We study the temporal evolution of the combustion flowfield established by the interaction of ram accelerator-type projectiles with an explosive gas mixture accelerated to hypersonic speeds in an expansion tube. The Navier-Stokes equations for a chemically reacting gas mixture are solved in a fully coupled manner using an implicit, time accurate algorithm. The solution procedure is based on a spatially second order, total variation diminishing scheme and a temporally second order, variable-step, backward differentiation formula method. The hydrogen-oxygen-argon chemistry is modeled with a 9-species, 19-step mechanism. The accuracy of the solution method is first demonstrated by several benchmark calculations. Numerical simulations of expansion tube flowfields are then presented for two different geometries: an axisymmetric projectile and a ram accelerator configuration. The development of the shock-induced combustion process is followed. The temporal variations of the calculated thrust and drag forces on the ram accelerator projectile are also presented. In the axisymmetric projectile case, which was designed to ensure combustion only in the boundary layer, the radial extent of the flame front during the initial transient phase was surprisingly large. In the ram accelerator configuration the flame propagated upstream along both the projectile and tube wall boundary layers, resulting in unstart.