Moisture and insulation deterioration are important factors that cause the failure of epoxy packaging materials. Thus, improving the long-term stability of epoxy resins in a hot and humid environment is an important prerequisite for electronic components to adapt to complex working conditions and achieve high power densities. In this study, fluorinated graphene doped with hydroxy-terminated poly(dimethylsiloxane) was prepared and self-assembled into a micro/nanostructure on the surface of an epoxy resin, which effectively improved the surface hydrophobicity of the epoxy resin. In addition, the doping with hydroxy-terminated poly(dimethylsiloxane) modified the fluorinated graphene filler, thereby forming an arch bridge energy band structure inside the epoxy resin and thus regulating carrier migration. The water absorption of the epoxy resin decreased from 1.02 to 0.24%, and the surface water contact angle increased from 93.58 to 133.2°. Moreover, the electrical insulation performance of the modified epoxy resin was greatly improved when the surface resistivity and flashover voltage increased by 50.5 and 36.4%, respectively. Therefore, the proposed method realizes a simultaneous improvement in the hydrophobicity and insulation of epoxy resins.
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