Instrumental Background Research Articles

Spectral Background Calibration of Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) Spectrometer Onboard the Perseverance Rover Enables Identification of a Ubiquitous Martian Spectral Component.

The Perseverance rover landed at Jezero crater, Mars, on 18 February 2021, with a payload of scientific instruments to examine Mars' past habitability, look for signs of past life, and process samples for future return to Earth. The instrument payload includes the Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) deep ultraviolet Raman and fluorescence imaging spectrometer designed to detect, characterize, and map the presence of organics and minerals on the Martian surface. Operation and engineering constraints sometimes result in the acquisition of spectra with features near the detection limit. It is therefore important to separate instrumental (background) spectral components and spectral components inherent to Martian surface materials. For SHERLOC, the instrumental background is assessed by collecting spectra in the stowed-arm configuration where the instrument is pointed at the Martian nighttime sky with no surface sample present in its optical path. These measurements reveal weak Raman and fluorescence background spectral signatures as well as charged-coupled device pixels prone to erroneous intensity spikes separate from cosmic rays. We quantitatively describe these features and provide a subtraction procedure to remove the spectral background from surface spectra. By identifying and accounting for the SHERLOC Raman background features within the median Raman spectra of Martian target scans, we find that the undefined silicate spectral feature interpreted to be either amorphous silicate or plagioclase feldspar is ubiquitously found in every Mars target Raman scan collected through Sol 751.

Dark matter line searches with the Cherenkov Telescope Array

Monochromatic gamma-ray signals constitute a potential smoking gun signature for annihilating or decaying dark matter particles that could relatively easily be distinguished from astrophysical or instrumental backgrounds. We provide an updated assessment of the sensitivity of the Cherenkov Telescope Array (CTA) to such signals, based on observations of the Galactic centre region as well as of selected dwarf spheroidal galaxies. We find that current limits and detection prospects for dark matter masses above 300 GeV will be significantly improved, by up to an order of magnitude in the multi-TeV range. This demonstrates that CTA will set a new standard for gamma-ray astronomy also in this respect, as the world's largest and most sensitive high-energy gamma-ray observatory, in particular due to its exquisite energy resolution at TeV energies and the adopted observational strategy focussing on regions with large dark matter densities. Throughout our analysis, we use up-to-date instrument response functions, and we thoroughly model the effect of instrumental systematic uncertainties in our statistical treatment. We further present results for other potential signatures with sharp spectral features, e.g. box-shaped spectra, that would likewise very clearly point to a particle dark matter origin.

Water Cherenkov muon veto for the COSINUS experiment: design and simulation optimization

COSINUS is a dark matter (DM) direct search experiment that uses sodium iodide (NaI) crystals as cryogenic calorimeters. Thanks to the low nuclear recoil energy threshold and event-by-event discrimination capability, COSINUS will address the long-standing DM claim made by the DAMA/LIBRA collaboration. The experiment is currently under construction at the Laboratori Nazionali del Gran Sasso, Italy, and employs a large cylindrical water tank as a passive shield to meet the required background rate. However, muon-induced neutrons can mimic a DM signal therefore requiring an active veto system, which is achieved by instrumenting the water tank with an array of photomultiplier tubes (PMTs). This study optimizes the number, arrangement, and trigger conditions of the PMTs as well as the size of an optically invisible region. The objective was to maximize the muon veto efficiency while minimizing the accidental trigger rate due to the ambient and instrumental background. The final configuration predicts a veto efficiency of 99.63 ± 0.16% and 44.4 ± 5.6% in the tagging of muon events and showers of secondary particles, respectively. The active veto will reduce the cosmogenic neutron background rate to 0.11 ± 0.02 cts·\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\cdot $$\\end{document}kg-1·\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{-1}\\cdot $$\\end{document}year-1,\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{-1},$$\\end{document} corresponding to less than one background event in the region of interest for the whole COSINUS-1π\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\pi $$\\end{document} exposure of 1000 kg·\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\cdot $$\\end{document}days.

Transition Edge Sensors with Sub-eV Resolution And Cryogenic Targets (TESSERACT) at the underground laboratory of Modane (LSM)

The future TESSERACT experiment will search for individual galactic DM particles below the proton mass through interactions with advanced, ultra-sensitive detectors. Currently TESSERACT is in a design phase aiming to produce fully defined detector technologies that will explore DM masses down to 10 MeV. It is designed to be sensitive to DM candidates interacting with the detector target material in producing both nuclear recoil DM (NRDM) and electron recoil (ERDM). To do so, multiple target materials will be used with varying detection strategies to ensure the capability to both actively reject the so-called low-energy excess and discriminate nuclear recoils against electron recoils. In addition to maximizing sensitivity to a variety of DM interactions, this provides an independent handle on instrumental backgrounds. Nowadays, the TESSERACT project encompasses two US-based technologies, namely HeRALD using superfluid helium as a target material, and SPICE using polar crystals (Al2O3 and SiO2) and scintillating crystals such as GaAs. In these proceedings, we discuss the recent proposal to host the future TESSERACT experiment at the Modane Underground Laboratory (LSM) and add a third French-based cryogenic semiconducting (Ge, Si) detector technology to the TESSERACT payload.

DarkSide-20k Veto Photon-Detector Units: construction and characterization

DarkSide-20k is a global direct dark matter search experiment situated underground at LNGS (Italy), designed to reach a total exposure of 200 tonne-years nearly free from instrumental backgrounds. The core of the detector is a dual-phase Time Projection Chamber (TPC) filled with 50 tonne of low-radioactivity liquid argon.The entire TPC wall is surrounded by a gadolinium-loaded polymethylmethacrylate (Gd-PMMA), which acts as a neutron veto, immersed in a second low-radioactivity liquid argon bath enclosed in a stainless steel vessel. The neutron veto is equipped with large-area Silicon PhotoMultiplier (SiPM) array detectors, placed on the outside of the TPC wall. SiPMs are arranged in a compact design meant to minimize the material used for PCBs, cables and connectors: the so-called Veto Photon-Detector Units (vPDUs).A vPDU comprises 16 vTiles, each containing 24 SIPMs, together with front-end electronics, and amotherboard, which distributes voltage and control signals, sums vTiles channels, and drives theelectrical signal transmission. The neutron veto will be equipped with 120 vPDUs. The paper willfocus on the production of the first vPDUs, describing the assembly chain in the U.K. institutes, inorder to underline the rigorous QA/QC procedures, up to the final characterization of the firstcompleted prototypes. Tests will be extensively performed in liquid nitrogen baths either for thesingle vTiles and for the assembled vPDUs, with the purpose of assigning a “quality passport” toeach component.

Interference of the gas chromatography- mass spectrometry instrumental background on the determination of trace cyclic volatile methylsiloxanes and exclusion of it by delayed injection

Cyclic volatile methylsiloxanes (cVMS) have been widely found in various types of environmental media and attracted increasing attention as new pollutants. However, there is still a great challenge in the accurate quantification of trace cVMS, due to their volatility, and the high background originating from GC/MS accessories and surroundings. In this work, the main sources of the high background were investigated in detail for octamethylcyclotetrasiloxane (D4), decmethylcyclopentasiloxane (D5) and dodecmethylcyclohexosiloxane (D6). Several effective measures were employed to minimize these backgrounds, including the delayed injection method to minimize the interference from the injection septum. Then, a GC–MS method was developed for the accurate determination of D4, D5 and D6, with a linear range of 2 - 200 μg/L. The coefficient of determination was 0.9982–0.9986, the limit of detection (LOD) was 0.40–0.52 μg/L, and the quantitative range was 1.88–190 μg/L. Good reproducibility and recovery were obtained, indicating the reliability of the established analytical method.

The relationship between student engagement and dropout risk in early adolescence

One of the most reliable predictors of school effectiveness is student engagement, which is not only related to students’ current achievement but also long-term outcomes. Using linear regression and structural equation modeling procedures, the present study was aimed at examining the relationship between dropout risk, dimensions of student engagement, and family background. The survey study involved 3251 7th grade Hungarian students who completed the adapted Student Engagement Instrument and self-reported background questionnaire. According to the results, student performance is mainly related to parents’ educational attainment, but a moderate or weak correlation with behavioral, academic, and cognitive engagement is also detectable. While affective engagement shows a weak association with performance, it correlates with other engagement dimensions linked to achievement. This result suggests that support from parents, peers, and teachers may have an indirect effect on achievement; however, the present study could not confirm this hypothetical model. Based on our data, parental educational attainment and student engagement account for approximately 41 % of student performance which draws attention to the complexity of the relationship between student engagement and performance and highlights the importance of a comprehensive approach to dropout and student engagement in this context.

Assessing background contamination of sample tubes used in human biomonitoring by non-targeted liquid chromatography–high resolution mass spectrometry

Controlling and minimising background contamination is crucial for maintaining a high quality of samples in human biomonitoring targeting organic chemicals. We assessed the contamination of three previous types and one newly introduced medical-grade type of sample tubes used for storing human body fluids at the German Environmental Specimen Bank. Aqueous extracts from these tubes were analysed by non-targeted liquid chromatography-high resolution mass spectrometry (LC-HRMS) before and after a dedicated cleaning procedure. After peak detection using MZmine, Bayesian hypothesis testing was used to group peaks into those originating either from instrumental and laboratory background contamination, or actual tube contaminants, based on if their peak height was reduced, increased or not affected by the cleaning procedure. For all four tube types 80–90% of the 2475 peaks (1549 in positive and 926 in negative mode) were assigned to laboratory/instrumental background, which we have to consider as potential sample tube contaminants. Among the tube contaminants, results suggest a considerable difference in the contaminant peak inventory and the absolute level of contamination among the different sample tube types. The cleaning procedure did not affect the largest fraction of peaks (50–70%). For the medical grade tubes, the removal of contaminants by the cleaning procedure was strongest compared to the previous tubes, but in all cases a small fraction increased in intensity after cleaning, probably due to a release of oligomers or additives. The identified laboratory background contaminants were mainly semi-volatile polymer additives such as phthalates and phosphate esters. A few compounds could be assigned solely as tube-specific contaminants, such as N,N-dibutylformamide and several constituents of the oligomeric light stabiliser Tinuvin-622. A cleaning procedure before use is an effective way to standardise the used sample tubes and minimises the background contamination, and therefore increases sample quality and therewith analytical results.

THE STUDY OF X-RAY SPECTRUM OF COMA GALAXY CLUSTER

The X-ray spectrum of the Coma galaxy cluster was studied using the data from the XMM-Newton observatory. We combined 7 observations performed with the MOS camera of XMM-Newton in the 40′ × 40′ region centered at the Coma cluster. The analyzed observations were performed in 2000–2005 and have a total duration of 196 ksec. We focus on the analysis of the MOS camera spectra due to their lower affection by strong instrumental line-like background. The obtained spectrum was fitted with a model including contributions from the Solar system/Milky Way hot plasma and a power law X-ray background. The contribution of the instrumental background was modeled as a power law (not convolved with the effective area) and a number of Gaussian lines. The contribution from the Coma cluster was modeled with a single-temperature hot plasma emission. In addition, we searched for possible non-thermal radiation present in the vicinity of the center of the Coma cluster, originating e.g. from synchrotron emission of relativistic electrons on a turbulent magnetic field. We compared the results with previous works by other authors and spectra obtained from other instruments that operate in the similar energy range of 1−10 keV. Careful and detailed spectrum analysis shall be a necessary contribution to our future work – searching for axion-like dark matter particles’ manifestations in the Coma cluster.

Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit

Abstract. Volatile organic compound (VOC) emissions and subsequent oxidation contribute to the formation of secondary pollutants and poor air quality in general. As more VOCs at lower mixing ratios have become the target of air quality investigations, their quantification has been aided by technological advancements in proton-transfer-reaction time-of-flight mass spectrometry (PTR-TOF-MS). However, such quantification requires appropriate instrument background measurements and calibrations, particularly for VOCs without calibration standards. This study utilized a Vocus PTR-TOF-MS coupled with a gas chromatograph for real-time and speciated measurements of ambient VOCs in Boulder, Colorado, during spring 2021. The aim of these measurements was to understand and characterize instrument response and temporal variability as to inform the quantification of a broader range of detected VOCs. Fast, frequent calibrations were made every 2 h in addition to daily multipoint calibrations. Sensitivities derived from the fast calibrations were 5 ± 6 % (average and 1 standard deviation) lower than those derived from the multipoint calibrations due to an offset between the calibrations and instrument background measurement. This offset was caused, in part, by incomplete mixing of the standard with diluent. These fast calibrations were used in place of a normalization correction to account for variability in instrument response and accounted for non-constant reactor conditions caused by a gradual obstruction of the sample inlet. One symptom of these non-constant conditions was a trend in fragmentation, although the greatest observed variability was 6 % (1 relative standard deviation) for isoprene. A PTR Data Toolkit (PTR-DT) was developed to assess instrument performance and rapidly estimate the sensitivities of VOCs which could not be directly calibrated on the timescale of the fast calibrations using the measured sensitivities of standards, molecular properties, and simple reaction kinetics. Through this toolkit, the standards' sensitivities were recreated within 1 ± 8 % of the measured values. Three clean-air sources were compared: a hydrocarbon trap, zero-grade air and ultra-high purity nitrogen, and a catalytic zero-air generator. The catalytic zero-air generator yielded the lowest instrument background signals for the majority of ions, followed by the hydrocarbon trap. Depending on the ionization efficiency, product ion fragmentation, ion transmission, and instrument background, standards' limits of detection (5 s measurement integration) derived from the catalytic zero-air generator and the fast calibration sensitivities ranged from 2 ppbv (methanol) to 1 pptv (decamethylcyclopentasiloxane; D5 siloxane) with most standards having detection limits below 20 pptv. Finally, applications of measurements with low detection limits are considered for a few low-signal species including sub-parts-per-trillion by volume (pptv) enhancements of icosanal (and isomers; 1 min average) in a plume of cooking emissions, and sub-parts-per-trillion by volume enhancements in dimethyl disulfide in plumes containing other organosulfur compounds. Additionally, chromatograms of hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, and decamethylcyclopentasiloxane (D3, D4, and D5 siloxanes, respectively), combined with high sensitivity, suggest that online measurements can reasonably be associated with the individual isomers.

Skipper-CCD sensors for the Oscura experiment: requirements and preliminary tests

Oscura is a proposed multi-kg skipper-CCD experiment designed for a dark matter (DM) direct detection search that will reach unprecedented sensitivity to sub-GeV DM-electron interactions with its 10 kg detector array. Oscura is planning to operate at SNOLAB with 2070 m overburden, and aims to reach a background goal of less than one event in each electron bin in the 2–10 electron ionization-signal region for the full 30 kg-year exposure, with a radiation background rate of 0.01 dru.[1 dru (differential rate unit) corresponds to 1 event/kg/day/keV.] In order to achieve this goal, Oscura must address each potential source of background events, including instrumental backgrounds. In this work, we discuss the main instrumental background sources and the strategy to control them, establishing a set of constraints on the sensors' performance parameters. We present results from the tests of the first fabricated Oscura prototype sensors, evaluate their performance in the context of the established constraints and estimate the Oscura instrumental background based on these results.

Impact of impurities in shielding material on simulations of instrument background in space

Impact of impurities in shielding material on simulations of instrument background in space

Measuring the Cosmic X-Ray Background in 3–20 KeV with Stray Light from NuSTAR

By characterizing the contribution of stray light to large data sets from the CXB Measurement X-ray observatory collected over 2012–2017, we report a measurement of the cosmic X-ray background (CXB) in the 3–20 keV energy range. These data represent ∼20% sky coverage while avoiding Galactic ridge X-ray emission and are less weighted by deep survey fields than previous measurements with CXB Measurement. Images in narrow energy bands are stacked in detector space and spatially fit with a model representing the stray light and uniform pattern expected from the CXB and the instrumental background, respectively. We establish baseline flux values from Earth-occulted data and validate the fitting method on stray-light observations of the Crab, which further serve to calibrate the resulting spectra. We present independent spectra of the CXB with the focal plane module FPMA and FPMB detector arrays, which are in excellent agreement with the canonical characterization by HEAO 1 and are 10% lower than most subsequent measurements: and . We discuss these results in light of previous measurements of the CXB and consider the impact of systematic uncertainties on our spectra.

Research on accurate non-contact temperature measurement method for telescope mirror.

Non-contact temperature measurement for a solar telescope mirror is critical for improving the mirror seeing and thermal deformation of solar telescopes, a long-standing challenge in astronomy. This challenge arises from the telescope mirror's inherent weak thermal radiation, often overwhelmed by reflected background radiations due to its high reflectivity. In this work, an infrared mirror thermometer (IMT) is equipped with a thermally-modulated reflector, and a measurement method based on an equation for extracting mirror radiation (EEMR) has been developed for probing the accurate radiation and temperature of the telescope mirror. Using this approach, we can extract the mirror radiation from the instrumental background radiation via the EEMR. This reflector has been designed to amplify the mirror radiation signal incident on the infrared sensor of IMT, while inhibiting the radiation noise from the ambient environment. In addition, we also propose a set of evaluation methods for IMT performance based on EEMR. The results reveal that the temperature measurement accuracy of IMT to the solar telescope mirror using this measurement method can be achieved better than ±0.15°C.

Seismotectonics, Geomorphology and Paleoseismology of the Doroud Fault, a Source of Seismic Hazard in Zagros

In this study, the active tectonics, paleoseismicity, and seismic hazards of the Doroud Fault are examined through high-resolution satellite image interpretations, field investigations, outcrop and trench excavations, and the dating of geochronology samples. The Doroud Fault (DF), one of the essential segments of the Main Recent Fault in the northern margin of the Zagros mountain range, has a historical and instrumental background of high seismicity. We present the first constraints from tectonic geomorphology and paleoseismology along the Doroud Fault near the capital city of Dorud. Detailed observations from satellite imagery, field investigations, real-time kinematic (RTK) measurements, paleoseismological trenching, the radiocarbon (C14), and optically stimulated luminescence (OSL) as ages allowed us to map the fault in detail, describe and characterize its kinematics, and document its recent activity and seismic behavior (cumulative displacements, paleoseismicity, and magnitude, as well as recurrence interval) relevant to the recent seismic activity of the Doroud Fault during the late Holocene as one of the most important seismogenic faults in Zagros. Modern alluvial terraces of gullies and loess accumulations are systematically deflected and/or offset with co-seismic rupture, landslides, and scarps, indicating that the Doroud Fault has been active in the late Quaternary and is characterized by dextral strike–slip movements with a normal component. In addition, our findings provide a comprehensive analysis of the fault displacement, the timing of paleoearthquakes, and the right-lateral slip rate of the Doroud Fault. The late Holocene slip rate of the Doroud Fault using the OSL dating the gully is as follows: the minimum and maximum horizontal slip rates are estimated to be 1.82 and 2.71 mm/yr, and vertical slip rates of 1.03 and 1.53 mm/yr are calculated for the past 4600 ± 900 years in the middle segment of the fault. This study focused on a paleoseismological trench within the archeological sites of Darbe-Astaneh. The central portion of the fault has historically hosted more than nine earthquakes in the last 66 ka years, according to the study’s findings. According to paleoseismology studies, the Doroud Fault has the seismic capability to cause earthquakes with a magnitude of more than 7.4 and a total slip rate of about 3.83 ± 0.1 m. The average recurrence interval for the identified paleoearthquakes is approximately 104 ± 7 years.

Handling the Background in IXPE Polarimetric Data

Imaging X-ray Polarimetry Explorer (IXPE) is a Small Explorer mission by NASA and Agenzia Spaziale Italiana, launched on 2021 December 9, dedicated to investigating X-ray polarimetry allowing angular-, time-, and energy-resolved observations in the 2–8 keV energy band. IXPE is in the science observation phase since 2022 January; it is comprised of three identical telescopes with grazing-incidence mirrors, each one having in the focal plane a gas pixel detector. In this paper, we present a possible guideline to obtain an optimal background selection in polarimetric analysis, and a rejection strategy to remove instrumental background. This work is based on the analysis of IXPE observations, aiming to improve as much as possible the polarimetric sensitivity. In particular, the developed strategies have been applied as a case study to the IXPE observation of the 4U 0142+61 magnetar.

Toward the ultimate reach of current imaging atmospheric Cherenkov telescopes and their sensitivity to TeV dark matter

Indirect detection opens a unique window for probing thermal dark matter (DM): the same annihilation process that determined the relic abundance in the early Universe drives the present day astrophysical signal. While TeV-scale particles weakly coupled to the Standard Model face undoubted challenges from decades of null searches, the scenario remains compelling, and simple realizations such as Higgsino DM remain largely unexplored. The fate of such scenarios could be determined by gamma-ray observations of the centre of the Milky Way with Imaging Atmospheric Cherenkov Telescopes (IACTs). We consider the ultimate sensitivity of current IACTs to a broad range of TeV-scale DM candidates - including specific ones such as the Wino, Higgsino, and Quintuplet. To do so, we use realistic mock H.E.S.S.-like observations of the inner Milky Way halo, and provide a careful assessment of the impact of recent Milky Way mass modeling, instrumental and astrophysical background uncertainties in the Galactic Center region, and the theoretical uncertainty on the predicted signal. We find that the dominant systematic for IACT searches in the inner Galaxy is the unknown distribution of DM in that region, however, beyond this the searches are currently statistically dominated indicating a continued benefit from more observations. For two-body final states at $1~{\rm TeV}$, we find a H.E.S.S.-like observatory is sensitive to $\langle \sigma v \rangle \sim 3 \times 10^{-26}-4 \times 10^{-25}~{\rm cm}^3{\rm s}^{-1}$, except for neutrino final states, although we find results competitive with ANTARES. In addition, the thermal masses for the Wino and Quintuplet can be probed; the Higgsino continues to be out of reach by at least a factor of a few. Our conclusions are also directly relevant to the next generation Cherenkov Telescope Array, which remains well positioned to be the discovery instrument for thermal DM.

New constraints on decaying dark matter from INTEGRAL/SPI

ABSTRACTBased on almost 20 yr of data collected by the high-resolution spectrometer SPI on board the International Gamma-Ray Astrophysics Laboratory (INTEGRAL), we present constraints on a decaying dark matter particle undergoing a decay into two bodies, at least one of which is a photon, manifesting itself via a narrow line-like spectral feature. Our ON-OFF type analysis of the Milky Way observations allowed us to constrain the lifetime to be ≳1020−1021 yr for DM particles with masses $40\, \text{keV}\, \lt \, M_{\text{DM}}\, \lt \, 14\, \text{MeV}$. Within this mass range, our analysis also reveals 32 line-like features detected at ≥3σ significance, 29 of which coincide with known instrumental and astrophysical lines. In particular, we report on the detection of the electron-positron annihilation (511 keV) and 26Al (1809 keV) lines with spatial profiles consistent with previous results in the literature. For the particular case of the sterile neutrino DM, we report the limits on the mixing angle as a function of sterile neutrino mass. We discuss the dominant impact of systematic uncertainties connected to the strongly time-variable INTEGRAL/SPI instrumental background as well as the ones connected to the uncertainties of MW DM density profile measurements on the derived results.

Advantages of Multiplexing Ability of the Orbitrap Mass Analyzer in the Multi-Mycotoxin Analysis.

In routine measurements, the length of the analysis time and nfumber of samples analysed during a time unit are crucial parameters, which are especially important for the food analysis, particularly in the case of mycotoxin determinations. High-resolution equipment, including time-of-flight or Orbitrap analyzators, can provide stable instrumental background for high-throughput analyses. In this report, a short, 1 min MS-based multi-mycotoxin method was developed with the application of a short column as a reduced chromatographic separation, taking advantages of the multiplexing and high-resolution capability of the QExactive Orbitrap MS possessing sub-1 ppm mass accuracy. The performance of the method was evaluated regarding selectivity, LOD, LOQ, linearity, matrix effect, and recovery, and compared to a UHPLC-MS/MS method. The final multiplexing method was able to quantify 11 mycotoxins in defined ranges (aflatoxins (corn, 2.8-600 μg/kg; wheat, 1.5-350 μg/kg), deoxynivalenol (corn, 640-9600 μg/kg; wheat, 128-3500 μg/kg), fumonisins (corn, 20-1500 μg/kg; wheat, 30-3500 μg/kg), HT-2 (corn, 64-5200 μg/kg; wheat, 61-3500 μg/kg), T-2 (corn, 10-800 μg/kg; wheat, 4-250 μg/kg), ochratoxin (corn, 4.7-600 μg/kg; wheat, 1-1000 μg/kg), zearalenone (corn, 64-4800 μg/kg; wheat, 4-500 μg/kg)) within one minute in corn and wheat matrices at the MRL levels stated by the European Union.

Determination of uranium isotopes in marine sediments and seawaters by SF ICP-MS after rapid chemical separation using TK200 resin.

This work provided a novel analytical procedure for rapid and precise uranium isotopic determination in marine sediment and seawater, using a new type of extraction resin, TK200 resin, in combination with microwave digestion (for marine sediments), Fe(OH)3 co-precipitation (for seawater), and single collector sector field-inductively coupled plasma mass spectrometry (SF ICP-MS) measurement. The removal ability of TK200 extraction chromatography for the interfering elements (IEs) Hg, Pb, Th, Pt, Tl, and the matrix rare earth elements (REEs) was carefully investigated. High decontamination factors (DFs) were obtained for IEs and REEs. Accurate quantification of uranium isotope ratios was accomplished based on a "double-cycle" ICP-MS measurement method. The analytical method was optimized and validated with isotopic standards (IRMM-187), matrix-containing certified reference marine sediments (IAEA-384, IAEA-385, and IAEA-412), and seawater reference material (IAEA-443). A stable chemical recovery of ~ 90% was obtained for both types of marine environmental samples, and the method showed great efficiency with a total analytical time of less than 6h. The proposed procedure was validated following ISO/IEC 17025 guidelines. The important factors affecting the isotope ratio results (instrument background, procedural blank, memory effects, peak tailing, mass discrimination, dead time, and hydride interferences) were considered in the estimation of combined uncertainties. This work provides an alternative way for the determination of trace uranium isotope ratios and can be applied in the emergency monitoring of nuclear accidents and marine environmental analysis.