Infiltration Of Meteoric Water Research Articles

Re-interpreting renewable and non-renewable water resources in the over-pressured Pannonian Basin

With climate change, population growth and the resulting escalating water shortage, humanity is increasingly turning to non-renewable and even fossil groundwater resources, which poses a major challenge to sustainable water management. In this study, 2D basin-scale numerical simulations were carried out on the COMSOL Multiphysics® finite element numerical platform to identify non-renewable water resources in the Central Pannonian Basin (Central Europe, Hungary) based on the lack of hydraulic connection to recharge areas. The concept and boundary conditions (fixed water table configuration at the top, pressure-elevation profiles on the lateral sides, and constant pressure on the bottom) were derived from a previous basin-scale hydraulic data evaluation study, while the hydrostratigraphic subdivision was based on seismic and well log interpretations. As a result, topography-driven groundwater flow systems fed by meteoric water infiltration were separated from a transition zone, which contains non-renewable groundwater resources and covers 85% area of the simulated 110 km long and roughly 1600 m deep cross-section what was previously thought to be fully renewable. Such complex flow pattern and re-interpretation of the renewable and non-renewable groundwater resources can be expected in any terrestrial sedimentary basin with over-pressured flow domains.

Diagenesis Variation in Different Distributary Channels of Shallow Water Lacustrine Delta Deposits and Implication for High-Quality Reservoir Prediction: A Case Study in the Chang 8 Member in Caijiamiao Area, Sw Ordos Basin, China

Tight oil reservoirs are considered important exploration targets in lacustrine basins. High-quality reservoir prediction is difficult as the reservoirs have complex distributions of depositional facies and diagenesis processes. Previous research has found that the diagenesis process of tight oil sandstones varies greatly in different depositional facies. However, diagenesis variation in different depositional facies is still poorly studied, especially in distributary channels of shallow water delta deposits in lacustrine basins. Based on the description of core samples, the observation of rock slices, the interpretation of well logging data, and the analysis of porosity and permeability data, the differences in the lithofacies types, diagenesis processes, and pore structures of different distributary channels have been clarified. Ultimately, a model of diagenesis and reservoir heterogeneity distribution in the shallow-water delta of Chang 8 Member of the Yanchang Formation in the Caijiamiao area of the Ordos Basin has been established. This research indicates that the main distributary channels in the study area are dominated by massive bedding sandstone lithofacies, while the secondary distributary channels are primarily characterized by cross-bedding sandstone lithofacies. There are significant differences in the compaction, dissolution, and cementation of authigenic chlorite and carbonate among different parts of the distributary channels. Plastic mineral components, such as clay and mica, are abundant in sheet sands, and are more influenced by mechanical and chemical compaction. Influenced by the infiltration of meteoric water and hydrocarbon generation, dissolution pores are relatively well-developed in the underwater distributary channel reservoirs. A large amount of carbonate cementation, such as calcite and siderite, is found within the sandstone at the interface between sand and mud. The occurrence of authigenic chlorite exhibits a clear sedimentary microfacies zonation, but there is little difference in the kaolinite and siliceous cementation among different microfacies reservoirs. Finally, a model of diagenetic differences and reservoir quality distribution within dense sand bodies has been established. This model suggests that high-quality reservoirs are primarily developed in the middle of distributary channels, providing a theoretical basis for the further fine exploration and development of oil and gas in the study area.

World-class amethyst-agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes

AbstractThe amethyst and agate geodes from the Los Catalanes Gemmological District in Uruguay represent one of the main deposits of its kind worldwide. The geometry of the deposit is horizontal, with an irregular distribution of amethyst geodes within the upper level of the basalt lava flows and shows strong variations in their abundance, as well as quality, geometry, and shape. Reliable exploration guides are scarce, and the limited knowledge of the geological parameters controlling its occurrence makes exploration unpredictable, leading to inaccurate reserve estimation. Based on cutting-edge methods including nucleation-assisted microthermometry of one-phase fluid inclusions and determination of triple oxygen isotope in silicates and carbonates, as well as analysis of geode-hosted water and groundwater, we estimate the crystallisation temperatures in the range between 15 and 60 °C. These low temperatures point to amethyst crystallisation after the emplacement of the complete basalt pile. The mineralising fluid shows isotopic signatures consistent with meteoric water and very low salinities from pure water up to rarely over 3 wt% NaCl-eq., likely sourced from the groundwater hosted in the aquifers in the basaltic sequence and underlying units. Based on the insights provided by the new data, we propose the combination of open- and closed-system crystallisation inside pre-existing cavities due to the episodic infiltration of meteoric water in a rather stable geological context.

Hydrogeochemical and isotopic investigations of groundwater in the reclaimed desert located between EL Nasr canal and Mariut Tableland, NW Coast, Egypt

A complete understanding of groundwater dynamics and its interaction with surface water under the impact of agricultural activities is vital for local agriculture, ecology, and residents of dry regions, which is not commonly recognized in arid areas. This research outlines the geochemical characteristics, recharge sources, and potential factors impacting groundwater quality in a new land reclamation located in the small basin of Abu Mina, which is part of the Western Nile Delta region.1 Thirty-one groundwater samples and two surface water samples were collected in 2021 to represent the Pleistocene aquifer and were subjected to multivariate statistical, hydrochemical, and stable isotope analyses. Data analysis demonstrates that Na+ > Ca2+ > Mg2+ > K+ and SO42– > Cl– > HCO3– > NO3– are the predominant cations and anions, respectively. Groundwater salinity ranged from 465.60 to 6455.18 mg/l, with slightly alkaline. Most of the water samples fall into one of three types of facies: Ca–Cl, Na–Cl, and Mixed Ca–Mg–Cl, in decreasing order. The meteoric genesis index (r2) indicates that deep meteoric water percolation dominates the Pleistocene aquifer. The aquiline diagrams, correlation matrix, and different ionic ratios indicate that evaporation, reverse ion exchange reactions, and the dissolution of carbonate and silicate minerals are the main processes governing groundwater chemistry. Factor analysis (FA) indicated that three factors explain groundwater hydrochemistry, accounting for 71.98% of the total variance. According to the rotating components matrix (F1–F3), the chemistry of the Quaternary aquifer is principally affected by evaporation, ion exchange reactions, and anthropogenic influences. Additionally, salinity increases due to the return flow of irrigation activities and mixing between old and recent water. The stable isotopes (δ18O and δ2H) indicate that the Quaternary aquifer receives groundwater recharge through the return flow of excess irrigation and canal seepage. Under desert reclamation conditions, groundwater salinization processes should be given special consideration. All groundwater samples are appropriate for agricultural irrigation based on the Sodium Adsorption Ratio (SAR), Permeability Index (PI), Percent Sodium (%Na), and Residual Sodium Carbonate (RSC).

Geologic and Tectonic Controls on Deep Fracturing, Weathering, and Water Flow in the Central California Coast Range

AbstractThe creation of fractures in bedrock dictates water movement through the critical zone, controlling weathering, vadose zone water storage, and groundwater recharge. However, quantifying connections between fracturing, water flow, and chemical weathering remains challenging because of limited access to the deep critical zone. Here we overcome this challenge by coupling measurements from borehole drilling, groundwater monitoring, and seismic refraction surveys in the central California Coast Range. Our results show that the subsurface is highly fractured, which may be driven by the regional geologic and tectonic setting. The pervasively fractured rock facilitates infiltration of meteoric water down to a water table that aligns with oxidation in exhumed rock cores and is coincident with the adjacent intermittent first‐order stream channel. This work highlights the need to incorporate deep water flow and weathering due to pervasive fracturing into models of catchment water balances and critical zone weathering, especially in tectonically active landscapes.

Geological modeling of a tectonically controlled hydrothermal system in the southwestern part of the Pannonian basin (Croatia)

Geothermal energy is an important resource in the green economy transition. For the preservation of a geothermal resource it is crucial to assess its renewability and the sustainability of the exploitation. These aspects are influenced by the interaction among the physical, chemical, geological, and hydrogeological processes. The reconstruction of the geological assemblage allows the detailing of the geometries of the reservoir and fracture systems that influence the fluid flow and the water/rock interaction. The control of regional/local scale fault and fold systems on the development of the Daruvar hydrothermal system (DHS), located in Croatian part of the Pannonian basin, is detailed in this work. Field investigations were conducted to collect structural data on strata orientation and fault/fracture systems. The dataset was integrated with geological and geophysical data to develop composite geological profiles and a 3D geological model. Results display a pattern of generally N-S and E-W striking folds and cogenetic fracture systems with orientations parallel to the fold axes. The geological reconstruction was integrated with geophysical, hydrogeological, and geochemical data to propose a conceptual model of the DHS. The DHS is a topographically driven system hosted in a Mesozoic carbonate reservoir where E-W striking fracture systems are regional flow paths that enable infiltration of meteoric water to 1 km depth and its reheating in its reservoir area. In Daruvar, an anticline and fault/fracture systems accommodate the uplift of reservoir to shallow depths, promoting the bedrock fracturing and increase of the permeability field. These conditions favor the localized upwelling of thermal water resulting in four thermal springs (38°C and 50°C) in Daruvar city area. This work highlights the importance of employing a multidisciplinary approach to detail the complex interaction among the processes driving the geothermal resource.

Late-fracture calcite veins decode natural gas preservation

The preservation of natural gas can be easily dismissed by late crustal deformations, which are often concealed by fracture-filling calcite vein networks. This study introduces a novel approach to confine the timeframe of natural gas-leakage processes by employing coupled in situ U–Pb dating and clumped isotope (Δ47) analysis of late-fracture calcite veins associated with brittle deformation in caprock/unconventional reservoirs during basin uplift. Specifically, Δ47 and U–Pb data were acquired for fracture calcite veins that formed in high-angle or vertical fractures within the early Silurian shale reservoirs of the Southeastern Sichuan Basin in China. Absolute U–Pb ages revealed two distinct calcite precipitation events at 6.89 ± 0.18 and 3.55 ± 0.11 Ma, respectively. The primary mechanism for shale gas escape from early Silurian shale reservoirs was the leakage of natural gas through activated high-angle faults that had remained unsealed since at least 6.89 Ma. At approximately 3.55 Ma, the overlying weathered layer was lifted to the surface of the Earth, facilitating the connection between meteoric water and shale reservoirs through activated fractures. Natural gas leakage occurred concurrently with meteoric water infiltration, and a non-linear mixing effect between methanogenesis and meteoric water, as well as intense ventilation along the water-bearing fracture surface, is identified as the cause of delayed late-fracture calcite precipitation, leading to an abnormal δ13C of calcite vein (up to +22.1‰). This approach holds significant implications for assessing natural-gas preservation in uplifted basins worldwide.

Geological features of the Zn-Pb prospect in the Bou-Izourane district (Morocco)

The Zn-Pb mineralization in the Bou-Izourane district, located in the High Atlas Mountains of Morocco, contains estimated reserves of 40 200 tons of ore with an average grade of 20% Zn and 3.5% Pb. It is developed on N–S to NNW–SSE-trending faults that cut Liassic carbonate marl deposits. The paragenetic mineral sequence consists of galena, sphalerite and late-stage calcite. Oxidation phases of galena into cerussite and sphalerite into smithsonite are common in the Bou-Izourane ore, linked to the infiltration of meteoric waters and the oxidation of these sulphides. The Zn-Pb mineralization runs parallel to the fluorite veins associated with the igneous rocks of Tamazeght, but no petrographic or field relationship has been demonstrated between these two mineralizations (i.e., Zn-Pb and fluorite). The distribution of rare earth elements and yttrium (REY) in the Zn-Pb mineralization of Bou-Izourane shows a notable similarity with the Mississippi Valley Type (MVT) mineralization of the Central High Atlas of Morocco, although the concentrations more closely resemble those of REY in fluorite linked to the magmatic-hydrothermal activity of Tamazeght. However, the analysis of their distribution in post-fluorite calcite and post-Zn-Pb calcite reveals a strong concordance, suggesting that these two calcites are associated with the same phase and have a common origin. The classification of the Zn-Pb prospect in Bou-Izourane remains controversial, fluctuating between an MVT-type mineralization, similar to most Zn-Pb mineralizations in the Central High Atlas of Morocco, and a mineralization linked to the magmatic-hydrothermal activity of Tamazeght, which could provide heat and metallogenic material. Characterizing the Zn-Pb ore of Bou-Izourane is crucial for the future exploration of zinc and lead deposits in the High Atlas of Morocco and could advance the development of Zn-Pb mining in the region, from artisanal exploitation to professional mining

Numerical modelling of an advective geothermal system in the Central Andes: Sustainable utilization through borehole heat exchangers

The utilization of low-enthalpy geothermal resources emerges as a promising solution for district heating in the Central Andes region. Focused on the Pismanta field, a representative example of the prevalent advective geothermal systems in the area, this study investigates into the intricate dynamics of the geothermal reservoir. Situated within a fault-controlled basin, the Pismanta field undergoes deep infiltration of meteoric water, leading to peak temperatures of up to 90 °C. Numerical simulations conducted at varying scales yield critical insights into the characteristics, efficient exploitation, and potential repercussions of energy extraction from the reservoir. A comprehensive approach is adopted to facilitate the optimal management of this geothermal resource and a strategic closed-loop system comprising 10 shallow interconnected borehole heat exchangers (BHE) is proposed. This recommendation takes into account the specific basin geometry and the intricate interplay of pressures within the confined geothermal reservoir. Extensive simulations over a 10-year period show the sensitivity of the system to operating flow rates. By employing the suggested configuration, it is anticipated that a maximum thermal power extraction of 1 MW can be achieved. The circulating water within the system is projected to maintain a temperature of approximately 26 °C.

Barnacle-rich facies as a tool for palaeoenvironmental reconstructions

Palaeoenvironmental data are fundamental in determining the manifold impacts of climate change. This paper argues that sessile barnacles are an excellent palaeoenvironmental proxy: they are present in nearly all nearshore environments, and their shell consists of diagenetically stable low-magnesium calcite and grows fast enough to record short-term variations. To demonstrate their utility, specimens from several Western Mediterranean Pliocene and Pleistocene barnacle-rich deposits are analysed herein, using for the first time a combination of sedimentology, taphonomy, stable isotope geochemistry and detailed comparisons with modern counterparts. Within shelf carbonate systems, barnacle diversity is highest in the shallow, nearshore waters and decreases moving offshore, thus providing a good proxy for the reconstruction of water depth and distance from the coastline. Barnacle taphonomy is also informative. Well-preserved complete specimens are characteristic of protected areas, whereas less well-preserved specimens occur in high-energy areas. The presence/absence of opercular plates is also particularly relevant for evaluating hydrodynamic conditions. As regards the C and O stable isotope ratios, due to the porous and coarse-grained nature of the deposits in which barnacle remains are usually found, the shells are often exposed to meteoric water percolation during diagenesis. Among the analysed specimens, only those collected from fine-grained deposits display no evidence of alteration and have isotopic ratios in line with those of their modern counterparts. These fossils display intra-shell variations that in modern barnacles have been related to short-term environmental changes (e.g., seasonal cycles). These results demonstrate that barnacles can always be useful for detailed palaeoenvironmental reconstructions based on skeletal assemblages. Furthermore, with further research aimed at gathering more data and assessing potentially interfering signals, they could become useful proxies for palaeoseasonality.

Quaternary low-temperature serpentinization and carbonation in the New Caledonia ophiolite

The low-temperature alteration (< 150 °C) of ophiolites by infiltrated meteoric waters removes atmospheric CO2 through mineral carbonation and is assumed to generate H2 and possibly CH4 according to so-called serpentinization reactions. This overall alteration pattern is primarily constrained by the chemical composition of alkaline springs that are issued in several ophiolites worldwide. Here we report on the fingerprint, as veinlet mineralization, of the reactive percolation of such meteoric waters in the New Caledonia ophiolite (Massif du Sud). The mineralization which resulted from carbonation and serpentinization reactions, is young (< 2 Ma) and formed at a temperature of ca. 95 °C. It is mainly composed of lizardite, dolomite, magnetite ± pyroaurite. Thermochemical simulation of mineral–water equilibria shows that the percolating aqueous fluid was alkaline and H2 bearing. The δ13C of dolomite is exceptionally high, between 7.1 and up to 17.3‰, and is interpreted as evidence of low-temperature methanogenesis. Overall, the percolating fluid had a chemical composition similar to that of the waters issued today in the (hyper)alkaline springs of the Massif du Sud. The studied veinlets are thus interpreted as a sample of the plumbing system that fed an ancient Quaternary alkaline spring in the area.

Vanadium mineralization at Los Chihuidos sediment-hosted Cu–V deposit, Neuquén Basin, Argentina: An approach to vanadium ore forming processes

Vanadium mineralization at Los Chihuidos deposit of the Neuquén Basin is linked to the development of a redox front system related to the inflow of hydrocarbons into the red sandstone of the Huincul Formation. Interaction of hydrocarbons with oxidized red beds and connate water generated redox reactions where hematite was dissolved due to iron reduction resulting in the discoloration of the red strata. At the contact between oxidized red sandstone and reduced white sandstone, precipitation of specific mineral phases resulted in the V ore with minor amounts of Cu. With the implementation of the redox interface, abundant V-montmorillonite and V-hematite precipitated at the more oxidizing conditions and Cu-V-corrensite-type at the more reducing conditions of the redox front. As the redox front advanced with fluids constantly migrating into the reservoir, more reducing conditions were stablished, promoting chloritization and minor illitization with V-Cu incorporation and continuous upgrading of the ore. Main ore mineralogy consists of clay minerals including V-bearing montmorillonite, Cu-V-corrensite-type, V-di-trioctahedral chlorite and Cu-tri-trioctahedral chlorite with minor V-illite–smectite mixed-layer minerals and associated secondary V-hematite. Chloritization over illitization was favored due to high amounts of Fe and Mg in detrital clasts and in connate fluids and by low K availability related to low amounts of detrital K-feldspar. The spatial transition of V and /or Cu bearing clay minerals observed through the mineralized redox front at Los Chihuidos deposit (kaolinite → smectite → illite/smectite → corrensite-type → di- trioctahedral -chlorite → tri- trioctahedral -chlorite) and the related variation of V–Cu concentrations in bulk rock are indicative of increasing pH and decreasing Eh of resident solutions from red to white sandstones during the hypogene mineralization process. Late influx of Cu-rich oxidized basinal brines precipitated main copper ore with Cu-sulfides in the white sandstone up to the contact with the redox front in contact with hydrocarbons. During uplift and exhumation, percolation of meteoric water promoted remobilization of V and Cu and the precipitation of oxidized V–Cu ore.

Climatic, depositional and environmental controls on early carbonate cementation in fluvial and shallow marine sandstones

Sandstones with carbonate cements are found in a variety of depositional settings (e.g. fluvial, lacustrine, deltaic, shallow marine) with abundances ranging from just a few volume percent to pervasive pore-filling cements and are of major interest due to their impact on reservoir quality. Despite the widespread occurrence of such cements, predictive models for eogenetic carbonate cementation have yet to be developed. Hence, investigations on the controls and distribution of early carbonate precipitation are necessary to improve the accuracy of predictions of the nature and distribution of diagenetic alterations. We conducted a petrological and petrophysical analysis of early near-surface carbonate cementation in siliciclastic and mixed siliciclastic-carbonate sandstones from fluvial and shallow marine environments to reconstruct eogenetic processes and their associated controls. Furthermore, sediment burial scenarios up to a loading of 50 MPa were simulated with the reservoir quality prediction software Touchstone to evaluate the impact of carbonate cements on the compaction behaviour of the rocks. Results highlight the importance of climate, depositional environment and detrital composition and texture in regards to the precipitation processes of near-surfaces carbonate cements and burial development. Our data shows that the presence and distribution of early carbonate cements reflects a complex interaction of several parameters, such as the composition and texture of detrital material in the source area, the availability and infiltration of meteoric or marine waters and the presence of precursor carbonate during deposition. Burial simulations demonstrate the strengthening effect of early carbonate cementation and its influence on the development of intergranular volume and porosity during burial with up to five times less porosity loss due to compaction than without near-surface cementation.

Hydrothermal Systems Characterized by Crustal Thermally‐dominated Structures of Southeastern China

AbstractSoutheastern China (SE China) is located in the Pacific tectonic domain and has experienced a series of tectonomagmatic events induced by the subduction of the Paleo‐Pacific Plate since the late Mesozoic. The subduction formed a series of NE‐NNE oriented faults under a NW–SE regional stress field, along which a number of thermal springs occur. Previous studies have focused on the genesis mechanism of specific geothermal fields in SE China, but the general characteristics of hydrothermal systems in SE China remains unclear. In this study, we investigate the correlation between geothermal activity, hydrochemical type and regional faults by studying the distribution of hydrothermal activity and geochemical properties of typical hydrothermal systems in SE China. The hydrothermal systems in SE China have a crustal thermally‐dominated structural origin unique to the specific geological and tectonic conditions of the Eurasian Plate margin. The upwelling of the asthenosphere and the widespread granitoids with high radiogenic heat production in SE China provide major heat sources for regional geothermal anomalies. The NE‐oriented crustal thermally‐dominated faults are critical for the formation of geothermal anomalies and NW‐oriented extensional faults have created favorable conditions for meteoric water infiltration, transportation and the formation of thermal springs.

Interdisciplinary Research on Medieval Fresco Subjected to Degradation Processes in the Corbii de Piatră Cave Church.

This paper presents research on the degradation processes of the fresco painting in the cave church of Corbii de Piatră Hermitage under the influence of meteoric infiltration water and environmental factors. The medieval fresco dates from the end of the 13th century and the beginning of the 14th century, being painted on a sandstone wall. The infiltration of meteoric water through this wall, the temperature variations, the environment and the repeated wetting/drying processes determined the degradation of the fresco, resulting in its detachment from large surfaces. This research established correlations between the processes that take place, the structural transformations, the changes in composition and the adhesion of the fresco to the sandstone wall. The results have been made available to conservation and restoration specialists, in order to choose appropriate materials and technologies. This paper presents findings regarding the pictorial material and introduces new analysis techniques in research on the degradation processes of the fresco painting in the cave church of Corbii de Piatră Hermitage under the influence of meteoric infiltration water and environmental factors.

40Ar-39Ar dating, fluid inclusion, and isotopic constraints on the timing, fluid evolution, and deposition of the polymetallic Nuocang Pb–Zn deposit in the western Nyainqêntanglha belt

The Nyainqêntanglha polymetallic belt (NPB) is western China's foremost skarn Pb–Zn metallogenic belt. Significant progress has been made in determining these ore deposits' age and origin. However, the precipitation mechanisms and mineralization controls for these deposits remain unresolved. 40Ar/39Ar dating, fluid inclusion (FI), and H-O-S-Pb isotopic data are presented for the Nuocang deposit, a newly discovered polymetallic Pb-Zn skarn deposit in the western NPB, with the goal to trace age and, especially, the major fluid processes associated with hydrothermal evolution leading to the precipitation of ore. The muscovite yields an 40Ar-39Ar plateau age of 59.68 ± 0.60 Ma, which closely resembles typical skarn deposits within the NPB, indicating that it formed during the main collisional stage of the India–Eurasia continent. In the Nuocang base-metal skarn deposit, three ore-related stages can be discerned and subdivided: 1) the pre-ore stage, containing the prograde and early retrograde metasomatic skarn minerals, 2) the syn-ore stage, including the late retrograde metasomatic minerals and sulfides, and 3) the post-ore stage of quartz, calcite, and chlorite alteration. Correspondingly, three types of FI (L, V, and S type) have been identified. The ore-forming fluids evolved from moderate to high temperature between 340 and 440 °C primarily, but up to 571 °C, and moderate to high salinity (concentrated ∼8–18 wt% NaCl-equiv., but up to 48.1 wt% NaCl equiv.) in the pre-ore stage. During the syn-ore stage, the fluids were at low to moderate temperature (between 200 and 320 °C) and low salinity (∼2 to 12 wt% NaCl-equiv.) and developed in low temperature (∼120–200 °C) and low salinity (∼2–8 wt% NaCl equiv.) in the post-ore stage. The calculated δDH2O values of the transparent minerals were −180 to −106 ‰ during the pre-ore stage, −141 to −59 ‰ during the syn-ore stage, and −152 to −105 ‰ during the post-ore stage. The δ18OH2O values were −1.2 to 3.8 ‰ during the pre-ore stage, −4.7 to −2.3 ‰ during the syn-ore stage, and −10.9 to −5.0 ‰ during the post-ore stage, respectively.Based on these results, the magmatic fluids appeared to have gradually evolved into meteoric. Meteoric water is believed to play a significant role in metal deposition within magmatic-hydrothermal systems. Locally, boiling is also considered another key mechanism for ore precipitation. The S-Pb isotope values of the sulfide metals indicate that the metallogenic materials were predominantly derived from an upper crustal source mixing with minor amounts of mantle–derived components. This study suggests that the fluid mixing is related to geostatic pressure variations and infiltration of meteoric waters into the hydrothermal system and are key mechanisms triggering Pb-Zn ore deposition in the NPB.

A study on the effects of fault architecture on fluid circulation in the Gediz Graben by the finite volume method

It is widely recognized that in geothermal fields, meteoric water infiltrates deep into the subsurface of the earth and then travels through cracks and fractures, returning to the surface as it becomes heated. The patterns of fluid flow are primarily determined by the interaction between forces driven by gravity and pressure gradients. The ultimate forms of fluid flow patterns are primarily determined by the anisotropies of permeability associated with fault zones. In this study, a series of numerical simulations utilizing the finite volume approach were conducted to investigate the effects of fault zone architecture on fluid flow patterns and temperature distributions. Four distinct types of fault zone architecture were created in the simulations, including localized barrier, combined conduit-barrier, localized conduit, and distributed conduit. The results revealed that fault zone architecture has only a minor effect on fluid flow velocities and temperature distributions, except in cases along faults with very high permeabilities. The simulations suggest that this type of 2-D numerical modeling can be easily applied and utilized in other faulted geothermal systems.

The Characterization of a Fragment of a Medieval Fresco from Corbii de Piatră Cave Church

The fresco of the Corbii de Piatră Cave Church, dating from the end of the 13th century and the beginning of the 14th century, is applied to the sandstone wall. The degradation of the fresco on large surfaces, with many areas of detachment, has been determined by the infiltration of meteoric water through the sandstone wall on which it is applied, as well as temperature variations, and repeated wetting/drying processes. However, there are small portions of fresco that show good adhesion to the wall. The present research, aimed at providing scientific data to restorers and historians, involves the advanced characterization of a fragment of fresco with good adhesion to the wall and is being carried out by an interdisciplinary team. The stratigraphy, microstructure, compaction defects, chemical composition, and variation of chemical composition in the fresco from the pictorial surface to the mortar-sandstone interface were determined. Correlations were established between degradation processes and wall adhesion.

Environmental controls on the hydrogen isotopic composition of volcanic glass from the Southern Afar rift, eastern Ethiopia

Hydrogen stable isotope values of hydrated volcanic glass as a proxy for the isotopic composition of past meteoric waters provide an opportunity for reconstructing past climates. Here we present new hydrogen stable isotope values from 63 individual tuffs from the Afar region in the lower Awash Valley of eastern Ethiopia. The hydrogen isotopic results from volcanic glass spanning the last 6.4 Ma show a wide distribution with values ranging between −89 and − 32 ‰ (VSMOW). The variability is consistent with the observed paleo-depositional setting (i.e., lower values for fluvial settings while higher values are recorded in lacustrine settings). The reconstructed hydrogen isotopic values of parent waters are considerably lower than those of modern meteoric waters, suggesting a bias toward lower values during the hydration of volcanic glass.Reconstructed hydrogen stable isotope values of water derived from volcanic glass differ from other proxies of regional climate in northeast Africa, pointing to the controls of local meteoric waters on the hydrogen isotopic composition of volcanic glass. There is agreement between the reconstructed isotopic composition of parent waters and the lowest hydrogen isotopic values of modern precipitation in the Awash catchment that correspond to periods of large rainfall. This correspondence probably indicates that volcanic glass is preferentially hydrated during the wettest seasons. To test this idea, we compared the isotopic results from volcanic glass with the reconstructed isotopic composition of surface waters from soil carbonates deposited during the Pliocene and Pleistocene in the lower Awash Valley. The comparison reveals a considerable difference between proxies, with volcanic glass recording lower isotopic values than soil carbonates. Evaporative isotopic enrichment of water in shallow (<1 m) soil profiles probably accounts for the elevated values in soil carbonates. In contrast, the presence of smectite-rich vertisols above volcanic deposits appears to retard infiltration of meteoric waters deep into the subsurface. During rainfall events, vertisols swell and prevent all but the largest rainfall events from penetrating deep (>1 m) into the profiles and promoting the hydration of volcanic glass that display systematically lower isotopic values of meteoric waters than the mean annual rainfall.

Influence of Relative Sea-Level Rise, Meteoric Water Infiltration and Rock Weathering on Giant Volcanic Landslides

Recent studies have shown that giant landslides correlate with climatic variations. However, the precise processes involved in this phenomenon need to be better defined. This study investigates the causes of giant landslides using a modeling approach. Here, I show that the effect of meteoric water infiltration could be distinguished from that of the sea level rise in triggering paleo-landslides. It is possible to identify the cause of coastal paleo-landslides based on the age of occurrence and comparison with climatic signals when glacial maxima are wetter than during interglacial periods, as in Polynesia and East Equatorial Africa, but not in other cases (Caribbean, Indonesia). The role of pore-pressure variations and sea water loading variations is discussed. The interaction between the relative sea level rise, pre-existing relief and deep weak structure due to the presence of highly weathered lavas may trigger the conditions for a large landslide. Highly weathered lavas have very low friction angles in volcanic islands. When volcanoes are still active, pressure fluctuations in the magma chamber caused by sea level lowering are expected to play a significant role in the destabilization of the relief. Competing processes in real cases make it difficult to distinguish between these processes.