Breaking through the idea limitation of traditional single-scale and single-function sensors, a multi-scale and multi-function Janus metastructure (JMS) is proposed in this article, which is constructed by the specific methods to break its parity. Using the change of transmission spectrum, JMS can realize multi-physical quantities detection with different sensing performances, when electromagnetic waves propagate on positive and negative scales respectively. For selective gas detection, JMS can conveniently detect 0–3.5 % methane concentrations with sensitivity (S) of 22.932 THz/RIU and 0–3 % hydrogen concentrations with S of 43.494 THz/RIU, avoiding the problem of complex and dangerous external operation conditions required for previous gas sensors. Based on the electro-optical effect of nematic liquid crystal, JMS can realize wide-range electric field direction (EFD) sensing of 10°–80° and 100°–170° by taking the advantages of multi-scale detection, which is wider than existing 0°–90° EFD sensors. Because nematic liquid crystal is thermotropic, JMS can also achieve accurate temperature detection of 283.15–318.15 K. Finally, through comparison, it is proved that JMS proposed has the potential of multi-scenario applications, and meets the urgent demand for excellent performance sensors in the fields of dangerous gas transportation, atmospheric EFD detection and industrial manufacturing temperature control.