This study compares the performance of a laser ignition system vis-à-vis a conventional electrical spark ignition system in a constant volume combustion chamber. A custom-built constant-volume combustion chamber was used to compare the performance of the laser and spark ignition systems. A combination of three lenses in the optical path was used to create laser plasma in the constant volume combustion chamber. Initial chamber pressure and temperature were maintained constant at 4bar and 150 °C during the experiments. The effect of hydrogen enrichment of compressed natural gas on combustion was assessed for three relative air–fuel mixture strengths (λ: 1.0, 1.2 and 1.4) to compare the performance of both ignition systems. The laser ignition system exhibited superior combustion characteristics to the spark ignition system. The combustion duration of laser ignition was considerably lower than spark ignition. Three hydrogen-enriched natural gas blends (10HCNG, 20HCNG and 40HCNG) were assessed and compared with baseline compressed natural gas. Hydrogen enrichment improved the combustion characteristics, increasing the excess chamber pressure and reducing the combustion duration. Two locations were taken for assessing the performance of the laser ignition system in this study. The first location was the same as the spark from a conventional electrical spark ignition system, and the second was at the centre of the constant volume combustion chamber. The central location of laser ignition showed a higher reduction in the combustion duration than baseline spark ignition and its corresponding laser ignition, indicating its superiority. The ability to choose an ignition location centrally in the engine combustion chamber emerged to be a main advantage of laser ignition systems.