The number of patent ap plications for climate change mitigation technologies (CCMT) in China has shown a rapid development trend over the past decade. This study applies social network analysis (SNA) method and directed time-exponential random graph model(TERGM), while considering endogenous network structure variables, node variables and external network covariates, to analyze the Climate Change Mitigation Technology Innovation Cooperation Network (CCMTICN) formed in Chinese provinces, and analyzes the influencing factors and evolution of the CCMTICN from 2011 to 2021 using CCMT patent data from the Himmpat database. The results show that CCMTICN shows obvious core-edge structural characteristics; endogenous network structural variables have a non-negligible influence on the formation of the network, and other factors such as the information exchange network, industrialization level, knowledge level, and the degree of governmental intervention can promote the formation of CCMTICN; whereas, foreign direct investment, urbanization level, and carbon dioxide(CO2) emissions can inhibit the formation of CCMTICN. When considering the 11-year time effect of CCMTICN, it is found that the CCMT cooperative relationship between provinces remains relatively stable.