Rhuddanian.

Development of a lateral topographic weathering gradient in temperate forested podzols

Mineral weathering is an important soil-forming process driven by the interplay of water, organisms, solution chemistry, and mineralogy. The influence of hillslope-scale patterns of water flux on mineral weathering in soils is still not well understood, particularly in humid postglacial soils, which commonly harbor abundant weatherable primary minerals. Previous work in these settings showed the importance of lateral hydrologic patterns to hillslope-scale pedogenesis. In this study, we hypothesized that there is a corresponding relationship between hydrologically driven pedogenesis and chemical weathering in podzols in the White Mountains of New Hampshire, USA. We tested this hypothesis by quantifying the depletion of plagioclase in the fine fraction (≤2 mm) of closely spaced, similar-age podzols along a gradient in topography and depth to bedrock that controls lateral water flow. Along this gradient, laterally developed podzols formed through frequent, episodic flushing by upslope groundwater, and vertically developed podzols formed through characteristic vertical infiltration. We estimated the depletion of plagioclase-bound elements within the upper mineral horizons of podzols using mass transfer coefficients (τ) and quantified plagioclase losses directly through electron microscopy and microprobe analysis. Elemental depletion was significantly more pronounced in the upslope lateral eluvial (E horizon-dominant) podzols relative to lateral illuvial (B horizon-dominant) and vertical (containing both E and B horizons) podzols downslope, with median Na losses of ∼74 %, ∼56 %, and ∼40 %, respectively. When comparing genetic E horizons, Na and Al were significantly more depleted in laterally developed podzols relative to vertically developed podzols. Microprobe analysis revealed that ∼74 % of the plagioclase was weathered from the mineral pool of lateral eluvial podzols, compared to ∼39 % and ∼23 % for lateral illuvial podzols and vertically developed podzols, respectively. Despite this intense weathering, plagioclase remains the second most abundant mineral in soil thin sections. These findings confirm that the concept of soil development as occurring vertically does not accurately characterize soils in topographically complex regions. Our work improves the current understanding of pedogenesis by identifying distinct, short-scale gradients in mineral weathering shaped by local patterns of hydrology and topography.

Iron pools of the typical loess–palaeosol sequence and their environmental significance in northeastern China

AbstractThe iron content can be used as a proxy for the intensity of weathering and pedogenesis, which reflect long‐term climate cycles and short‐term climate fluctuations and events. In this study, a typical loess–palaeosol sequence for 19.85 m in thickness deposited since 423 ka BP in northeastern China was investigated, and its iron pools were determined. The results reveal that with increasing depth, the abundances of different forms of iron are consistent with the changes in the magnetic susceptibility. Iron (Fe) in all forms is more abundant in the palaeosol than in the loess. The silicate‐bound Fe pool (Fer = Fet − Fed) accounts for 60.4% of the total Fe (Fet), indicating weak pedogenesis. The Fe in the crystalline oxides (Fec = Fed − Feo) is predominantly free Fe (Fed), with a crystallinity [Fey = (Fed − Feo) × 100 / Fed] of as high as 97.2%. The coefficients of variation of the different forms of iron associated with the soil depth are as follows: Fec &gt; Fed &gt; poorly crystalline Fe (Feo) &gt; Fer &gt; Fet. The distribution of the forms of Fe throughout the profile is a clear indicator of the pedogenesis. The Fed, Fec, and Fe freeness (freeness = Fed × 100 / Fet) correlate with the magnetic susceptibility. The neoformation of iron (Fe) oxides was closely related to the degree of pedogenesis. More crystalline Fe oxides were found in the soil layers corresponding to warm interglacial periods. We detected variations in the abundance of the Fe pools for characterizing climate fluctuations that occurred in a short period of time. In this study, we demonstrated that when used in combination with dating techniques, morphological development indices, and magnetic susceptibility, the measurement of soil Fe pools can be extremely useful for tracing the iron evolution in the Earth's critical zone and reconstructing past climatic events in loess–palaeosol sequences.

Contrasting riverine K and Li isotope signatures during silicate weathering in the southeastern Tibetan Plateau

Mountain uplift produces steep slopes and rapid erosion rates, and hence exposes more silicate rocks to weathering and accelerates the drawdown of atmospheric CO2, driving global cooling over the Cenozoic. Riverine potassium (K) and lithium (Li) isotopes are two promising proxies for silicate weathering because the isotopes fractionate during secondary mineral formation associated with weathering and these two elements are highly enriched in silicate rocks. This study explores similarity and difference between K and Li isotope behaviors during weathering across the Lancang River in the southeastern Tibetan Plateau, in order to evaluate the role of these two isotopes in tracing silicate weathering in tectonically active mountains. Dissolved K and Li in the Lancang River mainstream are mainly derived from the dissolution of silicates. River waters are enriched in the heavy isotope of K (−0.35‰ to +0.05‰) and Li (+7.1‰ to +20.4‰) relative to suspended sediments (−0.56‰ to −0.42‰ and −2.3‰ to 0‰, respectively), and the element partitioning between dissolved and suspended loads controls dissolved δ7Li and δ41K values. Interesting, dissolved δ7Li and δ41K show the opposite evolution trends toward downstream. As the weathering intensity increases downstream (higher Si/(Na + K)⁎ ratios), the dissolved δ7Li values increase from 7.4‰ to 13.6‰, whereas dissolved δ41K values decrease from −0.04‰ to −0.26‰. Compared to its headwater with limited weathering, more secondary minerals (e.g., clays) are formed in the lower reaches (e.g., floodplains) with low physical erosion rates and high annual precipitation, driving more 6Li incorporated into clays, thus high dissolved δ7Li values downstream. While dissolved δ41K values and the fraction of 39K incorporated into secondary minerals are low in floodplains, this is consistent with observations that illite is a main K-bearing phase among clay minerals, and its content in the clay fraction in river sediment decreases as weathering intensity increases. Our study further supported that the increase in Cenozoic seawater δ7Li is related to weathering in floodplains rather than weathering of mountains, whereas K isotope fractionation mainly occurs in mountain regions. If Cenozoic seawater δ41K rise, as with δ7Li change, weathering at higher elevation may exerts more effect on high riverine and seawater δ41K values. This study improves our knowledge of K-Li isotope behaviors during present-day silicate weathering, and the response of K-Li isotopes in sedimentary archives to silicate weathering over geological time.

CHEMICAL COMPOSITION AND PEDOGENESIS OF SOILS OF AGRICULTURAL COLLEGE FARM, NAIRA, ANDHRA PRADESH

The study on elemental composition and pedogenesis of soils of Agricultural College farm, Naira of Srikakulam district was carried-out during 2021. The soils were developed from granite-gneiss parent material. Total silica (SiO2) content of soils ranged from 50.5 to 74.6 percentage. Silica content in general decreased with soil depth, while sesquioxides (R2O3), alumina (Al2O3), iron oxide (Fe2O3), CaO, K2O, Na2O, MnO were found increasing with depth. High silica/ sesquioxide ratio of soils indicated siliceous nature of soils. The aluminum oxide content of the profiles varied from 15.80% to 26.25%. Highest value was reported in lowland profile, whereas, the lowest value was recorded in rainfed upland profile. Iron oxide content varied from 5.04% to 8.50%. Iron oxide content showed slight variation within profiles. Among the other oxides, CaO &gt; MgO &gt; K2O &gt; Na2O was of the order as the soils were developed under semi-arid climate, wherein, basic cations have accumulated in these soil profiles due to limited leaching. The molar concentration of silica (SiO2) ranged from 0.841 to 1.24 moles, and molar concentration of sesquioxide ranged from 0.191 to 0.313 moles. The molar ratio of SiO2 / R2O3 varied from 2.68 to 6.51 in different soil profiles. The SiO2 / Al2O3 ratio varied from 3.33 to 8.02. These wider molar ratios indicated salacious nature of parent material and due to dominance of silica among chemical fractions. Midland (P3) and lowland (P4) soil profiles showed silt/clay ratio of less than 0.45 and upland profiles showed more than 0.45 indicating relatively advanced weathering in mid and lowland profiles while it was moderate weathering in upland profiles. The Weathering Index of Parker (WIP) values of the soils of study area ranged between 2.8 and 32.4. The lower WIP values (2.8 to 8.1) were associated with rainfed uplands and higher values of 14.7- 32.4 with irrigated low lands. The PIA values ranged from 67 to 97 tend to decrease with the depth in all profiles. The profiles examined have the CIA values varied from 66 to 95 indicating high to intense weathering. The CIA values decreased with depth in all the profiles. The surface horizons of P1 and P2 soil profiles were classified as moderately weathered. On the other hand, all subsurface horizons of these two profiles were highly weathered. However, in profiles P3 and P4 the CIA values ranged between 68 to 90 indicating that these soils were highly weathered. CIW values closely followed the trend of CIA values. The bases/R2O3 values of all profiles ranged from 0.061 to 0.608 and found increased with soil depth in all the profiles. Relatively higher values of bases/R2O3 were found in P4 (low lands) indicating base rich character. Middle land and lowland black soil profiles showed silt/clay ratio of less than 0.45 and upland profiles showed morethan 0.45 indicating relatively advanced weathering in mid and lowland profiles while moderate weathering in upland profiles.

Assessment of Weathering Intensity and Pedogenesis of Lithosequence Located in Two Agroecological Zones of Nigeria

Elemental oxides can help to identify processes of soil formation and the degree of soil development. This study assessed soil development and weathering intensity in soils developed on schist and older granite in upland tropical rain forest and southern guinea savanna agro ecological zones of Nigeria. Soil profile samples were collected in each of the study locations. In the laboratory, total elemental oxides was determined using the energy dispersing X-ray Fluorescence (EDXRF) XRF SPEC (Minipal 4). The relative intensity of weathering of total elemental oxides was determined by choosing titanium as the suitable indexing element and the relative gain or loss of element was estimated using relative retained element (Ro) equation. Result obtained, revealed that SiO2 was the most abundant in the soils. Distribution of Al2O3 and CaO showed the direction of the pedogenic age. Older granite soil had higher values of Al2O3 and lower values of CaO. There was negative relationship of SiO2 with Al2O3 and Fe2O3. The trace elemental oxides were less than 1% and zirconium oxide was the most retained oxide in the soils. Soil which developed on schist retained more of the trace elements than soil on older granite. There was evidence of alitization, ferritization and desillication in the soils. Parent materials contributed to loss and gain of trace elemental oxides. Older granite soil was more weathered and pedologically older than schist derived soils.