The features and regularities of self−assembly and self− organization processes in the diffusion−limited conditions (method of drops) of aqueous (deionized water) colloidal solutions of multi−walled carbon nanotubes with aerosil under the influence of constant electric fields with a value varying of direct current voltage from 15 to 25 V have been studied. During droplet evaporation in an electric field, the processes of hierarchical structuring have been studied and the formation of linear piecewise with the sizes of 40—120 nm, fractal structures 25—45 nm and diffusion structures 250 nm from MWCNT — COOH + aerosil + H 2 O DI have been observed. These structures have been analyzed by methods of confocal microscopy, X−ray powder diffraction, Raman scattering, atomic force microscopy, FT−IR spectroscopy and scanning electron microscopy. The size of micro− and nanostructures in hyperbolic dependence of d = 1/U in the approximation d → 2R, and their growth rate increases as U 2 have been observed. Intensive ultrasonic dispersion proves to produce a centrally−axial arrangement located SWCNT after ultrasonic dispersing of functionalized MWCNT — COOH + aerosil + H 2 O DI colloidal solution, as confirmed by excitation of Raman lines in the low−wavelength region, the so−called breathing mode, resulting in the existence of mixed types sp 2 −hybridization with π− and σ−carbon bonds, as well as metallic and semiconducting conductivity, which indicates great practical importance of this structuring for the development of nanoelectronics.
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