Initial Pore Research Articles

An enhanced numerical model for considering coupled strain-softening and seepage effects on rock masses surrounding a submarine tunnel

The seepage of groundwater and the strain-softening of rock mass in a submarine tunnel expand the plastic region of rock, thereby affecting its overall stability. It is therefore essential to study the stress and strain fields in the rocks surrounding the submarine tunnel by considering the coupled effect of strain-softening and seepage. However, the evolution equation for the hydro-mechanical parameters in the existing fully coupled solution is a uniform equation that is unable to reproduce the characteristics of rock mass in practice. In this study, an updated numerical procedure for the submarine tunnel is derived by coupling strain-softening and seepage effect based on the experimental results. According to the hydro-mechanical coupling theory, the hydro-mechanical parameters such as elastic modulus, Poisson's ratio, Biot's coefficient and permeability coefficient of rocks are characterized by the fitting equations derived from the experimental data. Then, the updated numerical procedure is deduced with the governing equations, boundary conditions, seepage equations and fitting equations. The updated numerical procedure is verified accurately compared with the previous analytical solution. By utilizing the updated numerical procedure, the characteristics of stress field and the influences of initial pore water pressure, Biot's coefficient, and permeability coefficient on the stress, displacement and water-inflow of the surrounding rocks are discussed. Regardless of the variations in hydro-mechanical parameters, the stress distribution has a similar trend. The initial permeability coefficient exerts the most significant influence on the stress field. With the increases in initial pore water pressure and Biot's coefficient, the plastic region expands, and the water-inflow and displacement increase accordingly. Given the fact that the stability of the tunnel is more sensitive to the seepage force controlled by the hydraulic parameters, it is suggested to dewater the ground above the submarine tunnel to control the initial pore water pressure.

A modified pore evolution particle model applied to CaCO3 decomposition and CaO sintering during calcium looping CO2 cycles

The calcium looping of calcium-based carbonation/calcination cyclic reaction is an efficient decarbonization technology that can be applied to post-combustion carbon capture, solar thermal storage, and enhanced methane reforming hydrogen. The pore structure generated during the calcination stage greatly affects adsorption performance. Hence, the change of pore structure is crucial during the calcination. Existing models related to pore structure still need to be further improved regarding pore formation mechanisms. In this paper, a modified pore evolution model is proposed. The modified pore evolution model contains the kinetic equation, the CO2 diffusion equation, and the vacancy aggregates equation. The modified model considers the possibility of spontaneous pore formation in the mechanism, which can better fit the experimental results and provide higher simulation accuracy. The model reveals the diffusion of CO2 within the particles during decomposition, and spatiotemporal evolutionary properties of pore parameters. The pore change trend is the most obvious when the initial pores are mainly 3 nm mesopores. The pore evolution is relatively stable when the initial pores are mainly 25 nm mesopores. Besides, the particles experience significant pore migration during the sintering stage when the temperature reaches 1273 K. At 1073 K, the maximum pore size occurring during pore evolution did not exceed 40 nm. The model estimates a maximum pore size of more than 60 nm at 1273 K. The modified model can aid in a deeper comprehension of how the pore structure changes throughout the calcination process.

Quantitative classification evaluation model for tight sandstone reservoirs based on machine learning

Tight sandstone reservoirs are a primary focus of research on the geological exploration of petroleum. However, many reservoir classification criteria are of limited applicability due to the inherent strong heterogeneity and complex micropore structure of tight sandstone reservoirs. This investigation focused on the Chang 8 tight reservoir situated in the Jiyuan region of the Ordos Basin. High-pressure mercury intrusion experiments, casting thin sections, and scanning electron microscopy experiments were conducted. Image recognition technology was used to extract the pore shape parameters of each sample. Based on the above, through grey relational analysis (GRA), analytic hierarchy process (AHP), entropy weight method (EWM) and comprehensive weight method, the relationship index Q1 between initial productivity and high pressure mercury injection parameters and the relationship index Q2 between initial productivity and pore shape parameters are obtained by fitting. Then a dual-coupled comprehensive quantitative classification prediction model for tight sandstone reservoirs was developed based on pore structure and shape parameters. A quantitative classification study was conducted on the target reservoir, analyzing the correlation between reservoir quality and pore structure and shape parameters, leading to the proposal of favourable exploration areas. The research results showed that when Q1 ≥ 0.5 and Q2 ≥ 0.5, the reservoir was classified as type I. When Q1 > 0.7 and Q2 > 0.57, it was classified as type I1, indicating a high-yield reservoir. When 0.32 < Q1 < 0.47 and 0.44 < Q2 < 0.56, was classified as type II. When 0.1 < Q1 < 0.32 and 0.3 < Q2 < 0.44, it was classified as type III. Type I reservoirs exhibit a zigzag pattern in the northwest part of the study area. Thus, the northwest should be prioritized in actual exploration and development. Additionally, the initial productivity of tight sandstone reservoirs showed a positive correlation with the porosity, permeability, sorting coefficient, coefficient of variation, and median radius. Conversely, it demonstrated a negative correlation with the median pressure and displacement pressure. The perimeters of pores, their circularity, and the length of the major axis showed a positive correlation with the porosity, permeability, sorting coefficient, coefficient of variation, and median radius. On the other hand, they exhibited a negative correlation with the median pressure and displacement pressure. This study quantitatively constructed a new classification and evaluation system for tight sandstone reservoirs from the perspective of microscopic pore structure, achieving an overall model accuracy of 93.3%. This model effectively predicts and evaluates tight sandstone reservoirs. It provides new guidance for identifying favorable areas in the study region and other tight sandstone reservoirs.

Investigation on the responses of geotechnical materials to unloading and seepage based on the CFD-DEM coupling method

The unloading issue is prevalent in underground engineering and significantly affects construction safety and the operation of surrounding facilities, while research regarding it is still relatively scarce. A novel CFD-DEM coupling method with dynamic fluid meshes is proposed to reproduce the unloading effect and reveal its micro-scale mechanisms. It adopts uniformly distributed point sets to generate/update fluid meshes and solves with a proposed numerical mapping method. The one-dimensional linear unloading modeling method is further established. The numerically obtained excess pore pressure and rebound deformation under the one-way drained condition are compared with the analytical solutions. The coupling method demonstrates considerable reliability in forecasting the pore pressure response and its advantage for predicting rebound deformation is revealed. The evolutions of the fluid velocity field, particle displacement field, and pore pressure distribution profile are described. The influences of fluid compressibility, unloading rate, unloading volume and initial pore pressure on the unloading characteristics are carefully investigated. The results indicate that the pore pressure is obviously influenced by the selected factors. However, the impact of unloading volume on the final rebound deformation is most significant. Finally, influences of frictionless walls, two-way drained conditions, buoyancy and fluid viscosity on the unloading response are further discussed.

Influence of physical properties and shear rate on static liquefaction of saturated loess

Flow sliding instability of saturated loess slopes is a common geological hazard in loess areas of China. Previous studies have found that the occurrence of flow-slip loess landslides is closely related to static liquefaction and is controlled by physical characteristics and load conditions. In this work, we comprehensively study these influences of physical properties (i.e. initial pore structure, gradation, dry density) and shear rate on the static liquefaction of saturated loess through a series of consolidated undrained triaxial tests, and the effect mechanism of these related factors on the static liquefaction of saturated loess are also discussed. The results present that: (1) The peak deviator stress and the maximum pore pressure of the undisturbed loess are much greater than these of the remodeled one under each level of confining pressure (except 450 kPa). Further, the calculated liquefaction potential index (LPI) of undisturbed loess is much greater, indicating that undisturbed loess is more prone to static liquefaction due to the initial pore structure. (2) The lower the relative clay/silt content ratio of the saturated remodeled loess, the stronger the potential liquefaction ability. With the increase of the relative content of clay from 0.125 to 0.698, the stress-strain curve gradually transitions from strain softening to hardening. (3) The remodeled loess show the steady-state strength tends to continuously increase with the increase of dry density from 1.38 g/cm3 to 1.56 g/cm3, while the LPI increases first and then decreases, and the largest value appears when the dry density reaches to 1.44 g/cm3. The reason is that the value of 1.44 g/cm3 is the normal consolidated condition, which essentially reflects the potential liquefaction change during the transformation from under consolidated to over consolidated state.(4) The effect of shear rate on the stress-strain curve of remolded loess is not significant, but the peak strength and ultimate pore pressure show a trend of increasing and then decreasing with the increase of shear rate. There exists a “critical shear rate “of 0.1 mm/min reflecting the liquefaction of loess is more likely to occur when reaches to this critical value. (5) Based on the comparison of static liquefaction tests, the influencing factors of static liquefaction of saturated loess are: initial pore structure> gradation > dry density > shear rate. This study can provide a systematic evaluation for understanding the influencing factors of static liquefaction capacity of saturated loess (especially remolded one), and also has a reference for explaining the loess flow-sliding failure mechanism under disturbance conditions.

Galerkin Kantorovich Method for Solving the Terzaghi’s One-Dimensional Soil Consolidation Equation

This paper presents the Galerkin-Kantorovich variational method for solving the Terzaghi’s one-dimensional consolidation equation for two-way drainage conditions. The solution was considered as an infinite series of known coordinate (shape) functions and unknown function of time which we sought such that the resulting functional is minimized. The shape functions satisfied the hydraulic boundary conditions at the boundary of the consolidating soil. Galerkin-Kantorovich variational integral equation was thus formulated for the initial boundary value problem using residual minimization principles. The solution resulted in a system of first order ordinary differential equations in which was solved for Orthogonalization principles were used to obtain the integration constants in terms of initial pore water pressure, thus yielding the general solution. Solutions for constant initial excess pore water pressure were obtained and found to be the closed-form solution. The solutions were presented in terms of global (average) degrees of consolidation and tabulated. The results obtained were exact and identical with results previously found using separation of variables techniques.

Somatostatin modulation of initial fusion pores in Ca2+-triggered exocytosis from mouse chromaffin cells.

Somatostatin, a peptide hormone that activates G-protein-coupled receptors, inhibits the secretion of many hormones. This study investigated the mechanisms of this inhibition using amperometry recording of Ca2+-triggered catecholamine secretion from mouse chromaffin cells. Two distinct stimulation protocols, high-KCl depolarization and caffeine, were used to trigger exocytosis, and confocal fluorescence imaging was used to monitor the rise in intracellular free Ca2+. Analysis of single-vesicle fusion events (spikes) resolved the action of somatostatin on fusion pores at different stages. Somatostatin reduced spike frequency, and this reduction was accompanied by prolongation of pre-spike feet and slowing of spike rise times. This indicates that somatostatin stabilizes initial fusion pores and slows their expansion. This action on the initial fusion pore impacted the release mode to favour kiss-and-run over full-fusion. During a spike the permeability of a fusion pore peaks, declines and then settles into a plateau. Somatostatin had no effect on the plateau, suggesting no influence on late-stage fusion pores. These actions of somatostatin were indistinguishable between exocytosis triggered by high-KCl and caffeine, and fluorescence imaging showed that somatostatin had no effect on stimulus-induced rises in cytosolic Ca2+. Our findings thus demonstrate that the signalling cascades activated by somatostatin target the exocytotic machinery that controls the initial and expanding stages of fusion pores, while having no effect on late-stage fusion pores. As a result of its stronger inhibition of full-fusion compared to kiss-and-run, somatostatin will preferentially inhibit the secretion of large peptides over the secretion of small catecholamines. KEY POINTS: Somatostatin inhibits the secretion of various hormones by activating G-protein-coupled receptors. In this study, we used amperometry to investigate the mechanism by which somatostatin inhibits catecholamine release from mouse chromaffin cells. Somatostatin increased pre-spike foot lifetime and slowed fusion pore expansion. Somatostatin inhibited full-fusion more strongly than kiss-and-run. Our results suggest that the initial fusion pore is the target of somatostatin-mediated regulation of hormone release. The stronger inhibition of full-fusion by somatostatin will result in preferential inhibition of peptide release.

Research on ship-ice collision model and ship-bow fatigue failure Mechanism based on elastic-plastic ice constitutive relation

Collisions between sea ice and ships can damage the hull structure and pose a threat to crew safety in severe cases. The modelling of ice materials is crucial, but it is difficult to study ice-ship interactions. In this study, an ice constitutive model including the temperature factor was verified through experiments and numerical simulations of uniaxial and triaxial compression. Furthermore, the effects of salinity and porosity on the compressive strength of ice were studied using experiments and numerical simulations. The mechanical behaviour of sea ice was then simulated using the constitutive model mentioned above. A numerical model of collisions between polar ships and sea ice was established to investigate the ice-breaking processes of ships under different working conditions. The collision force and the level of structural damage were obtained. The influences of the initial pore size, hull speed, bow angle, and bow shape on the collision force and structural damage in the ship-ice collision process were analysed. Finally, fatigue damage to the bow structure at different ice thicknesses and speeds was calculated. The present results provide a reference for the structural design and optimisation of polar ships to a certain extent and improve the theory of ship-ice collisions.

Strength response investigation of defective C/C composite materials based on the Weibull model

In this study, the issue of random fiber strength resulting from initial fiber defects and matrix pore defects in the strength response of C/C composite materials is addressed. A method for generating random numbers following the Weibull distribution is proposed and an improved random sequence adsorption (RSA) algorithm is employed to describe pore defects in the matrix, ultimately leading to the development of a representative volume element (RVE) model for C/C composite materials. The influence of fiber strength distribution and pore defects on the mechanical properties of unidirectional C/C (UD-C/C) composite materials is analyzed. This study offers a new approach to investigate the mechanical behavior of C/C composite materials, taking into account both fiber initial defects and pore defects.

Observations on the role of internal sand moisture dynamics in wave-driven dune face erosion

Understanding and predicting dune erosion is crucial for coastal hazards mitigation, ecosystem preservation, as well as the protection of human settlements and infrastructure along sandy coastlines. However, our knowledge regarding the influence and potential importance of internal sand moisture content on wave-driven dune face erosion processes remains limited. This paper presents the findings from an extensive series of controlled wave flume experiments of eroding, unvegetated dunes, combining a range of wave conditions and water levels. A further variable that is studied directly for the first time is the internal moisture content of the dune. The initial moisture content and its evolving dynamics within the eroding dune face are quantified, revealing this to be a determining factor of the observed erosion rates, the final horizontal erosion distance, and the dune face failure type. Importantly, infiltration into the dune with each wave was not a driving mechanism of observed failures, but rather the rapid increase and then decrease of the phreatic surface within the dune, resulting in excess pore pressures and destabilization of the sediment matrix. Based on these observations two distinct mechanisms of shear failure and resulting dune face slumping are identified for unsaturated dunes corresponding to ‘minimum’ and ‘field capacity’ internal moisture content: Type 1 is associated with a circular failure surface in the absence of notching at the base of the dune, while for Type 2, notching is present and the failure surface is vertical. Under fully saturated conditions, the phreatic surface is observed to decouple from the wave runup, with excess water continuously exiting the dune face near the base. This results in rapid shear failure with no notching (Type 3). Significantly, dunes with saturated initial pore moisture content above the capillary fringe are observed to have up to 35 % greater erosion potential, consistently receding further landward than the two unsaturated counterparts as well as undergoing slumping in the absence of wave impact. A new conceptual framework is presented, comprising of a three-phase erosion sequence that directly links dune face failure mechanisms to wave runup and prevailing groundwater conditions.

Freezing‐Thawing Hysteretic Behavior of Soils

AbstractThe soil freezing characteristic curve (SFCC) plays a crucial role in investigating the soil freezing‐thawing process. Due to the challenges associated with measuring the SFCC, there is a shortage of high‐quality or rigorous test results with sufficient metadata to be effectively used for applications. Current researchers typically conduct freezing tests to measure the SFCC and assume a singular SFCC when studying the freezing‐thawing process of soils, although limited studies indicated that there is a hysteresis during the freezing and thawing process. In this paper, a series of freezing‐thawing tests were performed to assess the SFCC, utilizing a precise nuclear magnetic resonance apparatus. The test results reveal a hysteresis between the SFCC obtained from the freezing process and that from the thawing process. Through analyzing the test results, the hysteresis mechanism of the SFCC is attributed to supercooling. Supercooling inhibits initial pore ice formation during freezing, causing a drastic liquid water‐ice phase change once supercooling ends. Despite being considered closely related, the hysteresis of the SFCC differs from the soil water characteristic curve (SWCC), and the models used to simulate the hysteresis of SWCC cannot directly be used. To address the impact of supercooling on soil freezing‐thawing hysteresis, a novel theoretical model is proposed. Comparisons between the measured and predicted results affirm the validity of the proposed model.

Computational analysis of the simultaneous application of ultrasound and electric fields in a lipid bilayer

The combined application of electric fields and ultrasonic waves has shown promise in controlling cell membrane permeability, potentially resulting in synergistic effects that can be explored in the biotechnology industry. However, further clarification on how these processes interact is still needed. The objective of the present study was to investigate the atomic-scale effects of these processes on a DPPC lipid bilayer using molecular dynamics simulations. For higher electric fields, capable of independently forming pores, the application of an ultrasonic wave in the absence of cavitation yielded no additional effects on pore formation. However, for lower electric fields, the reduction in bilayer thickness induced by the shock wave catalyzed the electroporation process, effectively shortening the mean path that water molecules must traverse to form pores. When cavitation was considered, synergistic effects were evident only if the wave alone was able to generate pores through the formation of a water nanojet. In these cases, sonoporation acted as a mean to focus the electroporation effects on the initial pore formed by the nanojet. This study contributes to a better understanding of the synergy between electric fields and ultrasonic waves and to an optimal selection of processing parameters in practical applications of these processes.

Theoretical Analysis of Drilling Unloading and Pile-Side Soil Pressure Recovery of Nonsqueezing Pipe Piles Installed in K0-Consolidated Soils

Drilling with prestressed concrete (DPC) pipe pile is a nonsqueezing pile sinking technology, employing drilling, simultaneous pile sinking, a pipe pile protection wall, and pile side grouting. The unloading induced by drilling, the pipe pile supporting effect, and the dissipation of the negative excess pore-water pressure after pile sinking, all of which have significant effects on the recovery of soil pressure on the pile side, are the main concerns of this study, which aim to establish a method to reasonably evaluate the timing selection of pile side grouting. The theoretical solutions for characterizing the unloading and dissipation of the negative excess pore-water pressure are presented based on the cylindrical cavity contraction model and the separated variable method. By inverse-analyzing the measured initial pore pressure change data from borehole unloading, initial soil pressures on the pile side of each soil layer are determined using the presented theoretical solutions. Then, the presented theoretical solutions were verified through a comparative analysis with the corresponding measured results. Moreover, by introducing time-dependent coefficients αt1 and αt2 to characterize the pore pressure dissipation and rheology effects, the effects of the negative excess pore-water pressure dissipation on the pile-side soil pressure recovery are discussed in detail.

Measures and results of prevention and control on casing deformation and frac-hit in deep shale gas wells in southern Sichuan Basin

Casing deformation and frac-hit pose significant challenges to the development of deep shale gas in southern Sichuan Basin. By analyzing the mechanism and main control factors of casing deformation and frac-hit, two kinds of risk assessment methods were defined, and the overall prevention and control concept and practice were formulated. The results show that initial stress, pore pressure, fault development and large scale fracturing in local block are the main factors leading to the deformation. The development of fracture through well group and uncontrolled fracturing fluid volume are the main factors leading to pressure channeling. Based on this, the risk classification technology of casing deformation and frac-hit is established, and the dual-optimal, dual-control concept and technology are formed. In terms of the prevention and control of casing deformation, the formation of small-diameter bridge plug fracturing, large section combined fracturing, glass beads cementing, single-well staggered and platform straddle fracturing mode, dual-dimension controlled and lift fracturing, hyperbolic diagnosis, etc. Frac-hit prevention and control formed pump sequence optimization mode, physical and chemical temporary plugging and other methods. The above technology achieved casing deformation rate decreased from 50.4% to 25.4%, frac-hit rate decreased from 58.6% to 33.9%, and the average well kilometer EUR reached 0.52–0.7 million square meters, an increase of 7.7% compared with the previous research, with remarkable results.

Extended Aquifer System Pressure Behavior under Carbon Storage

Summary Most reported carbon storage projects have involved inexpensive carbon dioxide (CO2) capture from gas processing plants or ethanol refineries. However, widespread carbon capture and storage (CCS) application must avoid any risk that high capital investment cost for carbon capture from stationary point sources leads to unanticipated issues related to the aquifer storage. This paper reviews successful and unsuccessful carbon storage projects and explains simple extended aquifer system fundamentals that must be considered in selecting a storage aquifer. This study begins by evaluating reported carbon storage projects in the context of an extended aquifer system with specific attention to initial formation pore pressure and potential or known hydraulic vertical or lateral communication with hydrocarbon accumulations and/or fresh water. Further study focuses on how the contrast between injection well and aquifer pressure evolution enables understanding of the overall aquifer material balance. Finally, we consider implications of brine migration during and after long-term CO2 injection in unconfined aquifers. Experience in the petroleum industry with aquifer behavior includes presence or lack of water influx and production from hydrocarbon reservoirs that share a common aquifer. Of particular importance is the observation that hydrostatic initial formation pressure indicates the possibility that a petroleum system, or an extended aquifer system without hydrocarbon accumulation(s), connects to atmospheric pressure through an unconfined aquifer. In such cases, indefinite injection will never increase the regional aquifer pressure. Furthermore, initial formation pressure that exceeds hydrostatic pressure implies a petroleum system or an extended aquifer system that is volumetrically limited. In such cases, injection will increase the system pressure, and pressure monitoring can detect leakage from the system. Finally, CO2 injection into an aquifer will displace brine in the direction of lower pressure that could relate to distant production from the same aquifer or from hydrocarbon reservoirs with which it communicates. Reasons for known carbon storage project interruptions have included unexpected lateral plume migration or aquifer pressure increase during CO2 injection that might have been anticipated with attention to straightforward consideration of aquifer-enabled hydraulic communication. Such extended aquifer dynamics must be included in long-term models for permanent CO2 storage during and after injection.

Numerical investigation of heat extraction performance affected by stimulated reservoir volume and permeability evolution in the enhanced geothermal system

The high-permeability stimulated reservoir volume (SRV) containing artificial fractures is the main region for deep geothermal extraction. Evaluating the SRV distribution and the contributions of fluid pressure and thermal stress to permeability evolution is essential to accurately quantify heat extraction. Here, we employ the numerically calculated pore pressure and the field-measured rock failure as evaluation indicators to reasonably identify the SRV and investigate the effect of rock and fracture permeability evolution on heat extraction performance. We find that simply assuming the entire model as the SRV would significantly overestimate the heat extraction, and scientifically defining the SRV based on hydraulic fracturing is crucial. The variable rock permeability model extracts marginally less heat as the working fluid squeezes and cools surrounding rocks causing their lower permeability. In regions around the injection well, both the high fluid pressure and the thermal stress increase the fracture aperture and permeability, whereas the fluid pressure shows the opposite effect around the production well as it is lower than the initial pore pressure. When the main fractures connect injection and production wells, the widened fractures accelerate fluid flow, causing higher heat extraction for a short time (first 4 years); however, after 4 years’ operation, the heat extraction remains at a lower value for a long time as the increased fracture permeability causes more fluids to flow directly from main fractures to the production well without playing participating in heat exchange. When the main fractures do not connect injection and production wells, the increased fracture permeability slightly enhances the heat extraction over the geothermal extraction process with a relative error less than 0.025. This study provides guidance for the appropriate selection of geothermal extraction simulation assumptions.

Efficient production of activated carbon with well-developed pore structure based on fast pyrolysis-physical activation

As the most commonly used method for industrial activated carbon preparation, physical activation is usually accompanied by significant loss of raw materials, especially when the pore structure of activated carbon is well developed. This not only reduces yields, but also increases costs. To enhance both yield and pore structure of activated carbon, we proposed a facile and scalable method called "fast pyrolysis-physical activation". After fast pyrolysis, although the initial pore volume of the semi-coke decreases, the rapid release of volatiles promotes the increase of mesopore and macropore volumes and the development of micron-scale cracks, which is beneficial for CO2 mass transfer and reduces diffusion resistance. Therefore, compared to slow pyrolysis, the activated carbon produced through this method has a higher pore volume (increased by 25.9 %–30.0 %) and a larger SBET (increased by 26.7 %–38.3 %), while the yield remains almost unchanged. Consequently, due to the increase in pore volume and high yield of the activated carbon, the CO2 adsorption capacity (25 °C, 1 bar) of ACB-K700 increases from 2.02 mmol/g to 2.37 mmol/g compared to ACB-M700, and the total CO2 adsorption capacity of activated carbon prepared from the same mass of raw coal (1 g) increases from 1.07 mmol to 1.16 mmol. Due to the pre-formed pores inside the semi-coke, the gas activator molecules are able to penetrate deep into the particles, which not only reduces the ineffective etching that occurs on the surface, but also promotes the development of pore structure. In conclusion, this study provides a new pore development model for physical activation, and also provides a new method to produce activated carbon rapidly and massively, while the pore structure is well developed.

Study on mechanism of particle aggregation and pore formation during loess air-fall deposition based on discrete element method

The pore structure of aeolian deposits is essential for predicting their mechanical properties and the climatic conditions during their deposition. The discrete element method (DEM) is a practical approach for analysing the formation and evolution mechanisms of aeolian deposits’ pore structure. However, the effect of particle shape and non-contact van der Waals force on deposits’ pore structure with different particle sizes needs further exploration to enhance the efficiency and accuracy of DEM simulations. We developed a VdwForce model for DEM that accounts for the van der Waals force’s long-tail effect, and we conducted loess air-fall numerical tests that matched laboratory simulation tests. DEM simulations and laboratory tests show that the deposits’ porosity increased as the median particle size decreased, whether using spherical or actual shape particles in simulations. When deposits formed by particles with actual shapes have dense packing structures, simulations utilising spherical particles of the same size produce larger porosities. The primary reason of the alteration in the pore structure of the loess air-fall deposits is the shift in the quantity and pattern of particle agglomerates caused by van der Waals attractive force. So, the aggregation process during air-fall was essential for forming overhead pore structures.

The improvement on calcium leaching resistance of high SCMs content cement in ammonium chloride solution using particle gradation technique

Particle gradations of Portland cement (PC), fly ash (FA), and blast furnace slag (BFS) were optimized to improve the calcium leaching resistance of blended cement with high contents (up to 70%)of supplementary cementitious materials (SCMs). The results showed that optimized blended cement showed refined initial pore volume distribution, reduced portlandite (CH) content, finer CH macrocrystals and enhanced stability of C-(A)-S-H gel. Consequently, it displayed exceptional calcium leaching resistance with reduced losses in mechanical performance, mass and pore degradation after calcium leaching. Blended cement with 30% PC (D50 = 14.46 μm), 30% FA (D50 = 10.94 μm), 20% BFS (D50 = 10.52 μm), 13% BFS (D50 = 5.31 μm) and 7% BFS (D50 = 4.71 μm), showing compressive strength retention rate of 79.05% and mass loss rate of 1.64%, was suggested as viable choice for calcium leaching resistant concrete.

Direct Single Crystal to Amorphous Transformation and Memory Effect in AlPO4-17.

Pressure induced amorphization provides a distinct route to prepare novel amorphous materials. Single crystals of the porous aluminophosphate AlPO4-17 directly transform to an amorphous state beginning at 0.6 GPa, without fragmentation into polycrystalline material. Apart from a reduction in dimensions, the amorphous material retains the form of the initial single crystal. Remnant crystalline domains in the amorphous material also preserve the initial orientation of the single crystal. X-ray diffraction indicates the compression of the structure around the empty pores in the xy plane and such an amorphization mechanism is consistent with a direct structural relationship between the single crystal and amorphous forms. The collapse of the initial pore volume is almost complete at 2.5 GPa. A memory effect is observed in the amorphous form, which strongly expands on decompression. The present process opens the way for the synthesis of topologically ordered amorphous materials approaching "perfect glasses" with improved mechanical properties.