Integrated Ocean Drilling Program Site Research Articles

Low-high latitude forcing on the East Asian winter monsoon evolution since the last glacial maximum

Abstract The East Asian winter monsoon (EAWM) has a profound effect on the winter climate in East Asia. The modern EAWM variability is tightly linked to the high-latitude Northern Hemisphere climate change through the Siberian High and can also be regulated by the low-latitude El Niño-Southern Oscillation through oceanic or atmospheric teleconnections. However, the Quaternary EAWM evolution has long been only attributed to the high-latitude climate change, resulting in the uncertainty in interpreting the out-of-phased EAWM variation recording in the East Asian continent and marginal seas. Here we presented a sediment record at Integrated Ocean Drilling Program Site U1427 in the southern Japan Sea to reconstruct the EAWM evolution since the last glacial maximum. By combining our record with previous reconstructions and simulations, we found the synchronous relationship between winter monsoon in northern and southern regions of East Asia from ∼24 to 8 ka, but anti-correlated relationship since ∼8 ka. We proposed the winter insolation and Atlantic meridional overturning circulation were the main drivers from last glacial to early Holocene, and then ENSO became a dominant factor in controlling the regional heterogeneity of EAWM evolution in the middle and late Holocene. This research explains much of the controversy in the Quaternary EAWM records and highlights the low-high latitude interaction in East Asian winter climate change.

Effect of Size Fractions of Foraminifera on Reconstructing the Paleoceanography of Cretaceous Oceanic Anoxic Event 2

Abstract The globally recognized Cretaceous Oceanic Anoxic Event 2 was recorded at Integrated Ocean Drilling Program Site U1407 in the North Atlantic in sediments that were deposited under varying oxygen concentrations, conditions often associated with decreased foraminiferal test size. A >63-µm size fraction is typically used for collecting foraminifera that live in low-oxygen and deep-sea settings, particularly for paleoceanographic reconstructions where key environmental indicator species may be under-represented or absent in coarser sizes. Using 31 sediment samples from the site, we test the best size fraction to utilize when exploring biotic responses to an oceanic anoxic event. Counts of benthic and biserial (heterohelicid) planktic foraminifera from the standard >63-µm and finer 38–63-µm sieve sizes are compared to determine if critical information is lost if the smaller size fraction is not used. Results show similar trends in relative abundances for both size fractions. There are higher abundances in 38–63-µm residues, but species identification and counts are overly time-consuming for obtaining the general trends. We recommend the use of >63-µm sieves for foraminifera collected from low-oxygen sediments but encourage examination of the 38–63-µm fraction to verify intervals recognized as barren are truly absent of foraminifera.

Surface water mass dynamics at IODP Site U1313 through Principal Component Analysis: Evidence from coccolith assemblages in the ∼25–7 kyr interval

Coccolith assemblages from Integrated Ocean Drilling Program Site U1313 (North Atlantic; 41°0′N, 32°57.4′W) are analysed to assess temporal changes in surface water conditions from the Last Glacial Maximum (LGM) to the Middle Holocene (∼25–7 kyr). We perform Principal Component Analysis (PCA), involving both calcareous nannofossil assemblage data and other paleoenvironmental proxies. We reconstruct sea-surface dynamics using calcareous nannofossil assemblage variations and comparison with other previously published proxy data from Site U1313 including C37:4 alkenone, dolomite/calcite and quartz/calcite ratios, Uk’37 SST, as well as the sedimentation rate.We use variations in paleoproductivity proxies, cold and warm water group abundance, and the PCA results to infer North Atlantic Current (NAC) and North Atlantic Transitional Waters (NATW) migration through the studied interval. These proxies are also used to highlight variations in the Subtropical Gyre dynamics. Warming episodes are recorded during the LGM and Heinrich Stadial (HS) 1 as a result of northward expansion of the Subtropical Gyre. High coccolithophore productivity episodes characterize HS 1 and 2, and are concomitant with increasing terrigenous input. Both processes are considered a consequence of iceberg influence, which transport nutrients and ice-rafted debris to the area. A southward shift of the Subpolar Front and NAC favour the expansion of cold water from 25.3 ka to the end of the Younger Dryas, whereas the early Holocene is characterized by NATW influence resulting from northward migration of the NAC and Azores Current.

Barium isotope compositions of altered oceanic crust from the IODP Site 1256 at the East Pacific rise

This study reports barium (Ba) isotope compositions of intact altered oceanic crust (AOC) recovered from Integrated Ocean Drilling Program (IODP) Site 1256, East Pacific Rise (EPR), to investigate the behavior of Ba isotopes during both low-temperature seawater alteration and high-temperature hydrothermal alteration processes in the oceanic crust. The Ba isotope compositions of the volcanic section and sheeted dike complex have large variations and are mostly heavier than those of the fresh EPR MORB, with δ138/134Ba ranging from −0.01‰ to +0.39‰, which may be attributed to the modification of Ba isotopes by seawater and hydrothermal fluid during low-temperature and high-temperature alteration. The samples from the plutonic complex display much lighter Ba isotope compositions than the fresh EPR MORB, having δ138/134Ba values of −0.22‰ to −0.06‰, which may reflect the influence of late magmatic fluids. Because of the large Ba isotope variation in the AOC and the obvious difference in Ba isotope compositions between the AOC and the upper mantle, the recycling of the AOC could result in Ba isotope heterogeneity in the mantle and further indicate the application of Ba isotopes for tracing crustal material recycling in the Earth's mantle.

British–Irish Ice Sheet and polar front history of the Goban Spur, offshore southwest Ireland over the last 250 000 years

Deep Sea Drilling Program (DSDP) Site 548 was cored in 1984 at a water depth of 1256 m on the Goban Spur, offshore southwest Ireland. Coring retrieved a ~100‐m‐thick Pleistocene contourite sequence. This study uses planktonic foraminiferal assemblage and benthic foraminiferal oxygen isotope analyses to establish an age model for the upper 40 m of this core. This site's multidisciplinary analyses of planktonic foraminiferal assemblages, lithic grains, facies and calcium carbonate concentration reveal a 250 000‐year record of the North Atlantic polar front variability and British–Irish Ice Sheet (BIIS) history. The sequence is characterized by alternations of ice rafted debris (IRD) laden pelagic mud facies with calcium carbonate‐rich silty sand contourite facies that track glacial/interglacial cycles. The polar front migrated southward across the area several times during glacial maxima and stadial periods, while warmer Mediterranean Outflow Water (MOW) flowed northward across the region during interglacial and interstadial periods depositing contourites. Lithic analyses reveal a complex history of IRD deposition associated with iceberg calving from the Laurentide Ice Sheet and northwest European ice sheets, mainly the BIIS. Comparison between the Goban Spur (DSDP Site 548) and the Celtic Margin (MD03‐2692) and central North Atlantic Integrated Ocean Drilling Program (IODP) Site U1308 suggests differences between the ‘non‐Laurentide Ice Sheet’ Heinrich Events (HE) 6 and 3 at the Goban Spur, with IRD from the BIIS being prominent during HE 6 and IRD from other European ice sheets north of the BIIS likely being more dominant during HE 3. The nature of lithics in IRD‐rich horizons during Terminations 3, 3A, 2 and 1 suggests significant iceberg calving episodes preceding BIIS retreat during the onset of interstadial intervals.

Palynological implications for the paleoclimate and paleoceanographic reconstruction of the East Sea since the early Pleistocene at IODP site U1430

Palynomorphs, including pollen and dinoflagellate cysts from marine sediments, can provide a history of paleoclimate and paleoceanography. We present new palynological profiles based on a core from the Integrated Ocean Drilling Program Site U1430, which was drilled in the Ulleung Plateau East Sea. This core covers the past 2 Ma and spans the Mid-Pleistocene Transition (MPT, 1.2–0.8 Ma) and Mid-Brunhes Event (MBE, ∼0.43 Ma). Terrestrial and marine palynomorph records indicate orbital-scale variations in paleoclimate and paleoceanography, reflecting changes in the interconnections between vegetation, climate, and the ocean. Before the MPT, the high pollen taxa ratio and abundant temperate pollen suggest a relatively warm temperature associated with astronomical forcing-induced insolation changes. At ca. 1.3 Ma, boreal coniferous pollen increased, suggesting intensification of the East Asian winter monsoon (EAWM). The long-term trend of boreal coniferous pollen concentration was similar to that of benthic δ18O. This orbital scale boreal conifer pollen assemblage variation indicates Quaternary EAWM evolution controlled by changes in global ice volume and climatic cooling. The marine palynological data reflect the ocean circulation history of the study area, where sea level fluctuations and tectonic activity played important roles around the marginal sea. The abundance of warm-water dinoflagellate species after ca. 1.9 Ma, including Tuberculodinium vancampoae, indicates Tsushima Warm Current intrusion related to the expansion of the Korea (Tsushima) Strait. Nematosphaeropsis labyrinthus and other cold-water species increased markedly during the MPT, suggesting a low sea surface temperature and weakened vertical mixing of the East Sea due to the cooled climate and sea ice during the MPT. The marked sea level fluctuation associated with the glacial–interglacial cycling after the MBE resulted in an assemblage composition shift from cold to warm water species. Tsuga and Betula thrived during mild winters, primarily influenced by winter insolation. These genera were particularly prosperous in the early Pleistocene, coinciding with a strong intrusion of the Tsushima Warm Current (TWC). Our findings should be considered in developing a comprehensive understanding of the paleoclimate and paleoceanographic history of northern East Asia across the major climate transitions of the Pleistocene.

Eocene to Oligocene cooling and ice growth based on the geochemistry of interglacial mudstones from the East Antarctic continental shelf

AbstractThe Eocene-Oligocene Transition at c. 34 million years ago (Ma) marked the global change from greenhouse to icehouse and the establishment of the East Antarctic Ice Sheet (EAIS). How the ice-sheet behaviour changed during interglacials across this climate transition is poorly understood. We analysed major, trace and rare earth elemental data of late Eocene interglacial mudstone from Prydz Bay at Ocean Drilling Program Site 1166 and early Oligocene interglacial mudstone from Integrated Ocean Drilling Program Site U1360 on the Wilkes Land continental shelf. Both sites have comparable glaciomarine depositional settings. Lithofacies and provenance at Site 1166 in Prydz Bay are indicative of a late Eocene glacial retreat in the Lambert Graben. Palaeoclimate proxies, including the Chemical Index of Alteration, mean annual temperature and mean annual precipitation, show a dominant warm and humid palaeoclimate for the late Eocene interglacial. In contrast, at Site U1360, in the early Oligocene, the provenance and interglacial weathering regime remained relatively stable with conditions of physical weathering. These results confirm that the EAIS substantially retreated periodically during late Eocene interglacials and that subglacial basins probably remained partially glaciated during interglacials in the earliest Oligocene.

Sediment depositional pattern in the northern Japan Sea over the last 1200 ka and its linkages to orbital forcing

The semi‐enclosed marginal Japan Sea is sensitive to global changes and responds to orbital‐scale variability. Sediment core samples from Integrated Ocean Drilling Program Site U1423 were processed for detrital grain size and semi‐quantitative mineral analysis to assess the sediment characterization and depositional environment in the Japan Sea over the last 1200 ka. The mean grain data suggest the dominance of the silt size fraction over sand and clay in the whole period, while sand content increases dramatically between 600 and 150 ka. The end‐member energy modelling of grain size data suggests that sediment deposition took place under two energy conditions over the last 1200 ka. The low‐energy conditions observed during the middle Pleistocene transition (MPT) is mainly related to the wind deposition with the sediment characteristics being moderately to poorly sorted and coarse to nearly symmetrical skewed during global cooling and enhanced East Asian Winter Monsoon (EAWM) winds in the northern Japan Sea. Post MPT, periodic fluctuations between higher and lower energy conditions are observed, and the depositional environment is controlled by the EAWM wind, and precipitation intensity, glacio‐eustatic sea‐level changes and sea‐ice volumes. During the period, detrital sediments are poorly sorted and nearly symmetrically skewed, marked by the dominance of quartz, plagioclase and k‐feldspar. The spectral analysis grain size‐related data shows the presence of 228, 41 and 23 kyr orbital paced cycles, which are also observed in the Chinese Loess Plateau's normalized quartz mean grain size. This study is the first report of 228 kyr cycles from the Pleistocene Japan Sea sediments indicate that sediment deposition in the Japan Sea is associated with ~200 kyr eccentricity cycle as in the Chinese Loess Plateau.

Favocassidulina Tuberculata N. SP., A New Benthic Foraminifer from the Portuguese Continental Slope

Abstract Favocassidulina tuberculata, a new benthic foraminiferal species from Integrated Ocean Drilling Program Site U1391 drilled on the southwest Portuguese continental slope, is described. This new species has a slit-shaped apertural opening oblique to the test periphery instead of paralleling the periphery as the type species Favocassidulina favus (Brady) does. And more notably, this species possesses a test surface ornamented with tubercles, quite different from the coarse honeycomb wall structure of F. favus and the finely irregular cancellate surface ornamentation of other Favocassidulina species. This paper for the first time reports the presence of the genus Favocassidulina in the Atlantic Ocean.

North Atlantic Drift Sediments Constrain Eocene Tidal Dissipation and the Evolution of the Earth‐Moon System

AbstractCyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (<1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that the g4–g3 “grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.

Detrital glass in a Bering Sea sediment core yields a ca. 160 ka Marine Isotope Stage 6 age for Old Crow tephra

Abstract For decades, the Old Crow tephra has been a prominent stratigraphic marker for the onset of Marine Isotope Stage (MIS) 5e, the last interglaciation, in subarctic northwest North America. However, new zircon U-Pb dates for the tephra suggest that the tephra was deposited ca. 207 ka during MIS 7, with wide-ranging implications for chronologies of glaciation, paleoclimate, relict permafrost, and phylogeography. We analyzed ~1900 detrital glass shards from 28 samples collected at Integrated Ocean Drilling Program Site U1345 in the Bering Sea, which has a well-constrained age model from benthic foraminiferal δ18O. Except for one possibly contaminant shard dated at 165 ka, Old Crow tephra was absent from all samples spanning 220–160 ka. Old Crow tephra appeared abruptly at 157 ka, comprising >40% of detrital shards between 157 and 142 ka. This abrupt increase in the concentration of detrital Old Crow tephra, its absence in earlier intervals, and its presence at low concentrations in all samples between 134 and 15 ka collectively indicate that the tephra was deposited during the middle of MIS 6 with a likely age of 159 ± 8 ka. As a result, the late Quaternary chronostratigraphic framework for unglaciated northwest North America remains intact, and the timing of key events in the region (e.g., bison entry into North America; interglacial paleoclimate; permafrost history; the penultimate glaciation) does not require wholesale revision.

Early Pleistocene calcareous nannofossil assemblages from the Gulf of Cadiz reveal glacial-interglacial and millennial-scale variability

Coccolithophore high resolution (300 years) quantitative analyses have been carried out on Early Pleistocene sediment samples from Integrated Ocean Drilling Program Site U1387 retrieved in the Gulf of Cadiz. The studied interval is well constrained by the δ18O chronological frame and covers marine isotope stage (MIS) 48 to MIS 45, from 1465.9 ka to 1389.9 ka. The aim is to investigate paleoenvironmental changes during a poorly known interval of the “41 ky world” and understand how climate dynamics controlled coccolithophore abundance and variation at orbital up to millennial scale. Assemblage composition variation and Principal Component Analysis (PCA) indicate that temperature and nutrient availability are the main factors influencing coccolithophores. Precession forcing combined with hydrological and atmospheric dynamics affect changes in coccolithophore assemblage composition and abundance highlighting glacial-interglacial cycles and a millennial scale variability, which is more evident during glacials than during interglacials. Interglacial MIS 47 onset is more abrupt than MIS 45 inception in relation to a more prominent insolation maximum, which favors the sharp increase and highest abundance of warm water taxa in the early MIS 47. Short-term abundance peaks of C. pelagicus spp. pelagicus during glacials document polar-subpolar melting water influx into the Gulf of Cadiz and southward migration of the subpolar front during episodes of high volume ice-sheet in the north hemisphere and reduced Atlantic Meridional Overturning circulation. In late MIS 48 the lowest coccolithophore productivity, induced by colder and stratified surface waters, a terminal stadial has been inferred. Enhanced short-term glacial productivity is favored by higher mixing and nutrient content in surface water due to the strengthened westerly winds during +NAO-like phases. This promotes arid condition and upwelling along the studied site. The interglacial short-term coccolithophore productivity increases are associated with insolation maxima and enhanced nutrients of land origin during more humid periods led by -NAO-like phases, which induce the southward position of the westerlies and higher precipitation in the Mediterranean region and North Africa, in agreement with the contemporary sapropel occurrences in Mediterranean Sea. Our data-set suggests a connection between climate dynamics in the Gulf of Cadiz and east of Gibraltar Strait during the Early Pleistocene as well as a relationship with the north hemisphere ice-sheet dynamics.

Coccolithophore paleoproductivity since the Last Glacial Maximum in the Atlantic Ocean: Relationship with calcification and preservation variability

Paleoproductivity, calcification and preservation patterns are presented from calcareous nannoplankton paleo-assemblages records covering the last ∼25 kyr retrieved from Integrated Ocean Drilling Program Sites U1385 (37°34.285′N; 10°7.562′W) and U1313 (41°0.0′N; 32°57.4′W), located respectively along the Western Iberian Margin and in the North Atlantic Ocean. The main aim of the study is to provide paleoceanographic and paleoclimatic analyses together with an investigation of changes in coccolithophore calcification processes occurring in response to climate variability from the Last Glacial Maximum up to the Holocene. Coccolithophore calcification was investigated by comparing variations in coccolith thickness and total coccolith calcite; at the same time dissolution/preservation indices were used to better understand the response of coccolithophores to changes in environmental parameters.In general, the increasing CO2 recorded during the last 25 kyr has a negative effect on calcification, resulting in a reduction of the different species size-normalized thicknesses at both sites. However, differences between the responses at the two latitudes studied are identified, in particular during the Heinrich Stadials; in contrast, during both Younger Dryas and Holocene intervals, the different size-normalized species thicknesses show consistent patterns at the two sites. During the Last Glacial Maximum the influence of subtropical waters due to Azores Current recirculation leads to a moderate productivity, initially at Site U1385 and later at Site U1313. At the same time, temperature influences the calcification at both sites. At Site U1385, the temperature is the main parameter affecting the paleoproductivity during Heinrich Stadial events; in addition, during Heinrich Stadial 1 alone, it also affects the calcification. At Site U1313 the calcification processes during Heinrich Stadial events are apparently hampered by an increasing water turbidity, caused by icebergs acting as ice rafted debris transporters, which affects light filtration in the water column. Light availability is an important calcification-influencing factor. At Site U1313 during Heinrich Stadial 1 and at the Last Glacial Maximum inception, dissolution, a consequence of increased CO2 solubility in the colder ice-age ocean, has a negative influence on calcification. Furthermore, at Site U1313, in contrast to Site U1385, the continually increasing CO2 concentration recorded during the Bølling-Allerød hampers both calcification and preservation.

Quantification of Asian Dust Source Variabilities in Silt and Clay Fractions since 10 Ma by Parallel Factor (PARAFAC) Endmember Modeling at IODP Site U1425 in the Japan Sea

Abstract Japan sea sediments consist of various detrital materials of eolian and riverine origin. Understanding the provenance of eolian dust is vital for reconstructing the variability of wind patterns and monsoons in the past. New and complete eolian accumulation rates from Taklimakan, Gobi, and Ordos are reconstructed at Integrated Ocean Drilling Program (IODP) Site U1425 in the Japan Sea using parallel factor (PARAFAC) endmember modeling. Our results show that Taklimakan dust is dominated by the silt fraction, while Gobi dust is dominated by the clay fraction, and they are controlled by the relative contributions of different pathways of dust transport, such as the westerly winds and East Asian winter monsoon (EAWM). Clay-size dust from Gobi increased during three periods, late Miocene global cooling (LMGC), intensification of Northern Hemisphere Glaciation (iNHG), and mid-Pleistocene Transition (MPT), which reflected increased EAWM winds associated with global cooling and glaciation. Taklimakan became the major dust contributor to the Japan Sea sediments during the warmer climate periods in the latest Miocene to early Pliocene and the Late Pleistocene, where westerly wind activity dominated eolian transport. Dust from Ordos increased greatly 0.95-0.85 Ma due to enhanced Asian aridification since 2 Ma in Northwest China. Detrital flux from Japanese islands suggests that the East Asian summer monsoon (EASM) was stronger 9.6-8 Ma and weakened from 8 Ma to the Pleistocene.

Eocene relative paleointensity of the geomagnetic field from Integrated Ocean Drilling Program Site U1403 and U1408 sediments in the northwest Atlantic

Published relative paleointensity (RPI) records older than ∼3Ma are extremely limited in time and space. To develop a more robust understanding of RPI variations, we have conducted rock magnetic and paleomagnetic measurements on Eocene marine sediments recovered at Integrated Ocean Drilling Program (IODP) Sites U1403 and U1408 in the northwest Atlantic. A series of rock magnetic measurements indicate that the main remanence carrier is single domain biogenic magnetite. Paleomagnetic measurements yielded RPI records for Chrons C18–C21 and C22n, which correlates to ∼38.4–49.6Ma. The record is compromised in a few short intervals by inhomogeneous rock magnetic properties. RPI minima always occur at chron boundaries and RPI fluctuates between highs and lows within each chron. This record is the first to show that these characteristics persist at least since the onset of Chron C22n at ∼49.3Ma. We conclude that these are intrinsic and fundamental features of the geomagnetic field regardless of the polarity reversal rate. We produce a stacked RPI curve for Chron 18, named PIS-C18, on the basis of the RPI records obtained in this study and those from IODP Sites U1331 and U1332 in the equatorial Pacific that are matched by visual inspection. The PIS-C18 RPI of the stack is generally high with no prominent lows during Chron C18n.2n, whereas it is not as high and has several prominent lows almost equivalent to the RPI minima at the chron boundaries during Chrons C18n.1n and C18r. A histogram of RPI during Chron 18 is slightly skewed to the right, and the ratio of the standard deviation to the mean paleointensity is 0.38. These characteristics are similar to a histogram of the RPI stack for the last 1.5 million years. We interpret this to imply that character of the geodynamo for 104–106 years timescales has been unchanged since the Eocene.

Contrasting intensity of aragonite dissolution and dolomite cementation in glacial versus interglacial intervals of a subtropical carbonate succession

AbstractAragonite and high‐Mg calcite are abundant in modern, neritic carbonate systems but almost absent in their fossil counterparts. Dissolution of these metastable mineral phases commonly leaves no visible trace in the sedimentary record, compromising the derivation of palaeoenvironmental information from the rock record. The upper 25 m of Integrated Ocean Drilling Program (IODP) Site U1460 on the outer ramp of the western Australian Shelf were investigated to study shallow burial (tens of metres) marine diagenesis in organic‐carbon poor sediments using microscopic, total organic carbon, biomarkers and mineralogical analysis in combination with porewater geochemistry. Aragonite dissolution is negligible at the seafloor but intensifies ca 5 m below, even though bulk porewaters are supersaturated for aragonite. This apparent contradiction likely results from dissolution in undersaturated microenvironments. Aragonite dissolution below 5 to 6 m is on average more intense in interglacial compared to glacial intervals. The presence of disseminated framboidal pyrite and porewater results indicate that minor sulphate reduction is active at IODP Site U1460. Sulphate reduction is probably limited by the low organic matter content (ca 0.2%). It is well‐known from the literature that incipient sulphate reduction can lead to a drop in pH and consequently to carbonate dissolution. It is therefore assumed that the slightly higher concentration of organic matter in the interglacial intervals allowed increased aragonite dissolution during sulphate reduction compared to glacial beds. Low amounts of dolomite cement (<15%) start to form at the same depth (5 to 6 m) as aragonite dissolution intensifies. Dolomite formation and aragonite dissolution also show covariance on a metre‐scale below 5 to 6 m, indicating that a low carbonate saturation state might enhance dolomite formation. This mechanism provides an indirect link between dolomite formation, aragonite dissolution and orbital cycles. The outcome of this study, therefore, contributes to a better understanding of differential diagenesis in marine carbonates.

The Late Miocene‐Early Pliocene Biogenic Bloom in the Eastern Equatorial Pacific: New Insights From Integrated Ocean Drilling Program Site U1335

AbstractThe late Miocene‐early Pliocene “biogenic bloom” (BB) manifests as greatly enhanced biogenic sedimentation in sites along the Equator that has been linked to cooler sea surface temperature (SST) in the eastern equatorial Pacific (EEP). However, the full extent and geometry of the BB in the EEP is less known. To improve on this, we have generated new carbonate content (CaCO3%) and bulk carbonate stable isotope (δ13C and δ18O) records spanning the last 7 Ma at IODP Site U1335, located ca. 5° north of the Equator and to the west of the EEP. Site U1335 δ13C and δ18O records display high‐frequency variations coupled to changes in sediment composition and physical properties comparable to patterns seen at on‐Equator sites further east. During the late Miocene and the early Pliocene bulk δ18O is higher at Site U1335 compared to two off‐Equator sites further east, suggesting cooler SSTs generated by stronger equatorial upwelling reaching northwest of the modern core‐equatorial upwelling belt. Enhanced upwelling at Site U1335 is supported by relatively higher sedimentation rates prior to 4.6 Ma, symptomatic of higher biological production during the BB. These observations suggest that during the BB the equatorial upwelling circulation was more focused and less parallel to the Equator compared to present day.

Orbital and Suborbital‐Scale Variations of Productivity and Sea Surface Conditions in the Gulf of Alaska During the Past 54,000 Years: Impact of Iron Fertilization by Icebergs and Meltwater

AbstractAs a high‐nutrient and low‐chlorophyll region, the modern Gulf of Alaska (GoA) is strongly impacted by the limitation of iron. Paleostudies along the Alaskan slope have mainly focused on reconstructing environmental conditions over the past 18 ka. Based on micropaleontological, biogeochemical, and sedimentological parameters, we explore a sediment record covering the past 54 ka at Integrated Ocean Drilling Program Site U1419 to understand the impact of orbital‐ and suborbital‐scale climate variability on productivity and sea‐surface conditions. Close to the Cordilleran Ice Sheet (CIS), Site U1419 is ideally located to elucidate how the evolution of a large ice mass and glacial processes affected orbital‐ and suborbital‐scale changes in nutrients (e.g., iron) supply. Meltwater discharge from the northern CIS impacted sea surface dynamics of GoA coastal waters. The corresponding increases in bulk biogenic concentrations during Marine Isotope Stage (MIS) 3 and MIS 2 (54–17 ka) suggests a direct impact from iron fertilization. The lack of a consistent relationship between productivity and SST suggests that cooling of surface waters was not the dominant control on primary producers. The inundation of the subaerially exposed continental shelf during the last deglacial (17–10 ka) warming could have served as a major micronutrient source, accounting for a deglacial peak in production. Low productivity after the last deglaciation suggests reduced iron availability, which we link to reduced meltwater inputs from smaller ice masses onshore. Our multiproxy approach reveals a more comprehensive picture of late Quaternary productivity variations compared to earlier studies along the Alaskan margin. The impact of tidewater glaciers and meltwater discharge on past marine productivity and nutrient budget dynamics of high‐latitude coastal regions is discussed.

Controls on sedimentary accumulation of organic matter during Cretaceous Oceanic Anoxic Event 2, IODP site U1407, Southeast Newfoundland Ridge

The pelagic sediments from Integrated Ocean Drilling Program (IODP) Site U1407 in the western North Atlantic are characterized by a sequence of organic-lean and organic-rich sediments representing a major global episode of organic matter (OM) burial during Oceanic Anoxic Event 2 (OAE2). The OM-rich deposits (up to 16% total organic carbon) consist primarily of radiolarians which are rare/absent in the organic-lean sediments. New nannofossil biostratigraphy and the correlation with the global ẟ13C curve were used to constrain the timing of paleoceanographic changes below, within, and above OAE2 sediments. Data were combined from elemental concentrations, biomarkers, and abundances of benthic foraminifera, biserial (heterohelicids) planktic foraminifera, and radiolarians to reconstruct the evolution of these changes. The ẟ13C curve records a global negative excursion within organic-lean sediments not typically recorded in other sections preceding the initial rise in isotopic values that signals OM burial worldwide. Maximum OM accumulation occurred during the second positive isotopic excursion, which is associated with higher terrigenous input (indicated by long-chain n-alkanes and terrestrially derived elements) and water column stratification (suggested by the paleoindicator gammacerane). In addition, sesquiterpene biomarkers derived from cypress and other conifers suggest flooding of gymnosperm forests from increased rainfall coupled with rising sea levels and resulting higher water tables. Within mid-OAE2 sediments, a sharp increase in radiolarians and fish teeth/debris and a decrease in benthic foraminifera implies deposition of OM from increased productivity/upwelling under low oxygen in the lower part of the water column. Upwelling and water column stratification occurring asynchronously at the surface resulted from changes in precipitation, with stratification developing during more humid/wet conditions. Greenhouse warming during OAE2 likely increased precipitation, weathering and nutrient inputs. However, prolonged anoxia caused buried phosphorus to be recycled as indicated by higher redox-sensitive trace element and biolimiting element concentrations, sustaining primary production and further enriching the sediments in OM. We suggest that increased marine paleoproductivity was the primary control on the OM-rich sediment accumulation during OAE2, while low-oxygen conditions resulting from stratification of surface waters were essential to its preservation.

Late Eocene–early Miocene evolution of the southern Australian subtropical front: a marine palynological approach

Abstract. Improvements in our capability to reconstruct ancient surface-ocean conditions based on organic-walled dinoflagellate cyst (dinocyst) assemblages from the Southern Ocean provide an opportunity to better establish past position, strength and oceanography of the subtropical front (STF). Here, we aim to reconstruct the late Eocene to early Miocene (37–20 Ma) depositional and palaeoceanographic history of the STF in the context of the evolving Tasmanian Gateway as well as the potential influence of Antarctic circumpolar flow and intense waxing and waning of ice. We approach this by combining information from seismic lines (revisiting existing data and generating new marine palynological data from Ocean Drilling Program (ODP) Hole 1168A) in the western Tasmanian continental slope. We apply improved taxonomic insights and palaeoecological models to reconstruct the sea surface palaeoenvironmental evolution. Late Eocene–early Oligocene (37–30.5 Ma) assemblages show a progressive transition from dominant terrestrial palynomorphs and inner-neritic dinocyst taxa as well as cysts produced by heterotrophic dinoflagellates to predominantly outer-neritic/oceanic autotrophic taxa. This transition reflects the progressive deepening of the western Tasmanian continental margin, an interpretation supported by our new seismic investigations. The dominance of autotrophic species like Spiniferites spp. and Operculodinium spp. reflects relatively oligotrophic conditions, like those of regions north of the modern-day STF. The increased abundance in the earliest Miocene of Nematosphaeropsis labyrinthus, typical for modern subantarctic zone (frontal) conditions, indicates a cooling and/or closer proximity of the STF to the site . The absence of major shifts in dinocyst assemblages contrasts with other records in the region and suggests that small changes in surface oceanographic conditions occurred during the Oligocene. Despite the relatively southerly (63–55∘ S) location of Site 1168, the rather stable oceanographic conditions reflect the continued influence of the proto-Leeuwin Current along the southern Australian coast as Australia continued to drift northward. The relatively “warm” dinocyst assemblages at ODP Site 1168, compared with the cold assemblages at Antarctic Integrated Ocean Drilling Program (IODP) Site U1356, testify to the establishment of a pronounced latitudinal temperature gradient in the Oligocene Southern Ocean.